Objective The Yangtze craton collisional orogeny at ca. extensional events at ca. 1 experienced Paleoproterozoic 1.95-2.0 Ga and post-orogenic 85 Ga related to amalgamation of the Columbia (Nuna) supercontinent (Zh...Objective The Yangtze craton collisional orogeny at ca. extensional events at ca. 1 experienced Paleoproterozoic 1.95-2.0 Ga and post-orogenic 85 Ga related to amalgamation of the Columbia (Nuna) supercontinent (Zhao and Cawood, 2012). A ca. 2.15 Ga suprasubduction zone ophiolitic melange was recongized in the Archean- Paleoproterozoic Kongling Complex of the northern Yangtze craton (Han et al., 2017). However, the tectonic evolution in early Paleoproterozoic from 2.4 Ga to 2.2 Ga remains unclear. We report here the presence of a suite of Paleoproterozoic (2.2 Ga) granites in the Huangling dome, northern Yangtze craton, which may provide important insights into crustal growth processes in the craton prior to the assembly of Columbia.展开更多
The inert gas radioactive isotope ^(85)Kr(with a half-life of 10.74 years), due to its stable physical and chemical properties, is an ideal tracer for shallow groundwater dating. In such a dating application, first th...The inert gas radioactive isotope ^(85)Kr(with a half-life of 10.74 years), due to its stable physical and chemical properties, is an ideal tracer for shallow groundwater dating. In such a dating application, first the dissolved gas is extracted from groundwater in the field, then krypton is separated from the gas sample, and finally the isotopic abundance ^(85)Kr/Kr will be determined by an ATTA instrument. According to the atmospheric input curve of ^(85)Kr, the ^(85)Kr age of groundwater is determined. We conducted ^(85)Kr analysis in three wells in Zhengding County on the plains in front of the Taihang Mountains, and made a comparison with tritium(~3H) method.展开更多
Mica exhibits a relatively high Rb/Sr ratio and possesses a closure temperature for the Rb-Sr isotope system that is higher than the ore-forming temperature range of low-to medium-temperature deposits.Consequently,uti...Mica exhibits a relatively high Rb/Sr ratio and possesses a closure temperature for the Rb-Sr isotope system that is higher than the ore-forming temperature range of low-to medium-temperature deposits.Consequently,utilizing the laser ablation(LA)technique for in situ Rb-Sr dating in mica constitutes a significant methodology for resolving the mineralization chronology of low-to medium-temperature hydrothermal ore deposits.In this study,we employed a combination of a triple quadrupole inductively coupled plasma mass spectrometer(ICP-MS/MS)and 193 nm LA system with SF_6as the reaction gas to achieve interference removal of~(87)Rb~+on~(87)Sr~+.We then developed an in situ Rb-Sr dating method for mica.In addition,an investigation was conducted to identify the factors that could influence the analytical accuracy of the method.Subsequently,we applied the developed method to carry out in situ Rb-Sr dating for the ZBH-25 biotite,a national primary reference material(GBW04439)for K-Ar dating,and yielded a younger age(ca.12%,relative standard deviation,RSD)than the reference K-Ar age when using NIST SRM 610 as the reference material for external calibration.This finding indicated that in the process of determining Rb-Sr ages for mica by LA-ICP-MS/MS,there are significant matrix effects between the NIST SRM 610 and the mica samples,resulting in inaccurate Rb-Sr ages.In response to this issue,a two-step calibration method is proposed here.Based on external calibration using NIST SRM 610,ZBH-25 biotite is employed as a second external reference material to perform a second calibration of the sample data to correct the matrix effect between the glass standards and the natural mica samples,thereby improving the accuracy of Rb-Sr dating by LA-ICP-MS/MS.Using the proposed method,in situ Rb-Sr dating by LA-ICP-MS/MS was performed on mica samples from monzonite exposed in Mt.Dromedary,New South Wales,Australia,porphyritic granodiorite in Fangshan pluton and albionite granite in the Gyirong area of Tibet.The obtained Rb-Sr age results show agreement with the recommended values within the analytical uncertainty,which serves to validate the accuracy and effectiveness of the proposed method.展开更多
