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Behavior of Decayed Spruce (Picea abies) during Kraft Pulping
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作者 Markku Halonen Raimo Alén 《Paper And Biomaterials》 2020年第4期1-7,共7页
This study indicated that by applying an improved classification system to decayed large-diameter Norway spruce(Picea abies)wood,its use as raw material for kraft pulping without loss of pulp quality could be essentia... This study indicated that by applying an improved classification system to decayed large-diameter Norway spruce(Picea abies)wood,its use as raw material for kraft pulping without loss of pulp quality could be essentially increased.This is based on the fact that although the cooking yield of decayed spruce material which has been sorted according to these new recommendations is somewhat lower and Kappa number higher than those of sound wood material,the greatest part of the decayed stem(the outer part of the stem)contains long-fiber wood material which produces pulp of good quality.Therefore,large-diameter spruce logs can also be separately used,for example,in the manufacture of reinforcement pulp. 展开更多
关键词 Norway spruce kraft pulping wood decay fungal decay soft rot
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INTERFACE BEHAVIOR AND DECAY RATES OF COMPRESSIBLE NAVIER-STOKES SYSTEM WITH DENSITY-DEPENDENT VISCOSITY AND A VACUUM
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作者 郭真华 张学耀 《Acta Mathematica Scientia》 SCIE CSCD 2024年第1期247-274,共28页
In this paper,we study the one-dimensional motion of viscous gas near a vacuum,with the gas connecting to a vacuum state with a jump in density.The interface behavior,the pointwise decay rates of the density function ... In this paper,we study the one-dimensional motion of viscous gas near a vacuum,with the gas connecting to a vacuum state with a jump in density.The interface behavior,the pointwise decay rates of the density function and the expanding rates of the interface are obtained with the viscosity coefficientμ(ρ)=ρ^(α)for any 0<α<1;this includes the timeweighted boundedness from below and above.The smoothness of the solution is discussed.Moreover,we construct a class of self-similar classical solutions which exhibit some interesting properties,such as optimal estimates.The present paper extends the results in[Luo T,Xin Z P,Yang T.SIAM J Math Anal,2000,31(6):1175-1191]to the jump boundary conditions case with density-dependent viscosity. 展开更多
关键词 decay rates INTERFACE Navier-Stokes equations VACUUM
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THE GLOBAL EXISTENCE AND ANALYTICITY OF A MILD SOLUTION TO THE 3D REGULARIZED MHD EQUATIONS
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作者 肖存涛 邱华 姚正安 《Acta Mathematica Scientia》 SCIE CSCD 2024年第3期973-983,共11页
In this paper,we study the three-dimensional regularized MHD equations with fractional Laplacians in the dissipative and diffusive terms.We establish the global existence of mild solutions to this system with small in... In this paper,we study the three-dimensional regularized MHD equations with fractional Laplacians in the dissipative and diffusive terms.We establish the global existence of mild solutions to this system with small initial data.In addition,we also obtain the Gevrey class regularity and the temporal decay rate of the solution. 展开更多
关键词 regularized MHD equations fractional Laplacian global well-posedness ANALYTICITY decay rate
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GLOBAL CLASSICAL SOLUTIONS OF SEMILINEAR WAVE EQUATIONS ON R^(3)×T WITH CUBIC NONLINEARITIES
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作者 陶飞 《Acta Mathematica Scientia》 SCIE CSCD 2024年第1期115-128,共14页
In this paper,we establish global classical solutions of semilinear wave equations with small compact supported initial data posed on the product space R^(3)×T.The semilinear nonlinearity is assumed to be of the ... In this paper,we establish global classical solutions of semilinear wave equations with small compact supported initial data posed on the product space R^(3)×T.The semilinear nonlinearity is assumed to be of the cubic form.The main ingredient here is the establishment of the L^(2)-L^(∞)decay estimates and the energy estimates for the linear problem,which are adapted to the wave equation on the product space.The proof is based on the Fourier mode decomposition of the solution with respect to the periodic direction,the scaling technique,and the combination of the decay estimates and the energy estimates. 展开更多
