This paper proposes a low complexity control scheme for voltage control of a dynamic voltage restorer(DVR)in a three-phase system.The control scheme employs the fractional order,proportional-integral-derivative(FOPID)...This paper proposes a low complexity control scheme for voltage control of a dynamic voltage restorer(DVR)in a three-phase system.The control scheme employs the fractional order,proportional-integral-derivative(FOPID)controller to improve on the DVR performance in order to enhance the power quality in terms of the response time,steady-state error and total harmonic distortion(THD).The result obtained was compared with fractional order,proportionalintegral(FOPI),proportional-integral-derivative(PID)and proportional-integral(PI)controllers in order to show the effectiveness of the proposed DVR control scheme.A water cycle optimization algorithm(WCA)was utilized to find the optimal set for all the controller gains.They were used to solve four power quality issues;balanced voltage sag,balanced voltage swell,unbalanced voltage sag,and unbalanced voltage swell.It showed that one set of controller gain obtained from the WCA could solve all the power quality issues while the others in the literature needed an individual set of optimal gain for each power quality problem.To prove the concept,the proposed DVR algorithm was simulated in the MATLAB/Simulink software and the results revealed that the four optimal controllers can compensate for all the power quality problems.A comparative analysis of the results in various aspects of their dynamic response and%THD was discussed and analyzed.It was found that PID controller yields the most rapid performance in terms of average response time while FOPID controller yields the best performance in term of average%steady-state error.FOPI controller was found to provide the lowest THD percentage in the average%THD.FOPID did not differ much in average response from the PID and average%THD from FOPI;however,FOPID provided the most outstanding average steady-state error.According to the CBMA curve,the dynamic responses of all controllers fall in the acceptable power quality area.The total harmonic distortion(THD)of the compensated load voltage from all the controllers were within the 8%limit in accordance to the IEEE std.519-2014.展开更多
High-voltage lithium-ion batteries(HVLIBs) are considered as promising devices of energy storage for electric vehicle, hybrid electric vehicle, and other high-power equipment. HVLIBs require their own platform voltage...High-voltage lithium-ion batteries(HVLIBs) are considered as promising devices of energy storage for electric vehicle, hybrid electric vehicle, and other high-power equipment. HVLIBs require their own platform voltages to be higher than 4.5 V on charge. Lithium nickel manganese spinel LiNi_(0.5)Mn_(1.5)O_4(LNMO) cathode is the most promising candidate among the 5 V cathode materials for HVLIBs due to its flat plateau at 4.7 V. However, the degradation of cyclic performance is very serious when LNMO cathode operates over 4.2 V. In this review, we summarize some methods for enhancing the cycling stability of LNMO cathodes in lithium-ion batteries, including doping, cathode surface coating,electrolyte modifying, and other methods. We also discuss the advantages and disadvantages of different methods.展开更多
Modular multilevel resonant converter is an promising candidate for high voltage applications since it has advantageous features,such as high efficiency,high voltage capability and easy fault-tolerant operation.Howeve...Modular multilevel resonant converter is an promising candidate for high voltage applications since it has advantageous features,such as high efficiency,high voltage capability and easy fault-tolerant operation.However,the inequality of arm inductance in practice will lead to imbalance between the upper and lower arm voltages,which will induce large ripples in the circulating current and a dc bias on the voltage generated by modular circuits.To compensate for the voltage imbalance,effects of arm duty cycle changes on arm voltages are discussed.An arm voltage balancing control method is proposed:adjust arm duty cycle according to arm voltage deviation in every switching cycle.Simulation and experimental results are presented to validate the theoretical analysis and the proposed control method.展开更多
