Formation and transformation of metastable LPSO building blocks clusters in Mg-Gd-Y-Zn-Zr alloys by spinodal decomposition and heterogeneous nucleation

To study the formation and transformation mechanism of long-period stacked ordered(LPSO)structures,a systematic atomic scale analysis was conducted for the structural evolution of long-period stacked ordered(LPSO)structures in the Mg-Gd-Y-Zn-Zr alloy annealed at 300℃~500℃.Various types of metastable LPSO building block clusters were found to exist in alloy structures at different temperatures,which precipitate during the solidification and homogenization process.The stability of Zn/Y clusters is explained by the first principles of density functional theory.The LPSO structure is distinguished by the arrangement of its different Zn/Y enriched LPSO structural units,which comprises local fcc stacking sequences upon a tightly packed plane.The presence of solute atoms causes local lattice distortion,thereby enabling the rearrangement of Mg atoms in the different configurations in the local lattice,and local HCP-FCC transitions occur between Mg and Zn atoms occupying the nearest neighbor positions.This finding indicates that LPSO structures can generate necessary Schockley partial dislocations on specific slip surfaces,providing direct evidence of the transition from 18R to 14H.Growth of the LPSO,devoid of any defects and non-coherent interfaces,was observed separately from other precipitated phases.As a result,the precipitation sequence of LPSO in the solidification stage was as follows:Zn/Ycluster+Mg layers→various metastable LPSO building block clusters→18R/24R LPSO;whereas the precipitation sequence of LPSO during homogenization treatment was observed to be as follows:18R LPSO→various metastable LPSO building block clusters→14H LPSO.Of these,14H LPSO was found to be the most thermodynamically stable structure.

Enhancing the Interaction of Carbon Nanotubes by Metal-Organic Decomposition with Improved Mechanical Strength and Ultra-Broadband EMI Shielding Performance

The remarkable properties of carbon nanotubes(CNTs)have led to promising applications in the field of electromagnetic inter-ference(EMI)shielding.However,for macroscopic CNT assemblies,such as CNT film,achieving high electrical and mechanical properties remains challenging,which heavily depends on the tube-tube interac-tions of CNTs.Herein,we develop a novel strategy based on metal-organic decomposition(MOD)to fabricate a flexible silver-carbon nanotube(Ag-CNT)film.The Ag particles are introduced in situ into the CNT film through annealing of MOD,leading to enhanced tube-tube interactions.As a result,the electrical conductivity of Ag-CNT film is up to 6.82×10^(5) S m^(-1),and the EMI shielding effectiveness of Ag-CNT film with a thickness of~7.8μm exceeds 66 dB in the ultra-broad frequency range(3-40 GHz).The tensile strength and Young’s modulus of Ag-CNT film increase from 30.09±3.14 to 76.06±6.20 MPa(~253%)and from 1.12±0.33 to 8.90±0.97 GPa(~795%),respectively.Moreover,the Ag-CNT film exhibits excellent near-field shield-ing performance,which can effectively block wireless transmission.This innovative approach provides an effective route to further apply macroscopic CNT assemblies to future portable and wearable electronic devices.

LD端面泵浦Tm:SrF_(2)电光调Q激光器

高掺杂浓度的Tm^(3+)增益介质能通过交叉弛豫过程提高激光器的量子效率,但同时也会增加能量上转换带来的损耗,从而限制激光器效率的进一步提升。对Tm:SrF_(2)晶体的荧光特性以及激光性能展开研究。在激光二极管(LD)端面泵浦下,实现最大功率2.99 W的自由运转输出,激光器的泵浦阈值为0.89 W,中心波长1851 nm,斜效率高达82.1%。采用KTP电光调Q开关演示了Tm:SrF_(2)激光器的电光调Q输出特性。在500 Hz重复频率下,获得了1.02 mJ的最大单脉冲能量,泵浦阈值为2.01 W,最短脉冲宽度为45 ns,对应峰值功率为22.67 kW。实验结果表明,基于LD泵浦的Tm:SrF_(2)激光器具有非常高的效率,有望成为中红外光学参量振荡器(OPO)和光学参量放大器(OPA)的理想泵浦源。

