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押金返还制度下再制造闭环供应链的非合作-合作两型博弈模型
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作者 魏骊晓 李登峰 《管理工程学报》 CSCD 北大核心 2024年第4期283-301,共19页
针对两个制造商和一个回收商组成的再制造闭环供应链,本文构建了一个连续型非合作-合作两型博弈模型,研究制造商的定价策略及制造商与回收商的利润共享问题。本文首先在非合作博弈部分以制造商的销售价格为策略形成竞争局势,其次通过冯&... 针对两个制造商和一个回收商组成的再制造闭环供应链,本文构建了一个连续型非合作-合作两型博弈模型,研究制造商的定价策略及制造商与回收商的利润共享问题。本文首先在非合作博弈部分以制造商的销售价格为策略形成竞争局势,其次通过冯·诺伊曼方法确定合作博弈联盟的特征函数,利用Shapley值进行利润分配得到制造商和回收商的利润,然后将制造商分配得到的利润作为非合作博弈部分的支付函数,求解得到Nash均衡策略及最优利润。本文构建的非合作-合作两型博弈显著特点为非合作博弈部分局中人的策略为连续型且支付函数需要通过合作博弈部分确定,合作博弈部分局中人与非合作博弈部分的局中人不完全相同。本文通过对竞争模式、合作模式的对比分析说明了建立的非合作-合作两型博弈模型的合理性与有效性。最后,本文分析产品替代系数、回收难度系数和成本优势等参数对均衡定价策略及利润的影响,通过数值实例说明了政府收取制造商的单位押金对销售价格及利润的影响,为政府制定与实施押金返还制度提供合理建议。 展开更多
关键词 闭环供应链 再制造 利润共享 非合作-合作两型博弈 押金返还制度
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An aqueous BiI_(3)-Zn battery with dual mechanisms of Zn^(2+)(de)intercalation and I^(-)/I_(2)redox
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作者 Qi Deng Fangzhong Liu +3 位作者 Xiongwei Wu Changzhu Li Weibin Zhou Bei Long 《Journal of Energy Chemistry》 SCIE EI CAS CSCD 2024年第2期670-678,I0014,共10页
The development of aqueous battery with dual mechanisms is now arousing more and more interest.The dual mechanisms of Zn^(2+)(de)intercalation and I^(-)/I_(2)redox bring unexpected effects.Herein,differing from previo... The development of aqueous battery with dual mechanisms is now arousing more and more interest.The dual mechanisms of Zn^(2+)(de)intercalation and I^(-)/I_(2)redox bring unexpected effects.Herein,differing from previous studies using Zn I_(2)additive,this work designs an aqueous Bi I_(3)-Zn battery with selfsupplied I^(-).Ex situ tests reveal the conversion of Bi I_(3)into Bi(discharge)and Bi OI(charge)at the 1st cycle and the dissolved I^(-)in electrolyte.The active I^(-)species enhances the specific capacity and discharge medium voltage of electrode as well as improves the generation of Zn dendrite and by-product.Furthermore,the porous hard carbon is introduced to enhance the electronic/ionic conductivity and adsorb iodine species,proven by experimental and theoretical studies.Accordingly,the well-designed Bi I_(3)-Zn battery delivers a high reversible capacity of 182 m A h g^(-1)at 0.2 A g^(-1),an excellent rate capability with 88 m A h g^(-1)at 10 A g^(-1),and an impressive cyclability with 63%capacity retention over 20 K cycles at 10 A g^(-1).An excellent electrochemical performance is obtained even at a high mass loading of 6 mg cm^(-2).Moreover,a flexible quasi-solid-state Bi I_(3)-Zn battery exhibits satisfactory battery performances.This work provides a new idea for designing high-performance aqueous battery with dual mechanisms. 展开更多
关键词 Aqueous BiI_(3)-Zn battery Dual mechanisms I^(-)-induced uniform zinc deposition Ultralong cyclic life Flexible quasi-solid-state battery
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Re–Os dating of molybdenite and in-situ Pb isotopes of sulfides from the Lamo Zn–Cu deposit in the Dachang tin-polymetallic ore field, Guangxi, China 被引量:11
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作者 Hai Zhao Wenchao Su +5 位作者 Peng Xie Nengping Shen Jiali Cai Ming Luo Jie Li Zhian Bao 《Acta Geochimica》 EI CAS CSCD 2018年第3期384-394,共11页
The Dachang tin-polymetallic district, Guangxi,China, is one of the largest tin ore fields in the world. Both cassiterite-sulfide and Zn–Cu skarn mineralization are hosted in the Mid-Upper Devonian carbonate-rich sed... The Dachang tin-polymetallic district, Guangxi,China, is one of the largest tin ore fields in the world. Both cassiterite-sulfide and Zn–Cu skarn mineralization are hosted in the Mid-Upper Devonian carbonate-rich sediments adjacent to the underlying Cretaceous Longxianggai granite(91–97 Ma). The Lamo Zn–Cu deposit is a typical skarn deposit in the district and occurs at the contact zone between the Upper Devonian limestone and the granite.The ore minerals mainly consist of sphalerite, arsenopyrite,pyrrhotite, galena, chalcopyrite, and minor molybdenite.However, the age of mineralization and source of the metals are not well constrained. In this study, we use the molybdenite Re–Os dating method and in-situ Pb isotopes of sulfides from the Lamo deposit for the first time in order to directly determine the age of mineralization and the tracing source of metals. Six molybdenite samples yielded a more accurate Re–Os isochron age of 90.0 ± 1.1 Ma(MSWD = 0.72), which is much younger than the reported garnet Sm–Nd isochron age of 95 ± 11 Ma and quartz fluid inclusions Rb–Sr isochron age of 99 ± 6 Ma. This age is also interpreted as the age of Zn–Cu skarn mineralization in the Dachang district. Further, in this study we found that in-situ Pb isotopes of sulfides from the Lamo deposit and feldspars in the district's biotite granite and granitic porphyry dikes have a narrow range and an overlap of Pb isotopic compositions(^(206) Pb/^(204) Pb =18.417–18.594,^(207) Pb/^(204) Pb = 15.641–15.746, and^(208) Pb/^(204) Pb = 38.791–39.073), suggesting that the metals were mainly sourced from Cretaceous granitic magma. 展开更多
