基于^(13)C-NMR偶极去相技术的有机肥料中有机组分特征研究

【目的】在固体13C-NMR的交叉极化魔角旋转全边带抑制(cross polarization/magic angle spinning/total suppression of sidebands,CP/MAS/TOSS)技术得到的谱图中,质子碳与非质子碳的信号重叠。偶极去相(dipolar dephasing,DD)技术利用13C-1H异核耦合作用大小的差异,区分与不同质子结合的13C核基团。本研究基于DD技术探讨有机肥料中碳结构特征。【方法】供试有机肥料样品包括3种秸秆(小麦秸秆、玉米秸秆、水稻秸秆)、3种粪肥(鸡粪、牛粪、猪粪)和3种腐植酸肥(腐植酸铵、腐植酸钠、腐植酸钾)样品,利用13C-NMR谱的CP/MAS/TOSS结合DD技术,测定了不同来源的有机肥料样品图谱,比较其碳分布比例。【结果】秸秆和粪肥样品中烷氧碳组分较多,占鉴定出所有碳组分的比例分别为55%和31%~37%,非质子化的烷氧碳占比不到3%;秸秆、猪粪样品中非质子芳香碳占3%~4%,鸡粪和牛粪样品中非质子芳香碳分别占15%和11%,较秸秆和猪粪样品含有更多的非质子化芳香族化合物。粪肥和秸秆样品中甲氧基碳占比低于烷基氮。腐植酸样品以芳香碳、羧基碳和酰胺基碳为主,羧基碳和酰胺基碳占到12%~16%,总芳香族碳占48%~72%,非质子芳香碳占25%~37%,表明腐植酸芳香骨架上可能存在较多取代。【结论】基于CP/TOSS结合DD技术(偶极相移延时时间设置为40μs)分析结果发现,鸡粪和牛粪中非质子芳香碳占比高于猪粪和秸秆;腐植酸肥芳香族碳比例高于粪肥和秸秆,尤其是非质子芳香碳占比较高,表明腐植酸肥芳香化程度高于粪肥和秸秆。

Tunneling Electrons Triggered Energy Transfer between Coherently Coupled Donor-Acceptor Molecules

Energy transfer is ubiquitous in natural and artificial lightharvesting systems,and coherent energy transfer,a highly efficient energy transfer process,has been accepted to play a vital role in such systems.However,the energy oscillation of coherent energy transfer is exceedingly difficult to capture because of its evanescence due to the interaction with a thermal environment.Here a microscopic quantum model is used to study the time evolution of electrons triggered energy transfer between coherently coupled donoracceptor molecules in scanning tunneling microscope(STM).A series of topics in the plasmonic nanocavity(PNC)coupled donor-acceptor molecules system are discussed,including resonant and nonresonant coherent energy transfer,dephasing assisted energy transfer,PNC coupling strength dependent energy transfer,Fano resonance of coherently coupled donor-acceptor molecules,and polariton-mediated energy transfer.

Simultaneous measurements of global vibrational spectra and dephasing times of molecular vibrational modes by broadband time-resolved coherent anti-Stokes Raman scattering spectrography

In broadband coherent anti-Stokes Raman scattering （CARS） spectroscopy with supercontinuum （SC）, the simultaneously detectable spectral coverage is limited by the spectral continuity and the simultaneity of various spectral components of SC in an enough bandwidth. By numerical simulations, the optimal experimental conditions for improving the SC are obtained. The broadband time-resolved CARS spectrography based on the SC with required temporal and spectral distributions is realised. The global molecular vibrational spectrum with well suppressed nonresonant background noise can be obtained in a single measurement. At the same time, the measurements of dephasing times of various molecular vibrational modes can be conveniently achieved from intensities of a sequence of time-resolved CARS signals. It will be more helpful to provide a complete picture of molecular vibrations, and to exhibit a potential to understand not only both the solvent dynamics and the solute-solvent interactions, but also the mechanisms of chemical reactions in the fields of biology, chemistry and material science.

