Effects of Al and Co doping on the structural stability and high temperature cycling performance of LiNi_(0.5)Mn_(1.5)O_(4) spinel cathode materials

The poor structural stability and capacity retention of the high-voltage spinel-type LiNi_(0.5)Mn_(1.5)O_(4)(LNMO)limits their further application.Herein,Al and Co were doped in LNMO materials for a more stable structure and capacity.The LNMO,LiNi_(0.45)Al_(0.05)Mn_(1.5)O_(4)(LNAMO)and LiNi_(0.45)Co_(0.05)Mn_(1.5)O_(4)(LNCMO)were synthesized by calcination at 900℃ for 8 h,which was called as solid-phase method and applied universally in industry.XRD,FT-IR and CV test results showed the synthesized samples have cation disordering Fd-3m space group structures.Moreover,the incorporation of Al and Co increased the cation disordering of LNMO,thereby increasing the transfer rate of Li+.The SEM results showed that the doped samples performed more regular and ortho-octahedral.The EDS elemental analysis confirmed the uniform distribution of each metal element in the samples.Moreover,the doped samples showed better electrochemical properties than undoped LNMO.The LNAMO and LNCMO samples were discharged with specific capacities of 116.3 mA·h·g^(-1)and 122.8 mA·h·g^(-1)at 1 C charge/discharge rate with good capacity retention of 95.8% and 94.8% after 200 cycles at room temperature,respectively.The capacity fading phenomenon of the doped samples at 50℃ and 1 C rate was significantly improved.Further,cations doping also enhanced the rate performance,especially for the LNCMO,the discharge specific capacity of 117.9 mA·h·g^(-1)can be obtained at a rate of 5 C.

Analysis on the Climatic Characteristics of High and Low Temperature in the East of Hexi Corridor in Recent 50 Years

[Objective] The research aimed to provide the certain theory basis for the accurate forecast and early warning of high and low temperature in the east of Hexi Corridor.[Method] Based on the high(the daily highest temperature ≥35 ℃) and low(the daily lowest temperature ≤-20 ℃) temperature data in five observatories in the east of Hexi Corridor during 1960-2009,the temporal and spatial distribution,intensity,continuity and circulation situation of high and low temperature were analyzed in detail by using the statistical method.[Result] The high temperature weather in the east of Hexi Corridor mainly happened in the edge of northeast desert,and the low temperature mainly happened in the mountain zone where the altitude was higher and the edge of north desert.As the climate became warm,the high temperature days showed the weak increase trend,and the intensity strengthened.The low temperature days showed the obvious decrease trend,and the intensity weakened.The high temperature weather mainly occurred in June,August,and the low temperature mainly occurred in January,February,December.The high and low temperature weather had the durative characteristic.The strong high and low temperature mainly occurred in the durative time of high and low temperature.The high temperature weather appeared in the zone where was controlled and affected by the subtropical high.The low temperature weather appeared in the zone where the strong cold air accumulated and invaded.[Conclusion] The research had the extremely important significance on servicing for the agriculture,preventing and reducing the natural disasters,promoting the local economic development.

Microstructure of Surface Layer Formed at Low Temperature and High Carbon Concentration Carburizing with Rare Earth Element

A suitable carburized microstructure with fine granular dispersed carbides in hypereutectoid zone,ultra fine martensite in matrix and recrystallized austenite to be refined to the grain size of 12～14 has been obtained by a new process,which is a high carbon concentration carburizing with rare earth element at low temperature(860～880℃)in a discontinuous gas carburization furnace.There was not much difference for the microstructure in eutectic zone between this and conventional process.Forming mechanism of granular carbides has been also studied in this paper.

Piezoelectric properties of low loss and high Curie temperature (Bi, La)FeO_3-Pb(Ti, Mn)O_3 ceramics with Mn doping

Piezoelectric ceramics of 0.6(Bi0.9La0.1)FeO3-0.4Pb(Ti1-xMnx)O3 (BLF-PTM) for x=0, 0.01, 0.02, and 0.03 were prepared by sol-gel process combined with a solid-state reaction method. The tan? for BLF-PTM of x=0.01 is just 0.006 at 1 kHz, drastically decreasing by using Mn dopants. The TC increases to 490 ℃ for BLF-PTM of x=0.02. Furthermore, Mn modification effectively enhances the poling state and the piezoelectric properties of BLF-PTM. The kp, Qm, d33, and g33 of 0.34, 403, and 124 pC1·N-1 and 37×10-3 Vm·N-1 are achieved for BLF-PTM of x=0.01. The results indicate that Mn modified BLF-PTM is a competitive high power and high temperature piezoelectric material with excellent piezoelectric properties.