关键词 semilinear wave equation product space decay estimate energy estimate global solution
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MINIMIZERS OF L^(2)-SUBCRITICAL VARIATIONAL PROBLEMS WITH SPATIALLY DECAYING NONLINEARITIES IN BOUNDED DOMAINS
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作者 陈彬 高永帅 +1 位作者 郭玉劲 吴越 《Acta Mathematica Scientia》 SCIE CSCD 2024年第3期984-996,共13页
This paper is concerned with the minimizers of L^(2)-subcritical constraint variar tional problems with spatially decaying nonlinearities in a bounded domain Ω of R~N(N≥1).We prove that the problem admits minimizers... This paper is concerned with the minimizers of L^(2)-subcritical constraint variar tional problems with spatially decaying nonlinearities in a bounded domain Ω of R~N(N≥1).We prove that the problem admits minimizers for any M> 0.Moreover,the limiting behavior of minimizers as M→∞ is also analyzed rigorously. 展开更多
关键词 decaying nonlinearity L~2-subcritical MINIMIZERS bounded domains mass concentration
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Dissipation-Driven Superradiant Phase Transition of a Two-Dimensional Bose-Einstein Condensate in a Double Cavity
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作者 Bo-Hao Wu Xin-Xin Yang +1 位作者 Yu Chen Wei Zhang 《Chinese Physics Letters》 SCIE EI CAS CSCD 2024年第6期44-48,共5页
We study superradiant phase transitions in a hybrid system of a two-dimensional Bose–Einstein condensate of atoms and two cavities arranged with a tilt angle.By adjusting the loss rate of cavities,we map out the phas... We study superradiant phase transitions in a hybrid system of a two-dimensional Bose–Einstein condensate of atoms and two cavities arranged with a tilt angle.By adjusting the loss rate of cavities,we map out the phase diagram of steady states within a mean field framework.It is found that when the loss rates of the two cavities are different,superradiant transitions may not occur at the same time in the two cavities.A first-order phase transition is observed between the states with only one cavity in superradiance and both in superradiance.In the case that both cavities are superradiant,a net photon current is observed flowing from the cavity with small decay rate to the one with large decay rate.The photon current shows a non-monotonic dependence on the loss rate difference,owing to the competition of photon number difference and cavity field phase difference.Our findings can be realized and detected in experiments. 展开更多
关键词 EINSTEIN TRANSITIONS DECAY
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αDecay in extreme laser fields within a deformed Gamow-like model
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作者 Qiong Xiao Jun-Hao Cheng +3 位作者 Yang-Yang Xu You-Tian Zou Jun-Gang Deng Tong-Pu Yu 《Nuclear Science and Techniques》 SCIE EI CAS CSCD 2024年第2期131-144,共14页
In this study, the effect of extreme laser fields on the α decay process of ground-state even–even nuclei was investigated.Using the deformed Gamow-like model, we found that state-of-the-art lasers can cause a sligh... In this study, the effect of extreme laser fields on the α decay process of ground-state even–even nuclei was investigated.Using the deformed Gamow-like model, we found that state-of-the-art lasers can cause a slight change in the α decay penetration probability of most nuclei. In addition, we studied the correlation between the rate of change of the α decay penetration probability and angle between the directions of the laser electric field and α particle emission for different nuclei. Based on this correlation, the average effect of extreme laser fields on the half-life of many nuclei with arbitrary α particle emission angles was calculated. The calculations show that the laser suppression and promotion effects on the α decay penetration probability of the nuclei population with completely random α particle-emission directions are not completely canceled.The remainder led to a change in the average penetration probability of the nuclei. Furthermore, the possibility of achieving a higher average rate of change by altering the spatial shape of the laser is explored. We conclude that circularly polarized lasers may be helpful in future experiments to achieve a more significant average rate of change of the α decay half-life of the nuclei population. 展开更多