关键词 MOLYBDENITE Re-Os DATING IN-SITU leadisotopes SKARN deposit - DACHANG
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Zircon U–Pb dating and whole-rock elemental geochemistry of the Shazi anatase deposit in Qinglong,Western Guizhou,SW China 被引量:4
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作者 Jun Sun Zhao Jingyu Aiguo Nie 《Acta Geochimica》 EI CAS CSCD 2017年第2期329-338,共10页
The Shazi deposit is a large-scale anatase deposit in Qinglong, Guizhou Province. Zircon grains from this deposit yielded a zircon U–Pb age of *259 Ma, representing the formation age of the deposit's parent rocks... The Shazi deposit is a large-scale anatase deposit in Qinglong, Guizhou Province. Zircon grains from this deposit yielded a zircon U–Pb age of *259 Ma, representing the formation age of the deposit's parent rocks.This age is identical to the eruption age of the Emeishan large igneous province, indicating a synchronous magmatic event. The rare-earth-element patterns of laterite samples were similar to those of the weathered basalt sample, and sub-parallel to those of the Emeishan high-Ti basalts,implying a genetic relationship between the laterite and the basalt. The Chemical Index of Alteration values of laterite ranged from 96 to 98, suggesting a high degree of weathering. SiO_2, MgO, and alkaline metal elements decreased with increasing degree of weathering, while Al_2O_3, Fe_2O_3,and TiO_2 increased. We found the highest TiO_2 in laterite and the lowest in pillow basalts, indicating that Ti migrated from basalt to laterite.Our U–Pb dating and whole-rock elemental geochemistry analyses suggest that the Emeishan basalt is the parent rock of the Shazi anatase ore deposit.Based on our analysis, we propose a metallogenic model to explain the ore-forming process, in which the karst terrain formed by the Emeishan mantle plume and the subsequent basaltic magma eruption were the key factors in the formation the Shazi anatase ore deposit. 展开更多
关键词 Anatase deposit Zircon U-Pb - Emeishan basalt Karst terrain
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The Evolutionary History of Ore-forming Processes of Metallic Ore Deposits in Northern Guangxi
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作者 Chen Yuchuan, Mao Jinwen and Wang Ping’an Chinese Academy of Geological Sciences, Beijing Fei Zhenbi 《Acta Geologica Sinica(English Edition)》 SCIE CAS CSCD 1995年第2期155-170,共16页
The northern Guangxi region is an important rare metal, rare earth metal and polymetallic metallogenic province. In the region there exist five metallogenic series and two metallogenic subseries, whose metallogenesis ... The northern Guangxi region is an important rare metal, rare earth metal and polymetallic metallogenic province. In the region there exist five metallogenic series and two metallogenic subseries, whose metallogenesis shows features of polycyclic spiral evolution throughout the geological history. As far as various cycles are concerned, mantle-derived ore substances were reduced while crust-derived ore substances increased from early to late timesfin the whole geological evolutionary history, mantle-derived substances decreased gradually while crust-derived ones increased. Meanwhile ore element associations became more and more varied. In terms of space, mineralization migrated from the old basement outwards, i.e. from west to east during the Precambrian, and from north to south during the Phanerozoic, and again from east to west during the Yanshanian. 展开更多
关键词 metallogenic series evolutionary history of ore - forming processes metallogenic model rare metal- nonferrous metal deposit
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Characterization of Cd1-xZnxTe(0≤x≤1) Nanolayers Grown by Atomic Layer Deposition on GaSb and GaAs(001) Oriented Substrates
