The development of aqueous battery with dual mechanisms is now arousing more and more interest.The dual mechanisms of Zn^(2+)(de)intercalation and I^(-)/I_(2)redox bring unexpected effects.Herein,differing from previo...The development of aqueous battery with dual mechanisms is now arousing more and more interest.The dual mechanisms of Zn^(2+)(de)intercalation and I^(-)/I_(2)redox bring unexpected effects.Herein,differing from previous studies using Zn I_(2)additive,this work designs an aqueous Bi I_(3)-Zn battery with selfsupplied I^(-).Ex situ tests reveal the conversion of Bi I_(3)into Bi(discharge)and Bi OI(charge)at the 1st cycle and the dissolved I^(-)in electrolyte.The active I^(-)species enhances the specific capacity and discharge medium voltage of electrode as well as improves the generation of Zn dendrite and by-product.Furthermore,the porous hard carbon is introduced to enhance the electronic/ionic conductivity and adsorb iodine species,proven by experimental and theoretical studies.Accordingly,the well-designed Bi I_(3)-Zn battery delivers a high reversible capacity of 182 m A h g^(-1)at 0.2 A g^(-1),an excellent rate capability with 88 m A h g^(-1)at 10 A g^(-1),and an impressive cyclability with 63%capacity retention over 20 K cycles at 10 A g^(-1).An excellent electrochemical performance is obtained even at a high mass loading of 6 mg cm^(-2).Moreover,a flexible quasi-solid-state Bi I_(3)-Zn battery exhibits satisfactory battery performances.This work provides a new idea for designing high-performance aqueous battery with dual mechanisms.展开更多
The Dachang tin-polymetallic district, Guangxi,China, is one of the largest tin ore fields in the world. Both cassiterite-sulfide and Zn–Cu skarn mineralization are hosted in the Mid-Upper Devonian carbonate-rich sed...The Dachang tin-polymetallic district, Guangxi,China, is one of the largest tin ore fields in the world. Both cassiterite-sulfide and Zn–Cu skarn mineralization are hosted in the Mid-Upper Devonian carbonate-rich sediments adjacent to the underlying Cretaceous Longxianggai granite(91–97 Ma). The Lamo Zn–Cu deposit is a typical skarn deposit in the district and occurs at the contact zone between the Upper Devonian limestone and the granite.The ore minerals mainly consist of sphalerite, arsenopyrite,pyrrhotite, galena, chalcopyrite, and minor molybdenite.However, the age of mineralization and source of the metals are not well constrained. In this study, we use the molybdenite Re–Os dating method and in-situ Pb isotopes of sulfides from the Lamo deposit for the first time in order to directly determine the age of mineralization and the tracing source of metals. Six molybdenite samples yielded a more accurate Re–Os isochron age of 90.0 ± 1.1 Ma(MSWD = 0.72), which is much younger than the reported garnet Sm–Nd isochron age of 95 ± 11 Ma and quartz fluid inclusions Rb–Sr isochron age of 99 ± 6 Ma. This age is also interpreted as the age of Zn–Cu skarn mineralization in the Dachang district. Further, in this study we found that in-situ Pb isotopes of sulfides from the Lamo deposit and feldspars in the district's biotite granite and granitic porphyry dikes have a narrow range and an overlap of Pb isotopic compositions(^(206) Pb/^(204) Pb =18.417–18.594,^(207) Pb/^(204) Pb = 15.641–15.746, and^(208) Pb/^(204) Pb = 38.791–39.073), suggesting that the metals were mainly sourced from Cretaceous granitic magma.展开更多
The Shazi deposit is a large-scale anatase deposit in Qinglong, Guizhou Province. Zircon grains from this deposit yielded a zircon U–Pb age of *259 Ma, representing the formation age of the deposit's parent rocks...The Shazi deposit is a large-scale anatase deposit in Qinglong, Guizhou Province. Zircon grains from this deposit yielded a zircon U–Pb age of *259 Ma, representing the formation age of the deposit's parent rocks.This age is identical to the eruption age of the Emeishan large igneous province, indicating a synchronous magmatic event. The rare-earth-element patterns of laterite samples were similar to those of the weathered basalt sample, and sub-parallel to those of the Emeishan high-Ti basalts,implying a genetic relationship between the laterite and the basalt. The Chemical Index of Alteration values of laterite ranged from 96 to 98, suggesting a high degree of weathering. SiO_2, MgO, and alkaline metal elements decreased with increasing degree of weathering, while Al_2O_3, Fe_2O_3,and TiO_2 increased. We found the highest TiO_2 in laterite and the lowest in pillow basalts, indicating that Ti migrated from basalt to laterite.Our U–Pb dating and whole-rock elemental geochemistry analyses suggest that the Emeishan basalt is the parent rock of the Shazi anatase ore deposit.Based on our analysis, we propose a metallogenic model to explain the ore-forming process, in which the karst terrain formed by the Emeishan mantle plume and the subsequent basaltic magma eruption were the key factors in the formation the Shazi anatase ore deposit.展开更多
The northern Guangxi region is an important rare metal, rare earth metal and polymetallic metallogenic province. In the region there exist five metallogenic series and two metallogenic subseries, whose metallogenesis ...The northern Guangxi region is an important rare metal, rare earth metal and polymetallic metallogenic province. In the region there exist five metallogenic series and two metallogenic subseries, whose metallogenesis shows features of polycyclic spiral evolution throughout the geological history. As far as various cycles are concerned, mantle-derived ore substances were reduced while crust-derived ore substances increased from early to late timesfin the whole geological evolutionary history, mantle-derived substances decreased gradually while crust-derived ones increased. Meanwhile ore element associations became more and more varied. In terms of space, mineralization migrated from the old basement outwards, i.e. from west to east during the Precambrian, and from north to south during the Phanerozoic, and again from east to west during the Yanshanian.展开更多