关键词 αDecay Deformed Gamow-like model HALF-LIVES Extreme laser field Penetration probability
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Efficiency of a Modular Cleanroom for Space Applications
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作者 Matthew R.Coburn Charlie Young +3 位作者 Chris Smith Graham Schultz Miguel Robayo Zheng-Tong Xie 《Fluid Dynamics & Materials Processing》 EI 2024年第3期547-562,共16页
A prototype cleanroom for hazardous testing and handling of satellites prior to launcher encapsulation,satisfying the ISO8 standard has been designed and analyzed in terms of performances.Unsteady Reynolds Averaged Na... A prototype cleanroom for hazardous testing and handling of satellites prior to launcher encapsulation,satisfying the ISO8 standard has been designed and analyzed in terms of performances.Unsteady Reynolds Averaged Navier-Stokes(URANS)models have been used to study the related flow field and particulate matter(PM)dispersion.The outcomes of the URANS models have been validated through comparison with equivalent large-eddy simulations.Special attention has been paid to the location and shape of the air intakes and their orientation in space,in order to balance the PM convection and diffusion inside the cleanroom.Forming a cyclone-type flow pattern inside the cleanroom is a key to maintaining a high ventilation efficiency. 展开更多
关键词 DIFFUSER LES PM RANS unsteady flow exponential decay
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SHARP MORREY REGULARITY THEORY FOR A FOURTH ORDER GEOMETRICAL EQUATION
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作者 向长林 郑高峰 《Acta Mathematica Scientia》 SCIE CSCD 2024年第2期420-430,共11页
This paper is a continuation of recent work by Guo-Xiang-Zheng[10].We deduce the sharp Morrey regularity theory for weak solutions to the fourth order nonhomogeneous Lamm-Rivière equation △^{2}u=△(V▽u)+div(w▽... This paper is a continuation of recent work by Guo-Xiang-Zheng[10].We deduce the sharp Morrey regularity theory for weak solutions to the fourth order nonhomogeneous Lamm-Rivière equation △^{2}u=△(V▽u)+div(w▽u)+(▽ω+F)·▽u+f in B^(4),under the smallest regularity assumptions of V,ω,ω,F,where f belongs to some Morrey spaces.This work was motivated by many geometrical problems such as the flow of biharmonic mappings.Our results deepens the Lp type regularity theory of[10],and generalizes the work of Du,Kang and Wang[4]on a second order problem to our fourth order problems. 展开更多
关键词 fourth order elliptic equation regularity theory Morrey space decay estimates Riesz potential
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Overshoot phenomena:Observation and simulation
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作者 Ting Feng MoRan Liu +2 位作者 ShiMin He Xiang Wang Chen Zhou 《Earth and Planetary Physics》 EI CAS CSCD 2024年第2期391-399,共9页
High-power O-mode radio waves can excite artificial instabilities in the F region,according to experiments conducted at the European Incoherent Scatter Science Association(EISCAT)heating facility.The main instabilitie... High-power O-mode radio waves can excite artificial instabilities in the F region,according to experiments conducted at the European Incoherent Scatter Science Association(EISCAT)heating facility.The main instabilities include the parametric decay instability(PDI),oscillating two-stream instability(OTSI),and thermal parametric instability(TPI).The PDI and OTSI not only compete with each other,but also compete with the TPI,leading to a two-stage overshoot phenomenon:a miniovershoot occurs on a millisecond time scale after pump-on,followed by the main overshoot.We gain insight into the miniovershoot via a generalized Zakharov model,whereas the main overshoot can be observed as an enhanced plasma line overshoot phenomenon in incoherent scatter radar spectra.We can also observe that the zero-frequency ion line exists only in the initial heating period after a cold start and that the upshifted and downshifted ion lines behave irregularly in the spectra.The simulation results show that competition between the PDI and OTSI leads to an initial peak,which we named the pre-miniovershoot.The following processes,namely ion density caviton generation,and collapse and cascade in the development of the PDI,contribute to the miniovershoot phenomenon. 展开更多