Thin Film Chip Resistors with High Resistance and Low Temperature Coefficient of Resistance

High resistance thin film chip resistors(0603 type) were studied,and the specifications are as follows:1 k? with tolerance about ±0.1% after laser trimming and temperature coefficient of resistance(TCR) less than ±15×10-6/℃.Cr-Si-Ta-Al films were prepared with Ar flow rate and sputtering power fixed at 20 standard-state cubic centimeter per minute(sccm) and 100 W,respectively.The experiment shows that the electrical properties of Cr-SiTa-Al deposition films can meet the specification requirements of 0603 ty...

Structures and Low Temperature Magnetic Anomalies of High Pressure RE_2CuO_4

A series of oxygen-doped RE_2CuO_4 (RE=Nd, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm) was synthesized using high-pressure/oxygen-doped technique. The structures and low temperature magnetic properties were investigated. The XRD patterns indicate that the structures of high oxygen pressure RE_2CuO_4 (only for RE=Sm, Eu) samples are pure T′ phase, but when RE= Gd, Tb, Dy, Ho, Er, Tm, the structures turn to disorder. The magnetic anomalies that occurred at T^30 K are observed in high oxygen pressure RE_2CuO_4. It is found that the transition temperatures of weak ferromagnetic anomalies are nearly independent of the rare-earth components. Thus, the O-doping plays an important role in anomalous magnetic properties of RE_2CuO_(4+δ). The magnetic anomalies in RE_2CuO_4 are considered to be due to ferromagnetic clusters formed in the Cu-O plane after the oxygen doping.

Enhanced Biodegradation of High-Salinity and Low- Temperature Crude-Oil Wastewater by Immobilized Crude-Oil Biodegrading Microbiota

High salt and low temperature are the bottlenecks for the remove of oil contaminants by enriched crude-oil degrading microbiota in Liaohe Estuarine Wetland(LEW),China.To improve the performance of crude-oil removal,microbiota was further immobilized by two methods,i.e.,sodium alginate(SA),and polyvinyl alcohol and sodium alginate(PVA+SA).Results showed that the crude oil was effectively removed by the enrichment with an average degrading ratio of 19.42-31.45 mg(L d)^(−1).The optimal inoculum size for the n-alkanes removal was 10%and 99.89%.Some members of genera Acinetobacter,Actinophytocola,Aquabac-terium,Dysgonomonas,Frigidibacter,Sphingobium,Serpens,and Pseudomonas dominated in crude-oil degrading microflora.Though the removal efficiency was lower than free bacteria when the temperature was 15℃,SA and PVA+SA immobilization im-proved the resistance to salinity.The composite crude-oil degrading microbiota in this study demonstrated a perspective potential for crude oil removal from surface water under high salinity and low temperature conditions.

Low-temperature performance and high-rate discharge capability of AB_5-type non-stoichiometric hydrogen storage alloy

Low-temperature performance and high-rate discharge capability of AB5-type non-stoichiometric hydrogen storage are studied. X-ray diffraction(XRD),pressure-composition-temperature(PCT) curves and electrochemical impedance spectroscopy(EIS) are applied to characterize the electrochemical properties of ABx(x=4.8,4.9,5.0,5.1,5.2) alloys. The results show that the non-stoichiometric alloys exhibit better electrochemical properties compared with that of the AB5 alloy.

Study on Carburizing Kinetics of Low-carbon Steel at High-temperature and Short-term

In this paper, the carburizing kinetics of low-carbon steel at high-temperature and short-term in liquid cast-iron were studied by metallographic microscope, chemical analysis and so on, and the microstructure of carburized layer was also analyzed. The results show that the carburizing rate of low-carbon steel at high-temperature and short-term is so fast, and the microstructure of carburized layer possess higher carbon content, and cementite, pearlite and ferrite exist in carburized layer structure simultaneously. Besides, the kinetic equations of permeating layer forming have been presented, and the carburizing mechanism was preliminary discussed also.

Study on Temperature Disaster Indicators of Passion Fruit in Southwest Fujian, China

In China, meteorological forecasting relies on meteorological data obtained from regional and national stations. However, there were discrepancies between the data collected from the meteorological station at the passion fruit growing base and the data from regional and national stations. Consequently, the high and low temperature disaster indicators determined by the meteorological station at the passion fruit growing base cannot be applied to meteorological forecasting. To address this issue and facilitate the monitoring and early warning of high and low temperature disasters in passion fruit cultivation in Fujian, China, we used multi-source hourly temperature data (including the data from meteorological observation stations in passion fruit growing bases, the nearest regional stations, and national surface conventional meteorological observation stations) in three cities in southwestern Fujian (Longyan, Sanming, and Zhangzhou) spanning the years 2020 to 2022. By employing comprehensive statistical analysis methods (0.5 interval division and Cumulative frequency), we identified that passion fruit in southwestern Fujian was susceptible to high temperature disasters during the blooming-fruiting period, as well as low temperature disasters during the sprouting period. Consequently, we developed high and low temperature disaster indicators based on data from regional and national stations for different phenological periods of passion fruit in this region.

