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Preparation and Reinforcement Adaptability of Jute Fiber Reinforced Magnesium Phosphate Cement Based Composite Materials
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作者 刘芯州 郭远臣 +3 位作者 WANG Rui XIANG Kai WANG Xue YE Qing 《Journal of Wuhan University of Technology(Materials Science)》 SCIE EI CAS CSCD 2024年第4期999-1009,共11页
To improve the brittleness characteristics of magnesium phosphate cement-based materials(MPC)and to promote its promotion and application in the field of structural reinforcement and repair,this study aimed to increas... To improve the brittleness characteristics of magnesium phosphate cement-based materials(MPC)and to promote its promotion and application in the field of structural reinforcement and repair,this study aimed to increase the toughness of MPC by adding jute fiber,explore the effects of different amounts of jute fiber on the working and mechanical properties of MPC,and prepare jute fiber reinforced magnesium phosphate cement-based materials(JFRMPC)to reinforce damaged beams.The improvement effect of beam performance before and after reinforcement was compared,and the strengthening and toughening mechanisms of jute fiber on MPC were explored through microscopic analysis.The experimental results show that,as the content of jute fiber(JF)increases,the fluidity and setting time of MPC decrease continuously;When the content of jute fiber is 0.8%,the compressive strength,flexural strength,and bonding strength of MPC at 28 days reach their maximum values,which are increased by 18.0%,20.5%,and 22.6%compared to those of M0,respectively.The beam strengthened with JFRMPC can withstand greater deformation,with a deflection of 2.3 times that of the unreinforced beam at failure.The strain of the steel bar is greatly reduced,and the initial crack and failure loads of the reinforced beam are increased by 192.1%and 16.1%,respectively,compared to those of the unreinforced beam.The JF added to the MPC matrix dissipates energy through tensile fracture and debonding pull-out,slowing down stress concentration and inhibiting the free development of cracks in the matrix,enabling JFRMPC to exhibit higher strength and better toughness.The JF does not cause the hydration of MPC to generate new compounds but reduces the amount of hydration products generated. 展开更多
关键词 magnesium phosphate cement jute fiber reinforcement of damaged beam flexural behavior
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有机无机杂化钙钛矿电镜表征的虚与实 被引量:5
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作者 陈树林 张颖 +8 位作者 赵晋津 秘周 张敬民 曹健 冯吉才 张光磊 亓钧雷 李江宇 高鹏 《Science Bulletin》 SCIE EI CAS CSCD 2020年第19期1643-1649,M0004,共8页
近年来,由于合成价格低廉以及光电转化效率高,基于有机无机杂化钙钛矿材料的太阳能电池得到了飞速发展.然而这些材料容易分解,这极大地限制了该技术的商业化应用.基于透射电子显微镜的表征有助于解析这些材料的降解机理.然而杂化钙钛矿... 近年来,由于合成价格低廉以及光电转化效率高,基于有机无机杂化钙钛矿材料的太阳能电池得到了飞速发展.然而这些材料容易分解,这极大地限制了该技术的商业化应用.基于透射电子显微镜的表征有助于解析这些材料的降解机理.然而杂化钙钛矿材料对电子束辐照十分敏感,易引起结构失稳甚至分解,进而阻碍我们获取真实结构信息.本文利用低电子束剂量成像技术系统地研究了不同实验条件下杂化钙钛矿的结构不稳定性,揭示了最优的透射电镜表征条件.我们发现,低温(-180°C)并没有减缓束损伤,反而导致了快速的非晶化;较高的加速电压有利于降低损伤;MAPbI3(100)面比(001)面更稳定.基于这些发现,我们成功地获得了MAPbI3原始的原子结构,并确定了其表征窗口非常窄.这些发现有助于指导未来对这些电子束敏感材料的电子显微表征,也有助于寻找提高钙钛矿型太阳能电池稳定性的策略. 展开更多
关键词 Organic-inorganic hybrid perovskites Transmission electron microscopy beam damage mechanism Atomic structure CH3NH3PbI3 Facet dependency
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