Characterization of localized corrosion pathways in 2195-T8 Al-Li alloys exposed to acidic solution

The corrosion properties of aluminum-lithium(Al-Li) alloys, which are potential materials used to construct for tanks of liquid rockets or missiles, are essential for safe propellant storage and transport. In order to manifest the corrosion resistance of the 2195 Al-Li alloy in practical propellant tanks filled with N2O4, the alloy was soaked in 30% nitric acid solution, an accelerating corrosion environment, to test its corrosion behavior. Scanning electron microscopy(SEM) and transmission electron microscopy(TEM)were used to characterize microstructure and corrosion morphology of the alloy. Focused ion beam(FIB),combined with SEM, was used to demonstrate localized corrosion features and the propagation of corrosion pathways beneath the alloy surface. It was found that the corrosion network was formed with most intergranular corrosion and sparse intragranular corrosion. Additionally, the distribution and number of intermetallic particles influenced the localized corrosion degree and the direction of corrosion pathways. Aggregated particles made corrosion pathways continuously and caused more severe corrosion. The results from this work were valid and useful to corrosion prevention and protection for storage safety on propellant tanks in N_(2)O_(4).

Influence of deformation on the corrosion behavior of LZ91 Mg-Li alloy

The effect of rolling and forging on the microstructure and corrosion behavior of LZ91 alloy was investigated using an electron probe micro-analyzer,immersion and electrochemical tests.Results showed that the area fraction of theβ-Li phase remained unchanged,and the grain size of theβ-Li phase decreased after forging.The as-rolled forged alloy(FR-LZ91)exhibited the highest area fraction of theβ-Li phase and the longest grains.The corrosion resistance of the forged LZ91 alloy increased due to grain refinement that prevented further corrosion during the immersion test.Among the experimental alloys,FR-LZ91 showed the highest resistance of corrosion film and charge transfer resistance values due to its protective film caused by the high area fraction of theβ-Li phase.

Comparison of the corrosion behaviour of AZ31B magnesium alloy under immersion test and potentiodynamic polarization test in NaCl solution

This paper reports the comparative evaluation of the corrosion behaviour of AZ31B magnesium alloy under immersion and potentiodynamic polarization test in NaCl solution at different chloride ion concentrations,pH value and exposure time.The specimens were exposed to immersion and polarization environments in order to evaluate their corrosion rates.Empirical relationship was established to predict the corrosion rate of AZ31B magnesium alloy.Three factors,five level,central composite rotatable design matrix was used to minimize the number of experimental conditions.Response surface methodology was used to develop the relationship.The developed relationship can be effectively used to predict the corrosion rate of AZ31B magnesium alloy at 95%confidence level for both the testing.This research work proves a better corrosion resistance of AZ31B magnesium alloy at the alkaline solution than the acidic and the neutral solutions,moreover,low corrosion rate was found at low concentrated solution and higher exposure time respectively.

Salt spray corrosion test of micro-plasma oxidation ceramic coatings on Ti alloy

Ceramic coatings were prepared on Ti-6Al-4V alloy in NaAlO2 solution by micro-plasma oxidation （MPO）. The salt spray tests of the coated samples and the substrates were carded out in a salt spray test machine. The phase composition and surface morphology of the coatings were investigated by XRD and SEAM. Severe corrosion occurred on the substrate surface, while there were no obvious corrosion phenomena on the coated samples. The coatings were composed of Al2TiO5 and a little α-Al2O3 and mille TiO2, and the salt spray test did not change the composition of the coatings. The weight loss rate of the coatings decreased with increasing MPO time because of the increase in density and thickness of the coatings. The surface morphology of the coatings was influenced by salt spray corrosion test. Among the coated samples, the coating prepared for 2 h has the best corrosion resistance under salt spray test.

SIMULATION TEST APPARATUS FOR MARINE CORROSION

This paper describes the setup and working mechanism of a simulation test apparatus for marine corrosion. Experimental results showed the apparatus can basically reflect the corrosion behavior of steel in various marine environments, and is simple, convenient, and reliable for testing steel used for marine engineering.