Tectonically, the large-scale right-lateral strike-slip movement along the Red River fault zone is char-acterized at its late phase with the southeastward extension and deformation of the Northwestern Yunnan normal fa...Tectonically, the large-scale right-lateral strike-slip movement along the Red River fault zone is char-acterized at its late phase with the southeastward extension and deformation of the Northwestern Yunnan normal fault depression on its northern segment, and the dextral shear displacement on its central-southern segment. Research of the relations between stratum deformation and fault movement on the typical fault segments, such as Jianchuan, southeast Midu, Yuanjiang River, Yuanyang, etc. since the Miocene Epoch shows that there are two times dextral faulting dominated by normal shearing occurring along the Red River fault zone since the Miocene Epoch. The fission track dating (abbrevi-ated to FT dating, the same below) is conducted on apatite samples collected from the above fault segments and relating to these movements. Based on the measured single grain’s age and the con-fined track length, we choose the Laslet annealing model to retrieve the thermal history of the samples, and the results show that the fault zone experienced two times obvious shear displacement, one in 5.5 ± 1.5 MaBP and the other in 2.1± 0.8 MaBP. The central-southern segment sees two intensive uplifts of mountain mass in the Yuanjiang River-Yuanyang region at 3.6―3.8 MaBP and 1.6―2.3 MaBP, which correspond to the above-mentioned two dextral normal displacement events since the late Miocene Epoch.展开更多
Four samples from a Permian reservoir in the Ordos Basin of North China were separated into twelve fractions in grain sizes of 〈0.5, 0.5-1 and 1-2 μm. Using the ^40Ar-^39Ar step-heating method, all of the fractions ...Four samples from a Permian reservoir in the Ordos Basin of North China were separated into twelve fractions in grain sizes of 〈0.5, 0.5-1 and 1-2 μm. Using the ^40Ar-^39Ar step-heating method, all of the fractions essentially yielded plateau ages ranging from 172.5 to 217.1 Ma. These scattered plateau ages might not have been obtained from pure diagenetic illites but from mixed clay minerals, although the samples were disaggregated using a gentle freeze-thaw cycle to free them of non-clay minerals. A regional thermal event, as suggested by several proxies, led to intensive iHitization as a distinct diagenetic process when the Yanshanian Movement triggered magmatism around the entire North China Block during the Jurassic to Cretaceous. Thermal illites formed during a short time period, whereas detrital illites came from various sources. The scattered plateau ages could have resulted from mixed degassing of thermal and detrital illites. Within one sample, the plateau ages decrease with the diminution of grain sizes, but it is difficult to extrapolate to the detrital-illite-free ages. Because the plateau age is a mixture of ages for thermal and detrital illites, this regression analysis studies the dependence of the plateau ages on the synthetic values of contents and ages of detrital illites instead of on the grain sizes. Comparing the samples to one another, the plateau ages show the same trend among the different grain sizes. Weighted by the contents and ages of detrital illites, linear regression analysis revealed the relationship between the plateau ages and the relative weight proportions. Based on iterated calculations, a thermal event age and a set of weight proportions were derived. The regressed thermal event age is 163.3±1.6 Ma, which coincides with regional thermal activities and links to gas accumulation.展开更多
As one of the best established low temperature thermochronology techniques,apatite fission-track(AFT)analysis has proved an important tool for constraining a wide variety of upper crustal processes,e.g.,landscape evol...As one of the best established low temperature thermochronology techniques,apatite fission-track(AFT)analysis has proved an important tool for constraining a wide variety of upper crustal processes,e.g.,landscape evolution,hydrocarbon exploration and tectonics[1].The most common method employed for AFT analysis is the external detector method(EDM)[1]and this involves the thermal neutron irradiation of samples for determination of展开更多