ZnTe, CdTe, and the ternary alloy CdZnTe are important semiconductor materials used widely for the detection of an important range of electromagnetic radiation as gamma ray and X-ray. Although, recently these material...ZnTe, CdTe, and the ternary alloy CdZnTe are important semiconductor materials used widely for the detection of an important range of electromagnetic radiation as gamma ray and X-ray. Although, recently these materials have acquired renewed importance due to the new explored nanolayer properties of modern devices. In addition, as shown in this work they can be grown using uncomplicated synthesis techniques based on the deposition in vapour phase of the elemental precursors. This work presents the results obtained from the deposition of nanolayers of these materials using the precursor vapour on GaAs and GaSb (001) substrates. This growth technique, extensively known as atomic layer deposition (ALD), allows the layers growth with nanometric dimension. The main results presented in this work are the used growth parameters and the results of the structural characterization of the layers by the means of Raman spectroscopy measurements. Raman scattering shows the peak corresponding to longitudinal optical (LO)-ZnTe, which is weak and slightly redshift in comparison with that reported for the ZnTe bulk at 210 cm^-1. For the case of the CdTe nanolayer, Raman spectra presented the LO-CdTe peak, which is indicative of the successful growth of the layer. Its weak and slightly redshift in comparison with that reported for the CdTe bulk can be related with the nanometric characteristic of this layer. The performed high-resolution X-ray diffraction (HR-XRD) measurement allows to study some important characteristics such as the crystallinity of the grown layer. In addition, the HR-XRD measurement suggests that the crystalline quality has dependence on the growth temperature.展开更多
The Liaoji Proterozoic rift is an inter-intracontinenatl rift developed from Archean granite-greenstone tectonic regime and contains many important mineral deposits of U, B, magnesite, Pb-Zn, Au, Ag, Co and P. These d...The Liaoji Proterozoic rift is an inter-intracontinenatl rift developed from Archean granite-greenstone tectonic regime and contains many important mineral deposits of U, B, magnesite, Pb-Zn, Au, Ag, Co and P. These deposits were formed as the result of late mobilization, transportation and concentfation of the previously enriched ore-forming mate- rials in several ore-bearing formations formed during the rift stage. So the metallogeny of these deposits in the rift shows both inheritance and new generation of the ore-forming materials. In future ore-searching practice, attentions should be paid on the studies of the ore-bearing formations in the rift, on the multiple stages of metallogeny and and on multiple derivations of the ore-forming materials.展开更多
The three measurement periods: the TOMS Nimbus-7 TOMSN7L3 v008 from 1978 to 1993, the TOMS EP TOMSEPL3 v008 from 1996 to 2005 and the OMI OMTO3d v003 from 2004 to 2008 have allowed the presence of dust to be observed ...The three measurement periods: the TOMS Nimbus-7 TOMSN7L3 v008 from 1978 to 1993, the TOMS EP TOMSEPL3 v008 from 1996 to 2005 and the OMI OMTO3d v003 from 2004 to 2008 have allowed the presence of dust to be observed in the 10°North to 20°North latitudinal band (10 - 20 band) of Africa. The 10 - 20 band has a permanent dust presence. The AERONET data show AOD peaks exceeding 2 in Senegal and Niger (on an AOD scale). The statistical study reveals intra-annual relationships in deposition. In Senegal, a significant deposition is observed.展开更多
Room temperature sputtered inorganic nickel oxide(NiO_(x))is one of the most promising hole transport layers(HTL)for perovskite-sillion 2-terminal tandem solar cells with the aid of ultrathin and compact organic layer...Room temperature sputtered inorganic nickel oxide(NiO_(x))is one of the most promising hole transport layers(HTL)for perovskite-sillion 2-terminal tandem solar cells with the aid of ultrathin and compact organic layers to passivate the surface defects.In this study,the aromatic solvent with different substituent groups was used to regulate the conformation of poly[bis(4-phenyl)(2,4,6-trimethylphenyl)am ine](PTAA)layer.As a result,the single-junction perovskite solar cell(PSC)gained a power conversion efficiency(PCE)of 20.63%,contributing to a 27.21%efficiency for monolithic perovskite/silicon(double-side polished)2-terminal tandem solar cell,by applying the alkyl aromatic solvent to enhance theπ-πstacking of PTAA molecular chains.The tandem solar cell can maintain 95%initial efficiency after aging over 1000 h.This study provides a universal approach for improving the photovoltaic performance of NiO_(x)/polymer-based perovskite/silicon tandem solar cells and other single junction inverted PSCs.展开更多
To understand the dynamics of added nitrogen (N) in alpine meadow and the role of alpine plants and soil microorganisms in the retention of deposited N, the fate of 15 N labeled nitrate and ammonium salts was...To understand the dynamics of added nitrogen (N) in alpine meadow and the role of alpine plants and soil microorganisms in the retention of deposited N, the fate of 15 N labeled nitrate and ammonium salts was determined in an alpine meadow for two months. Two weeks after 15 N application, total recovery of 15 N from NO - 3_ 15 N was 73.5% while it was 78% from NH + 4_ 15 N. More 15 N was recovered in plants than in soil organic matter or in microbial biomass, irrespective of forms of N added. After one month, 70.6% of added NO - 3_ 15 N and 57.4% of NH + 4_ 15 N were recovered in soils and plants. 15 N recovered in soil organic matter decreased greatly while that recovered in plants varied little, irrespective of the form N. Compared with the results of two weeks after 15 N application, more NO - 3_ 15 N than NH + 4_ 15 N was recovered in microbial biomass. Total recovery was 58.4% (six weeks) and 67% (eight weeks) from NO - 3_ 15 N, and 43.1% and 49% from NH + 4_ 15 N, respectively. Both plants and soil microorganism recovered more NO - 3_ 15 N than NH + 4_ 15 N. But plants recovered more 15 N than soil microorganisms. During the whole experiment plants retained more NO - 3_N and 15 N than soil microorganisms while 15 N recovered in inorganic N pool did not exceed 1% due to lower amount of inorganic N. This indicates that plants play more important roles in the retention of deposited N although microbial biomass can be an important sink for deposited N in early days after N application.展开更多
