Grain growth kinetics and densification mechanism of(TiZrHfVNbTa)C high-entropy ceramic under pressureless sintering

The grain growth kinetics and densification mechanism of(TiZrHfVNbTa)C high-entropy carbide ceramic are investigated in this work.A single phase carbide with a rock-salt structure is formed until 2300°C,below which an apparent aggregation of V,Zr and Hf exists.It is associated with the slow diffusion rate of V element as well as the relatively poor solubility of VC in HfC(as well as ZrC).The grain growth mechanism gradually changes from surface diffusion to volume diffusion and then grain boundary diffusion with increasing sintering temperature.This is attributed to the variation of activation energy of grain growth.The densification mechanism is principally dominated by the mass transport through lattice diffusion with the activation energy of 839±53 k J/mol.Through the design of two-step sintering,it is verified that the solid solution formation can effectively promote the densification process.

Mechanical densification synthesis of single-crystalline Ni-rich cathode for high-energy lithium-ion batteries

The intergranular microcracking in polycrystalline Ni-rich cathode particle is led by anisotropic volume change and stress corrosion along grain boundary,accelerating battery performance decay.Herein,we have suggested a simple but advanced solid-state method that ensures both uniform transition metal distribution and single-crystalline morphology for Ni-rich cathode synthesis without sophisticated coprecipitation.Pelletization-assisted mechanical densification(PAMD)process on solid-state precursor mixture enables the dynamic mass transfer through the increased solid-solid contact area which facilitates the grain growth during sintering process,readily forming micro-sized single-crystalline particle.Furthermore,the improved chemical reactivity by a combination of capillary effect and vacancyassisted diffusion provides homogeneous element distribution within each primary particle.As a result,single-crystalline Ni-rich cathode with PAMD process has eliminated a potential evolution of intergranular cracking,thus achieving superior energy retention capability of 85%over 150 cycles compared to polycrystalline Ni-rich particle even after high-pressure calendering process(corresponding to electrode density of~3.6 g cm^(-3))and high cut-off voltage cycling.This work provides a concrete perspective on developing facile synthetic route of micron-sized single-crystalline Ni-rich cathode materials for high energy density lithium-ion batteries(LIBs).

Deformation and Densification Laws of Powder Cold Forging

The deformation and densification laws of preform upsetting and closed-die forging were researched based on experimental results of cold forging of deoxidized Fe powder sintering porous material under different initial conditions such as friction factor, ratio between height and diameter and relative density. The fracture limit criteria＂ for powder cold-forging upsetting and the limit strain curve were achieved. The effect of friction facto,, ratlt, between height and diameter and relative density on fracture strain limitation was emphatically analyzed. The limit process parameter curves for the deformation of upsetting were also confirmed. Laws of deformation, densification and density distribution for closed-die forging of powder perform during cold-forging were further analyzed and discussed with the help of experimental phase analysis. As a result, this experiment established theoretical foundations for the design of preform and die as well as optimization of technological process parameters.

Improving Densification and Mechanical Properties of FeAl/TiC Composites by Addition of Ni

FeAl/TiC composites were fabricated by hot pressing blended elemental powders. The effects of Ni-doping on thedensification and mechanical properties of the composites were studied. Results show that the density of the composites decreases with the content of TiC increasing, and the addition of Ni significantly improves the densificationprocess by enhancing mass transfer in the bonding phase. The mechanical properties of the composites are closelyrelated with their porosity. Besides increasing the density of the composites, the addition of Ni improves the mechanical properties by other three effects: solution-strengthening the bonding phase, strengthening the FeAI-TiC interfaceand increasing ductile fracture in FeAl phase.

Creep deformation behavior during densification of ZrB_(2)-SiBCN ceramics with ZrO_(2) additive

ZrB_(2)-SiBCN ceramics with ZrO_(2) additive are hot-pressed under a constant applied pressure.The densification behavior of the composites is studied in a view of creep deformation by means of the Bernard-Granger and Guizard model.With determination of the stress exponent(n)and the apparent activation energy(Q_(d)),the specific deformation mechanisms controlling densification are supposed.Within lower temperature ranges of 1300-1400℃,the operative mechanism is considered to be grain boundary sliding accommodated by atom diffusion of the polymer-derived SiBCN(n=1,Q_(d)=123±5 kJ/mol)and by viscous flow of the amorphous SiBCN(n=2,Qd=249±5 kJ/mol).At higher temperatures,the controlling mechanism transforms to lattice or intra-granular diffusion creep(n=3-5)due to gradual consumption of the amorphous phase.It is suggested that diffusion of oxygen ions inside ZrO_(2) into the amorphous SiBCN decreases the viscosity,modifies the fluidity,and contributes to the grain boundary mobility.

Sintering kinetics involving grain growth and densification of Mg-PSZ nanopowders

Sintering kinetics have been found to be effective in judging the evolution of ceramics.By using magnesium oxide-partially stabilized zirconia(Mg-PSZ)powder prepared by co-precipitation as raw materials,the evolution of densification and grain growth for Mg-PSZ ceramics were investigated.The results indicated that the densification of samples was mainly controlled by grain boundary diffusion in intermediate sintering stage.During the sintering process,the grain growth mechanisms included normal grain growth,abnormal grain growth and solid solution drag-controlled grain growth.Interestingly,the apparent activation energy for grain growth of Mg-PSZ ceramics is lower than that of ZrO_(2)–Y_(2)O_(3)ceramics in the solid solution drag-controlled grain grow process,which will cause grain to grow easily.The sintering kinetics and microstructure of Mg-PSZ ceramics were studied,and the kinetic equation of grain growth at different temperatures was established.The results show that the strength difference between Mg-PSZ and yttrium oxide-stabilized zirconia is closely related to the easy grain growth of Mg-PSZ ceramics.

Physical study on the vibrated packing densification of mono-sized cylindrical particles

Systematic physical experiments examining the packing densification of mono-sized cylindrical parti- cles subject to 3D mechanical vibration were carried out. The influence of vibration conditions such as vibration time, frequency, amplitude, vibration strength, container size, and the aspect ratio and spheric- ity of the particle on the packing density were analyzed and discussed. For each initial packing density with a certain aspect ratio, operating parameters were optimized to achieve much denser packing. The results indicate that the packing density initially increases with vibration time and then remains con- stant. The effects of vibration frequency and amplitude on the packing densification have similar trends, i.e. the packing density first increases with the vibration frequency or amplitude to a high value and then decreases; too large or small frequency or amplitude does not enhance densification. Increasing the container size can reduce container wall effects and help achieve a high packing density. Varying the particle aspect ratio and sphericity can lead to different dense random packing structures. Overall, based on results of the examined systems, the highest random packing density obtained in an infinite sized container can reach 0.73, which agrees well with corresponding numerical and analytical results in the literature.