LA-MC-ICPMS U-Pb dating has been performed on detrital zircons from the Upper Carboniferous Tai-yuan Formation (N-8) in the Ningwu-Jingle Basin, west of the North China Craton (NCC). The ages of 72 detrital zircon gra...LA-MC-ICPMS U-Pb dating has been performed on detrital zircons from the Upper Carboniferous Tai-yuan Formation (N-8) in the Ningwu-Jingle Basin, west of the North China Craton (NCC). The ages of 72 detrital zircon grains are divided into three groups: 303―320 Ma (6 grains), 1631―2194 Ma (37 grains, peaked at 1850 Ma), 2318―2646 Ma (29 grains, peaked at 2500 Ma). Detrital zircons of Group 2 and Group 3 were likely derived from the basement of the NCC. Group 1 zircons exhibit 176Hf/177Hf ratios ranging from 0.281725 to 0.282239, with corresponding negative εHf(t) values of -12.4―-30.3 and old Hf model ages of 1.4―2.2 Ga. These characteristics show a strong resemblance to those of Carboniferous igneous zircons from the Inner Mongolia Paleo-uplift (IMPU) on the northern margin of the NCC, but differ significantly from those of the Xing-Meng Orogenic Belt, suggesting that the source of the Tai-yuan Formation partly came from the IMPU. All detrital zircons of Group 1 have relatively high Th/U ratios (> 0.67), indicating a magmatic origin. The mean age (304 ± 6 Ma) of the two youngest grains is close to the depositional age of the Taiyuan Formation, suggesting a strong tectonic uplift and magmatism in the IMPU during the Late Carboniferous. This paper provides important geological evidence for the activation of the northern margin of the NCC in the Late Paleozoic.展开更多
The aim of this study is to establish the prevailing conditions of changing climatic trends and change point dates in four selected meteorological stations of Uyo, Benin, Port Harcourt, and Warri in the Niger Delta re...The aim of this study is to establish the prevailing conditions of changing climatic trends and change point dates in four selected meteorological stations of Uyo, Benin, Port Harcourt, and Warri in the Niger Delta region of Nigeria. Using daily or 24-hourly annual maximum series (AMS) data with the Indian Meteorological Department (IMD) and the modified Chowdury Indian Meteorological Department (MCIMD) models were adopted to downscale the time series data. Mann-Kendall (MK) trend and Sen’s Slope Estimator (SSE) test showed a statistically significant trend for Uyo and Benin, while Port Harcourt and Warri showed mild trends. The Sen’s Slope magnitude and variation rate were 21.6, 10.8, 6.00 and 4.4 mm/decade, respectively. The trend change-point analysis showed the initial rainfall change-point dates as 2002, 2005, 1988, and 2000 for Uyo, Benin, Port Harcourt, and Warri, respectively. These prove positive changing climatic conditions for rainfall in the study area. Erosion and flood control facilities analysis and design in the Niger Delta will require the application of Non-stationary IDF modelling.展开更多
The Erguna ductile shear zone is situated in the Erguna Massif,which has been exposed along the eastern bank of the Erguna River in northeastern China.The authors present comprehensive study results on the macro-and m...The Erguna ductile shear zone is situated in the Erguna Massif,which has been exposed along the eastern bank of the Erguna River in northeastern China.The authors present comprehensive study results on the macro-and micro-structures,finite strain and kinematic vorticity,quartz electron backscatter diffraction(EBSD)fabrics,and geochronology of granitic rocks in the Erguna ductile shear zone.The deformed granitic rocks have experienced significant SE-trending dextral strike-slip shearing.Finite strain and kinematic vorticity in all deformed granitic rocks indicate that the deformation is characterized by simple sheardominated general shearing with S-L tectonites.Mineral deformation behaviors and quartz C-axis textures demonstrate that the deformed granitic rocks developed under greenschist to amphibolite facies conditions at deformation temperatures ranging from 450 to 550℃.New LA-ICP-MS zircon U-Pb ages indicate that these granitic rocks were formed in Early Triassic(~248.6 Ma)and Early Cretaceous(~136.7 Ma).All the evidence indicates that this deformation may have occurred in Early Cretaceous and was related to the compression resulting from the final closure of the Mongol-Okhotsk Ocean.展开更多