A two-year study in a typical red soil region of Southern China was conductedto determine 1) the dry deposition velocity (V_d) for SO_2 and particulate SO_4^(2-) above abroadleaf forest, and 2) atmospheric sulfur flux...A two-year study in a typical red soil region of Southern China was conductedto determine 1) the dry deposition velocity (V_d) for SO_2 and particulate SO_4^(2-) above abroadleaf forest, and 2) atmospheric sulfur fluxes so as to estimate the contribution of variousfractions in the total. Using a resistance model based on continuous hourly meteorological data,atmospheric dry sulfur deposition in a forest was estimated according to V_d and concentrations ofboth atmospheric SO_2 and particulate SO_4^(2-). Meanwhile, wet S deposition was estimated based onrainfall and sulfate concentrations in the rainwater. Results showed that about 99% of the drysulfur deposition flux in the forest resulted from SO_2 dry deposition. In addition, the observeddry S deposition was greater in 2002 than in 2000 because of a higher average concentration of SO_2in 2002 than in 2000 and not because of the average dry deposition velocity which was lower for SO_2in 2002. Also, dry SO_2 deposition was the dominant fraction of deposited atmospheric sulfur inforests, contributing over 69% of the total annual sulfur deposition. Thus, dry SO_2 depositionshould be considered when estimating sulfur balance in forest ecological systems.展开更多
The Gacun Kuroko-type deposit, Southwestern China, is hosted in rhyolitic rocks associated with the underlying mafic rocks occurred in the - 1000 m deep fault - bounded basin within the intra -arc rifting zone which f...The Gacun Kuroko-type deposit, Southwestern China, is hosted in rhyolitic rocks associated with the underlying mafic rocks occurred in the - 1000 m deep fault - bounded basin within the intra -arc rifting zone which formed on the Triassic Yidun island - arc. Two vertically separated alteration systems are recognized: one is conformable or semiconformable alteration zone developed in - 150 m thick mafic unit 1-1.5 km below the massive sulfide ore body; the other is discordant alteration pipe directly surrounded around stockwork ore within rhyolitic unit. The lower conformable alteration zone extending for several kilometers along strike is characterized by silicification and epidotization which result in the development of quartz vein and quartz-epidote vein systems in mafic lava flows and replacement of primary minerals and groundmass in spilitized mafic volcanics and dikes by quartz, epidote - group minerals and sodic plagioclase. Sulfides often occur in the vein system and altered mafic volcanics. Quartz solubility relation indicates that silicification is a consequence of interaction of Si- saturated fluids with mafic rocks in a higher temperature system (T>340℃), intensifying by intrusion of mafic dike or high-level acidic magma chamber. The alteration pipe of diameter about 2 km shows a similar mineralogical zoning to Kuroko deposits of Japan. The sequence is quartz + hyalophane; sericite + chlorite + quartz and zeolite-like zones from core to margins of the pipe. The chlorite core only occurs in the root part of the alteration pipe and downwards transfers into epidote - chlorite and epidote - quartz vein swarm extending 500 m downwards. The felsic rocks away from the orebody and alteration pipe took place district-scale alteration, which has typical low-temperature mineral association: illite + albite + quartz + calcite. Whole -rock and quartz δ18O values indicate that district - scale alteration is a result of interaction of seawater with rocks at lower temperature (T<200℃)under water-dominated condition. However, the altered rocks from the pipe show remarkably δ18O enrichment, and bulk -rock δ18O values decreased gradually toward stockwork orebody from 15.1‰-l5. 75‰ in zeolite-like zone and 12. 05‰-14. 2‰ in sericite - quartz zone to 11.3 ‰ - 14. 4‰ in quartz - hyalophane zone. The filled temperatures of fluid inclusions in quartz and sphalerite lie in the ranges of 280 -320 ℃ for quartz - hyalophane zone and 250 ℃ to 297 ℃ for sericite-quartz zone. The estimated δ18O values of hydrothermal fluids are 7. 98‰ and3.2‰, respectively, based on quartz δ18O data in the deposit. The lower conformable alteration is considered to be approximately coeval with the alteration pipe, based on the SiO2 concentration in the fluids, which restrict the main fluid - rock reaction zone to be located in mafic horizon by quartz barometer, and metal element flux calculation and sulfide - epidote vein system developed both in alteration systems. High - salinity fluid inclusions in gangue quartz (>8% eq. NaCl) from stockwork ore and in quartz phenocryst (>40% eq. NaCl) in footwall rhyolite strongly suggest the existence of hot-saline brine to react with mafic complex and leach metal components, which probably originates mainly from magmatic fluid derived from high-level acidic magma chamber. The brine layer located in mafic unit possibly heats and drives the overlying single -pass convective seawater reacting with felsic rocks. The 'density window' may be expected to occur on the interface between seawater and brine layer, when the brine becomes to be gravitationally instability by the turbulent entrainment of seawater during magmatic and/or tectonic activities. The sulfide mineralization and alteration pipe is inter preted as an effect of the 'density window' through which the mixed fluids of brine with seawater adiabatically discharges upwards.展开更多