基于Twin Builder的110kV油浸式变压器3维磁场降阶模型及损耗分析

为解决3维变压器磁场有限元仿真计算效率低的问题,提出基于本征正交分解法的磁场降阶模型与基于二次多项式的损耗响应面模型。以1台110 kV变压器为算例,首先建立了考虑绕组涡流损耗的变压器磁场仿真模型,通过仿真分析了其在额定工况下的磁场及损耗分布;其次,通过仿真试验设计获取了多组工况下的磁场与损耗数据,在Twin Builder中训练得到变压器磁场的各降阶模块;最后,搭建面向数字孪生应用的变压器3维磁场降阶模型,实现了变压器磁场损耗的快速计算与云图分布的可视化。与计算单数据相比,仿真结果考虑了涡流效应的绕组损耗在靠近端部时有明显升高,最大值分别出现在高、低压绕组两端,约为绕组中部损耗的1.3~1.65倍。基于该磁场结果建立的降阶模型在计算效率方面较全阶模型有显著提升,将实际仿真时间缩短至0.76s,可满足数字孪生应用场景下的磁场快速计算需求。

Dynamic mode decomposition of the geomagnetic field over the last two decades

Earth’s magnetic field,which is generated in the liquid outer core through the dynamo action,undergoes changes on timescales of a few years to several million years,yet the underlying mechanisms responsible for the field variations remain to be elucidated.In this study,we apply a novel data analysis technique developed in fluid dynamics,namely the dynamic mode decomposition,to analyze the geomagnetic variations over the last two decades when continuous satellite observations are available.The dominant dynamic modes are extracted by solving an eigen-value problem,so one can identify modes with periods longer than the time span of data.Our analysis show that similar dynamic modes are extracted from the geomagnetic secular variation and secular acceleration,justifying the validity of applying the dynamic mode decomposition method to geomagnetic field.We reveal that the geomagnetic field variations are characterized by a global mode with period of 58 years,a localized mode with period of 16 years and an equatorially trapped mode with period of 8.5 years.These modes are possibly related to magnetohydrodynamic waves in the Earth’s outer core.

DE RHAM DECOMPOSITION FOR RIEMANNIAN MANIFOLDS WITH BOUNDARY

In this paper,we extend the classical de Rham decomposition theorem to the case of Riemannian manifolds with boundary by using the trick of the development of curves.

Helmholtz Decomposition of Vector Fields Using an Optimal Preconditioned Conjugate Gradient Algorithm

In this article, we study numerically a Helmholtz decomposition methodology, based on a formulation of the mathematical model as a saddle-point problem. We use a preconditioned conjugate gradient algorithm, applied to an associated operator equation of elliptic type, to solve the problem. To solve the elliptic partial differential equations, we use a second order mixed finite element approximation for discretization. We show, using 2-D synthetic vector fields, that this approach, yields very accurate solutions at a low computational cost compared to traditional methods with the same order of approximation.

A dynamic-mode-decomposition-based acceleration method for unsteady adjoint equations at low Reynolds numbers

The computational cost of unsteady adjoint equations remains high in adjoint-based unsteady aerodynamic op-timization.In this letter,the solution of unsteady adjoint equations is accelerated by dynamic mode decomposi-tion(DMD).The pseudo-time marching of every real-time step is approximated as an infinite-dimensional linear dynamical system.Thereafter,DMD is utilized to analyze the adjoint vectors sampled from these pseudo-time marching.First-order zero frequency mode is selected to accelerate the pseudo-time marching of unsteady adjoint equations in every real-time step.Through flow past a stationary circular cylinder and an unsteady aerodynamic shape optimization example,the efficiency of solving unsteady adjoint equations is significantly improved.Re-sults show that one hundred adjoint vectors contains enough information about the pseudo-time dynamics,and the adjoint dominant mode can be precisely predicted only by five snapshots produced from the adjoint vectors,which indicates DMD analysis for pseudo-time marching of unsteady adjoint equations is efficient.

Proper orthogonal decomposition based seismic source wavefield reconstruction for finite element reverse time migration

The large storage requirement is a critical issue in cross-correlation imaging-condition based reverse time migration(RTM),because it requires the operation of the source and receiver wavefields at the same time.The boundary value method(BVM),based on the finite difference method(FDM),can be used to reconstruct the source wavefield in the reverse time propagation in the same way as the receiver wavefield,which can reduce the storage burden of the RTM data.Considering that the FDM cannot well handle models with discontinuous material properties and rough interfaces,we develop a source wavefield reconstruction strategy based on the finite element method(FEM),using proper orthogonal decomposition(POD)to enhance computational efficiency.In this method,we divide the whole time period into several segments,and construct the POD basis functions to get a reduced order model(ROM)for the source wavefield reconstruction in each segment.We show the corresponding quantitative analysis of the storage requirement of the POD-FEM.Numerical tests on the homogeneous model show the effectiveness of the proposed method,while the layered model and part of the Marmousi model tests indicate that the POD-FEM can keep an excellent balance between computational efficiency and memory usage compared with the full-stored method(FSM)and the BVM,and can be effectively applied in imaging.