基金supported by the funded project of the China Geological Survey(grants No.12120113061700,121201009000150013 and DD20160029)
文摘Objective The Yangtze craton collisional orogeny at ca. extensional events at ca. 1 experienced Paleoproterozoic 1.95-2.0 Ga and post-orogenic 85 Ga related to amalgamation of the Columbia (Nuna) supercontinent (Zhao and Cawood, 2012). A ca. 2.15 Ga suprasubduction zone ophiolitic melange was recongized in the Archean- Paleoproterozoic Kongling Complex of the northern Yangtze craton (Han et al., 2017). However, the tectonic evolution in early Paleoproterozoic from 2.4 Ga to 2.2 Ga remains unclear. We report here the presence of a suite of Paleoproterozoic (2.2 Ga) granites in the Huangling dome, northern Yangtze craton, which may provide important insights into crustal growth processes in the craton prior to the assembly of Columbia.
基金supported by the National Natural Science Foundation of China (41102151)Public Science and Technology Research Funds Projects of Ministry of Land and Resources(201511046)
文摘The inert gas radioactive isotope ^(85)Kr(with a half-life of 10.74 years), due to its stable physical and chemical properties, is an ideal tracer for shallow groundwater dating. In such a dating application, first the dissolved gas is extracted from groundwater in the field, then krypton is separated from the gas sample, and finally the isotopic abundance ^(85)Kr/Kr will be determined by an ATTA instrument. According to the atmospheric input curve of ^(85)Kr, the ^(85)Kr age of groundwater is determined. We conducted ^(85)Kr analysis in three wells in Zhengding County on the plains in front of the Taihang Mountains, and made a comparison with tritium(~3H) method.
基金supported by the National Natural Science Foundation of China(Grant No.42173035)the Chinese Academy of Sciences“Key Technology Talent”Project。
文摘Mica exhibits a relatively high Rb/Sr ratio and possesses a closure temperature for the Rb-Sr isotope system that is higher than the ore-forming temperature range of low-to medium-temperature deposits.Consequently,utilizing the laser ablation(LA)technique for in situ Rb-Sr dating in mica constitutes a significant methodology for resolving the mineralization chronology of low-to medium-temperature hydrothermal ore deposits.In this study,we employed a combination of a triple quadrupole inductively coupled plasma mass spectrometer(ICP-MS/MS)and 193 nm LA system with SF_6as the reaction gas to achieve interference removal of~(87)Rb~+on~(87)Sr~+.We then developed an in situ Rb-Sr dating method for mica.In addition,an investigation was conducted to identify the factors that could influence the analytical accuracy of the method.Subsequently,we applied the developed method to carry out in situ Rb-Sr dating for the ZBH-25 biotite,a national primary reference material(GBW04439)for K-Ar dating,and yielded a younger age(ca.12%,relative standard deviation,RSD)than the reference K-Ar age when using NIST SRM 610 as the reference material for external calibration.This finding indicated that in the process of determining Rb-Sr ages for mica by LA-ICP-MS/MS,there are significant matrix effects between the NIST SRM 610 and the mica samples,resulting in inaccurate Rb-Sr ages.In response to this issue,a two-step calibration method is proposed here.Based on external calibration using NIST SRM 610,ZBH-25 biotite is employed as a second external reference material to perform a second calibration of the sample data to correct the matrix effect between the glass standards and the natural mica samples,thereby improving the accuracy of Rb-Sr dating by LA-ICP-MS/MS.Using the proposed method,in situ Rb-Sr dating by LA-ICP-MS/MS was performed on mica samples from monzonite exposed in Mt.Dromedary,New South Wales,Australia,porphyritic granodiorite in Fangshan pluton and albionite granite in the Gyirong area of Tibet.The obtained Rb-Sr age results show agreement with the recommended values within the analytical uncertainty,which serves to validate the accuracy and effectiveness of the proposed method.