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作者 Joel Díaz-Reyes Roberto Saúl Castillo-Ojeda José Eladio Flores-Mena 《Journal of Electronic Science and Technology》 CAS CSCD 2019年第2期97-108,共12页
ZnTe, CdTe, and the ternary alloy CdZnTe are important semiconductor materials used widely for the detection of an important range of electromagnetic radiation as gamma ray and X-ray. Although, recently these material... ZnTe, CdTe, and the ternary alloy CdZnTe are important semiconductor materials used widely for the detection of an important range of electromagnetic radiation as gamma ray and X-ray. Although, recently these materials have acquired renewed importance due to the new explored nanolayer properties of modern devices. In addition, as shown in this work they can be grown using uncomplicated synthesis techniques based on the deposition in vapour phase of the elemental precursors. This work presents the results obtained from the deposition of nanolayers of these materials using the precursor vapour on GaAs and GaSb (001) substrates. This growth technique, extensively known as atomic layer deposition (ALD), allows the layers growth with nanometric dimension. The main results presented in this work are the used growth parameters and the results of the structural characterization of the layers by the means of Raman spectroscopy measurements. Raman scattering shows the peak corresponding to longitudinal optical (LO)-ZnTe, which is weak and slightly redshift in comparison with that reported for the ZnTe bulk at 210 cm^-1. For the case of the CdTe nanolayer, Raman spectra presented the LO-CdTe peak, which is indicative of the successful growth of the layer. Its weak and slightly redshift in comparison with that reported for the CdTe bulk can be related with the nanometric characteristic of this layer. The performed high-resolution X-ray diffraction (HR-XRD) measurement allows to study some important characteristics such as the crystallinity of the grown layer. In addition, the HR-XRD measurement suggests that the crystalline quality has dependence on the growth temperature. 展开更多
关键词 - SUBSTRATES atomic layer deposition(ALD) defect generation mechanism TERNARY alloy Cd1-xZnxTe Zn and Cd mixture
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The Forming Conditions of and Ore-searching Direction for B, Mg,Pb, Zn and Au Deposits in the Liaoji Proterozoic Rift
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作者 Zhu Yongzheng and Yao Fengliang (College of Earth Sciences,Jilin University, Changchun 130026 P. R. China) 《Global Geology》 2001年第1期20-25,共6页
The Liaoji Proterozoic rift is an inter-intracontinenatl rift developed from Archean granite-greenstone tectonic regime and contains many important mineral deposits of U, B, magnesite, Pb-Zn, Au, Ag, Co and P. These d... The Liaoji Proterozoic rift is an inter-intracontinenatl rift developed from Archean granite-greenstone tectonic regime and contains many important mineral deposits of U, B, magnesite, Pb-Zn, Au, Ag, Co and P. These deposits were formed as the result of late mobilization, transportation and concentfation of the previously enriched ore-forming mate- rials in several ore-bearing formations formed during the rift stage. So the metallogeny of these deposits in the rift shows both inheritance and new generation of the ore-forming materials. In future ore-searching practice, attentions should be paid on the studies of the ore-bearing formations in the rift, on the multiple stages of metallogeny and and on multiple derivations of the ore-forming materials. 展开更多
关键词 Liaoji PROTEROZOIC rift B Mg Pb - Zn AU deposits ORE - forming conditions ORE - SEARCHING direction
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The Dust Comportment in the Latitudinal Band 10°North - 20°North in Africa: Emission and Deposition
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作者 Abdoulaye Bouya Diop Abdoulaye Sy +9 位作者 Abdoul Karim Mbodji Abdou Karim Farota Malick Wade Adoum Mahamat Moussa Babacar Niang Aichetou Dia Diop Bara Ndiaye Bouya Diop Amadou Thierno Gaye Aboubakary Diakhaby 《Journal of Geoscience and Environment Protection》 2022年第5期139-159,共21页