The Yunkai Area is located at the southern South China Block and is part of the Qinzhou Bay-Hangzhou Bay Metallogenic Belt, which is a famous polymetallic mineralization belt. The Xinhua Pb–Zn–(Ag)deposit is located...The Yunkai Area is located at the southern South China Block and is part of the Qinzhou Bay-Hangzhou Bay Metallogenic Belt, which is a famous polymetallic mineralization belt. The Xinhua Pb–Zn–(Ag)deposit is located in the western part of Yunkai Area, with an abundance of Pubei batholiths. Zircon U–Pb geochronology of Pubei batholiths shows that crystallization age ranges from 251.9 ± 2.2 to 244.3 ± 1.8 Ma, thus belonging to Indosinian orogeny. Geochemistry and Sr isotopic compositions of the Pubei batholiths show that it is derived from the partial melting of large scale crustal melting during the stage of exhumation and uplifting of the lower-middle crust. In addition, strontium isotope of sphalerite from the Xinhua Pb–Zn–(Ag) deposit, has limited ranges in ^(87)Rb/^(86)Sr and ^(87)Sr/^(86)Sr, ranging from 0.4077 to 1.0449, and 0.718720 to 0.725245, respectively. The initial ^(87)Sr/^(86)Sr ratios of sphalerite ranges between 0.718720 and 0.725245, which is higher than that of upper continental crust and lower than that of the Pubei batholiths, illustrating the fluid might be derived from the mixing of Pubei pluton and upper continental crust.展开更多
Influenced by neo-tectonic movement, the Sanhu area of China's Qaidam Basin formed in the Quaternary in response to migration of its depocentre. A study of core material from the Qijia 1 Well reveals novel Quaternary...Influenced by neo-tectonic movement, the Sanhu area of China's Qaidam Basin formed in the Quaternary in response to migration of its depocentre. A study of core material from the Qijia 1 Well reveals novel Quaternary aqueously deposited aeolian sandstones in the Qigequan Formation of the Sanhu area. Here we report the sedimentary petrology and geochemistry data of these deposits that constrain their depositional history. Evidence for aeolian influence during deposition includes: sorting and roundness, pure quartz sand with single mode grain size distribution and few suspension materials,very fine sand grain size distribution indicating sorting by saltation and suspension transport, dish-shaped and crescentshaped pits in grain surfaces indicating aeolian transport and chemical composition similar to that observed in active or recent dune deposits, namely enrichment in Si O_2, Na_2 O, and Mg O relative to the sand dam sediment in the lakeshore.Identification of these aqueously deposited aeolian sandstones expands the range of sedimentary deposit types found in the Sanhu area and improves understanding of its paleoclimatic history.展开更多
Li-doped ZnO thin films had been grown by radio frequency magnetron sputtering and then annealed under various annealing temperatures. The characteristics of ZnO films were examined by XRD, FESEM, Hall measurement and...Li-doped ZnO thin films had been grown by radio frequency magnetron sputtering and then annealed under various annealing temperatures. The characteristics of ZnO films were examined by XRD, FESEM, Hall measurement and optical transmission spectra. Results showed that p type conduction was observed in Li doped ZnO films annealed at 500-600 ℃ and thep type ZnO films possessed a good crystalline with c-axis orientation, dense surface, and average transmission of about 85% in visible spectral region.展开更多
The Habo alkaline intrusion, which is located in the south of the Sanjiang area, Yunnan Province, China, is a typical Cenozoic alkaline intrusion. There are a series of small to medium-sized Au and Pb-(Zn) deposits ...The Habo alkaline intrusion, which is located in the south of the Sanjiang area, Yunnan Province, China, is a typical Cenozoic alkaline intrusion. There are a series of small to medium-sized Au and Pb-(Zn) deposits around this intrusion. Those deposits are spatially associated with the Habo alkaline intrusion. (1) The δ^34S values of sulfides from Au deposits range from -1.91‰ to 2.69 ‰, which are similar to those of Pb-(Zn) deposits (-3.82 ‰ to -0.05 ‰) and both indicate a much greater contribution from magma. (2) The Habo alkaline intrusion has relatively homogeneous Pb isotopic compositions with ^206pb/^204pb ranging from 18.608 to 18.761, ^207pb/^204pb from 15.572 to 15.722 and ^20spb/^204pb from 38.599 to 39.110. These Pb isotope ratios are similar to those of Au deposits, whose ^206pb/^204pb range from 18.564 to 18.734, ^20Tpb/^20apb from 15.582 to 15.738 and ^208pb/^204pb from 38.592 to 39.319. Pb ratios in both the intrusion and Au deposits suggest that Pb mainly derived from the depth, probably represents a mixture of mantle and crust. Pb-(Zn) deposits, however, show a decentralized trait, and most of them are similar to that of the alkaline intrusion with ^206pb/^204pb ranging from 18.523 to 18.648, ^207pb/^204pb from 15.599 to 15.802, and ^20spb/^204pb from 38.659 to 39.206. (3) In the plumbotectonic diagram ^20Tpb/^204pb versus ^206pb/^204pb, almost all of Au and Pb-(Zn) deposits have the same projection area with the Habo alkaline intrusion, which indicates that those deposits almost share the same source with the alkaline intrusion. (4) Isotopic age of the Habo alkaline intrusion is 36-33 Ma, which is similar to that of Beiya, whose ore- related alkaline porphyries age is 38-31 Ma and molybdenite Re-Os age is 36.9 Ma. Therefore, along with S-Pb isotope traits, we suggest that the Habo Au and Pb-(Zn) deposits should be typically Ailaoshan-Red RiverCenozoicalkaline-related deposits and ore-forming ages of these deposits should be later than that of the Habo alkaline intrusion.展开更多