基金the National Natural Science Foundation of China (Grant No.40272087)
文摘Tectonically, the large-scale right-lateral strike-slip movement along the Red River fault zone is char-acterized at its late phase with the southeastward extension and deformation of the Northwestern Yunnan normal fault depression on its northern segment, and the dextral shear displacement on its central-southern segment. Research of the relations between stratum deformation and fault movement on the typical fault segments, such as Jianchuan, southeast Midu, Yuanjiang River, Yuanyang, etc. since the Miocene Epoch shows that there are two times dextral faulting dominated by normal shearing occurring along the Red River fault zone since the Miocene Epoch. The fission track dating (abbrevi-ated to FT dating, the same below) is conducted on apatite samples collected from the above fault segments and relating to these movements. Based on the measured single grain’s age and the con-fined track length, we choose the Laslet annealing model to retrieve the thermal history of the samples, and the results show that the fault zone experienced two times obvious shear displacement, one in 5.5 ± 1.5 MaBP and the other in 2.1± 0.8 MaBP. The central-southern segment sees two intensive uplifts of mountain mass in the Yuanjiang River-Yuanyang region at 3.6―3.8 MaBP and 1.6―2.3 MaBP, which correspond to the above-mentioned two dextral normal displacement events since the late Miocene Epoch.
基金supported by the National Natural Science Foundation of China(No.40572081)the Chinese Academy of Sciences(No.KZCX1-SW-18)
文摘Four samples from a Permian reservoir in the Ordos Basin of North China were separated into twelve fractions in grain sizes of 〈0.5, 0.5-1 and 1-2 μm. Using the ^40Ar-^39Ar step-heating method, all of the fractions essentially yielded plateau ages ranging from 172.5 to 217.1 Ma. These scattered plateau ages might not have been obtained from pure diagenetic illites but from mixed clay minerals, although the samples were disaggregated using a gentle freeze-thaw cycle to free them of non-clay minerals. A regional thermal event, as suggested by several proxies, led to intensive iHitization as a distinct diagenetic process when the Yanshanian Movement triggered magmatism around the entire North China Block during the Jurassic to Cretaceous. Thermal illites formed during a short time period, whereas detrital illites came from various sources. The scattered plateau ages could have resulted from mixed degassing of thermal and detrital illites. Within one sample, the plateau ages decrease with the diminution of grain sizes, but it is difficult to extrapolate to the detrital-illite-free ages. Because the plateau age is a mixture of ages for thermal and detrital illites, this regression analysis studies the dependence of the plateau ages on the synthetic values of contents and ages of detrital illites instead of on the grain sizes. Comparing the samples to one another, the plateau ages show the same trend among the different grain sizes. Weighted by the contents and ages of detrital illites, linear regression analysis revealed the relationship between the plateau ages and the relative weight proportions. Based on iterated calculations, a thermal event age and a set of weight proportions were derived. The regressed thermal event age is 163.3±1.6 Ma, which coincides with regional thermal activities and links to gas accumulation.