The spinel LiNi_(0.5)Mn_(1.5)O_(4)(LNMO)has been attracted great attention as lithium ion cathode material due to its high voltage and large energy density.However,the practical application of LNMO is still limited by...The spinel LiNi_(0.5)Mn_(1.5)O_(4)(LNMO)has been attracted great attention as lithium ion cathode material due to its high voltage and large energy density.However,the practical application of LNMO is still limited by poor cycling stability.Herein,to improve the cycling stability of spinel LNMO,it was treated with anneal process at 900℃for 2 h after prepared by traditional solid-state method(LNMO-A).LNMO-A sample presented better electrochemical property especially under high rate,with capacity of 91.2 mAhg^(-1) after 1000 cycles under 10 C.Its superior electrochemical property was ascribed to the anneal process,resulting a stable crystal structure,indicated by XRD and Raman results of electrodes after 1000 cycles under 10 C and the longer solid-solution reaction,revealed by in-situ XRD.In addition,the optimized particle size,micro morphology and the larger BET area surface induced by the recrystallization in anneal process also contributes to its superior electrochemical property.What's more,the thin layer,which interacted LNMO-A particles with each other,induced by particles remelting in anneal process is also beneficial for its excellent electrochemical property.This study not only improved the electrochemical properties by anneal process,but also revealed the origins and mechanisms for its improvement.展开更多
This paper presents a new AC chopper voltage conditioner, which can generate high quality sinusoidal waveforms with adjustable amplitudes. The circuit structure, operation principle, and control mode are analyzed in d...This paper presents a new AC chopper voltage conditioner, which can generate high quality sinusoidal waveforms with adjustable amplitudes. The circuit structure, operation principle, and control mode are analyzed in detail, the system essentially consisting of an equal duty cycle modulation AC voltage buck chopper and a voltage polarity change H-bridge, a full-wave rectifier, to perform tightly closed-loop control of the AC chopper voltage condtioner, a digital controller on a new converter model has been developed. The controller has very well dynamic response. To evaluate the new circuit and proposed control scheme, a 5kW conditioner is developed and the experimental results demonstrate that the system has good performances.展开更多
A two-input boost converter with voltage multiplier cell is proposed in this paper. Then a family of two-input converters with and without voltage multiplier cell are derived and their results are compared to achieve ...A two-input boost converter with voltage multiplier cell is proposed in this paper. Then a family of two-input converters with and without voltage multiplier cell are derived and their results are compared to achieve high voltage gain, low duty cycle, and reduced voltage stress. From the analysis of different topologies, a modified two-input converter with two-stage voltage multiplier cell has good operating characteristics. The switch voltage stress and duty cycle of the modified converter is significantly very less than that of the other converter topologies. The modified DC-DC converter with 50% duty cycle achieves a voltage gain of 10 and the results are verified by using MATLAB/Simulink software.展开更多
Control strategy affects directly the working performances of dynamic voltage regulator (DVR). One-cycle control is an effective nonlinear signal modulation control method. In this paper, a new one-cycle control sch...Control strategy affects directly the working performances of dynamic voltage regulator (DVR). One-cycle control is an effective nonlinear signal modulation control method. In this paper, a new one-cycle control scheme for DVR was proposed in single phase supply system. On the basis of principle analysis, the corresponding one-cycle control model for DVR was built up, which is characterized by simple control circuits, good control performance, and high control precision. As an example, a control model for single-phase DVR was simulated by using Matlab/Simulink and SimPowerSystem. The results show that the load voltage could be compensated quickly at the points of supply voltage stepping down and up, and the relative error was less than 4% in the whole voltage sag process. Both theory analysis and simulation results show that the new one-cycle control scheme for DVR is effective.展开更多