A preliminary study on the advance and the retreat of Qingtu Lake and its climatic records of the Holocene lacustrine deposits has been made through comprehensive analysis. The study shows that the modes characteristi...A preliminary study on the advance and the retreat of Qingtu Lake and its climatic records of the Holocene lacustrine deposits has been made through comprehensive analysis. The study shows that the modes characteristics of climatic change in Eastern Hexi Corridor was provided with the corresponding relationship of warm moist and cold dry during the scale longer than hundred years. As a result of climatic changes and human activities, Qingtu Lake cycle has undergone four lake retreated and three lake advanced stages since 6000 a B.P. Based on the study on lacustrine sedimentary color, grain size, Fe 3+ /Fe 2+ and organic matter, the authors put forward that a warm period existed during the phase of 335-480 A.D. in the studied area. This warm period could be further testified by a lot of evidences obtained from the historical documents and the natural records of Qingtu Lake. In brief, the evolution of lakes in Eastern Hexi Corridor is characterized by sedimentary continuity, fast sedimentary rate and high resolution, it not only indicate the paleoenvironmental and climatic change in Holocene, but also can reflect the intensity of Eastern Asia monsoon.展开更多
基金funding from National Natural Science Foundation of China(52103053,52102312)Huxiang Young Talents of Hunan Province(2022RC1004)+1 种基金Macao Young Scholars Program(AM2021011)Foundation of State Key Laboratory of Utilization of Woody Oil Resource(GZKF202126)。
文摘The development of aqueous battery with dual mechanisms is now arousing more and more interest.The dual mechanisms of Zn^(2+)(de)intercalation and I^(-)/I_(2)redox bring unexpected effects.Herein,differing from previous studies using Zn I_(2)additive,this work designs an aqueous Bi I_(3)-Zn battery with selfsupplied I^(-).Ex situ tests reveal the conversion of Bi I_(3)into Bi(discharge)and Bi OI(charge)at the 1st cycle and the dissolved I^(-)in electrolyte.The active I^(-)species enhances the specific capacity and discharge medium voltage of electrode as well as improves the generation of Zn dendrite and by-product.Furthermore,the porous hard carbon is introduced to enhance the electronic/ionic conductivity and adsorb iodine species,proven by experimental and theoretical studies.Accordingly,the well-designed Bi I_(3)-Zn battery delivers a high reversible capacity of 182 m A h g^(-1)at 0.2 A g^(-1),an excellent rate capability with 88 m A h g^(-1)at 10 A g^(-1),and an impressive cyclability with 63%capacity retention over 20 K cycles at 10 A g^(-1).An excellent electrochemical performance is obtained even at a high mass loading of 6 mg cm^(-2).Moreover,a flexible quasi-solid-state Bi I_(3)-Zn battery exhibits satisfactory battery performances.This work provides a new idea for designing high-performance aqueous battery with dual mechanisms.
基金supported by the National Science Foundation of China(Grants Nos.41672080,41772079,41272113)Outstanding Talent Foundation of the Institute of Geochemistry,Chinese Academy of Sciences
文摘The Dachang tin-polymetallic district, Guangxi,China, is one of the largest tin ore fields in the world. Both cassiterite-sulfide and Zn–Cu skarn mineralization are hosted in the Mid-Upper Devonian carbonate-rich sediments adjacent to the underlying Cretaceous Longxianggai granite(91–97 Ma). The Lamo Zn–Cu deposit is a typical skarn deposit in the district and occurs at the contact zone between the Upper Devonian limestone and the granite.The ore minerals mainly consist of sphalerite, arsenopyrite,pyrrhotite, galena, chalcopyrite, and minor molybdenite.However, the age of mineralization and source of the metals are not well constrained. In this study, we use the molybdenite Re–Os dating method and in-situ Pb isotopes of sulfides from the Lamo deposit for the first time in order to directly determine the age of mineralization and the tracing source of metals. Six molybdenite samples yielded a more accurate Re–Os isochron age of 90.0 ± 1.1 Ma(MSWD = 0.72), which is much younger than the reported garnet Sm–Nd isochron age of 95 ± 11 Ma and quartz fluid inclusions Rb–Sr isochron age of 99 ± 6 Ma. This age is also interpreted as the age of Zn–Cu skarn mineralization in the Dachang district. Further, in this study we found that in-situ Pb isotopes of sulfides from the Lamo deposit and feldspars in the district's biotite granite and granitic porphyry dikes have a narrow range and an overlap of Pb isotopic compositions(^(206) Pb/^(204) Pb =18.417–18.594,^(207) Pb/^(204) Pb = 15.641–15.746, and^(208) Pb/^(204) Pb = 38.791–39.073), suggesting that the metals were mainly sourced from Cretaceous granitic magma.
基金supported by the Natural Science Foundation of China (Grant No.41262005)
文摘The Shazi deposit is a large-scale anatase deposit in Qinglong, Guizhou Province. Zircon grains from this deposit yielded a zircon U–Pb age of *259 Ma, representing the formation age of the deposit's parent rocks.This age is identical to the eruption age of the Emeishan large igneous province, indicating a synchronous magmatic event. The rare-earth-element patterns of laterite samples were similar to those of the weathered basalt sample, and sub-parallel to those of the Emeishan high-Ti basalts,implying a genetic relationship between the laterite and the basalt. The Chemical Index of Alteration values of laterite ranged from 96 to 98, suggesting a high degree of weathering. SiO_2, MgO, and alkaline metal elements decreased with increasing degree of weathering, while Al_2O_3, Fe_2O_3,and TiO_2 increased. We found the highest TiO_2 in laterite and the lowest in pillow basalts, indicating that Ti migrated from basalt to laterite.Our U–Pb dating and whole-rock elemental geochemistry analyses suggest that the Emeishan basalt is the parent rock of the Shazi anatase ore deposit.Based on our analysis, we propose a metallogenic model to explain the ore-forming process, in which the karst terrain formed by the Emeishan mantle plume and the subsequent basaltic magma eruption were the key factors in the formation the Shazi anatase ore deposit.
