Effect of Rare Earth Elements on Depositing Rate of Nickel Alloy Brush Plating Coatings

The effect of four kinds of rare earth elements on the depositing rate of Ni-based alloy brush plating coatings was investigated. The results indicate that all of the selected rare earth elements increase the depositing rate of Ni-based alloy coatings, and Sm increases the depositing rate most obviously. There is an optimum amount of rare earth addition in the plating solution. With the change of plating voltage to a certain extent, the results reveal no differences. The mechanism of the increase of the depositing rate was analyzed.

Prediction Model of Wax Deposition Rate in Waxy Crude Oil Pipelines by Elman Neural Network Based on Improved Reptile Search Algorithm

A hard problem that hinders the movement of waxy crude oil is wax deposition in oil pipelines.To ensure the safe operation of crude oil pipelines,an accurate model must be developed to predict the rate of wax deposition in crude oil pipelines.Aiming at the shortcomings of the ENN prediction model,which easily falls into the local minimum value and weak generalization ability in the implementation process,an optimized ENN prediction model based on the IRSA is proposed.The validity of the new model was confirmed by the accurate prediction of two sets of experimental data on wax deposition in crude oil pipelines.The two groups of crude oil wax deposition rate case prediction results showed that the average absolute percentage errors of IRSA-ENN prediction models is 0.5476% and 0.7831%,respectively.Additionally,it shows a higher prediction accuracy compared to the ENN prediction model.In fact,the new model established by using the IRSA to optimize ENN can optimize the initial weights and thresholds in the prediction process,which can overcome the shortcomings of the ENN prediction model,such as weak generalization ability and tendency to fall into the local minimum value,so that it has the advantages of strong implementation and high prediction accuracy.

Growth Rate of a-Si∶H Film Influenced by Magnetic Field Gradient in MWECR CVD Plasma System

The magnetic field profiles,which are produced by three ways in the deposition chamber and plasma chamber of single coil divergent field MWECR CVD system,are investigated.The magnetic field gradient of these magnetic field profiles is obtained quantitatively by using Lorentz fit.The results indicate that the gradient value of the magnetic field profile near by the substrate,which is produced by a coil current with 137.7A if a SmCo permanent magnet is equipped under the substrate holder,is the largest;when the SmCo permanent magnet is taken away,the larger one is produced by the coil current with 137.7A and the smallest one produced by a coil current with 115.2A.High deposition rate of a-Si∶H film is observed near by the substrate with high magnetic field gradient.But uneven deposition rate along the radius of the sample holder is also found by infrared analysis technology when sample is deposited in magnetic field profile,which is produced by the coil current with 137.7A if the SmCo permanent magnet is equipped under the substrate holder.

Challenges and opportunities in the production of magnesium parts by directed energy deposition processes

Mg-alloys have gained considerable attention in recent years for their outstanding properties such as lightweight,high specific strength,and corrosion resistance,making them attractive for applications in medical,aerospace,automotive,and other transport industries.However,their widespread application is hindered by their low formability at room temperature due to limited slip systems.Cast Mg-alloys have low mechanical properties due to the presence of casting defects such as porosity and anisotropy in addition to the high scrap.While casting methods benefit from established process optimization techniques for these problems,additive manufacturing methods are increasingly replacing casting methods in Mg alloys as they provide more precise control over the microstructure and allow specific grain orientations,potentially enabling easier optimization of anisotropy properties in certain applications.Although metal additive manufacturing(MAM)technology also results in some manufacturing defects such as inhomogeneous microstructural evolution and porosity and additively manufactured Mg alloy parts exhibit lower properties than the wrought parts,they in general exhibit superior properties than the cast counterparts.Thus,MAM is a promising technique to produce Mg alloy parts.Directed energy deposition processes,particularly wire arc directed energy deposition(WA-DED),have emerged as an advantageous additive manufacturing(AM)technique for metallic materials including magnesium alloys,offering advantages such as high deposition rates,improved material efficiency,and reduced production costs compared to subtractive processes.However,the inherent challenges associated with magnesium,such as its high reactivity and susceptibility to oxidation,pose unique hurdles in the application of this technology.This review paper delves into the progress made in the application of DED technology to Mg-alloys,its challenges,and prospects.Furthermore,the predominant imperfections,notably inhomogeneous microstructure evolution and porosity,observed in Mg-alloy components manufactured through DED are discussed.Additionally,the preventive measures implemented to counteract the formation of these defects are explored.

