Crystalline porous ionic salts(CPISs) represent a new type of porous materials constructed by electrostatic interaction, however, synthesis of CPISs bearing pre-designed functionality while exhibiting permanent porosi...Crystalline porous ionic salts(CPISs) represent a new type of porous materials constructed by electrostatic interaction, however, synthesis of CPISs bearing pre-designed functionality while exhibiting permanent porosity is still challenging. Herein we report the facile synthesis of a series of CPISs 1-3 built from photocatalytic-active polyoxometalate(POM) clusters and cationic Zr-based capsules, which showed open porous frameworks with BET surface area up to 33 m^(2)/g and high activity and selectivity for photodriven aerobic oxidation of alcohols to aldehydes. Compared with the pristine POM cluster {W10}, 1 can promote the reaction in much higher efficiency due to the concerted catalysis of preinstalled {W10} and Zr-based capsule together with open channels. This work highlights the advantage of CPISs as porous heterogeneous catalysts in organic transformation, and may shed light on the rational design of more delicate CPISs-derived functional materials.展开更多
To improve the proton conduction of crystalline porous organic salts(CPOS-l),H2SO4 and H3PO4 were introduced into the channel to obtain H2SO4@CPOS-1 and H3PO4@CPOS-1.Compared to CPOS-1,the proton conductivities of H2S...To improve the proton conduction of crystalline porous organic salts(CPOS-l),H2SO4 and H3PO4 were introduced into the channel to obtain H2SO4@CPOS-1 and H3PO4@CPOS-1.Compared to CPOS-1,the proton conductivities of H2SO4@CPOS-1 and H3PO4@CPOS-1 increased two orders of magnitude and one order of magnitude at 303 K and 100%RH,respectively.It can be attributed to the increasing concentration of the protons,which disso ciates trom the acids.展开更多
基金supported by National Natural Science Foundation of China (Nos. 92161111, 21901037, 21901038)Shanghai Pujiang Program (No. 19PJ1400200)+1 种基金the Program for Professor of Special Appointment (Eastern Scholar) at Shanghai Institutions of Higher LearningFundamental Research Funds for the Central Universities (No. 2232019G-07)。
文摘Crystalline porous ionic salts(CPISs) represent a new type of porous materials constructed by electrostatic interaction, however, synthesis of CPISs bearing pre-designed functionality while exhibiting permanent porosity is still challenging. Herein we report the facile synthesis of a series of CPISs 1-3 built from photocatalytic-active polyoxometalate(POM) clusters and cationic Zr-based capsules, which showed open porous frameworks with BET surface area up to 33 m^(2)/g and high activity and selectivity for photodriven aerobic oxidation of alcohols to aldehydes. Compared with the pristine POM cluster {W10}, 1 can promote the reaction in much higher efficiency due to the concerted catalysis of preinstalled {W10} and Zr-based capsule together with open channels. This work highlights the advantage of CPISs as porous heterogeneous catalysts in organic transformation, and may shed light on the rational design of more delicate CPISs-derived functional materials.
基金Supported by the National Natural Science Foundation of China(Nos.91956108,21871103)the"111"Project,China(No.BP0719036)the Foundation of the Science and Technology Department of Jilin Province,China(No.20180414009GH).
文摘To improve the proton conduction of crystalline porous organic salts(CPOS-l),H2SO4 and H3PO4 were introduced into the channel to obtain H2SO4@CPOS-1 and H3PO4@CPOS-1.Compared to CPOS-1,the proton conductivities of H2SO4@CPOS-1 and H3PO4@CPOS-1 increased two orders of magnitude and one order of magnitude at 303 K and 100%RH,respectively.It can be attributed to the increasing concentration of the protons,which disso ciates trom the acids.