关键词 OVERSHOOT parametric decay instability oscillating two-stream instability COMPETITION
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Estimation of surface geometry on combustion characteristics of AP/HTPB propellant under rapid depressurization
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作者 Kaixuan Chen Zhenwei Ye +1 位作者 Xiaochun Xue Yonggang Yu 《Defence Technology(防务技术)》 SCIE EI CAS CSCD 2024年第3期546-558,共13页
The 2D sandwich model serves as a potent tool in exploring the influence of surface geometry on the combustion attributes of Ammonium perchlorate/Hydroxyl-terminated polybutadiene(AP/HTPB)propellant under rapid pressu... The 2D sandwich model serves as a potent tool in exploring the influence of surface geometry on the combustion attributes of Ammonium perchlorate/Hydroxyl-terminated polybutadiene(AP/HTPB)propellant under rapid pressure decay.The thickness of the sandwich propellant is derived from slicing the 3D random particle packing,an approach that enables a more effective examination of the micro-flame structure.Comparative analysis of the predicted burning characteristics has been performed with experimental studies.The findings demonstrate a reasonable agreement,thereby validating the precision and soundness of the model.Based on the typical rapid depressurization environment of solid rocket motor(initial combustion pressure is 3 MPa and the maximum depressurization rate is 1000 MPa/s).A-type(a flatter surface),B-type(AP recesses from the combustion surface),and C-type(AP protrudes from the combustion surface)propellant combustion processes are numerically simulated.Upon comparison of the evolution of gas-phase flame between 0.1 and 1 ms,it is discerned that the flame strength and form created by the three sandwich models differ significantly at the beginning stage of depressurization,with the flame structures gradually becoming harmonized over time.Conclusions are drawn by comparison extinction times:the surface geometry plays a pivotal role in the combustion process,with AP protrusion favoring combustion the most. 展开更多
关键词 AP/HTPB propellant BDP model Rapid pressure decay Burning surface geometry
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THE OPTIMAL LARGE TIME BEHAVIOR OF 3D QUASILINEAR HYPERBOLIC EQUATIONS WITH NONLINEAR
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作者 王涵 张映辉 《Acta Mathematica Scientia》 SCIE CSCD 2024年第3期1064-1095,共32页
We are concerned with the large-time behavior of 3D quasilinear hyperbolic equations with nonlinear damping.The main novelty of this paper is two-fold.First,we prove the optimal decay rates of the second and third ord... We are concerned with the large-time behavior of 3D quasilinear hyperbolic equations with nonlinear damping.The main novelty of this paper is two-fold.First,we prove the optimal decay rates of the second and third order spatial derivatives of the solution,which are the same as those of the heat equation,and in particular,are faster than ones of previous related works.Second,for well-chosen initial data,we also show that the lower optimal L^(2) convergence rate of the k(∈[0,3])-order spatial derivatives of the solution is(1+t)^(-(2+2k)/4).Therefore,our decay rates are optimal in this sense.The proofs are based on the Fourier splitting method,low-frequency and high-frequency decomposition,and delicate energy estimates. 展开更多
关键词 quasilinear hyperbolic equations large time behavior optimal decay rates
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NνDEx-100 conceptual design report
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作者 Xi-Guang Cao Yan-Long Chang +35 位作者 Kai Chen Emilio Ciuffoli Li-Min Duan Dong-Liang Fang Chao-Song Gao Surja K.Ghorui Peng-Chong Hu Qiang Hu Si-Yuan Huang Ze-Yu Huang Lei Lang Yu-Lan Li Zhi-Jie Li Tian-Yu Liang Jun Liu Chen-Gui Lu Fa-Tai Mai Yuan Mei Hao Qiu Xiang-Ming Sun Xiao-Xing Tang Hu-Lin Wang Qian-Ming Wang Le Xiao Mu-Yun Xiao Jian-Yu Xin Nu Xu Peng Yang Yi-Chen Yang Zhen Yang Zong-Yang Yu Dong-Liang Zhang Jun-Wei Zhang Cheng-Xin Zhao Dou Zhu NνDEx-100 collaboration 《Nuclear Science and Techniques》 SCIE EI CAS CSCD 2024年第1期18-33,共16页