Development and application of multi-field coupled high-pressure triaxial apparatus for soil

The increasing severity of ground subsidence,ground fissure and other disasters caused by the excessive exploitation of deep underground resources has highlighted the pressing need for effective management.A significant contributing factor to the challenges faced is the inadequacy of existing soil mechanics experimental instruments in providing effective indicators,creating a bottleneck in comprehensively understanding the mechanisms of land subsidence.It is urgent to develop a multi-field and multi-functional soil mechanics experimental system to address this issue.Based soil mechanics theories,the existing manufacturing capabilities of triaxial apparatus and the practical demands of the test system,a set of multi-field coupled high-pressure triaxial system is developed tailored for testing deep soils(at depths of approximately 3000 m)and soft rock.This system incorporates specialized design elements such as high-pressure chamber and horizontal deformation testing devices.In addition to the conventional triaxial tester functions,its distinctive feature encompass a horizontal deformation tracking measuring device,a water release testing device and temperature control device for the sample.This ensemble facilitates testing of horizontal and vertical deformation water release and other parameters of samples under a specified stress conditions,at constant or varying temperature ranging from-40℃–90℃.The accuracy of the tested parameters meets the requirements of relevant current specifications.The test system not only provides scientifically robust data for revealing the deformation and failure mechanism of soil subjected to extreme temperature,but also offers critical data support for major engineering projects,deep exploration and mitigation efforts related to soil deformation-induced disaster.

Effect of microstructure on the low temperature toughness of high strength pipeline steels

Microstructure observations and drop-weight tear test were performed to study the microstructures and mechanical properties of two kinds of industrial X70 and two kinds of industrial X80 grade pipeline steels. The effective grain size and the fraction of high angle grain boundaries in the pipeline steels were investigated by electron backscatter diffraction analysis. It is found that the low temperature toughness of the pipeline steels depends not only on the effective grain size, but also on other microstructural factors such as martensite-austenite （MA） constituents and precipitates. The morphology and size of MA constituents significantly affect the mechanical properties of the pipeline steels. Nubby MA constituents with large size have significant negative effects on the toughness, while smaller granular MA constituents have less harmful effects. Similarly, larger Ti-rich nitrides with sharp corners have a strongly negative effect on the toughness, while fine, spherical Nb-rich carbides have a less deleterious effect. The low temperature toughness of the steels is independent of the fraction of high angle grain boundaries.

Large-Scale Circulation Features Typical of Wintertime Extensive and Persistent Low Temperature Events in China

A pair of northeast-southwest-tilted mid-tropospheric ridges and troughs on the continental scale was observed to be the key circulation feature common among wintertime extensive and persistent low tempera-ture events (EPLTE) in China.During the persistence of such anomalous circulations,the split flow over the inner Asian continent and the influent flow over the southeast-ern coast of China correspond well to the expanded and amplified Siberian high with tightened sea level pressure gradients and hence,a strong,cold advection over south-eastern China.The western Pacific subtropical high tends to expand northward during the early stages of most EPLTEs.

ISOCHRONOUS STRESS-STRAIN CURVES OF LOW ALLOY STEEL CROSS-WELD-SPECIMEN AT HIGH TEMPERATURE

In this work, a parametric approach is presented and utilized to determine the creep properties of weldments; then the model of creep strain for cross weld specimen is given. On the basis of the experimental results, attempt has been made to establish equations of the isochronous stress-strain for weld joint that can predict the function of loading and service time in use of the creep data of base metal and weld metal.

Effect of high temperature on the balance between photosynthetic light absorption and energy utilization in Chlorella pyrenoidosa(Chlorophyceae)

Chlorella pyrenoidosa(Chlorophyceae)is widely cultured for production of health food and animal feed.In outdoors,mass cultivation of C.pyrenoidosa often suffers from high temperature.A better understanding of the effects of high temperature on photosynthesis and photoprotection can help optimize the productivity ofC.pyrenoidosa cultures.In this study,we investigated effect of high temperature(35,38,or 41℃)on the balance between photosynthetic light absorption and energy utilization of C.pyrenoidosa.In contrast to 30℃,higher temperature of 35 or 38℃did not inhibit the growth of C.pyrenoidosa.Treatment in 35℃maintained the balance.Moreover,the PSI acceptor side in 38℃was over-reduced and PSII reaction centers were over-excited under strong light,which destroyed the balance and generated active oxygen species(AOS).However,the activated antioxidant enzymes might remove completely the over-production of AOS,thereby protect C.pyrenoidosa cells from photodamage.It shows that this C.pyrenoidosa strain could tolerate as high as 38℃.Furthermore,treatment in 41℃resulted in more lack of the balance than that in 38℃.However,the activities of antioxidant enzymes stopped increasing in 41℃,and were not strong enough to remove the excess AOS.Therefore,treatment in 41℃could decrease the growth ofC.pyrenoidosa.In addition,strong and longtime light exposure would cause serious photodamage to C.pyrenoidosa cells.

