A series of novel ester-capped carbosilane dendrimers（G0-COOCH3–G2-COOCH3） were designed and successfully synthesized via a hybrid divergent–convergent method through a facile hydrosilylation reaction. The structu...A series of novel ester-capped carbosilane dendrimers（G0-COOCH3–G2-COOCH3） were designed and successfully synthesized via a hybrid divergent–convergent method through a facile hydrosilylation reaction. The structures of these dendrimers were confirmed by FTIR,1H NMR, and HRMS analyses.展开更多
An efficient synthesis of high generation conjugated polyphenylene dendrimer-based β-diketones was investi- gated using simple synthetic methods. The new dendrimer-based β-diketones were characterized by NMR, MS and...An efficient synthesis of high generation conjugated polyphenylene dendrimer-based β-diketones was investi- gated using simple synthetic methods. The new dendrimer-based β-diketones were characterized by NMR, MS and elemental analysis. The UV-Vis and fluorescence spectra of these β-diketones in different solvents were investigated The photoluminescent （PL） quantum yield and TG and DSC curves were also investigated. A new intermediate, 1-bromo-3,5-diiodobenzene, was developed to synthesize high generation dendrimers with good yields.展开更多
基金support by the National Natural Science Foundation of China(No.21307053)China Postdoctoral Science Foundation Funded Project(No.2013M541911)+1 种基金Promotive Research Fund for Excellent Young and Middle-Aged Scientists of Shandong Province(No.BS2013CL044)Natural Science Foundation of Ludong University(No.LY2011004)
文摘A series of novel ester-capped carbosilane dendrimers（G0-COOCH3–G2-COOCH3） were designed and successfully synthesized via a hybrid divergent–convergent method through a facile hydrosilylation reaction. The structures of these dendrimers were confirmed by FTIR,1H NMR, and HRMS analyses.
文摘An efficient synthesis of high generation conjugated polyphenylene dendrimer-based β-diketones was investi- gated using simple synthetic methods. The new dendrimer-based β-diketones were characterized by NMR, MS and elemental analysis. The UV-Vis and fluorescence spectra of these β-diketones in different solvents were investigated The photoluminescent （PL） quantum yield and TG and DSC curves were also investigated. A new intermediate, 1-bromo-3,5-diiodobenzene, was developed to synthesize high generation dendrimers with good yields.