The three measurement periods: the TOMS Nimbus-7 TOMSN7L3 v008 from 1978 to 1993, the TOMS EP TOMSEPL3 v008 from 1996 to 2005 and the OMI OMTO3d v003 from 2004 to 2008 have allowed the presence of dust to be observed ... The three measurement periods: the TOMS Nimbus-7 TOMSN7L3 v008 from 1978 to 1993, the TOMS EP TOMSEPL3 v008 from 1996 to 2005 and the OMI OMTO3d v003 from 2004 to 2008 have allowed the presence of dust to be observed in the 10&#176;North to 20&#176;North latitudinal band (10 - 20 band) of Africa. The 10 - 20 band has a permanent dust presence. The AERONET data show AOD peaks exceeding 2 in Senegal and Niger (on an AOD scale). The statistical study reveals intra-annual relationships in deposition. In Senegal, a significant deposition is observed. 展开更多
关键词 Dust Source Area AOD 10° North - 20° North African Band depositION SAHEL
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Solvents incubatedπ-πstacking in hole transport layer for perovskite-silicon 2-terminal tandem solar cells with 27.21%efficiency
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作者 Qiaoyan Ma Jufeng Qiu +10 位作者 Yuzhao Yang Fei Tang Yilin Zeng Nanxi Ma Bohao Yu Feiping Lu Chong Liu Andreas Lambertz Weiyuan Duan Kaining Ding Yaohua Mai 《Journal of Energy Chemistry》 SCIE EI CAS CSCD 2023年第7期25-30,I0002,共7页
Room temperature sputtered inorganic nickel oxide(NiO_(x))is one of the most promising hole transport layers(HTL)for perovskite-sillion 2-terminal tandem solar cells with the aid of ultrathin and compact organic layer... Room temperature sputtered inorganic nickel oxide(NiO_(x))is one of the most promising hole transport layers(HTL)for perovskite-sillion 2-terminal tandem solar cells with the aid of ultrathin and compact organic layers to passivate the surface defects.In this study,the aromatic solvent with different substituent groups was used to regulate the conformation of poly[bis(4-phenyl)(2,4,6-trimethylphenyl)am ine](PTAA)layer.As a result,the single-junction perovskite solar cell(PSC)gained a power conversion efficiency(PCE)of 20.63%,contributing to a 27.21%efficiency for monolithic perovskite/silicon(double-side polished)2-terminal tandem solar cell,by applying the alkyl aromatic solvent to enhance theπ-πstacking of PTAA molecular chains.The tandem solar cell can maintain 95%initial efficiency after aging over 1000 h.This study provides a universal approach for improving the photovoltaic performance of NiO_(x)/polymer-based perovskite/silicon tandem solar cells and other single junction inverted PSCs. 展开更多
关键词 Tandem solar cells Low temperature deposition Hole transporting property π-πstacking Alkyl aromatic solvent
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基于政府驱动与市场驱动的押金返还制度研究——考虑闭环供应链竞争的回收决策分析
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作者 黄燕婷 刘艺 郑本荣 《运筹与管理》 CSCD 北大核心 2024年第1期51-56,共6页
在一个原制造商、一个再制造商和一个回收商组成的闭环供应链中,考虑制造商竞争,基于押金返还制度,分别构建四种押金模式,研究押金返还制度对闭环供应链定价和回收决策的影响。研究发现:(1)在由政府向制造商收取押金和由政府向回收商收... 在一个原制造商、一个再制造商和一个回收商组成的闭环供应链中,考虑制造商竞争,基于押金返还制度,分别构建四种押金模式,研究押金返还制度对闭环供应链定价和回收决策的影响。研究发现:(1)在由政府向制造商收取押金和由政府向回收商收取押金的模式下,回收率随着单位押金的增加而提高,政府驱动的押金返还制度能有效促进废旧产品的回收再制造;(2)在由再制造商对消费者收取押金的模式下,再制造商的利润随着单位押金的增加而增加,市场驱动的押金返还制度会对再制造商的利润产生积极作用;(3)与无押金模式相比,对原制造商而言,在政府向制造商收取押金模式下,产品售价提高,在再制造商向消费者及政府向回收商收取押金模式下,产品售价下降;而对再制造商而言,存在押金返还制度时,其产品售价均下降。研究结论基于押金返还制度的视角,对制造商的回收策略选择和政府选择合理的激励政策具有一定的参考价值。 展开更多
关键词 闭环供应链 押金返还制度 制造商竞争 回收
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Fate of ^(15)N Labeled Nitrate and Ammonium Salts Added to an Alpine Meadow in the Qinghai-Xizang Plateau, China 被引量:5
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作者 徐兴良 欧阳华 +1 位作者 裴志永 周才平 《Acta Botanica Sinica》 CSCD 2003年第3期276-281,共6页
To understand the dynamics of added nitrogen (N) in alpine meadow and the role of alpine plants and soil microorganisms in the retention of deposited N, the fate of 15 N labeled nitrate and ammonium salts was... To understand the dynamics of added nitrogen (N) in alpine meadow and the role of alpine plants and soil microorganisms in the retention of deposited N, the fate of 15 N labeled nitrate and ammonium salts was determined in an alpine meadow for two months. Two weeks after 15 N application, total recovery of 15 N from NO - 3_ 15 N was 73.5% while it was 78% from NH + 4_ 15 N. More 15 N was recovered in plants than in soil organic matter or in microbial biomass, irrespective of forms of N added. After one month, 70.6% of added NO - 3_ 15 N and 57.4% of NH + 4_ 15 N were recovered in soils and plants. 