基金This research was supported by the Chinese Foundation for Development of Geological Science and Technology (Project 49273162)the National Natural Science Foundation of China(Project 49273162)
文摘The northern Guangxi region is an important rare metal, rare earth metal and polymetallic metallogenic province. In the region there exist five metallogenic series and two metallogenic subseries, whose metallogenesis shows features of polycyclic spiral evolution throughout the geological history. As far as various cycles are concerned, mantle-derived ore substances were reduced while crust-derived ore substances increased from early to late timesfin the whole geological evolutionary history, mantle-derived substances decreased gradually while crust-derived ones increased. Meanwhile ore element associations became more and more varied. In terms of space, mineralization migrated from the old basement outwards, i.e. from west to east during the Precambrian, and from north to south during the Phanerozoic, and again from east to west during the Yanshanian.
文摘ZnTe, CdTe, and the ternary alloy CdZnTe are important semiconductor materials used widely for the detection of an important range of electromagnetic radiation as gamma ray and X-ray. Although, recently these materials have acquired renewed importance due to the new explored nanolayer properties of modern devices. In addition, as shown in this work they can be grown using uncomplicated synthesis techniques based on the deposition in vapour phase of the elemental precursors. This work presents the results obtained from the deposition of nanolayers of these materials using the precursor vapour on GaAs and GaSb (001) substrates. This growth technique, extensively known as atomic layer deposition (ALD), allows the layers growth with nanometric dimension. The main results presented in this work are the used growth parameters and the results of the structural characterization of the layers by the means of Raman spectroscopy measurements. Raman scattering shows the peak corresponding to longitudinal optical (LO)-ZnTe, which is weak and slightly redshift in comparison with that reported for the ZnTe bulk at 210 cm^-1. For the case of the CdTe nanolayer, Raman spectra presented the LO-CdTe peak, which is indicative of the successful growth of the layer. Its weak and slightly redshift in comparison with that reported for the CdTe bulk can be related with the nanometric characteristic of this layer. The performed high-resolution X-ray diffraction (HR-XRD) measurement allows to study some important characteristics such as the crystallinity of the grown layer. In addition, the HR-XRD measurement suggests that the crystalline quality has dependence on the growth temperature.
文摘The Liaoji Proterozoic rift is an inter-intracontinenatl rift developed from Archean granite-greenstone tectonic regime and contains many important mineral deposits of U, B, magnesite, Pb-Zn, Au, Ag, Co and P. These deposits were formed as the result of late mobilization, transportation and concentfation of the previously enriched ore-forming mate- rials in several ore-bearing formations formed during the rift stage. So the metallogeny of these deposits in the rift shows both inheritance and new generation of the ore-forming materials. In future ore-searching practice, attentions should be paid on the studies of the ore-bearing formations in the rift, on the multiple stages of metallogeny and and on multiple derivations of the ore-forming materials.
文摘The three measurement periods: the TOMS Nimbus-7 TOMSN7L3 v008 from 1978 to 1993, the TOMS EP TOMSEPL3 v008 from 1996 to 2005 and the OMI OMTO3d v003 from 2004 to 2008 have allowed the presence of dust to be observed in the 10°North to 20°North latitudinal band (10 - 20 band) of Africa. The 10 - 20 band has a permanent dust presence. The AERONET data show AOD peaks exceeding 2 in Senegal and Niger (on an AOD scale). The statistical study reveals intra-annual relationships in deposition. In Senegal, a significant deposition is observed.
基金supported by the National Key R&D Program of China(2018YFB1500103)the National Natural Science Foundation of China(62104082)+1 种基金the Guangdong Basic and Applied Basic Research Foundation(2022A1515010746,2022A1515011228)the Science and Technology Program of Guangzhou(202201010458)。
文摘Room temperature sputtered inorganic nickel oxide(NiO_(x))is one of the most promising hole transport layers(HTL)for perovskite-sillion 2-terminal tandem solar cells with the aid of ultrathin and compact organic layers to passivate the surface defects.In this study,the aromatic solvent with different substituent groups was used to regulate the conformation of poly[bis(4-phenyl)(2,4,6-trimethylphenyl)am ine](PTAA)layer.As a result,the single-junction perovskite solar cell(PSC)gained a power conversion efficiency(PCE)of 20.63%,contributing to a 27.21%efficiency for monolithic perovskite/silicon(double-side polished)2-terminal tandem solar cell,by applying the alkyl aromatic solvent to enhance theπ-πstacking of PTAA molecular chains.The tandem solar cell can maintain 95%initial efficiency after aging over 1000 h.This study provides a universal approach for improving the photovoltaic performance of NiO_(x)/polymer-based perovskite/silicon tandem solar cells and other single junction inverted PSCs.
文摘To understand the dynamics of added nitrogen (N) in alpine meadow and the role of alpine plants and soil microorganisms in the retention of deposited N, the fate of 15 N labeled nitrate and ammonium salts was determined in an alpine meadow for two months. Two weeks after 15 N application, total recovery of 15 N from NO - 3_ 15 N was 73.5% while it was 78% from NH + 4_ 15 N. More 15 N was recovered in plants than in soil organic matter or in microbial biomass, irrespective of forms of N added. After one month, 70.6% of added NO - 3_ 15 N and 57.4% of NH + 4_ 15 N were recovered in soils and plants. 15 N recovered in soil organic matter decreased greatly while that recovered in plants varied little, irrespective of the form N. Compared with the results of two weeks after 15 N application, more NO - 3_ 15 N than NH + 4_ 15 N was recovered in microbial biomass. Total recovery was 58.4% (six weeks) and 67% (eight weeks) from NO - 3_ 15 N, and 43.1% and 49% from NH + 4_ 15 N, respectively. Both plants and soil microorganism recovered more NO - 3_ 15 N than NH + 4_ 15 N. But plants recovered more 15 N than soil microorganisms. During the whole experiment plants retained more NO - 3_N and 15 N than soil microorganisms while 15 N recovered in inorganic N pool did not exceed 1% due to lower amount of inorganic N. This indicates that plants play more important roles in the retention of deposited N although microbial biomass can be an important sink for deposited N in early days after N application.