Observing nuclear neutrinoless double beta (0vββ) decay would be a revolutionary result in particle physics.Observing such a decay would prove that the neutrinos are their own antiparticles,help to study the absolut... Observing nuclear neutrinoless double beta (0vββ) decay would be a revolutionary result in particle physics.Observing such a decay would prove that the neutrinos are their own antiparticles,help to study the absolute mass of neutrinos,explore the origin of their mass,and may explain the matter-antimatter asymmetry in our universe by lepton number violation.We propose developing a time projection chamber (TPC) using high-pressure ^(82)SeF_(6) gas and Topmetal silicon sensors for readout in the China Jinping Underground Laboratory (CJPL) to search for neutrinoless double beta decay of82Se,called the NvDEx experiment.Besides being located at CJPL with the world’s thickest rock shielding,NvDEx combines the advantages of the high Qββ(2.996 MeV) of82Se and the TPC’s ability to distinguish signal and background events using their different topological characteristics.This makes NvDEx unique,with great potential for low-background and high-sensitivity 0 vββsearches.NvDEx-100,a NvDEx experiment phase with 100 kg of SeF_(6)gas,is being built,with plans to complete installation at CJPL by 2025.This report introduces 0 vββ physics,the NvDEx concept and its advantages,and the schematic design of NvDEx-100,its subsystems,and background and sensitivity estimation. 展开更多
关键词 Neutrinoless double beta decay Time projection chamber ^(82)SeF_(6) China Jinping Underground Laboratory
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Microbial Growth and Decay: A Commented Review of the Model
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作者 Alberto Schiraldi 《Advances in Microbiology》 CAS 2024年第1期1-10,共10页
The paper reviews previous publications and reports some comments about a semi empirical model of the growth and decay process of a planktonic microbial culture. After summarizing and reshaping some fundamental mathem... The paper reviews previous publications and reports some comments about a semi empirical model of the growth and decay process of a planktonic microbial culture. After summarizing and reshaping some fundamental mathematical expressions, the paper highlights the reasons for the choice of a suitable time origin that makes the parameters of the model self-consistent. Besides the potential applications to predictive microbiology studies and to effects of bactericidal drugs, the model allows a suitable proxy of the fitness of the microbial culture, which can be of interest for the studies on the evolution across some thousand generations of a Long Term Evolution Experiment. 展开更多
关键词 Microbial Cultures MODEL Time Scale Growth and Decay EVOLUTION
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Calculation of Particle Decay Times in the Standard Model
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作者 Jan Helm 《Journal of Modern Physics》 2024年第3期271-321,共51页
We present here a two-step method of classification and calculation for decay rates in the Standard Model. The first step is a phenomenological classification method, which is an extended and improved schematic experi... We present here a two-step method of classification and calculation for decay rates in the Standard Model. The first step is a phenomenological classification method, which is an extended and improved schematic experimental formula for decay width originally introduced by Chang. This schematic formula separates decays into seven classes. Furthermore, from it is derived a process-specific interaction energy m<sub>X</sub>. The second step is a numerical calculation method, which calculates this interaction energy m<sub>X</sub> numerically by minimization of action from the Lagrangian of the process, from which follows the decay width via the phenomenological formula. The Lagrangian is based on an extension of the Standard Model, the extended SU(4)-preon-model. A comparison of numerically calculated and observed decay widths for a large selection of decays shows a good agreement. 展开更多
关键词 Particle Decay Decay Width Interaction Energy Minimization of Action Ex-tension of Standard Model