15 N recovered in soil organic matter decreased greatly while that recovered in plants varied little, irrespective of the form N. Compared with the results of two weeks after 15 N application, more NO - 3_ 15 N than NH + 4_ 15 N was recovered in microbial biomass. Total recovery was 58.4% (six weeks) and 67% (eight weeks) from NO - 3_ 15 N, and 43.1% and 49% from NH + 4_ 15 N, respectively. Both plants and soil microorganism recovered more NO - 3_ 15 N than NH + 4_ 15 N. But plants recovered more 15 N than soil microorganisms. During the whole experiment plants retained more NO - 3_N and 15 N than soil microorganisms while 15 N recovered in inorganic N pool did not exceed 1% due to lower amount of inorganic N. This indicates that plants play more important roles in the retention of deposited N although microbial biomass can be an important sink for deposited N in early days after N application. 展开更多
关键词 alpine meadow soil microorganisms retention of deposited N percentage of 15 N recovery fate of NO - 3_ 15 N and NH + 4_ 15 N
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Mg-9Gd-3Y镁合金PEO-EPD复合膜层组织结构与耐蚀性研究 被引量:1
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作者 李建平 王刚 +2 位作者 王萍 郭永春 杨忠 《西安工业大学学报》 CAS 2014年第2期118-123,共6页
为了提高镁合金的耐蚀性,本文利用扫描电镜分析了Mg-9Gd-3Y(GW93)镁稀土合金表面等离子电解氧化陶瓷层、等离子电解氧化-电泳复合膜层和电泳膜层的表面与纵截面形貌组织,利用傅立叶红外光谱仪(FT-IR)分析了电泳膜层有机官能团类型,用电... 为了提高镁合金的耐蚀性,本文利用扫描电镜分析了Mg-9Gd-3Y(GW93)镁稀土合金表面等离子电解氧化陶瓷层、等离子电解氧化-电泳复合膜层和电泳膜层的表面与纵截面形貌组织,利用傅立叶红外光谱仪(FT-IR)分析了电泳膜层有机官能团类型,用电化学测试手段和盐雾试验方法测试了该合金不同处理膜层的耐蚀性,讨论了电泳电压和固体粉料分数对等离子电解氧化-电泳复合膜层厚度、成膜速率和耐蚀性的影响.研究结果表明,随着电压、固体份的升高,等离子电解氧化-电泳复合涂层厚度和成膜速率呈增大趋势,腐蚀速率随着电压升高呈先减小后增大的趋势,随着固体份的增加呈降低趋势.电泳电压为70V,固体份为19%时,在等离子电解氧化膜层上生成陶瓷层与有机化合物层结合紧密的等离子电解氧化-电泳复合膜层,腐蚀电流密度比等离子电解氧化膜层降低两个数量级,自腐蚀电位正移200mV,耐蚀性提高近13倍. 展开更多
关键词 GW93镁合金 等离子电解氧化-电泳涂覆 复合膜层结构 耐蚀性 plasma electrolytic oxidation-electrophoretic deposition(PEO-EPD)
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电商预售模式下消费者权益保护的突出问题及对策研究
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作者 高兴怡 陈沅梓 《河北法律职业教育》 2024年第10期123-128,共6页
2023年全国消协组织共受理了1328496件消费者投诉,而作为新兴消费模式,电商预售对消费者权益的保障更是亟待规制。虚假宣传屡禁不止、平台自拟的机制缺乏法律依据、“定金不退”条款含法律风险等问题都是电商预售模式下消费者权益保护... 2023年全国消协组织共受理了1328496件消费者投诉,而作为新兴消费模式,电商预售对消费者权益的保障更是亟待规制。虚假宣传屡禁不止、平台自拟的机制缺乏法律依据、“定金不退”条款含法律风险等问题都是电商预售模式下消费者权益保护不容忽视的现实障碍。基于对相关现行法律规章与司法实践的研究,电商预售模式下要加强对消费者权益的保护,依靠细化和补充相关的法律条款,优化平台的立体化治理机制,强化行政指导和行业自律等对策,以促进电商产业高质量发展。 展开更多
关键词 电商预售 消费者权益保护 虚假宣传 价保 定金不退
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Atmospheric Sulfur Deposition for a Red Soil Broadleaf Forest in Southern China 被引量:6
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作者 XUCheng-Kai HUZheng-Yi +3 位作者 CAIZu-Cong WANGTi-Jian HEYuan-Qiu CAOZhi-Hong 《Pedosphere》 SCIE CAS CSCD 2004年第3期323-330,共8页
A two-year study in a typical red soil region of Southern China was conductedto determine 1) the dry deposition velocity (V_d) for SO_2 and particulate SO_4^(2-) above abroadleaf forest, and 2) atmospheric sulfur flux... A two-year study in a typical red soil region of Southern China was conductedto determine 1) the dry deposition velocity (V_d) for SO_2 and particulate SO_4^(2-) above abroadleaf forest, and 2) atmospheric sulfur fluxes so as to estimate the contribution of variousfractions in the total. Using a resistance model based on continuous hourly meteorological data,atmospheric dry sulfur deposition in a forest was estimated according to V_d and concentrations ofboth atmospheric SO_2 and particulate SO_4^(2-). Meanwhile, wet S deposition was estimated based onrainfall and sulfate concentrations in the rainwater. Results showed that about 99% of the drysulfur deposition flux in the forest resulted from SO_2 dry deposition. In addition, the observeddry S deposition was greater in 2002 than in 2000 because of a higher average concentration of SO_2in 2002 than in 2000 and not because of the average dry deposition velocity which was lower for SO_2in 2002. Also, dry SO_2 deposition was the dominant fraction of deposited atmospheric sulfur inforests, contributing over 69% of the total annual sulfur deposition. Thus, dry SO_2 depositionshould be considered when estimating sulfur balance in forest ecological systems. 展开更多
关键词 atmospheric sulfur deposition dry deposition velocity particulateSO_4^(2-) red soil SO_2
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Double Convective Hydrothermal System beneath Massive Sulfide Orebody in Gacun Deposit,Southwestern China 被引量:2
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作者 Hou ZengqianInstitute of Mineral Deposits, CAGS, Beijing 100037Mo Xuanxue Department of Geology and Mineral Resources, China University of Geosdences, Beijing 100083Urabe Tetsuro Geological Survey of Japan, Higash 1-1-3, Tsukuba, Ibaraki, 305, Japan 《Journal of Earth Science》 SCIE CAS CSCD 1995年第2期114-130,共17页