基金jointly supported by the Fundamental Scientific Research of the Institute of Geology, China Earthquake Administration (IGCEA1509)the National Natural Science Foundation of China (41603054 and 41474053)China Scholarship Council
文摘As one of the best established low temperature thermochronology techniques,apatite fission-track(AFT)analysis has proved an important tool for constraining a wide variety of upper crustal processes,e.g.,landscape evolution,hydrocarbon exploration and tectonics[1].The most common method employed for AFT analysis is the external detector method(EDM)[1]and this involves the thermal neutron irradiation of samples for determination of
基金Supported by National Natural Science Foundation of China (Grant Nos 90714001, 40673038 and 40573015)the CAS/SAFEA International Partnership Program for Creative Research Teams
文摘LA-MC-ICPMS U-Pb dating has been performed on detrital zircons from the Upper Carboniferous Tai-yuan Formation (N-8) in the Ningwu-Jingle Basin, west of the North China Craton (NCC). The ages of 72 detrital zircon grains are divided into three groups: 303―320 Ma (6 grains), 1631―2194 Ma (37 grains, peaked at 1850 Ma), 2318―2646 Ma (29 grains, peaked at 2500 Ma). Detrital zircons of Group 2 and Group 3 were likely derived from the basement of the NCC. Group 1 zircons exhibit 176Hf/177Hf ratios ranging from 0.281725 to 0.282239, with corresponding negative εHf(t) values of -12.4―-30.3 and old Hf model ages of 1.4―2.2 Ga. These characteristics show a strong resemblance to those of Carboniferous igneous zircons from the Inner Mongolia Paleo-uplift (IMPU) on the northern margin of the NCC, but differ significantly from those of the Xing-Meng Orogenic Belt, suggesting that the source of the Tai-yuan Formation partly came from the IMPU. All detrital zircons of Group 1 have relatively high Th/U ratios (> 0.67), indicating a magmatic origin. The mean age (304 ± 6 Ma) of the two youngest grains is close to the depositional age of the Taiyuan Formation, suggesting a strong tectonic uplift and magmatism in the IMPU during the Late Carboniferous. This paper provides important geological evidence for the activation of the northern margin of the NCC in the Late Paleozoic.
文摘The aim of this study is to establish the prevailing conditions of changing climatic trends and change point dates in four selected meteorological stations of Uyo, Benin, Port Harcourt, and Warri in the Niger Delta region of Nigeria. Using daily or 24-hourly annual maximum series (AMS) data with the Indian Meteorological Department (IMD) and the modified Chowdury Indian Meteorological Department (MCIMD) models were adopted to downscale the time series data. Mann-Kendall (MK) trend and Sen’s Slope Estimator (SSE) test showed a statistically significant trend for Uyo and Benin, while Port Harcourt and Warri showed mild trends. The Sen’s Slope magnitude and variation rate were 21.6, 10.8, 6.00 and 4.4 mm/decade, respectively. The trend change-point analysis showed the initial rainfall change-point dates as 2002, 2005, 1988, and 2000 for Uyo, Benin, Port Harcourt, and Warri, respectively. These prove positive changing climatic conditions for rainfall in the study area. Erosion and flood control facilities analysis and design in the Niger Delta will require the application of Non-stationary IDF modelling.
基金Supported by the National Key R&D Program(No.2017YFC0601401-03).
文摘The Erguna ductile shear zone is situated in the Erguna Massif,which has been exposed along the eastern bank of the Erguna River in northeastern China.The authors present comprehensive study results on the macro-and micro-structures,finite strain and kinematic vorticity,quartz electron backscatter diffraction(EBSD)fabrics,and geochronology of granitic rocks in the Erguna ductile shear zone.The deformed granitic rocks have experienced significant SE-trending dextral strike-slip shearing.Finite strain and kinematic vorticity in all deformed granitic rocks indicate that the deformation is characterized by simple sheardominated general shearing with S-L tectonites.Mineral deformation behaviors and quartz C-axis textures demonstrate that the deformed granitic rocks developed under greenschist to amphibolite facies conditions at deformation temperatures ranging from 450 to 550℃.New LA-ICP-MS zircon U-Pb ages indicate that these granitic rocks were formed in Early Triassic(~248.6 Ma)and Early Cretaceous(~136.7 Ma).All the evidence indicates that this deformation may have occurred in Early Cretaceous and was related to the compression resulting from the final closure of the Mongol-Okhotsk Ocean.