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Global Existence and Decay of Solutions for a Class of a Pseudo-Parabolic Equation with Singular Potential and Logarithmic Nonlocal Source
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作者 Xiaoxin Yang 《Journal of Applied Mathematics and Physics》 2024年第1期181-193,共13页
This article investigates the well posedness and asymptotic behavior of Neumann initial boundary value problems for a class of pseudo-parabolic equations with singular potential and logarithmic nonlinearity. By utiliz... This article investigates the well posedness and asymptotic behavior of Neumann initial boundary value problems for a class of pseudo-parabolic equations with singular potential and logarithmic nonlinearity. By utilizing cut-off techniques and combining with the Faedo Galerkin approximation method, local solvability was established. Based on the potential well method and Hardy Sobolev inequality, derive the global existence of the solution. In addition, we also obtained the results of decay. 展开更多
关键词 Nonlocal Parabolic Equation Singular Potential Logarithmic Nonlocal Source Global Existence DECAY
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Hyperparameter Tuning for Deep Neural Networks Based Optimization Algorithm 被引量:2
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作者 D.Vidyabharathi V.Mohanraj 《Intelligent Automation & Soft Computing》 SCIE 2023年第6期2559-2573,共15页
For training the present Neural Network(NN)models,the standard technique is to utilize decaying Learning Rates(LR).While the majority of these techniques commence with a large LR,they will decay multiple times over ti... For training the present Neural Network(NN)models,the standard technique is to utilize decaying Learning Rates(LR).While the majority of these techniques commence with a large LR,they will decay multiple times over time.Decaying has been proved to enhance generalization as well as optimization.Other parameters,such as the network’s size,the number of hidden layers,drop-outs to avoid overfitting,batch size,and so on,are solely based on heuristics.This work has proposed Adaptive Teaching Learning Based(ATLB)Heuristic to identify the optimal hyperparameters for diverse networks.Here we consider three architec-tures Recurrent Neural Networks(RNN),Long Short Term Memory(LSTM),Bidirectional Long Short Term Memory(BiLSTM)of Deep Neural Networks for classification.The evaluation of the proposed ATLB is done through the various learning rate schedulers Cyclical Learning Rate(CLR),Hyperbolic Tangent Decay(HTD),and Toggle between Hyperbolic Tangent Decay and Triangular mode with Restarts(T-HTR)techniques.Experimental results have shown the performance improvement on the 20Newsgroup,Reuters Newswire and IMDB dataset. 展开更多
关键词 Deep learning deep neural network(DNN) learning rates(LR) recurrent neural network(RNN) cyclical learning rate(CLR) hyperbolic tangent decay(HTD) toggle between hyperbolic tangent decay and triangular mode with restarts(T-HTR) teaching learning based optimization(TLBO)
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Effects of sequential decay on collective flows and nuclear stopping power in heavy-ion collisions at intermediate energies 被引量:1
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作者 Kui Xiao Peng-Cheng Li +2 位作者 Yong-Jia Wang Fu-Hu Liu Qing-Feng Li 《Nuclear Science and Techniques》 SCIE EI CAS CSCD 2023年第4期175-184,共10页
In this study, the rapidity distribution, collective flows, and nuclear stopping power in ^(197)Au+^(197)Au collisions at intermediate energies were investigated using the ultrarelativistic quantum molecular dynamics(... In this study, the rapidity distribution, collective flows, and nuclear stopping power in ^(197)Au+^(197)Au collisions at intermediate energies were investigated using the ultrarelativistic quantum molecular dynamics(UrQMD) model with GEMINI++ code. The UrQMD model was adopted to simulate the dynamic evolution of heavy-ion collisions, whereas the GEMINI++ code was used to simulate the decay of primary fragments produced by UrQMD. The calculated results were compared with the INDRA and FOPI experimental data. It was found that the rapidity distribution, collective flows, and nuclear stopping power were affected to a certain extent by the decay of primary fragments, especially at lower beam energies. Furthermore, the experimental data of the collective flows and nuclear stopping power at the investigated beam energies were better reproduced when the sequential decay effect was included. 展开更多
