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Hydrothermal Synthesis and Structure of [(PbCl_2)(μ-Pyz)_(1/2)]_n (Pyz = Pyrazine) 被引量:1
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作者 LIAO Qiu-Xia ZHANG Jian QIN Ye-Yan YAO Yuan-Gen 《Chinese Journal of Structural Chemistry》 SCIE CAS CSCD 北大核心 2006年第7期789-792,共4页
A novel 2-D lead-containing hybrid compound, [(PbCl2)(μ-Pyz)1/2], (Pyz = pyrazine) 1, has been synthesized by the hydrothermal assembly of pyrazine with lead chloride. Elemental analysis and X-ray crystal struc... A novel 2-D lead-containing hybrid compound, [(PbCl2)(μ-Pyz)1/2], (Pyz = pyrazine) 1, has been synthesized by the hydrothermal assembly of pyrazine with lead chloride. Elemental analysis and X-ray crystal structure analyses were carded out for the structural determination and characterization of the title compound. Compound 1 crystallizes in orthorhombic, space group lbam, with a = 19.5558(18), b = 7.1939(6), c = 7.5449(6) A, V = 1061.44(16) .A^3, C2H2Cl2NPb, Mr= 318.14, Z = 8, Dc= 3.982 g/cm^3, μ = 32.63 mm^-1, F(000) = 1096.0, R = 0.0368 and wR = 0.0901 for 623 observed reflections (I 〉 2σ(I)). 展开更多
关键词 crystal structure lead chloride pyrazine
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Fault-Tolerant Resolvability of Certain Crystal Structures
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作者 Sathish Krishnan Bharati Rajan 《Applied Mathematics》 2016年第7期599-604,共6页
An ordered set W of vertices of a graph G is called a resolving set, if all the vertices of G are uniquely determined by the vector of distances to the vertices in W. The metric dimension of G is the minimum cardinali... An ordered set W of vertices of a graph G is called a resolving set, if all the vertices of G are uniquely determined by the vector of distances to the vertices in W. The metric dimension of G is the minimum cardinality of a resolving set of G. A resolving set W for G is fault-tolerant if W\{v} is also a resolving set, for each v in W, and the fault-tolerant metric dimension of G is the minimum cardinality of such a set. In this paper we determine the metric dimension and fault-tolerant metric dimension problems for the graphs of certain crystal structures. 展开更多
关键词 Resolving Set Metric Dimension Fault-Tolerant metric Dimension crystal structures Bismuth Tri-Iodide lead chloride Quartz
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CuCl·C_4H_4N_2配位聚合物的水热合成、表征及晶体结构研究
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作者 陈淑卿 林丞 章文贡 《福建师范大学学报(自然科学版)》 CAS CSCD 北大核心 2007年第6期72-76,共5页
采用水热法合成了CuCl.C4H4N2配位聚合物,以X-射线衍射分析晶体结构,结果表明该配位聚合物为单斜晶系,空间群P2/c,a=0.381 46(10)nm,b=0.635 43(14)nm,c=1.148 8(3)nm,α=90.00(°),β=96.05(2)(°),γ=90.00(°),V=0.276 9... 采用水热法合成了CuCl.C4H4N2配位聚合物,以X-射线衍射分析晶体结构,结果表明该配位聚合物为单斜晶系,空间群P2/c,a=0.381 46(10)nm,b=0.635 43(14)nm,c=1.148 8(3)nm,α=90.00(°),β=96.05(2)(°),γ=90.00(°),V=0.276 91(12)nm3,Z=2.采用紫外-可见光谱、荧光光谱、傅里叶变换红外光谱、元素分析、X光电子能谱分析、热重-示差扫描量热分析和变温磁化强度分析等手段,对其结构进行表征. 展开更多
关键词 氯化亚铜 吡嗪 水热 晶体结构
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