Study of bias voltage effect on the performance of ta-C coating prepared by high power impulse magnetron sputtering

The mechanical and frictional properties of ta-C coatings deposited on the substrate surface affect applications in the field of cutting tools and wear-resistant components.In this paper,the effect of bias parameters on the performance of ta-C coatings was investigated based on high power impulse magnetron sputtering(HiPIMS)technology.The results show that bias voltage has a significant effect on the deposition rate,structure,and wear resistance of the coating.In the range of bias voltage−50 V to−200 V,the ta-C coating performance was the best under bias voltage−150 V.The thickness reached 530.4 nm,the hardness value reached 35.996 GPa,and the bonding force in-creased to 14.2 N.The maximum sp3 bond content was 59.53% at this condition.

Online evaluation of electroless deposition rate by electrochemical noise method

Continuous noise resistance calculation(CNRC)technique was used for online determination of the electroless nickel deposition rate on zirconium pretreated magnesium alloy.For this purpose,the noise resistance(R_n) variation with time was calculated for the pretreated alloy surface in the electroless plating solution.The CNRC results were described by energy dispersive X-ray spectroscopy(EDS)and scanning electron microscopy(SEM)techniques.Also,potentiodynamic polarization and gravimetric measurements were used for determination of the electroless deposition rate at the same time period and the results were compared with the CNRC results.The Rn variation with plating time shows that the electroless plating consists of different stages with various deposition rates.The results of the CNRC and polarization methods were not in acceptable agreement due to the limitations of the polarization method for online monitoring of the deposition rate.However,the results of the gravimetric measurements were in complete agreement with the CNRC technique and so,the CNRC can be considered as suitable tool for online evaluation of the electroless deposition rate.

Effect of deposition rate on microstructure and mechanical properties of wire arc additive manufacturing of Ti-6Al-4V components

Wire arc additive manufacturing(WAAM)is a novel manufacturing technique by which high strength metal components can be fabricated layer by layer using an electric arc as the heat source and metal wire as feedstock,and offers the potential to produce large dimensional structures at much higher build rate and minimum waste of raw material.In the present work,a cold metal transfer(CMT)based additive manufacturing was carried out and the effect of deposition rate on the microstructure and mechanical properties of WAAM Ti-6Al-4V components was investigated.The microstructure of WAAM components showed similar microstructural morphology in all deposition conditions.When the deposition rate increased from 1.63 to 2.23 kg/h,the ultimate tensile strength(UTS)decreased from 984.6 MPa to 899.2 MPa and the micro-hardness showed a scattered but clear decline trend.

Investigation on the deposition rate and the dilution ratio of plasma surface welding

A new kind of plasma technology with both high deposition rate and low dilution ratio was developed under the calculation and analysis of the arc flame characteristics of plasma arc,the kinematics behavior of powder and powder's heating in the arc. Compared with normal plasma surfacing method, the idea using constricting nozzle with small orifice diameter, long plasma arc and increasing the distance from meeting point of the two beams of powder to workpiece, to achieve the goals of high deposition rate and low dilution ratio, was put forward here. In order to prove this idea, a set of experimental system was built up and obtained satisfied results including high deposition rate(more than 25 kg/h )and low dilution ratio(less than 5%). The success of this study offers a promising prospect for developing the powder plasma surface welding in China and may open a way to improve this technology further in efficiency and quality.