关键词 Heavy-ion collisions Sequential decay effect Collective flow Nuclear stopping power
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Effects of methionine treatment on storage quality and antioxidant activity of postharvest jujube fruit
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作者 LIU Yao LEI Xing-meng +2 位作者 GUO Yu-xiao YAO Shi-xiang ZENG Kai-fang 《Journal of Integrative Agriculture》 SCIE CAS CSCD 2023年第9期2893-2904,共12页
Jujube fruits usually suffer from physiological disorders or infectious diseases during storage,leading to quality deterioration,softening,or rotting.Therefore,this study aims to investigate the effect of methionine s... Jujube fruits usually suffer from physiological disorders or infectious diseases during storage,leading to quality deterioration,softening,or rotting.Therefore,this study aims to investigate the effect of methionine soaking treatment on the postharvest jujube fruit decay rate and storage quality.Methionine treatment significantly reduced the decay rate of postharvest jujube fruit and effectively maintained fruit color and titratable acid.Methionine treatment effectively delayed the decrease of firmness,soluble solids,ascorbic acid,and lignin contents in jujube fruit.Methionine treatment reduced the content of alanine and phenylalanine,and increased the content of glycine in jujube fruit,but displayed no significant effect on total amino acid content.In addition,jujube fruits in the methionine treatment group had a higher total phenolic and flavonoid content and antioxidant capacity,both in free and bound forms.Compared with the control,methionine treatment also significantly increased the content of individual phenolic acid fractions(gallic acid,vanillic acid,and syringic acid)and flavonoid fractions(catechin,epicatechin,rutin)in free form as well as individual phenolic acid fractions in bound form(gallic acid and ferulic acid)in jujube fruits.Overall,this study suggested that the methionine treatment could be used as a prospective preservative to reduce the postharvest decay of jujube fruit and alleviate its nutritional quality deterioration during cold storage at 4°C. 展开更多
关键词 METHIONINE JUJUBE decay rate sensory quality nutritional value
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Competitive Redox Chemistries in Vanadium Niobium Oxide for Ultrafast and Durable Lithium Storage
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作者 Xiaobo Ding Jianhao Lin +2 位作者 Huiying Huang Bote Zhao Xunhui Xiong 《Nano-Micro Letters》 SCIE EI CAS CSCD 2023年第11期90-103,共14页
Niobium pentoxide(Nb_(2)O_(5))anodes have gained increasing attentions for high-power lithium-ion batteries owing to the outstanding rate capability and high safety.However,Nb2O5 anode suffers poor cycle stability eve... Niobium pentoxide(Nb_(2)O_(5))anodes have gained increasing attentions for high-power lithium-ion batteries owing to the outstanding rate capability and high safety.However,Nb2O5 anode suffers poor cycle stability even after modified and the unrevealed mechanisms have restricted the practical applications.Herein,the over-reduction of Nb5+has been demonstrated to be the critical reason for the capacity loss for the first time.Besides,an effective competitive redox strategy has been developed to solve the rapid capacity decay of Nb_(2)O_(5),which can be achieved by the incorporation of vanadium to form a new rutile VNbO_(4)anode.The highly reversible V^(3+)/V^(2+)redox couple in VNbO_(4)can effectively inhibit the over-reduction of Nb^(5+).Besides,the electron migration from V^(3+)to Nb5+can greatly increase the intrinsic electronic conductivity for VNbO4.As a result,VNbO4 anode delivers a high capacity of 206.1 mAh g^(−1)at 0.1 A g^(−1),as well as remarkable cycle performance with a retention of 93.4%after 2000 cycles at 1.0 A g^(−1).In addition,the assembled lithium-ion capacitor demonstrates a high energy density of 44 Wh kg^(−1)at 5.8 kW kg^(−1).In summary,our work provides a new insight into the design of ultra-fast and durable anodes. 展开更多
关键词 Niobium pentoxide Capacity decay Over-reduction Vanadium niobium oxide Lithium-ion capacitor
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