基金Project supported by the National Key Basic Research Support Foundation (NKBRSF) of China (No. 1999011805)the Knowledge Innovation Program of Chinese Academy of Sciences (No.ISSASIP0205) the State Key Laboratory of Soil and Sustainable Agriculture, C
文摘A two-year study in a typical red soil region of Southern China was conductedto determine 1) the dry deposition velocity (V_d) for SO_2 and particulate SO_4^(2-) above abroadleaf forest, and 2) atmospheric sulfur fluxes so as to estimate the contribution of variousfractions in the total. Using a resistance model based on continuous hourly meteorological data,atmospheric dry sulfur deposition in a forest was estimated according to V_d and concentrations ofboth atmospheric SO_2 and particulate SO_4^(2-). Meanwhile, wet S deposition was estimated based onrainfall and sulfate concentrations in the rainwater. Results showed that about 99% of the drysulfur deposition flux in the forest resulted from SO_2 dry deposition. In addition, the observeddry S deposition was greater in 2002 than in 2000 because of a higher average concentration of SO_2in 2002 than in 2000 and not because of the average dry deposition velocity which was lower for SO_2in 2002. Also, dry SO_2 deposition was the dominant fraction of deposited atmospheric sulfur inforests, contributing over 69% of the total annual sulfur deposition. Thus, dry SO_2 depositionshould be considered when estimating sulfur balance in forest ecological systems.
基金The study is supported by Agence of International Science and Technology, Japan
文摘The Gacun Kuroko-type deposit, Southwestern China, is hosted in rhyolitic rocks associated with the underlying mafic rocks occurred in the - 1000 m deep fault - bounded basin within the intra -arc rifting zone which formed on the Triassic Yidun island - arc. Two vertically separated alteration systems are recognized: one is conformable or semiconformable alteration zone developed in - 150 m thick mafic unit 1-1.5 km below the massive sulfide ore body; the other is discordant alteration pipe directly surrounded around stockwork ore within rhyolitic unit. The lower conformable alteration zone extending for several kilometers along strike is characterized by silicification and epidotization which result in the development of quartz vein and quartz-epidote vein systems in mafic lava flows and replacement of primary minerals and groundmass in spilitized mafic volcanics and dikes by quartz, epidote - group minerals and sodic plagioclase. Sulfides often occur in the vein system and altered mafic volcanics. Quartz solubility relation indicates that silicification is a consequence of interaction of Si- saturated fluids with mafic rocks in a higher temperature system (T>340℃), intensifying by intrusion of mafic dike or high-level acidic magma chamber. The alteration pipe of diameter about 2 km shows a similar mineralogical zoning to Kuroko deposits of Japan. The sequence is quartz + hyalophane; sericite + chlorite + quartz and zeolite-like zones from core to margins of the pipe. The chlorite core only occurs in the root part of the alteration pipe and downwards transfers into epidote - chlorite and epidote - quartz vein swarm extending 500 m downwards. The felsic rocks away from the orebody and alteration pipe took place district-scale alteration, which has typical low-temperature mineral association: illite + albite + quartz + calcite. Whole -rock and quartz δ18O values indicate that district - scale alteration is a result of interaction of seawater with rocks at lower temperature (T<200℃)under water-dominated condition. However, the altered rocks from the pipe show remarkably δ18O enrichment, and bulk -rock δ18O values decreased gradually toward stockwork orebody from 15.1‰-l5. 75‰ in zeolite-like zone and 12. 05‰-14. 2‰ in sericite - quartz zone to 11.3 ‰ - 14. 4‰ in quartz - hyalophane zone. The filled temperatures of fluid inclusions in quartz and sphalerite lie in the ranges of 280 -320 ℃ for quartz - hyalophane zone and 250 ℃ to 297 ℃ for sericite-quartz zone. The estimated δ18O values of hydrothermal fluids are 7. 98‰ and3.2‰, respectively, based on quartz δ18O data in the deposit. The lower conformable alteration is considered to be approximately coeval with the alteration pipe, based on the SiO2 concentration in the fluids, which restrict the main fluid - rock reaction zone to be located in mafic horizon by quartz barometer, and metal element flux calculation and sulfide - epidote vein system developed both in alteration systems. High - salinity fluid inclusions in gangue quartz (>8% eq. NaCl) from stockwork ore and in quartz phenocryst (>40% eq. NaCl) in footwall rhyolite strongly suggest the existence of hot-saline brine to react with mafic complex and leach metal components, which probably originates mainly from magmatic fluid derived from high-level acidic magma chamber. The brine layer located in mafic unit possibly heats and drives the overlying single -pass convective seawater reacting with felsic rocks. The 'density window' may be expected to occur on the interface between seawater and brine layer, when the brine becomes to be gravitationally instability by the turbulent entrainment of seawater during magmatic and/or tectonic activities. The sulfide mineralization and alteration pipe is inter preted as an effect of the 'density window' through which the mixed fluids of brine with seawater adiabatically discharges upwards.