Robust Quantum Secure Direct Communication and Deterministic Secure Quantum Communication over Collective Dephasing Noisy Channel

We propose two schemes for quantum secure direct communication (QSDC) and deterministic securequantum communication (DSQC) over collective dephasing noisy channel.In our schemes,four special two-qubit statesare used as the quantum channel.Since these states are unchanged through the collective dephasing noisy channel,the effect of the channel noise can be perfectly overcome.Simultaneously,the security against some usual attacks canbe ensured by utilizing the various checking procedures.Furthermore,these two schemes are feasible with present-daytechnique.

Robustness of Genuine Tripartite Entanglement under Collective Dephasing

We study the robustness of genuine multipartite entanglement for a system of three qubits under collective dephasing. Using a computable entanglement monotone for multipartite systems, we find that almost every state is quite robust under this type of decoherence. We analyze random states and weighted graph states at infinity and find all of them to be genuinely entangled.

Entanglement and non-Markovianity of a spin-S system in a dephasing environment

We study the entanglement （measured by negativity） evolution and the non-Markovianity for the dynamical process of a spin-S system embedded in dephasing environments. The exact analytical solution is presented, which shows that the decoherence function governs the evolutions of coherence, entanglement, and the non-Markovianity of the correspond- ing dynamical processes. For Ohmic and sub-Ohmic reservoirs, the negativity decreases monotonically in time and the corresponding dynamics is Markovian. While for super-Ohmic reservoirs with non-monotonic decoherence function, the negativity appears as the phenomenon of revival and the corresponding dynamics is non-Markovian. The relation between non-Markovianity and the system dimension is studied.

Role of phase fluctuation and dephasing in the enhancing continuous variable entanglement of a two-photon coherent beat laser

A steady state analysis of the nonclassical features and statistical properties of the cavity radiation of a two- photon coherent beat laser is presented. Results show that the degree of two-mode squeezing, detectable entanglement and intensity of the cavity radiation can increase with the deviation of the phase fluctuations of the laser employed in preparing the atoms, but decrease with the increasing rate at which the induced coherence superposition decays. Although it is found that varying the phase fluctuations and dephasing can lead to modification in the quantum features and statistical properties of the radiation, it does not alter the similarity in the nature of the degree of entanglement detectable by the criteria following from Duan-Giedke-Cirac Zoller and logarithmic negativity in a perceivable manner. Since the intensity and quantum features can be readily enhanced, this system is expected to be a viable source of a strong robust entangled （squeezed） light under various conditions. Moreover, comparison of the mean number of photon pairs with intensity difference shows that the chance of inciting a two-photon process can be enhanced by changing the rate of dephasing and phase fluctuations.

Optical Bloch Equations Modified with Phonon-Induced Intensity-Dependent Dephasing

We extend the exciton population equations of a two-level quantum dot system with weak excitation to the ones with strong excitations, in which, the phonon-induced intensity-dependent dephasing time and decay rate are involved. The straightforward calculated populations from the modified population equations demonstrate the damping behavior of Rabi oscillation as the external field increasing. The effect of the intensity-dependent dephasing time and the intensity-dependent decay rate are also discussed.

Quantum parameter estimation in a spin-boson dephasing quantum system by periodical projective measurements

In this paper,we explore how to estimate the phase damping parameter γ and the tunneling amplitude parameter ？from a spin-boson dephasing quantum model by periodical projective measurements.The preparation of initial states is accomplished by performing the period measurements in our scheme.The parameter γ can be always estimated when projective measurement bases are chosen as θ = π/2 and φ = 0.Based on the estimated value of γ and the interval information of ？,we can select another measurement bases（θ = π/4 and φ = π/2） to obtain the estimated value of ？.A coherent control is indispensable to estimate ？ if γ is in the interval of ？;whereas the control is not necessary if γ is out of the known interval of ？.We establish the relation between the optimal period time and the parameter γ or ？ in terms of Fisher information.Although the optimal measurement period cannot be selected beforehand,the aforementioned relation can be utilized to adjust the measurement period to approach the optimal one.