LD泵浦Nd:YAG晶体双波长和频激光器

通过激光二极管(LD)泵浦Nd:YAG产生1064 nm、1319 nm、1338 nm基频光,利用KTP晶体第二类相位匹配获得波长分别为589/593 nm的和频激光输出。从Nd:YAG晶体能级跃迁特性出发,揭示了Nd:YAG作为工作物质可以产1319/1338 nm激光的可能性。通过非线性光学转换频率及相关理论,分析了产生双波长和频输出的原理,同时也为多波长激光器的研究提供了参考。

Rate-limiting factors in hydrate decomposition through depressurization across various scales:A mini-review

Natural gas hydrate is an energy resource for methane that has a carbon quantity twice more than all traditional fossil fuels combined.However,their practical application in the field has been limited due to the challenges of long-term preparation,high costs and associated risks.Experimental studies,on the other hand,offer a safe and cost-effective means of exploring the mechanisms of hydrate dissociation and optimizing exploitation conditions.Gas hydrate decomposition is a complicated process along with intrinsic kinetics,mass transfer and heat transfer,which are the influencing factors for hydrate decomposition rate.The identification of the rate-limiting factor for hydrate dissociation during depressurization varies with the scale of the reservoir,making it challenging to extrapolate findings from laboratory experiments to the actual exploitation.This review aims to summarize current knowledge of investigations on hydrate decomposition on the subject of the research scale(core scale,middle scale,large scale and field tests)and to analyze determining factors for decomposition rate,considering the various research scales and their associated influencing factors.

Progress in the research on organic piezoelectric catalysts for dye decomposition

Organic contaminants have posed a direct and substantial risk to human wellness and the environment.In recent years,piezo-electric catalysis has evolved as a novel and effective method for decomposing these contaminants.Although piezoelectric materials offer a wide range of options,most related studies thus far have focused on inorganic materials and have paid little attention to organic materi-als.Organic materials have advantages,such as being lightweight,inexpensive,and easy to process,over inorganic materials.Therefore,this paper provides a comprehensive review of the progress made in the research on piezoelectric catalysis using organic materials,high-lighting their catalytic efficiency in addressing various pollutants.In addition,the applications of organic materials in piezoelectric cata-lysis for water decomposition to produce hydrogen,disinfect bacteria,treat tumors,and reduce carbon dioxide are presented.Finally,fu-ture developmental trends regarding the piezoelectric catalytic potential of organic materials are explored.

Generalized load graphical forecasting method based on modal decomposition

In a“low-carbon”context,the power load is affected by the coupling of multiple factors,which gradually evolves from the traditional“pure load”to the generalized load with the dual characteristics of“load+power supply.”Traditional time-series forecasting methods are no longer suitable owing to the complexity and uncertainty associated with generalized loads.From the perspective of image processing,this study proposes a graphical short-term prediction method for generalized loads based on modal decomposition.First,the datasets are normalized and feature-filtered by comparing the results of Xtreme gradient boosting,gradient boosted decision tree,and random forest algorithms.Subsequently,the generalized load data are decomposed into three sets of modalities by modal decomposition,and red,green,and blue(RGB)images are generated using them as the pixel values of the R,G,and B channels.The generated images are diversified,and an optimized DenseNet neural network was used for training and prediction.Finally,the base load,wind power,and photovoltaic power generation data are selected,and the characteristic curves of the generalized load scenarios under different permeabilities of wind power and photovoltaic power generation are obtained using the density-based spatial clustering of applications with noise algorithm.Based on the proposed graphical forecasting method,the feasibility of the generalized load graphical forecasting method is verified by comparing it with the traditional time-series forecasting method.