Prevention of Q235 Steel Corrosion using Waterborne Rust Inhibitor

Sorbitol,triethanolamine,sodium benzoate,boric acid,and sodium carbonate were mixed to prepare a waterborne rust inhibitor.A temperature and humidity accelerated corrosion test was applied to investigate the corrosion behaviour of waterborne rust inhibitor coated Q235 steel and original Q235 steel,which was carried out in a temperature and humidity test chamber(WSHW-1000)at a temperature of 80℃and humidity of 95%.Compared with the original Q235,waterborne rust inhibitor coated Q235 has better resistance to corrosion in hot and humid ambient conditions.Electrochemical impedance spectroscopy and potentiodynamic polarization were measured with a three-electrode cell in 3.5%NaCl aqueous solution on a CHI760E potentiostat/galvanostat.Molecular dynamics was simulated to verify the synergistic corrosion inhibitory mechanism of sodium carbonate and triethanolamine.The test shows that the prepared waterborne rust inhibitor can reduce the tendency of Q235 to corrosion and can also effectively reduce the corrosion rate.

Evaluation of Expansion Process to Improve Corrosion Resistance of Copper Tubes with High Residual Carbon on the Inner Surface

Residual carbon on the inner surface of copper tubes is known to be a cause of pitting corrosion. We showed previously that the rapid filling test was useful to evaluate the pitting corrosion resistance of copper tubes. Immersion tests using the rapid evaluation test solution showed that corrosion occurs on the entire surface of copper tubes with low residual carbon amounts, while those with high residual carbon amounts show pitting corrosion. Therefore, it is necessary to improve the corrosion resistance of copper tubes with high residual carbon amount, which are expected to undergo pitting corrosion. As pitting corrosion occurs when anodes are locally concentrated on part of the metal surface, it has been suggested that anodes be dispersed over the entire surface by the processing of the metal surface. Metal processing methods have various purposes, including changing the shape and properties of metals, and in this case, leading to desirable surface properties (such as expansion and drawing processes). Here, we focused on the expansion process and its effects on corrosion resistance of copper tubes. The results showed that hydraulic expansion has a significant effect on the inner copper surface by improving corrosion resistance as the anode area increases.

Quantitative Detection of Corrosion State of Concrete Internal Reinforcement Based on Metal Magnetic Memory

Corrosion can be very harmful to the service life and several properties of reinforced concrete structures.The metal magnetic memory(MMM)method,as a newly developed spontaneous magnetic flux leakage(SMFL)non-destructive testing(NDT)technique,is considered a potentially viable method for detecting corrosion damage in reinforced concrete members.To this end,in this paper,the indoor electrochemical method was employed to accelerate the corrosion of outsourced concrete specimens with different steel bar diameters,and the normal components Bz and its gradient of the SMFL fields on the specimen surfaces were investigated based on the metal magnetic memory(MMM)method.The experimental results showed that the SMFL experimental Bz curves are consistent with the analytical results of the theoretical model.Furthermore,the crest-to-trough behavior on the Bz signal curve and its zero-point gradient spacing can more accurately indicate the corroded area’s extent.Then,a magnetic characteristic parameter W based on a large amount of experimental data was established to characterize the degree of corrosion of the steel bars.The magnetic characteristic parameter W is linearly related to the maximum cross-sectional area loss rate
of the corroded reinforcement.This paper will lay the foundation for future research on corrosion detection of reinforced concrete structures based on the MMM method and provide a feasible way for non-destructive detection of corrosion independent of the influence of reinforcement diameter and magnetization history.

Atmospheric corrosion of carbon steel in acid rain by accelerated weathering test

In this work, the accelerated weathering test of immersion-wet-dry combined cycles was carried ont. The artificial acid rain of NaHSO3-(NH4)2SO4-H2SO4 solution system was selected as immersion solution. Acidity of artificial acid rain affected corrossion weight loss of carbon steel, and pH 4.1 was found to be a critical point. Anodic reaction resistance of the samples during accelerated weathering test increased with exposed time by electrochemical measurement.

Novel accelerated corrosion test for LY12CZ and LC4CS aluminum alloys

A new accelerated corrosion test—comprehensive environmental test (CET) was developed in order to estimate the outdoor corrosion of aluminum alloys in marine environment. The environmental characteristics in CET were studied by atmospheric corrosion monitor (ACM), and the morphology of corrosion product was observed by SEM. The correlation between the accelerated corrosion tests and outdoor exposure was discussed. The results show that the anti-corrosion ranking for LY12CZ, LC4CS, clad LY12CZ, and clad LC4CS in CET is the same as that of the alloys exposed outdoor, and ACM study shows that CET demonstrates the same environmental characteristics as that exposed outdoor. CET is a more accurate accelerated corrosion test, and a mathematical relation was obtained to describe the relation between CET and outdoor test.