The Gacun Kuroko-type deposit, Southwestern China, is hosted in rhyolitic rocks associated with the underlying mafic rocks occurred in the - 1000 m deep fault - bounded basin within the intra -arc rifting zone which f... The Gacun Kuroko-type deposit, Southwestern China, is hosted in rhyolitic rocks associated with the underlying mafic rocks occurred in the - 1000 m deep fault - bounded basin within the intra -arc rifting zone which formed on the Triassic Yidun island - arc. Two vertically separated alteration systems are recognized: one is conformable or semiconformable alteration zone developed in - 150 m thick mafic unit 1-1.5 km below the massive sulfide ore body; the other is discordant alteration pipe directly surrounded around stockwork ore within rhyolitic unit. The lower conformable alteration zone extending for several kilometers along strike is characterized by silicification and epidotization which result in the development of quartz vein and quartz-epidote vein systems in mafic lava flows and replacement of primary minerals and groundmass in spilitized mafic volcanics and dikes by quartz, epidote - group minerals and sodic plagioclase. Sulfides often occur in the vein system and altered mafic volcanics. Quartz solubility relation indicates that silicification is a consequence of interaction of Si- saturated fluids with mafic rocks in a higher temperature system (T>340℃), intensifying by intrusion of mafic dike or high-level acidic magma chamber. The alteration pipe of diameter about 2 km shows a similar mineralogical zoning to Kuroko deposits of Japan. The sequence is quartz + hyalophane; sericite + chlorite + quartz and zeolite-like zones from core to margins of the pipe. The chlorite core only occurs in the root part of the alteration pipe and downwards transfers into epidote - chlorite and epidote - quartz vein swarm extending 500 m downwards. The felsic rocks away from the orebody and alteration pipe took place district-scale alteration, which has typical low-temperature mineral association: illite + albite + quartz + calcite. Whole -rock and quartz δ18O values indicate that district - scale alteration is a result of interaction of seawater with rocks at lower temperature (T<200℃)under water-dominated condition. However, the altered rocks from the pipe show remarkably δ18O enrichment, and bulk -rock δ18O values decreased gradually toward stockwork orebody from 15.1‰-l5. 75‰ in zeolite-like zone and 12. 05‰-14. 2‰ in sericite - quartz zone to 11.3 ‰ - 14. 4‰ in quartz - hyalophane zone. The filled temperatures of fluid inclusions in quartz and sphalerite lie in the ranges of 280 -320 ℃ for quartz - hyalophane zone and 250 ℃ to 297 ℃ for sericite-quartz zone. The estimated δ18O values of hydrothermal fluids are 7. 98‰ and3.2‰, respectively, based on quartz δ18O data in the deposit. The lower conformable alteration is considered to be approximately coeval with the alteration pipe, based on the SiO2 concentration in the fluids, which restrict the main fluid - rock reaction zone to be located in mafic horizon by quartz barometer, and metal element flux calculation and sulfide - epidote vein system developed both in alteration systems. High - salinity fluid inclusions in gangue quartz (>8% eq. NaCl) from stockwork ore and in quartz phenocryst (>40% eq. NaCl) in footwall rhyolite strongly suggest the existence of hot-saline brine to react with mafic complex and leach metal components, which probably originates mainly from magmatic fluid derived from high-level acidic magma chamber. The brine layer located in mafic unit possibly heats and drives the overlying single -pass convective seawater reacting with felsic rocks. The 'density window' may be expected to occur on the interface between seawater and brine layer, when the brine becomes to be gravitationally instability by the turbulent entrainment of seawater during magmatic and/or tectonic activities. The sulfide mineralization and alteration pipe is inter preted as an effect of the 'density window' through which the mixed fluids of brine with seawater adiabatically discharges upwards. 展开更多
关键词 hydrothermal alteration hot - saline brine fluid-rock reaction oxygenisotope Kuroto-type deposit volcanogenic massive sulfide (VMS) deposit Gacun deposit .