The poor structural stability and capacity retention of the high-voltage spinel-type LiNi_(0.5)Mn_(1.5)O_(4)(LNMO)limits their further application.Herein,Al and Co were doped in LNMO materials for a more stable struct...The poor structural stability and capacity retention of the high-voltage spinel-type LiNi_(0.5)Mn_(1.5)O_(4)(LNMO)limits their further application.Herein,Al and Co were doped in LNMO materials for a more stable structure and capacity.The LNMO,LiNi_(0.45)Al_(0.05)Mn_(1.5)O_(4)(LNAMO)and LiNi_(0.45)Co_(0.05)Mn_(1.5)O_(4)(LNCMO)were synthesized by calcination at 900℃ for 8 h,which was called as solid-phase method and applied universally in industry.XRD,FT-IR and CV test results showed the synthesized samples have cation disordering Fd-3m space group structures.Moreover,the incorporation of Al and Co increased the cation disordering of LNMO,thereby increasing the transfer rate of Li+.The SEM results showed that the doped samples performed more regular and ortho-octahedral.The EDS elemental analysis confirmed the uniform distribution of each metal element in the samples.Moreover,the doped samples showed better electrochemical properties than undoped LNMO.The LNAMO and LNCMO samples were discharged with specific capacities of 116.3 mA·h·g^(-1)and 122.8 mA·h·g^(-1)at 1 C charge/discharge rate with good capacity retention of 95.8% and 94.8% after 200 cycles at room temperature,respectively.The capacity fading phenomenon of the doped samples at 50℃ and 1 C rate was significantly improved.Further,cations doping also enhanced the rate performance,especially for the LNCMO,the discharge specific capacity of 117.9 mA·h·g^(-1)can be obtained at a rate of 5 C.展开更多
Distribution generation(DG)technology based on a variety of renewable energy technologies has developed rapidly.A large number of multi-type DG are connected to the distribution network(DN),resulting in a decline in t...Distribution generation(DG)technology based on a variety of renewable energy technologies has developed rapidly.A large number of multi-type DG are connected to the distribution network(DN),resulting in a decline in the stability of DN operation.It is urgent to find a method that can effectively connect multi-energy DG to DN.photovoltaic(PV),wind power generation(WPG),fuel cell(FC),and micro gas turbine(MGT)are considered in this paper.A multi-objective optimization model was established based on the life cycle cost(LCC)of DG,voltage quality,voltage fluctuation,system network loss,power deviation of the tie-line,DG pollution emission index,and meteorological index weight of DN.Multi-objective artificial bee colony algorithm(MOABC)was used to determine the optimal location and capacity of the four kinds of DG access DN,and compared with the other three heuristic algorithms.Simulation tests based on IEEE 33 test node and IEEE 69 test node show that in IEEE 33 test node,the total voltage deviation,voltage fluctuation,and system network loss of DN decreased by 49.67%,7.47%and 48.12%,respectively,compared with that without DG configuration.In the IEEE 69 test node,the total voltage deviation,voltage fluctuation and system network loss of DN in the MOABC configuration scheme decreased by 54.98%,35.93%and 75.17%,respectively,compared with that without DG configuration,indicating that MOABC can reasonably plan the capacity and location of DG.Achieve the maximum trade-off between DG economy and DN operation stability.展开更多
相较于传统车载充电系统,集成型车载充电系统(integrated onboard charger system,IOCS)在成本、功率密度等方面具备显著优势。文中基于六相永磁电驱系统设计了一台IOCS,并研究了模型预测电流控制(model predictive current control,MP...相较于传统车载充电系统,集成型车载充电系统(integrated onboard charger system,IOCS)在成本、功率密度等方面具备显著优势。文中基于六相永磁电驱系统设计了一台IOCS,并研究了模型预测电流控制(model predictive current control,MPCC)算法在该系统并网模式下的应用。首先,分析所提IOCS的电路拓扑并建立数学模型,同时介绍传统MPCC的实施流程。然后,针对传统MPCC计算量大、稳态性能差等不足,提出一种基于占空比优化的MPCC(MPCC based on duty cycle optimization,DCO-MPCC)策略。一方面,减少备选电压矢量数量,降低电流预测环节带来的计算负担;另一方面,提出一种占空比优化技术,改善系统稳态性能。最后,通过实验验证了所提算法的有效性与优越性。实验结果表明,DCO-MPCC策略能够显著提升系统稳态性能并减少算法计算量。充电与车网互动(vehicle to grid,V2G)工况下,网侧电流总谐波畸变(total harmonic distortion,THD)分别降低6.18%与5.92%,算法运行时间减少17.54μs。展开更多