Corrosion behavior of an Al-6Mg-Sc-Zr alloy

The corrosion behavior of an Al-6Mg-Sc-Zr alloy was studied and compared with that of an Al-6Mg-Zr alloy. The addition of scandium into the Al-6Mg-Zr alloy reduced the susceptibility to exfoliation corrosion. By using the constant load tensile method in a 3.5 wt.% NaCl solution, the resistance to SCC of the Al-6Mg-Sc-Zr alloy was higher than that of the Al-6Mg-Zr alloy. When the specimens were not applied with an anodic current, the Al-6Mg-Sc-Zr alloy was resistance to SCC and no brittle cracking was found on the fracture surface. When an anodic current was applied, the Al-6Mg-Sc-Zr alloy specimens failed as a result of accelerated corrosion rather than SCC. It was believed that the addition of scandium re- sulted in （Al3Sc, Zr） particles that greatly refined grains and promoted the formation of homogeneous discontinuous distribution of β-phase in the alloy base, which much contributed to good corrosion resistance of the Al-6Mg-Sc-Zr alloy.

Prediction model for atmospheric corrosion of 7005-T4 aluminum alloy in industrial and marine environments

Accelerated corrosion tests of the 7005-T4 aluminum alloy were conducted to determine a suitable service life prediction method by using alternating wet–dry cycles in three kinds of solutions. The morphology and composition analysis of the corrosion product revealed that slight corrosion occurred on the surfaces of the samples immersed in a 0.25 wt% Na_2S_2O_8 solution. However, pitting corrosion occurred on the surfaces of the samples immersed in a 3.5 wt% NaCl solution, whereas exfoliation corrosion occurred on the surfaces of the samples immersed in a mixture of 0.25 wt% Na_2S_2O_8 and 3.5 wt% NaCl solutions. A power exponent relationship was observed between the mass loss and exposure time of the 7005-T4 aluminum alloy immersed in the three kinds of solutions. In the mixture of 0.25 wt% Na_2S_2O_8 and 3.5 wt% NaCl solutions, the mass loss of the aluminum alloy yielded the maximum value. Based on the calculation of the correlation coefficients, the alternating wet–dry procedure in a 3.5 wt% NaCl solution could be used to predict the corrosion behavior of 7005-T4 aluminum alloy exposed in the atmosphere of Qingdao, China. The prediction model is as follows: T = 104.28×t^(0.91), where T is the equivalent time and t is the exposure time.

Stress Corrosion Cracking of Nitrogen-containing Stainless Steel 316LN in High Temperature Water Environments

Stress corrosion cracking （SCC） of stainless steels and Ni-based alloys in high temperature water coolant is one of the key problems affecting the safe operation of nuclear power plants （NPPs）. The nitrogen-added stainless steel is a kind of possible candidate materials for mitigating SCC since reducing the carbon content and adding nitrogen to offset the loss in strength caused by the decrease in carbon content can mitigate the problem of sensitization. However, the reports of SCC of nitrogen-added stainless steels in high temperature water are few available. The effects of applied potential and sensitization treatment on the SCC of a newly developed nitrogen-containing stainless steel （SS） 316LN in high temperature water doped with chloride at 250 ℃ were studied by using slow strain rate tests （SSRTs）. The SSRT results are compared with our data previously published for 316 SS without nitrogen and 304NG SS with nitrogen, and the possible mechanism affecting the SCC behaviors of the studied steels is also discussed based on SSRT and microstucture analysis results. The susceptibility to cracking of 316LN SS normally increases with increasing potential. The susceptibility to SCC of 316LN SS was less than that of 316 SS and 304NG SS. Sensitization treatment at 700℃ for 30 h showed little effect on the S CC of 316LN S S and significant effect on the S CC of 316 S S. The predominant cracking mode for the 316LN S S in both annealed state and the state after the sensitization treatment was transgranular. The presented conditions of mitigating stress corrosion cracking are some useful information for the safe use of 316LN SS in NPPs.

Effect of Aluminum Tri-polyphosphate on Corrosion Behavior of Reinforcing Steel in Seawater Prepared Coral Concrete

Atri-polyphosphate was used as a corrosion inhibitor in the seawater prepared coral concrete, and its influence on the corrosion behavior of carbon steel, 304 austenitic stainless steel, and 2205 duplex stainless steel was studied by the open-circuit potential, electrochemical impedance spectroscopy, and potentiodynamic polarization, respectively. The results reveal that the corrosion potential and impedance of the reinforcing steel increase, while the corrosion current density decreases with the content of aluminum tripolyphosphate in the coral concrete. A low content of the corrosion inhibitor significantly retards the corrosion of the two stainless steels, but it cannot effectively inhibit the corrosion of the carbon steel in the coral concrete.In general, the carbon steel is unsuitable for the coral concrete for its poor corrosion resistance. In contrast,the stainless steels, especially the 2205 duplex stainless steel, shows an excellent anti-corrosion property in the seawater prepared coral concrete containing a certain amount of inhibitor, which is one of the satisfactory candidate methods to build the long-life coral concrete constructions.