Quantum speed limit of the double quantum dot in pure dephasing environment under measurement

The quantum speed limit(QSL)of the double quantum dot(DQD)system has been theoretically investigated by adopting the detection of the quantum point contact(QPC)in the pure dephasing environment.The Mandelstam–Tamm(MT)type of the QSL bound which is based on the trace distance has been extended to the DQD system for calculating the shortest evolving time.The increase of decoherence rate can weaken the capacity for potential speedup(CPS)and delay the evolving process due to the frequently measurement localizing the electron in the DQD system.The system needs longer time to evolve to the target state as the enhancement of dephasing rate,because the strong interaction between pure dephasing environment and the DQD system could vary the oscillation of the electron.Increasing the dephasing rate can sharp the QSL bound,but the decoherence rate would weaken the former effect and vice versa.Moreover,the CPS would be raised by increasing the energy displacement,while the enhancement of the coupling strength between two quantum dots can diminish it.It is interesting that there has an inflection point,when the coupling strength is less than the value of the point,the increasing effect of the CPS from the energy displacement is dominant,otherwise the decreasing tendency of the CPS is determined by the coupling strength and suppress the action of the energy displacement if the coupling strength is greater than the point.Our results provide theoretical reference for studying the QSL time in a semiconductor device affected by numerous factors.

Dephasing of quantum tunnelling in molecular nanomagnets

Dephasing mechanism of quantum tunnelling in molecular magnets has been studied by means of the spin-coherentstate path integral in a mean field approximation. It is found that the fluctuating uncompensated transverse field from the dipolar-dipolar interaction between molecular magnets contributes a random phase to the quantum interference phase. The resulting transition rate is determined by the average tunnel splitting over the random phase. Such a dephasing process leads to the suppression of quenching due to the quantum phase interference, and to the steps due to odd resonances in hysteresis loop survived, which is in good agreement with experimental observations in molecular nanomagnets Fes and Mn12.

Dynamics of Entanglement of Qutrit-Qutrit States with Stochastic Dephasing

The effect of stochastic dephasing on the dynamics of entanglement of qutrit-qutrit states is investigated by using negativity and bound entanglement defined with realignment criterion, From the analysis, we, find that the time evolution of quantum free entanglement and bound entanglement depends on the fluctuations of the stochastic variables and the parameters of the particular initial states of concern. Our results imply that some qutrits states display both distillability sudden death and entanglement sudden death, while some states do not display distillability sudden death but only entanglement sudden death.

Geometric Phases Corrected by Stochastic Dephasing

We analyze the effect of stochastic dephasing on geometric phases. The result implies that the correction of geometric phases relies on not only the fluctuation of the random variable in the stochastic process, but also the frequency of the system.

Disentanglement of Qubit in Dephasing Model

We investigate the entanglement evolution of two qubits that are initially in Werner state under the classical phase noise. We discuss the influence of mixture degree on disentanglement. It is showed that the more mixed the state, the shorter is the time of disentanglement.

联合退相位噪声下量子囚徒困境纳什均衡分析

为讨论量子囚徒困境模型在联合退相位噪声信道影响下纳什均衡策略情况,将联合退相位噪声引入到量子博弈中,通过MW量子化方案对囚徒困境博弈模型进行量子化,建立了联合退相位噪声信道下的量子囚徒困境博弈模型。通过讨论发现,在最大纠缠的条件下,参与者的收益关于噪声参数呈现出周期性的变化,且在同一周期内,随着噪声参数的增长,量子囚徒困境在不同的噪声区间出现了存在唯一纯量子纳什均衡解、两个纯量子纳什均衡解和没有纯量子的纳什均衡解的情况,在没有纯量子均衡解的两个噪声区间中,参与者会陷入类似于石头剪刀布的循环之中。说明在联合退相位噪声信道影响下,当噪声参数属于特定噪声区间时,参与者可以达成纳什均衡。