Efficient Direct Decomposition of NO over La_(0.8)A_(0.2)NiO_(3)(A=K, Ba, Y) Catalysts under Microwave Irradiation

La_(0.8)A_(0.2)NiO_(3) (A=K,Ba,Y) catalysts supported on the microwave-absorbing ceramic heating carrier were prepared by the sol-gel method.The crystalline phase and the catalytic activity of the La_(0.8)A_(0.2)NiO_(3)catalysts were characterized by XRD and H_(2) temperature-programmed reduction (TPR).The effects of reaction temperature,oxygen concentration,and gas flow rate on the direct decomposition of nitric oxide over the synthesized catalysts were studied under microwave irradiation (2.45 GHz).The XRD results indicated that the La_(0.8)A_(0.2)NiO_(3) catalysts formed an ABO_(3) perovskite structure,and the H_(2)-TPR results revealed that the relative reducibility of the catalysts increased in the order of La_(0.8)K_(0.2)NiO_(3)>La_(0.8)Ba_(0.2)NiO_(3)>La_(0.8)Y_(0.2)Ni O_(3).Under microwave irradiation,the highest NO conversion amounted to 98.9%,which was obtained with the La_(0.8)K_(0.2)NiO_(3) catalyst at 400℃.The oxygen concentration did not inhibit the NO decomposition on the La_(0.8)A_(0.2)NiO_(3) catalysts,thus the N_(2) selectivity exceeded 99.8%under excess oxygen at 550℃.The NOconversion of the La_(0.8)A_(0.2)NiO_(3) catalysts decreased linearly with the increase in the gas flow rate.

Facile preparation of Fe/N-based biomass porous carbon composite towards enhancing the thermal decomposition of DAP-4

Fe/N-based biomass porous carbon composite(Fe/N-p Carbon) was prepared by a facile high-temperature carbonization method from biomass,and the effect of Fe/N-p Carbon on the thermal decomposition of energetic molecular perovskite-based material DAP-4 was studied.Biomass porous carbonaceous materials was considered as the micro/nano support layers for in situ deposition of Fe/N precursors.Fe/Np Carbon was prepared simply by the high-temperature carbonization method.It was found that it showed the inherent catalysis properties for thermal decomposition of DAP-4.The heat release of DAP-4/Fe/N-p Carbon by DSC curves tested had increased slightly,compared from DAP-4/Fe/N-p Carbon-0.The decomposition temperature peak of DAP-4 at the presence of Fe/N-p Carbon had reduced by 79°C from384.4°C(pure DAP-4) to 305.4°C(DAP-4/Fe/N-p Carbon-3).The apparent activation energy of DAP-4thermal decomposition also had decreased by 29.1 J/mol.The possible catalytic decomposition mechanism of DAP-4 with Fe/N-p Carbon was proposed.

Reactive molecular dynamics insight into the thermal decomposition mechanism of 2,6-Bis(picrylamino)-3,5-dinitropyridine

2,6-bis(picrylamino)-3,5-dinitropyridine(PYX)has excellent thermostability,which makes its thermal decomposition mechanism receive much attention.In this paper,the mechanism of PYX thermal decomposition was investigated thoroughly by the ReaxFF-lg force field combined with DFT-B3LYP(6-311++G)method.The detailed decomposition mechanism,small-molecule product evolution,and cluster evolution of PYX were mainly analyzed.In the initial stage of decomposition,the intramolecular hydrogen transfer reaction and the formation of dimerized clusters are earlier than the denitration reaction.With the progress of the reaction,one side of the bitter amino group is removed from the pyridine ring,and then the pyridine ring is cleaved.The final products produced in the thermal decomposition process are CO_(2),H_(2)O,N_(2),and H_(2).Among them,H_(2)O has the earliest generation time,and the reaction rate constant(k_(3))is the largest.Many clusters are formed during the decomposition of PYX,and the formation,aggregation,and decomposition of these clusters are strongly affected by temperature.At low temperatures(2500 K-2750 K),many clusters are formed.At high temperatures(2750 K-3250 K),the clusters aggregate to form larger clusters.At 3500 K,the large clusters decompose and become small.In the late stage of the reaction,H and N in the clusters escaped almost entirely,but more O was trapped in the clusters,which affected the auto-oxidation process of PYX.PYX's initial decomposition activation energy(E_(a))was calculated to be 126.58 kJ/mol.This work contributes to a theoretical understanding of PYX's entire thermal decomposition process.

How can technology and efficiency alleviate the dilemma of economic growth and carbon emissions in China's industrial economy? A metafrontier decoupling decomposition analysis

This paper attempts to explore the decoupling relationship and its drivers between industrial economic increase and energy-related CO_(2) emissions(ICE). Firstly, the decoupling relationship was evaluated by Tapio index. Then, based on the DEA meta-frontier theory framework which taking into account the regional and industrial heterogeneity and index decomposition method, the driving factors of decoupling process were explored mainly from the view of technology and efficiency. The results show that during2000-2019, weak decoupling was the primary state. Investment scale expansion was the largest reason hindering decoupling process of industrial increase from ICE. Both energy saving and production technology achieved significant progress, which facilitated the decoupling process. Simultaneously, the energy technology gap and production technology gap among regions have been narrowed, and played a role in promoting decoupling process. On the contrary, both scale economy efficiency and pure technical efficiency have inhibiting effects on decoupling process. The former indicates that the scale economy of China's industry was not conducive to improve energy efficiency and production efficiency, while the latter indicates that resource misallocation problem may exist in both energy market and product market.