The low-temperature performance of Li-ion batteries(LIBs) has important impacts on their commercial applications. Besides the metallic lithium deposition, which is regarded as one of the main failure mechanisms of the...The low-temperature performance of Li-ion batteries(LIBs) has important impacts on their commercial applications. Besides the metallic lithium deposition, which is regarded as one of the main failure mechanisms of the LIBs at low temperatures, the synergistic effects originating from the cathode, anode, electrolyte, and separators to the batteries are still not clear. Here, the 21700-type cylindrical batteries were evaluated at a wide range of temperatures to investigate the failure mechanism of batteries. Voltage relaxation, and the post-mortem analysis combined with the electrochemical tests, unravel that the capacity degradation of batteries at low temperature is related to the lithium plating at graphite anodes,the formation of unsatisfied solid deposited/decomposed electrolyte mixture phase on the anode, the precipitation of solvent in the electrolytes and the block of separator pores, and the uneven dissolved transition metal-ions from the cathode. We hope this finding may open up a new avenue to alleviate the capacity degradation of advanced LIBs at low temperatures and shed light on the development of outstanding low-temperature LIBs via simultaneous optimization of all the components including electrodes, electrolytes and separators.展开更多
One-cycle-controlled(OCC)inverters are suitable for small single-phase photovoltaic distributed-generator systems because of their simplicity,phase-locked-loop free structure,grid voltage sensor-less operation,and cos...One-cycle-controlled(OCC)inverters are suitable for small single-phase photovoltaic distributed-generator systems because of their simplicity,phase-locked-loop free structure,grid voltage sensor-less operation,and cost-effectiveness.Grid voltage sensor-less control helps reduce cost and increases reliability in operation.However various sensors are used for implementation of a protection mechanism.In this paper,a grid voltage sensorless protection scheme for OCC based single-phase inverter systems is proposed.The estimated value of voltage at point of common coupling(VPCC)is used for protecting the system during over/under voltage conditions of the grid,implementing of voltage ride through conditions,and for disconnecting the grid during islanded conditions.The VPCC is estimated from the measured inverter current,switching pulses,and the measured dc-link voltage using a second-order filter.Simulation and experimental studies are performed to verify the efficacy of the proposed voltage sensor-less protection mechanism triggered using estimated VPCC.展开更多
基金This Research was Financially Supported by Faculty of Engineering,Mahasarakham University(Grant year 2021).
文摘This paper proposes a low complexity control scheme for voltage control of a dynamic voltage restorer(DVR)in a three-phase system.The control scheme employs the fractional order,proportional-integral-derivative(FOPID)controller to improve on the DVR performance in order to enhance the power quality in terms of the response time,steady-state error and total harmonic distortion(THD).The result obtained was compared with fractional order,proportionalintegral(FOPI),proportional-integral-derivative(PID)and proportional-integral(PI)controllers in order to show the effectiveness of the proposed DVR control scheme.A water cycle optimization algorithm(WCA)was utilized to find the optimal set for all the controller gains.They were used to solve four power quality issues;balanced voltage sag,balanced voltage swell,unbalanced voltage sag,and unbalanced voltage swell.It showed that one set of controller gain obtained from the WCA could solve all the power quality issues while the others in the literature needed an individual set of optimal gain for each power quality problem.To prove the concept,the proposed DVR algorithm was simulated in the MATLAB/Simulink software and the results revealed that the four optimal controllers can compensate for all the power quality problems.A comparative analysis of the results in various aspects of their dynamic response and%THD was discussed and analyzed.It was found that PID controller yields the most rapid performance in terms of average response time while FOPID controller yields the best performance in term of average%steady-state error.FOPI controller was found to provide the lowest THD percentage in the average%THD.FOPID did not differ much in average response from the PID and average%THD from FOPI;however,FOPID provided the most outstanding average steady-state error.According to the CBMA curve,the dynamic responses of all controllers fall in the acceptable power quality area.The total harmonic distortion(THD)of the compensated load voltage from all the controllers were within the 8%limit in accordance to the IEEE std.519-2014.
