A Cupro-8-thioquinoline coordination polymer, [Cu I(C_9H_6NS)]_n, was synthesized by methano-thermal reaction of CuCl and 8,8′-dithiodiquinoline (dtdq) in a molar ratio of 2∶1 at 160 ℃ for 7 d. X-Ray single crysta...A Cupro-8-thioquinoline coordination polymer, [Cu I(C_9H_6NS)]_n, was synthesized by methano-thermal reaction of CuCl and 8,8′-dithiodiquinoline (dtdq) in a molar ratio of 2∶1 at 160 ℃ for 7 d. X-Ray single crystal structure determination revealed the formation of a one-dimensional structure belonging to monoclinic crystal system, space group P2_1/c with cell parameters a=0.8043(1) nm, b=1.8949(3) nm, c=1.1048(1) nm, β=110.109(4)°, V=1.5810(4) nm 3 and Z=4. The crystal was found to be stable up to approximately 300 ℃ by thermal analysis and have an energy gap (E_g) of 2.0 eV exhibited by UV-Vis-NIR reflectance spectrum.展开更多
基金ProjectsupportedbytheNationalNaturalScienceFoundationofChina (No .2 96730 0 4)andtheStateKeyLaboratoryforStructuralChemistryofUnstableandStableSpecies ,China
文摘A Cupro-8-thioquinoline coordination polymer, [Cu I(C_9H_6NS)]_n, was synthesized by methano-thermal reaction of CuCl and 8,8′-dithiodiquinoline (dtdq) in a molar ratio of 2∶1 at 160 ℃ for 7 d. X-Ray single crystal structure determination revealed the formation of a one-dimensional structure belonging to monoclinic crystal system, space group P2_1/c with cell parameters a=0.8043(1) nm, b=1.8949(3) nm, c=1.1048(1) nm, β=110.109(4)°, V=1.5810(4) nm 3 and Z=4. The crystal was found to be stable up to approximately 300 ℃ by thermal analysis and have an energy gap (E_g) of 2.0 eV exhibited by UV-Vis-NIR reflectance spectrum.