Hygrothermal Study of a House Made of Local Biosourced Materials Based on Clay: Experimental Study

The purpose of this study is to experimentally analyze the thermal behavior of the walls of a prototype experimental house. A Datalogger and thermocouples were used on the experimental house to determine the temperatures of the exterior and interior walls. Also, “MSR” type HygroPuce was used to determine the exterior and interior temperatures and relative humidity of the habitat. The results show that a wall made of bio-based materials with a mixture of “earth + Hibiscus cannabinus L. fibers” allows reducing the fluctuations of the interior temperatures. We observe the peaks of temperatures on the external walls at 11:00 am and for the interior walls, the peaks are observed at 5:00 pm. The maximum thermal phase shift between the peaks of the external and internal temperatures is about 7.5 hours, and the maximum damping factor is 0.9. Also, we note that the thermal performance of the material used in the design of the envelope of the house is determined by the improvement of the response of the envelope in front of the external thermal solicitations.

中红外连续波单谐振光学参量振荡器热致相位失配

为了研究热致相位失配对中红外连续波单谐振光学参量振荡器(CW-SRO)输出效率的影响,结合CW-SRO计算模型和热传导方程,利用有限元分析方法,重点对输出3.3μm波长闲频光的CW-SRO进行了分析。计算了不同信号光输出耦合率及不同泵浦功率下CW-SRO晶体输出截面上热致相位失配量的分布。由计算结果可以看出:晶体吸收腔中振荡信号光是导致晶体热效应的主要因素;在相同的输入条件下,泵浦功率在30 W以上时CW-SRO的热致相位失配将会大大降低其泵浦损耗率;通过增加信号光输出耦合率的方法,可以减少热致相位失配对CW-SRO输出效率的影响,但CW-SRO的振荡阈值会增加。

样品弛豫时间对核磁共振信号的影响研究

研究了不同浓度CuSiO4水溶液样品的核磁共振信号的特点,讨论了在特定的磁场扫场周期下,样品横向弛豫时间对共振信号的影响.发现当样品的横向弛豫时间远远大于扫场周期时,微观磁矩的退相是造成核磁共振信号衰减的主要因素,此时在共振点前后都会形成周期性的振荡信号.

双色场相位平缓对远场前向太赫兹的增强

太赫兹辐射极性和幅度依赖于双色场相位。由于等离子体光丝中色散和Gouy相移,导致双色场的相对相位随着激光的传播发生改变。当相位的改变量大于π时,丝中的太赫兹电场极性发生反转,使得远场太赫兹辐射在离轴相位匹配角方向相干增强,而光轴前向相消减弱。通过对基频和倍频聚焦条件的调整和传输非线性色散的作用对双色场相对相位进行了调制,提出了可以使相对相位平缓的方法。模型计算证明了等离子体形成和Gouy相移调制是使双色场相移变平缓的原因。随后利用相位变平缓的条件得到了太赫兹发生极性反转的失相长度延长,最大长度近三倍于空气介质中的失相长度。在满足相位变平的条件下,远场太赫兹辐射在光轴前向的分布得到增强。

若干参数对瞬态电磁感应透明的影响

研究了原子梯形三能级系统的瞬态电磁感应透明特性 ,分析了系统各种参数 ,诸如瞬态作用时间、泵浦场和探测场的拉比频率、激光线宽及消相碰撞等因素对瞬态电磁感应透明的影响。结果表明 :在不考虑激光线宽及消相碰撞时 ,探测场的吸收随时间在零吸收附近作类似于阻尼减幅振荡 ,系统可实现无反转放大 ;随着泵浦场的拉比频率的减小及上能级驰豫速率的增大 ,感应透明将减弱。在考虑到激光线宽及消相碰撞等非相干因素时 ,对于一定的瞬态作用时间 ,感应透明将随着探测场拉比频率的增大而减弱。