基金supported by the foundation on the Creative Research Team Construction Promotion Project of Beijing Municipal Institutions and Science and Technology Foundation(ykj-2016-00161)partly supported by International Research Promotion Program(IRPR)of Osaka University
文摘High-voltage lithium-ion batteries(HVLIBs) are considered as promising devices of energy storage for electric vehicle, hybrid electric vehicle, and other high-power equipment. HVLIBs require their own platform voltages to be higher than 4.5 V on charge. Lithium nickel manganese spinel LiNi_(0.5)Mn_(1.5)O_4(LNMO) cathode is the most promising candidate among the 5 V cathode materials for HVLIBs due to its flat plateau at 4.7 V. However, the degradation of cyclic performance is very serious when LNMO cathode operates over 4.2 V. In this review, we summarize some methods for enhancing the cycling stability of LNMO cathodes in lithium-ion batteries, including doping, cathode surface coating,electrolyte modifying, and other methods. We also discuss the advantages and disadvantages of different methods.
基金the National Key Research and Development Program of China(No.2016YFB0100603)National Natural Science Foundation of China(No.51877193)。
文摘Modular multilevel resonant converter is an promising candidate for high voltage applications since it has advantageous features,such as high efficiency,high voltage capability and easy fault-tolerant operation.However,the inequality of arm inductance in practice will lead to imbalance between the upper and lower arm voltages,which will induce large ripples in the circulating current and a dc bias on the voltage generated by modular circuits.To compensate for the voltage imbalance,effects of arm duty cycle changes on arm voltages are discussed.An arm voltage balancing control method is proposed:adjust arm duty cycle according to arm voltage deviation in every switching cycle.Simulation and experimental results are presented to validate the theoretical analysis and the proposed control method.
基金Natural Science Foundation of Shandong Province(ZR2018MEM017)。
文摘The spinel LiNi_(0.5)Mn_(1.5)O_(4)(LNMO)has been attracted great attention as lithium ion cathode material due to its high voltage and large energy density.However,the practical application of LNMO is still limited by poor cycling stability.Herein,to improve the cycling stability of spinel LNMO,it was treated with anneal process at 900℃for 2 h after prepared by traditional solid-state method(LNMO-A).LNMO-A sample presented better electrochemical property especially under high rate,with capacity of 91.2 mAhg^(-1) after 1000 cycles under 10 C.Its superior electrochemical property was ascribed to the anneal process,resulting a stable crystal structure,indicated by XRD and Raman results of electrodes after 1000 cycles under 10 C and the longer solid-solution reaction,revealed by in-situ XRD.In addition,the optimized particle size,micro morphology and the larger BET area surface induced by the recrystallization in anneal process also contributes to its superior electrochemical property.What's more,the thin layer,which interacted LNMO-A particles with each other,induced by particles remelting in anneal process is also beneficial for its excellent electrochemical property.This study not only improved the electrochemical properties by anneal process,but also revealed the origins and mechanisms for its improvement.
文摘This paper presents a new AC chopper voltage conditioner, which can generate high quality sinusoidal waveforms with adjustable amplitudes. The circuit structure, operation principle, and control mode are analyzed in detail, the system essentially consisting of an equal duty cycle modulation AC voltage buck chopper and a voltage polarity change H-bridge, a full-wave rectifier, to perform tightly closed-loop control of the AC chopper voltage condtioner, a digital controller on a new converter model has been developed. The controller has very well dynamic response. To evaluate the new circuit and proposed control scheme, a 5kW conditioner is developed and the experimental results demonstrate that the system has good performances.