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Zircon U–Pb dating of Pubei granite and strontium isotope from sphalerite of the Xinhua Pb–Zn–(Ag) deposit,Yunkai Area of Guangxi Province,South China 被引量:2
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作者 Minfang Wang Xubo Zhang +1 位作者 Daohui Pi Xiaonan Guo 《Acta Geochimica》 EI CAS CSCD 2016年第2期156-171,共16页
The Yunkai Area is located at the southern South China Block and is part of the Qinzhou Bay-Hangzhou Bay Metallogenic Belt, which is a famous polymetallic mineralization belt. The Xinhua Pb–Zn–(Ag)deposit is located... The Yunkai Area is located at the southern South China Block and is part of the Qinzhou Bay-Hangzhou Bay Metallogenic Belt, which is a famous polymetallic mineralization belt. The Xinhua Pb–Zn–(Ag)deposit is located in the western part of Yunkai Area, with an abundance of Pubei batholiths. Zircon U–Pb geochronology of Pubei batholiths shows that crystallization age ranges from 251.9 ± 2.2 to 244.3 ± 1.8 Ma, thus belonging to Indosinian orogeny. Geochemistry and Sr isotopic compositions of the Pubei batholiths show that it is derived from the partial melting of large scale crustal melting during the stage of exhumation and uplifting of the lower-middle crust. In addition, strontium isotope of sphalerite from the Xinhua Pb–Zn–(Ag) deposit, has limited ranges in ^(87)Rb/^(86)Sr and ^(87)Sr/^(86)Sr, ranging from 0.4077 to 1.0449, and 0.718720 to 0.725245, respectively. The initial ^(87)Sr/^(86)Sr ratios of sphalerite ranges between 0.718720 and 0.725245, which is higher than that of upper continental crust and lower than that of the Pubei batholiths, illustrating the fluid might be derived from the mixing of Pubei pluton and upper continental crust. 展开更多
关键词 Zircon U-Pb Strontium isotope XinhuaPb-Zn-(Ag) deposit Yunkai Area - South China
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Discovery and significance of Quaternary aqueously deposited aeolian sandstones in the Sanhu area, Qaidam Basin, China 被引量:1
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作者 Wen-Jing Mao Shao-Bin Guo 《Petroleum Science》 SCIE CAS CSCD 2018年第1期41-50,共10页
Influenced by neo-tectonic movement, the Sanhu area of China's Qaidam Basin formed in the Quaternary in response to migration of its depocentre. A study of core material from the Qijia 1 Well reveals novel Quaternary... Influenced by neo-tectonic movement, the Sanhu area of China's Qaidam Basin formed in the Quaternary in response to migration of its depocentre. A study of core material from the Qijia 1 Well reveals novel Quaternary aqueously deposited aeolian sandstones in the Qigequan Formation of the Sanhu area. Here we report the sedimentary petrology and geochemistry data of these deposits that constrain their depositional history. Evidence for aeolian influence during deposition includes: sorting and roundness, pure quartz sand with single mode grain size distribution and few suspension materials,very fine sand grain size distribution indicating sorting by saltation and suspension transport, dish-shaped and crescentshaped pits in grain surfaces indicating aeolian transport and chemical composition similar to that observed in active or recent dune deposits, namely enrichment in Si O_2, Na_2 O, and Mg O relative to the sand dam sediment in the lakeshore.Identification of these aqueously deposited aeolian sandstones expands the range of sedimentary deposit types found in the Sanhu area and improves understanding of its paleoclimatic history. 展开更多
关键词 Qaidam Basin Qigequan Formation Aqueously deposited - Aeolian sandstones PALEOCLIMATE
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Structural, Optical and Electrical Properties of Li-doped ZnO Thin Films Influenced by Annealing Temperature 被引量:1
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作者 王冰 TANG Lidan +1 位作者 PENG Shujing WANG Jianzhong 《Journal of Wuhan University of Technology(Materials Science)》 SCIE EI CAS 2014年第5期873-876,共4页
Li-doped ZnO thin films had been grown by radio frequency magnetron sputtering and then annealed under various annealing temperatures. The characteristics of ZnO films were examined by XRD, FESEM, Hall measurement and... Li-doped ZnO thin films had been grown by radio frequency magnetron sputtering and then annealed under various annealing temperatures. The characteristics of ZnO films were examined by XRD, FESEM, Hall measurement and optical transmission spectra. Results showed that p type conduction was observed in Li doped ZnO films annealed at 500-600 ℃ and thep type ZnO films possessed a good crystalline with c-axis orientation, dense surface, and average transmission of about 85% in visible spectral region. 展开更多
