This study investigated the use of microbial analysis as a bioremediation option for remediating petroleum sludge, which is part of the waste stream generated in the petroleum industry. The aim is to reduce environmen...This study investigated the use of microbial analysis as a bioremediation option for remediating petroleum sludge, which is part of the waste stream generated in the petroleum industry. The aim is to reduce environmental burden caused by the discharge of untreated sludge. Sludge sample was cultured in other to isolate microorganisms for the sludge treatment. The selected strain of the organisms after screening were Aspergillus flavus, Aspergillus niger, Verticillus sp, Penicillum sp, and Microsporium audouinii. Bioreactors (labeled A, B, C, D and O) were designed for the treatment of petroleum sludge. These reactors contain 2.0 × 10<sup>-2</sup> m<sup>3</sup> of the diluted sludge samples and the isolated organisms for the treatment process. On a weekly basis, the control reactors received 1.5 × 10<sup>-3</sup> m<sup>3</sup> of fresh and saline water respectively. After 12 weeks of treatment, sludge physicochemical characteristics showed distinct variations. From the result, reactor D was the best in terms of remediating the sludge as compared to other reactors. Friedman non-parametric test was performed to check if the weeks of treatment affected the reduction of the total hydrocarbon content (THC) in the five reactors and also checked for significant differences in the THC after treatments. The drop in the THC of the treated sludge ranged from 56.0% to 67.3%. These results showed the possibility of enhanced biodegradation of petroleum sludge by hydrocarbon utilizing microorganisms (fungi).展开更多
This study investigated the effects of gaseous emissions from crude storage tank and gas flaring on air and rainwater quality in Bonny Industrial Island. Ambient air quality parameters, rainwater and weather parameter...This study investigated the effects of gaseous emissions from crude storage tank and gas flaring on air and rainwater quality in Bonny Industrial Island. Ambient air quality parameters, rainwater and weather parameters were collected at 60 m, 80 m, 100 m, 200 m and control plot for 4 weeks at the Bonny. Rainwater parameters were investigated using standard laboratory tests. Data analyses were done using Analysis of variance, pairwise t-test and Pearson’s correlation statistical tools. Results show that emission rates, volatile organic compound (VOC) noise and flare temperature decreased with increasing distance from flare points and crude oil storage tanks. Findings further revealed the emission rates varied significantly with distance away from the gas flaring point (F = 6.196;p = 0.004). The mean concentration of pollutants between gas flare site and crude oil storage tank showed that CO (0.02 ± 0.001 - 0.002 ±0.001), SPM (0.011 ± 0.001 - 0.01 ± 0.001), VOC (0.005 ± 0.001 - 0.01 ± 0.001) and NO<sub>2</sub> (0.04 ± 0.001 - 0.005 ± 0.000) had significant variations (p > 0.05) with CO, O<sub>3</sub> and NO<sub>2</sub> having higher concentrations at the gas flare site while SPM, and VOC were higher around the crude oil storage tank site. Wind turbulence was higher around the gas flaring point (4.93 TKE) than the crude oil storage tank (4.55 TKE). Similarly, there was significant variation in the sun radiation, precipitation, and wind speed caused by gas flaring (1582.25 w/m<sup>2</sup>, 436.25 mm, 0.53 m/s) and crude oil storage tank (1536.25 w/m<sup>2</sup>, 3.91.41 mm, 0.51 m/s). There were also significant variations in flared temperature (F = 22.144;p = 0.001);NO<sub>2</sub> (F = 8.250;p = 0.001), CO (F = 6.000;p = 0.004) and VOC (F = 5.574;p = 0.006) with distance from the gas flaring point. The variation in the rainwater parameters with distance from the gas flaring indicated significant variations in pH (F = 5.594;p = 0.006). The study showed that the concentration of VOC and particulates were high in the supposedly control area which is perceived to be safe for human habitation. Significant variations exist in emission rate (p = 0.015), flare temperature (p = 0.001), NO<sub>2</sub> (p = 0.003), VOC (p = 0.001), noise (p = 0.041), hydrogen carbonate (p = 0.037) and chromium (p = 0.032) between the gas flaring and crude oil storage tank. Regular monitoring is advocated to mitigate the harmful effects of the pollutants.展开更多