文摘A two-input boost converter with voltage multiplier cell is proposed in this paper. Then a family of two-input converters with and without voltage multiplier cell are derived and their results are compared to achieve high voltage gain, low duty cycle, and reduced voltage stress. From the analysis of different topologies, a modified two-input converter with two-stage voltage multiplier cell has good operating characteristics. The switch voltage stress and duty cycle of the modified converter is significantly very less than that of the other converter topologies. The modified DC-DC converter with 50% duty cycle achieves a voltage gain of 10 and the results are verified by using MATLAB/Simulink software.
基金The National Science and Technology Sup-port Project (No.2007BAA12B03)
文摘Control strategy affects directly the working performances of dynamic voltage regulator (DVR). One-cycle control is an effective nonlinear signal modulation control method. In this paper, a new one-cycle control scheme for DVR was proposed in single phase supply system. On the basis of principle analysis, the corresponding one-cycle control model for DVR was built up, which is characterized by simple control circuits, good control performance, and high control precision. As an example, a control model for single-phase DVR was simulated by using Matlab/Simulink and SimPowerSystem. The results show that the load voltage could be compensated quickly at the points of supply voltage stepping down and up, and the relative error was less than 4% in the whole voltage sag process. Both theory analysis and simulation results show that the new one-cycle control scheme for DVR is effective.
基金supported by the National Natural Science Foundation of China(52022109 and 51834008)Beijing Municipal Natural Science Foundation(2202047)+1 种基金National Key Research and Development Program of China(2021YFC2901100)Science Foundation of China University of Petroleum,Beijing(2462021QNX2010,2462020YXZZ019,2462020YXZZ016,and 2462022QZDX008)。
文摘The poor structural stability and capacity retention of the high-voltage spinel-type LiNi_(0.5)Mn_(1.5)O_(4)(LNMO)limits their further application.Herein,Al and Co were doped in LNMO materials for a more stable structure and capacity.The LNMO,LiNi_(0.45)Al_(0.05)Mn_(1.5)O_(4)(LNAMO)and LiNi_(0.45)Co_(0.05)Mn_(1.5)O_(4)(LNCMO)were synthesized by calcination at 900℃ for 8 h,which was called as solid-phase method and applied universally in industry.XRD,FT-IR and CV test results showed the synthesized samples have cation disordering Fd-3m space group structures.Moreover,the incorporation of Al and Co increased the cation disordering of LNMO,thereby increasing the transfer rate of Li+.The SEM results showed that the doped samples performed more regular and ortho-octahedral.The EDS elemental analysis confirmed the uniform distribution of each metal element in the samples.Moreover,the doped samples showed better electrochemical properties than undoped LNMO.The LNAMO and LNCMO samples were discharged with specific capacities of 116.3 mA·h·g^(-1)and 122.8 mA·h·g^(-1)at 1 C charge/discharge rate with good capacity retention of 95.8% and 94.8% after 200 cycles at room temperature,respectively.The capacity fading phenomenon of the doped samples at 50℃ and 1 C rate was significantly improved.Further,cations doping also enhanced the rate performance,especially for the LNCMO,the discharge specific capacity of 117.9 mA·h·g^(-1)can be obtained at a rate of 5 C.
文摘Distribution generation(DG)technology based on a variety of renewable energy technologies has developed rapidly.A large number of multi-type DG are connected to the distribution network(DN),resulting in a decline in the stability of DN operation.It is urgent to find a method that can effectively connect multi-energy DG to DN.photovoltaic(PV),wind power generation(WPG),fuel cell(FC),and micro gas turbine(MGT)are considered in this paper.A multi-objective optimization model was established based on the life cycle cost(LCC)of DG,voltage quality,voltage fluctuation,system network loss,power deviation of the tie-line,DG pollution emission index,and meteorological index weight of DN.Multi-objective artificial bee colony algorithm(MOABC)was used to determine the optimal location and capacity of the four kinds of DG access DN,and compared with the other three heuristic algorithms.Simulation tests based on IEEE 33 test node and IEEE 69 test node show that in IEEE 33 test node,the total voltage deviation,voltage fluctuation,and system network loss of DN decreased by 49.67%,7.47%and 48.12%,respectively,compared with that without DG configuration.In the IEEE 69 test node,the total voltage deviation,voltage fluctuation and system network loss of DN in the MOABC configuration scheme decreased by 54.98%,35.93%and 75.17%,respectively,compared with that without DG configuration,indicating that MOABC can reasonably plan the capacity and location of DG.Achieve the maximum trade-off between DG economy and DN operation stability.