基金supported by grants by the National Natural Science Foundation of China (No.41272097)the China Geological Survey Project (No.12120114016601)+1 种基金the Special Fund for Basic Scientific Research of Central Colleges, China University of Geosciences (Wuhan) (No.CUG120702)the Teaching Laboratory Foundation of China University of Geosciences (Wuhan) (No.SKJ2013085,SKJ2014010)
文摘The Yunkai Area is located at the southern South China Block and is part of the Qinzhou Bay-Hangzhou Bay Metallogenic Belt, which is a famous polymetallic mineralization belt. The Xinhua Pb–Zn–(Ag)deposit is located in the western part of Yunkai Area, with an abundance of Pubei batholiths. Zircon U–Pb geochronology of Pubei batholiths shows that crystallization age ranges from 251.9 ± 2.2 to 244.3 ± 1.8 Ma, thus belonging to Indosinian orogeny. Geochemistry and Sr isotopic compositions of the Pubei batholiths show that it is derived from the partial melting of large scale crustal melting during the stage of exhumation and uplifting of the lower-middle crust. In addition, strontium isotope of sphalerite from the Xinhua Pb–Zn–(Ag) deposit, has limited ranges in ^(87)Rb/^(86)Sr and ^(87)Sr/^(86)Sr, ranging from 0.4077 to 1.0449, and 0.718720 to 0.725245, respectively. The initial ^(87)Sr/^(86)Sr ratios of sphalerite ranges between 0.718720 and 0.725245, which is higher than that of upper continental crust and lower than that of the Pubei batholiths, illustrating the fluid might be derived from the mixing of Pubei pluton and upper continental crust.
基金funding support from the Qinghai Oilfield Company of the China National Petroleum Corporation
文摘Influenced by neo-tectonic movement, the Sanhu area of China's Qaidam Basin formed in the Quaternary in response to migration of its depocentre. A study of core material from the Qijia 1 Well reveals novel Quaternary aqueously deposited aeolian sandstones in the Qigequan Formation of the Sanhu area. Here we report the sedimentary petrology and geochemistry data of these deposits that constrain their depositional history. Evidence for aeolian influence during deposition includes: sorting and roundness, pure quartz sand with single mode grain size distribution and few suspension materials,very fine sand grain size distribution indicating sorting by saltation and suspension transport, dish-shaped and crescentshaped pits in grain surfaces indicating aeolian transport and chemical composition similar to that observed in active or recent dune deposits, namely enrichment in Si O_2, Na_2 O, and Mg O relative to the sand dam sediment in the lakeshore.Identification of these aqueously deposited aeolian sandstones expands the range of sedimentary deposit types found in the Sanhu area and improves understanding of its paleoclimatic history.
基金Funded by the Natural Science Foundation of Liaoning,China(No.201204916)Training Programme Foundation for the Talents by the Education Bureau of Liaoning Province,China(No.LJQ2013068)+1 种基金Key Program of Ministry of Education,China(No.212031)Liaoning College Creative Team(No.LT2013014)
文摘Li-doped ZnO thin films had been grown by radio frequency magnetron sputtering and then annealed under various annealing temperatures. The characteristics of ZnO films were examined by XRD, FESEM, Hall measurement and optical transmission spectra. Results showed that p type conduction was observed in Li doped ZnO films annealed at 500-600 ℃ and thep type ZnO films possessed a good crystalline with c-axis orientation, dense surface, and average transmission of about 85% in visible spectral region.
文摘The Habo alkaline intrusion, which is located in the south of the Sanjiang area, Yunnan Province, China, is a typical Cenozoic alkaline intrusion. There are a series of small to medium-sized Au and Pb-(Zn) deposits around this intrusion. Those deposits are spatially associated with the Habo alkaline intrusion. (1) The δ^34S values of sulfides from Au deposits range from -1.91‰ to 2.69 ‰, which are similar to those of Pb-(Zn) deposits (-3.82 ‰ to -0.05 ‰) and both indicate a much greater contribution from magma. (2) The Habo alkaline intrusion has relatively homogeneous Pb isotopic compositions with ^206pb/^204pb ranging from 18.608 to 18.761, ^207pb/^204pb from 15.572 to 15.722 and ^20spb/^204pb from 38.599 to 39.110. These Pb isotope ratios are similar to those of Au deposits, whose ^206pb/^204pb range from 18.564 to 18.734, ^20Tpb/^20apb from 15.582 to 15.738 and ^208pb/^204pb from 38.592 to 39.319. Pb ratios in both the intrusion and Au deposits suggest that Pb mainly derived from the depth, probably represents a mixture of mantle and crust. Pb-(Zn) deposits, however, show a decentralized trait, and most of them are similar to that of the alkaline intrusion with ^206pb/^204pb ranging from 18.523 to 18.648, ^207pb/^204pb from 15.599 to 15.802, and ^20spb/^204pb from 38.659 to 39.206. (3) In the plumbotectonic diagram ^20Tpb/^204pb versus ^206pb/^204pb, almost all of Au and Pb-(Zn) deposits have the same projection area with the Habo alkaline intrusion, which indicates that those deposits almost share the same source with the alkaline intrusion. (4) Isotopic age of the Habo alkaline intrusion is 36-33 Ma, which is similar to that of Beiya, whose ore- related alkaline porphyries age is 38-31 Ma and molybdenite Re-Os age is 36.9 Ma. Therefore, along with S-Pb isotope traits, we suggest that the Habo Au and Pb-(Zn) deposits should be typically Ailaoshan-Red RiverCenozoicalkaline-related deposits and ore-forming ages of these deposits should be later than that of the Habo alkaline intrusion.
文摘A preliminary study on the advance and the retreat of Qingtu Lake and its climatic records of the Holocene lacustrine deposits has been made through comprehensive analysis. The study shows that the modes characteristics of climatic change in Eastern Hexi Corridor was provided with the corresponding relationship of warm moist and cold dry during the scale longer than hundred years. As a result of climatic changes and human activities, Qingtu Lake cycle has undergone four lake retreated and three lake advanced stages since 6000 a B.P. Based on the study on lacustrine sedimentary color, grain size, Fe 3+ /Fe 2+ and organic matter, the authors put forward that a warm period existed during the phase of 335-480 A.D. in the studied area. This warm period could be further testified by a lot of evidences obtained from the historical documents and the natural records of Qingtu Lake. In brief, the evolution of lakes in Eastern Hexi Corridor is characterized by sedimentary continuity, fast sedimentary rate and high resolution, it not only indicate the paleoenvironmental and climatic change in Holocene, but also can reflect the intensity of Eastern Asia monsoon.