Laboratory and field testing of bolting systems subjected to highly corrosive environments

The capacity of ground support components which have been affected by corrosion is reduced and may ultimately lead to dynamic failure of the component and the strata. In order to maintain an effective,long-term ground support system, significant campaigns of rehabilitation are often required in corrosion affected areas which also expose the workers to hazardous conditions. The most common corrosion protection for steel ground support utilises sacrificial systems such as galvanising. Galvanising has previously been proven to be susceptible to some corrosion processes. Stainless steel is the most effective in resistance to corrosion, but can be cost prohibitive, and its mechanical properties often make it unsuited to use in ground support components. Providing an outer protective plastic coating to bolts has proven to be an effective means of protecting the inner steel bar from corrosion. However, these support systems tend to be susceptible to coating damage, and require post cement grouting to provide full encapsulation. In comparison to a standard bolt/resin system, they can be slow to install and expensive.These systems have also been shown to reduce overall load transfer performance of the bolting system. In order to provide a higher level of corrosion protection whilst maintaining current installation practices and bolting cycle times, Minova has developed the Enduro^(TM)steel ground support range. The Enduro^(TM) range consists of standard Minova steel ground support components which have been treated with a unique coating process. The Enduro^(TM)coating has been tested in the harshest of conditions, in laboratory controlled conditions and in underground trials. It has been proven to effectively resist or completely eliminate the formation of corrosion, even in the most aggressive environments. This paper explains the process and provides the details of the laboratory and underground corrosion performance testing carried out on Enduro^(TM)ground support products.

Effect of nonmetallic inclusions on localized corrosion of spring steel

Certain inclusions in high-strength 60Si2Mn-Cr spring steel result in poor resistance to localized corrosion.In this work,to study the effect of inclusions on the localized corrosion behavior of spring steel,accelerated corrosion tests were performed by immersing spring steel in 3wt%FeCl_(3)solution for different times.The results show that severe corrosion occurred in areas of clustered CaS inclusions.Sulfide inclusions containing Ca and Mg induced the strongest localized corrosion susceptibility.For the case of(Ca,Mn,Mg)S inclusions,the ability to induce localized corrosion susceptibility is ranked as follows:MgS>CaS>MnS.Moreover,CaS,(Ca,Mn)S,and(Ca,Mn,Mg)S inclusions were mainly responsible for inducing environmental embrittlement.

Microstructural, mechanical and corrosion characterization of an as-cast Mg-3Zn-0.4Ca alloy for biomedical applications

The as-cast Mg-3Zn-0.4Ca alloy shows a great potential to be used in biomedical applications due to its composition,mechanical properties and biodegradability.Zn and Ca appear naturally in the organism accomplishing vital functions.The alloy consists of an a-Mg matrix and a eutectic composed of a-Mg4-Ca2Mg6Zn3.The eutectic product enhances the mechanical properties of the studied alloy,causing strengthening and providing superior hardness values.In this alloy,cracks initiate at the intermetallic compounds and progress through the matrix because of the open network formed by the eutectics.Attending to the corrosion results,the eutectic product presents a noble potential compared to the a-Mg phase.For this reason,the corrosion progresses preferentially through the matrix,avoiding the(α-Mg+Ca2Mg6Zri3)eutectic product,when the alloy is in direct contact to Hank's solution.

Behavior of Stress Corrosion Cracking in a Magnesium Alloy

Slow strain rate testing （SSRT） was employed to study the stress corrosion cracking （SCC） behavior of ZE41 magnesium alloy in 0.01 M NaCl solution. Smooth tensile specimens with different thicknesses were strained dynamically in both longitudinal and transverse direction under permanent immersions at a strain rate of 10-6 s-1. It is found that ZE41 magnesium alloy is susceptible to SCC in 0.01 M NaCl solution. The SCC susceptibility of the thinner specimen is lower than that of the thicker specimen. Also, the longitudinal specimens are slightly more susceptible to SCC than the transverse specimens. The SCC mechanism of magnesium alloy is attributed to the combination of anodic dissolution with hydrogen embrittlement.