文摘相较于传统车载充电系统,集成型车载充电系统(integrated onboard charger system,IOCS)在成本、功率密度等方面具备显著优势。文中基于六相永磁电驱系统设计了一台IOCS,并研究了模型预测电流控制(model predictive current control,MPCC)算法在该系统并网模式下的应用。首先,分析所提IOCS的电路拓扑并建立数学模型,同时介绍传统MPCC的实施流程。然后,针对传统MPCC计算量大、稳态性能差等不足,提出一种基于占空比优化的MPCC(MPCC based on duty cycle optimization,DCO-MPCC)策略。一方面,减少备选电压矢量数量,降低电流预测环节带来的计算负担;另一方面,提出一种占空比优化技术,改善系统稳态性能。最后,通过实验验证了所提算法的有效性与优越性。实验结果表明,DCO-MPCC策略能够显著提升系统稳态性能并减少算法计算量。充电与车网互动(vehicle to grid,V2G)工况下,网侧电流总谐波畸变(total harmonic distortion,THD)分别降低6.18%与5.92%,算法运行时间减少17.54μs。
基金supported by the National Natural Science Foundation of China (U1664255, 21875022, 51802020, U1564206)the National Key R&D Program of China (2016YFB0100301)+2 种基金the Science and Technology Innovation Foundation of Beijing Institute of Technology Chongqing Innovation Center (2020CX5100006)the Young Elite Scientists Sponsorship Program by CAST (2018QNRC001)support from Beijing Institute of Technology Research Fund Program for Young Scholars。
文摘The low-temperature performance of Li-ion batteries(LIBs) has important impacts on their commercial applications. Besides the metallic lithium deposition, which is regarded as one of the main failure mechanisms of the LIBs at low temperatures, the synergistic effects originating from the cathode, anode, electrolyte, and separators to the batteries are still not clear. Here, the 21700-type cylindrical batteries were evaluated at a wide range of temperatures to investigate the failure mechanism of batteries. Voltage relaxation, and the post-mortem analysis combined with the electrochemical tests, unravel that the capacity degradation of batteries at low temperature is related to the lithium plating at graphite anodes,the formation of unsatisfied solid deposited/decomposed electrolyte mixture phase on the anode, the precipitation of solvent in the electrolytes and the block of separator pores, and the uneven dissolved transition metal-ions from the cathode. We hope this finding may open up a new avenue to alleviate the capacity degradation of advanced LIBs at low temperatures and shed light on the development of outstanding low-temperature LIBs via simultaneous optimization of all the components including electrodes, electrolytes and separators.
基金supported by the Science and Engineering Research Board,Department of Science and Technology,Government of India,under Grant ECR/2016/000876.
文摘One-cycle-controlled(OCC)inverters are suitable for small single-phase photovoltaic distributed-generator systems because of their simplicity,phase-locked-loop free structure,grid voltage sensor-less operation,and cost-effectiveness.Grid voltage sensor-less control helps reduce cost and increases reliability in operation.However various sensors are used for implementation of a protection mechanism.In this paper,a grid voltage sensorless protection scheme for OCC based single-phase inverter systems is proposed.The estimated value of voltage at point of common coupling(VPCC)is used for protecting the system during over/under voltage conditions of the grid,implementing of voltage ride through conditions,and for disconnecting the grid during islanded conditions.The VPCC is estimated from the measured inverter current,switching pulses,and the measured dc-link voltage using a second-order filter.Simulation and experimental studies are performed to verify the efficacy of the proposed voltage sensor-less protection mechanism triggered using estimated VPCC.