A new cyano-bridged GadoliniumⅢ-IronⅢ complex {[Gd(DMF)3(DMSO)(H2O)3](250 78(3) nm, c=1.413 03(1) nm, 穋m-3, Z=2, Mr=756.72, F(000)=760, Ⅲ) and the approxi-mately oriented octahedrally sixfold-coordinated Fe(Ⅲ) ar...A new cyano-bridged GadoliniumⅢ-IronⅢ complex {[Gd(DMF)3(DMSO)(H2O)3](250 78(3) nm, c=1.413 03(1) nm, 穋m-3, Z=2, Mr=756.72, F(000)=760, Ⅲ) and the approxi-mately oriented octahedrally sixfold-coordinated Fe(Ⅲ) are linked by a cyano-bridge group to construct a dinuclear compound. The {[Gd(DMF)3(DMSO)(H2O)3](Ⅲ)-Fe(Ⅲ) interaction is antiferromagnetic. CCDC: 223430.展开更多
文摘A new cyano-bridged GadoliniumⅢ-IronⅢ complex {[Gd(DMF)3(DMSO)(H2O)3](250 78(3) nm, c=1.413 03(1) nm, 穋m-3, Z=2, Mr=756.72, F(000)=760, Ⅲ) and the approxi-mately oriented octahedrally sixfold-coordinated Fe(Ⅲ) are linked by a cyano-bridge group to construct a dinuclear compound. The {[Gd(DMF)3(DMSO)(H2O)3](Ⅲ)-Fe(Ⅲ) interaction is antiferromagnetic. CCDC: 223430.