Enhanced Fourier Transform Using Wavelet Packet Decomposition

Many domains, including communication, signal processing, and image processing, use the Fourier Transform as a mathematical tool for signal analysis. Although it can analyze signals with steady and transitory properties, it has limits. The Wavelet Packet Decomposition (WPD) is a novel technique that we suggest in this study as a way to improve the Fourier Transform and get beyond these drawbacks. In this experiment, we specifically considered the utilization of Daubechies level 4 for the wavelet transformation. The choice of Daubechies level 4 was motivated by several reasons. Daubechies wavelets are known for their compact support, orthogonality, and good time-frequency localization. By choosing Daubechies level 4, we aimed to strike a balance between preserving important transient information and avoiding excessive noise or oversmoothing in the transformed signal. Then we compared the outcomes of our suggested approach to the conventional Fourier Transform using a non-stationary signal. The findings demonstrated that the suggested method offered a more accurate representation of non-stationary and transient signals in the frequency domain. Our method precisely showed a 12% reduction in MSE and a 3% rise in PSNR for the standard Fourier transform, as well as a 35% decrease in MSE and an 8% increase in PSNR for voice signals when compared to the traditional wavelet packet decomposition method.

Block Incremental Dense Tucker Decomposition with Application to Spatial and Temporal Analysis of Air Quality Data

How can we efficiently store and mine dynamically generated dense tensors for modeling the behavior of multidimensional dynamic data?Much of the multidimensional dynamic data in the real world is generated in the form of time-growing tensors.For example,air quality tensor data consists of multiple sensory values gathered from wide locations for a long time.Such data,accumulated over time,is redundant and consumes a lot ofmemory in its raw form.We need a way to efficiently store dynamically generated tensor data that increase over time and to model their behavior on demand between arbitrary time blocks.To this end,we propose a Block IncrementalDense Tucker Decomposition(BID-Tucker)method for efficient storage and on-demand modeling ofmultidimensional spatiotemporal data.Assuming that tensors come in unit blocks where only the time domain changes,our proposed BID-Tucker first slices the blocks into matrices and decomposes them via singular value decomposition(SVD).The SVDs of the time×space sliced matrices are stored instead of the raw tensor blocks to save space.When modeling from data is required at particular time blocks,the SVDs of corresponding time blocks are retrieved and incremented to be used for Tucker decomposition.The factor matrices and core tensor of the decomposed results can then be used for further data analysis.We compared our proposed BID-Tucker with D-Tucker,which our method extends,and vanilla Tucker decomposition.We show that our BID-Tucker is faster than both D-Tucker and vanilla Tucker decomposition and uses less memory for storage with a comparable reconstruction error.We applied our proposed BID-Tucker to model the spatial and temporal trends of air quality data collected in South Korea from 2018 to 2022.We were able to model the spatial and temporal air quality trends.We were also able to verify unusual events,such as chronic ozone alerts and large fire events.

Sparse Modal Decomposition Method Addressing Underdetermined Vortex-Induced Vibration Reconstruction Problem for Marine Risers

When investigating the vortex-induced vibration(VIV)of marine risers,extrapolating the dynamic response on the entire length based on limited sensor measurements is a crucial step in both laboratory experiments and fatigue monitoring of real risers.The problem is conventionally solved using the modal decomposition method,based on the principle that the response can be approximated by a weighted sum of limited vibration modes.However,the method is not valid when the problem is underdetermined,i.e.,the number of unknown mode weights is more than the number of known measurements.This study proposed a sparse modal decomposition method based on the compressed sensing theory and the Compressive Sampling Matching Pursuit(Co Sa MP)algorithm,exploiting the sparsity of VIV in the modal space.In the validation study based on high-order VIV experiment data,the proposed method successfully reconstructed the response using only seven acceleration measurements when the conventional methods failed.A primary advantage of the proposed method is that it offers a completely data-driven approach for the underdetermined VIV reconstruction problem,which is more favorable than existing model-dependent solutions for many practical applications such as riser structural health monitoring.