文章介绍用常规粉末冶金方法制备添加纳米 Ti N的 Ti C-10 Ti N-16 Mo-5 Co-5 N i-1C系金属陶瓷刀具 ,通过较系统的切削试验 ,研究了此种金属陶瓷刀具在切削正火态 45 #钢时的切削性能及磨损机理。结果表明 ,金属陶瓷刀具适用于较高速...文章介绍用常规粉末冶金方法制备添加纳米 Ti N的 Ti C-10 Ti N-16 Mo-5 Co-5 N i-1C系金属陶瓷刀具 ,通过较系统的切削试验 ,研究了此种金属陶瓷刀具在切削正火态 45 #钢时的切削性能及磨损机理。结果表明 ,金属陶瓷刀具适用于较高速度下的切削 ,其切削速度 vc、进刀量 f对刀具后刀面磨损量的影响较大 ,而切削深度 ap对刀具的磨损影响较小 ,刀具的失效形式主要是磨损。展开更多
An efficient and high-yielding synthesis of N~2-arylaminopyrimidine-5-carbonitrile derivatives starting from arylamines and 2-methylthio-pyrimidine-5-carbonitriIe derivatives has been developed in the presence of cesi...An efficient and high-yielding synthesis of N~2-arylaminopyrimidine-5-carbonitrile derivatives starting from arylamines and 2-methylthio-pyrimidine-5-carbonitriIe derivatives has been developed in the presence of cesium carbonate as basic reagent.This new protocol showed high chemical tolerance for a range of functional groups,and only the methylthio substituent on C2 of the pyrimidine ring was replaced with arylamine derivatives under the reaction conditions.展开更多
文摘An efficient and high-yielding synthesis of N~2-arylaminopyrimidine-5-carbonitrile derivatives starting from arylamines and 2-methylthio-pyrimidine-5-carbonitriIe derivatives has been developed in the presence of cesium carbonate as basic reagent.This new protocol showed high chemical tolerance for a range of functional groups,and only the methylthio substituent on C2 of the pyrimidine ring was replaced with arylamine derivatives under the reaction conditions.