关键词 doping defects physical vapor deposition processes OXIDES semiconducting -Ⅵmaterials heterojunction semiconductor devices
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The genetic relationship between Habo alkaline intrusion and its surrounding deposits, Yunnan Province, China: geological and S–Pb isotopic evidences 被引量:1
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作者 Zhongneng Meng Qian Zhang +3 位作者 Lin Ye Yupin Liu Jiangbo Lan Dapeng Wang 《Acta Geochimica》 EI CAS CSCD 2016年第4期391-407,共17页
The Habo alkaline intrusion, which is located in the south of the Sanjiang area, Yunnan Province, China, is a typical Cenozoic alkaline intrusion. There are a series of small to medium-sized Au and Pb-(Zn) deposits ... The Habo alkaline intrusion, which is located in the south of the Sanjiang area, Yunnan Province, China, is a typical Cenozoic alkaline intrusion. There are a series of small to medium-sized Au and Pb-(Zn) deposits around this intrusion. Those deposits are spatially associated with the Habo alkaline intrusion. (1) The δ^34S values of sulfides from Au deposits range from -1.91‰ to 2.69 ‰, which are similar to those of Pb-(Zn) deposits (-3.82 ‰ to -0.05 ‰) and both indicate a much greater contribution from magma. (2) The Habo alkaline intrusion has relatively homogeneous Pb isotopic compositions with ^206pb/^204pb ranging from 18.608 to 18.761, ^207pb/^204pb from 15.572 to 15.722 and ^20spb/^204pb from 38.599 to 39.110. These Pb isotope ratios are similar to those of Au deposits, whose ^206pb/^204pb range from 18.564 to 18.734, ^20Tpb/^20apb from 15.582 to 15.738 and ^208pb/^204pb from 38.592 to 39.319. Pb ratios in both the intrusion and Au deposits suggest that Pb mainly derived from the depth, probably represents a mixture of mantle and crust. Pb-(Zn) deposits, however, show a decentralized trait, and most of them are similar to that of the alkaline intrusion with ^206pb/^204pb ranging from 18.523 to 18.648, ^207pb/^204pb from 15.599 to 15.802, and ^20spb/^204pb from 38.659 to 39.206. (3) In the plumbotectonic diagram ^20Tpb/^204pb versus ^206pb/^204pb, almost all of Au and Pb-(Zn) deposits have the same projection area with the Habo alkaline intrusion, which indicates that those deposits almost share the same source with the alkaline intrusion. (4) Isotopic age of the Habo alkaline intrusion is 36-33 Ma, which is similar to that of Beiya, whose ore- related alkaline porphyries age is 38-31 Ma and molybdenite Re-Os age is 36.9 Ma. Therefore, along with S-Pb isotope traits, we suggest that the Habo Au and Pb-(Zn) deposits should be typically Ailaoshan-Red RiverCenozoicalkaline-related deposits and ore-forming ages of these deposits should be later than that of the Habo alkaline intrusion. 展开更多
关键词 The Habo Au and intrusion Ore genesis S-Pb materials Pb-(Zn) deposits - Alkaline isotope analyses - Source
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A PRELIMINARY RESEARCH ON THE CLIMATIC RECORDS OF LACUSTRINE DEPOSITS OF QINGTU LAKE IN THE LAST 6000 YEARS
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作者 王乃昂 高顺尉 《Chinese Geographical Science》 SCIE CSCD 1999年第4期48-54,共7页
A preliminary study on the advance and the retreat of Qingtu Lake and its climatic records of the Holocene lacustrine deposits has been made through comprehensive analysis. The study shows that the modes characteristi... A preliminary study on the advance and the retreat of Qingtu Lake and its climatic records of the Holocene lacustrine deposits has been made through comprehensive analysis. The study shows that the modes characteristics of climatic change in Eastern Hexi Corridor was provided with the corresponding relationship of warm moist and cold dry during the scale longer than hundred years. As a result of climatic changes and human activities, Qingtu Lake cycle has undergone four lake retreated and three lake advanced stages since 6000 a B.P. Based on the study on lacustrine sedimentary color, grain size, Fe 3+ /Fe 2+ and organic matter, the authors put forward that a warm period existed during the phase of 335-480 A.D. in the studied area. This warm period could be further testified by a lot of evidences obtained from the historical documents and the natural records of Qingtu Lake. In brief, the evolution of lakes in Eastern Hexi Corridor is characterized by sedimentary continuity, fast sedimentary rate and high resolution, it not only indicate the paleoenvironmental and climatic change in Holocene, but also can reflect the intensity of Eastern Asia monsoon. 展开更多
关键词 Qingtu LAKE HOLOCENE LACUSTRINE deposits CLIMATIC RECORDS WARM period of 355-480 A.D.
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