以某大型原油储备库为例,采用FDS火灾模拟软件对储罐罐内池火灾进行了数值模拟,得出了火灾发展过程、烟气质量分数分布以及热辐射强度的变化规律,火灾初期烟粒子浓度高的区域分布面积大,且烟粒子分布的面积也比较广,随着反应的进行,烟...以某大型原油储备库为例,采用FDS火灾模拟软件对储罐罐内池火灾进行了数值模拟,得出了火灾发展过程、烟气质量分数分布以及热辐射强度的变化规律,火灾初期烟粒子浓度高的区域分布面积大,且烟粒子分布的面积也比较广,随着反应的进行,烟粒子浓度逐渐降低,火焰逐渐明显,且主要分布在油面附近;热辐射强度随燃烧时间的延长而增强,最高值达35 kW/m2,最终下降并稳定在25 kW/m2左右.最后,对罐区固定消防设施以及移动消防设施的消防能力进行了评估.消防给水系统不能满足储罐罐内池火灾的灭火需求,泡沫灭火系统46 m in可以将火扑灭;满足5 m in原则的1号超特勤消防站不能满足该储罐发生池火灾所需要的消防车数量、移动泡沫炮数量、泡沫混合液量以及冷却水量.展开更多
文摘This study investigated the use of microbial analysis as a bioremediation option for remediating petroleum sludge, which is part of the waste stream generated in the petroleum industry. The aim is to reduce environmental burden caused by the discharge of untreated sludge. Sludge sample was cultured in other to isolate microorganisms for the sludge treatment. The selected strain of the organisms after screening were Aspergillus flavus, Aspergillus niger, Verticillus sp, Penicillum sp, and Microsporium audouinii. Bioreactors (labeled A, B, C, D and O) were designed for the treatment of petroleum sludge. These reactors contain 2.0 × 10<sup>-2</sup> m<sup>3</sup> of the diluted sludge samples and the isolated organisms for the treatment process. On a weekly basis, the control reactors received 1.5 × 10<sup>-3</sup> m<sup>3</sup> of fresh and saline water respectively. After 12 weeks of treatment, sludge physicochemical characteristics showed distinct variations. From the result, reactor D was the best in terms of remediating the sludge as compared to other reactors. Friedman non-parametric test was performed to check if the weeks of treatment affected the reduction of the total hydrocarbon content (THC) in the five reactors and also checked for significant differences in the THC after treatments. The drop in the THC of the treated sludge ranged from 56.0% to 67.3%. These results showed the possibility of enhanced biodegradation of petroleum sludge by hydrocarbon utilizing microorganisms (fungi).
文摘This study investigated the effects of gaseous emissions from crude storage tank and gas flaring on air and rainwater quality in Bonny Industrial Island. Ambient air quality parameters, rainwater and weather parameters were collected at 60 m, 80 m, 100 m, 200 m and control plot for 4 weeks at the Bonny. Rainwater parameters were investigated using standard laboratory tests. Data analyses were done using Analysis of variance, pairwise t-test and Pearson’s correlation statistical tools. Results show that emission rates, volatile organic compound (VOC) noise and flare temperature decreased with increasing distance from flare points and crude oil storage tanks. Findings further revealed the emission rates varied significantly with distance away from the gas flaring point (F = 6.196;p = 0.004). The mean concentration of pollutants between gas flare site and crude oil storage tank showed that CO (0.02 ± 0.001 - 0.002 ±0.001), SPM (0.011 ± 0.001 - 0.01 ± 0.001), VOC (0.005 ± 0.001 - 0.01 ± 0.001) and NO<sub>2</sub> (0.04 ± 0.001 - 0.005 ± 0.000) had significant variations (p > 0.05) with CO, O<sub>3</sub> and NO<sub>2</sub> having higher concentrations at the gas flare site while SPM, and VOC were higher around the crude oil storage tank site. Wind turbulence was higher around the gas flaring point (4.93 TKE) than the crude oil storage tank (4.55 TKE). Similarly, there was significant variation in the sun radiation, precipitation, and wind speed caused by gas flaring (1582.25 w/m<sup>2</sup>, 436.25 mm, 0.53 m/s) and crude oil storage tank (1536.25 w/m<sup>2</sup>, 3.91.41 mm, 0.51 m/s). There were also significant variations in flared temperature (F = 22.144;p = 0.001);NO<sub>2</sub> (F = 8.250;p = 0.001), CO (F = 6.000;p = 0.004) and VOC (F = 5.574;p = 0.006) with distance from the gas flaring point. The variation in the rainwater parameters with distance from the gas flaring indicated significant variations in pH (F = 5.594;p = 0.006). The study showed that the concentration of VOC and particulates were high in the supposedly control area which is perceived to be safe for human habitation. Significant variations exist in emission rate (p = 0.015), flare temperature (p = 0.001), NO<sub>2</sub> (p = 0.003), VOC (p = 0.001), noise (p = 0.041), hydrogen carbonate (p = 0.037) and chromium (p = 0.032) between the gas flaring and crude oil storage tank. Regular monitoring is advocated to mitigate the harmful effects of the pollutants.
文摘以某大型原油储备库为例,采用FDS火灾模拟软件对储罐罐内池火灾进行了数值模拟,得出了火灾发展过程、烟气质量分数分布以及热辐射强度的变化规律,火灾初期烟粒子浓度高的区域分布面积大,且烟粒子分布的面积也比较广,随着反应的进行,烟粒子浓度逐渐降低,火焰逐渐明显,且主要分布在油面附近;热辐射强度随燃烧时间的延长而增强,最高值达35 kW/m2,最终下降并稳定在25 kW/m2左右.最后,对罐区固定消防设施以及移动消防设施的消防能力进行了评估.消防给水系统不能满足储罐罐内池火灾的灭火需求,泡沫灭火系统46 m in可以将火扑灭;满足5 m in原则的1号超特勤消防站不能满足该储罐发生池火灾所需要的消防车数量、移动泡沫炮数量、泡沫混合液量以及冷却水量.