Low-temperature and high-voltage planar micro-supercapacitors based on anti-freezing hybrid gel electrolyte

Micro-supercapacitors(MSCs)are considered as highly competitive power sources for miniaturized electronics.However,narrow voltage window and poor anti-freezing properties of MSCs in conventional aqueous electrolytes lead to low energy density and limited environmental adaption.Herein,we report the construction of low-temperature and high-energy-density MSCs based on anti-freezing hybrid gel electrolytes(HGE)through introducing ethylene glycol(EG)additives into aqueous LiCl electrolyte.Since EG partially destroys hydrogen bond network among water molecules,the HGE exhibits maximum electrochemical stability window of 2.7 V and superior anti-freezing features with a glass transition temperature of-62.8℃.Further,the optimized MSCs using activated carbon microelectrodes possess impressive volumetric capacitance of 28.9 F cm^(-3)and energy density of 10.3 mWh cm^(-3)in the voltage of 1.6 V,2.6 times higher than MSCs tested in 1.2 V.Importantly,the MSCs display 68.3%capacitance retention even at-30℃ compared to the value at 25℃,and ultra-long cyclability with 85.7%of initial capacitance after 15,000 times,indicating extraordinary low-temperature performance.Besides,our devices offer favorable flexibility and modular integration.Therefore,this work provides a general strategy of realizing flexible,safe and anti-freezing microscale power sources,holding great potential towards subzero-temperature microelectronic applications.

Effect of low cycle fatigue pre-damage on very high cycle fatigue

Carbon-manganese steel is often applied in components of pipes in nuclear plant. Ultrasonic fatigue tests following low cycle fatigue （LCF） cycles damaged are used to study the strength of very high cycle fatigure （VHCF）. The comparison of test results of simple VHCF and cumulative fatigue （LCF plus VHCF） shows that LCF load influences the following VHCF strength. Continuum damage mechanics model is extended to VHCF region.

Microstructure studies of air-plasma-spray-deposited CoNiCrAlY coatings before and after thermal cyclic loading for high-temperature application

In the present study, bond-coats for thermal barrier coatings were deposited via air plasma spraying（APS） techniques onto Inconel 800 and Hastelloy C-276 alloy substrates. Scanning electron microscopy（SEM）, transmission electron microscopy（TEM）, X-ray diffraction（XRD）, and atomic force microscopy（AFM） were used to investigate the phases and microstructure of the as-sprayed, APS-deposited Co Ni Cr Al Y bond-coatings. The aim of this work was to study the suitability of the bond-coat materials for high temperature applications. Confirmation of nanoscale grains of the γ/γ′-phase was obtained by TEM, high-resolution TEM, and AFM. We concluded that these changes result from the plastic deformation of the bond-coat during the deposition, resulting in Co Ni Cr Al Y bond-coatings with excellent thermal cyclic resistance suitable for use in high-temperature applications. Cyclic oxidative stability was observed to also depend on the underlying metallic alloy substrate.

Advanced high-pressure transport measurement system integrated with low temperature and magnetic field

We briefly introduce a new high-pressure transport measurement system integrated with low temperature and magnetic field that is being established as one of the user experimental stations of the Synergetic Extreme Condition User Facilities in the Huairou District of Beijing, China. To demonstrate the capabilities of the system for condensed matter research, the emergence of some pressure-induced phenomena and physics related to superconductivity found previously is also introduced, and then a perspective for such an advanced high-pressure system is presented.

Effect of Rare Earth Elements on Low Frequency Fatigue of Hot Rolled Steel 60CrMnMo at High Temperature

The effect of rare earth(RE) on low frequency high temperature fatigue strength of hot rolled steel 60CrMnMo was investigated. The results show that by adding a certain amount of RE in steel 60CrMnMo, its serviceable life during low frequency fatigue test at high temperature can be improved.The number of cycles for fracture was increased by 18.5%～28.8%. The number of large inclusion particleswas reduced and the composition of inclusions and their shape were changed as well. The strip distances on fatigue fracture surface were decreased. It is concluded that the optimum amount of RE addtion is about 0.05 wt%～0. 10 wt%.