Effect of frequency and pulse-on time of high power impulse magnetron sputtering on deposition rate and morphology of titanium nitride using response surface methodology

Titanium nitride thin films were deposited on silicon by high power impulse magnetron sputtering(HiPIMS)method at different frequencies(162-637 Hz)and pulse-on time(60-322μs).Response surface methodology(RSM)was employed to study the simultaneous effect of frequency and pulse-on time on the current waveforms and the crystallographic orientation,microstructure,and in particular,the deposition rate of titanium nitride at constant time and average power equal to 250 W.The crystallographic structure and morphology of deposited films were analyzed using XRD and FESEM,respectively.It is found that the deposition rate of HiPIMS samples is tremendously dependent on pulse-on time and frequency of pulses where the deposition rate changes from 4.5 to 14.5 nm/min.The regression equations and analyses of variance(ANOVA)reveal that the maximum deposition rate(equal to(17±0.8)nm/min)occurs when the frequency is 537 Hz and pulse-on time is 212μs.The experimental measurement of the deposition rate under this condition gives rise to the deposition rate of 16.7 nm/min that is in good agreement with the predicted value.

Analysis on Suspended Sediment Deposition Rate for Muddy Coast of Reclaimed Land

A new expression for calculating suspended fine-sediment deposition rate is developed based on theoretic analysis and experiments. The resulting equation is applied to simulation of fine sediment deposition in the reclaimed land in the Hangzhou Bay, China. The hydrodynamic environment in this area is solved by use of a long wave model, which gives the 2D-velocity field and considers bathymetric changes due to fine sediment deposition. The expression is proved convenient to use in engineering practice, and the predicted deposition rate agrees with the annual data available from field measurements from the first year to the third year after the construction of the long groin as a reclaiming method.

Spatial and temporal gradients in the rate of dust deposition and aerosol optical thickness in southwestern Iran

The southwestern Iran is one of the regions that are most prone to dust events.The objective of this study is the analysis of the spatial and temporal distributions of dust deposition rate as a key factor for finding the relative impact of the dust.First,the monthly mean aerosol optical thickness(AOT)from Moderate Resolution Imaging Spectroradiometer(MODIS)was analyzed and compared with the dust amount variations from ground deposition rate(GDR),and the results were further used to investigate the spatial and temporal distributions of dust events in southwestern Iran for the period between 2014 and 2015.Moving air mass trajectories,using the Hybrid Single-Particle Lagrangian Integrated Trajectory(HYSPLIT)model,were proven to be a discriminator of their local and regional origin.The results from GDR analysis produced a correlation coefficient between dust event history and deposition rates at dust magnitudes of>0.93 that is meaningful at the 95%confidence level.Furthermore,the deposition rates varied from 3 g/m2 per month in summer to 10 g/m2 per month in spring and gave insight into the transport direction of the dust.Within the same time series,AOT correspondences with MODIS on Terra in four aerosol thickness layers(clean,thin,thick,and strong thick)were shown in relation to each other.The deepest mixed layers were observed in spring and summer with a thickness of approximately 3500 m above ground level in the study area.Investigations of ground-based observations were correlated with the same variations for each aerosol thickness layer from MODIS images and they can be applied to discriminate layers of aeolian dust from layers of other aerosols.Together,dust distribution plots from AOT participated to enhance mass calculations and estimation deposition rates from the thick and strong thick aerosol thickness layers using the results from GDR.Despite all the advances of AOT,under certain circumstances,ground-based observations are better able to represent aerosol conditions over the study area,which were tested in southwestern Iran,even though the low number of observations is a commonly acknowledged drawback of GDR.

Deposition rate and morphology of carbon nanotubes at different positions in a CVD reactor

Carbon nanotubes （CNTs） were synthesized through the catalytic decomposition of a ferrocene-xylene mixture in a horizontal chemical vapor deposition reactor. The deposition rate of CNTs along the axial direction was measured. The morphology of CNTs was observed by scanning electron microscopy （SEM） and transmission electron microscopy （TEM）. The results showed that the deposition rate of CNTs along the axial direction first increased and later decreased, the position achieving the maximum deposition rate was influenced by the operating conditions. The morphologies of CNTs also changed along the axial direction.

High Growth Rate of Microcrystalline Silicon Films Prepared by ICP-CVD with Internal Low Inductance Antennas

The plasma parameters in ICP-CVD system with internal low inductance antennas（LIA） were diagnosed by Langmuir probe.The ions density（Ni） reached 1011-1012 cm-3,and the electron temperature（Te） was below ca.2 eV,which was slightly decreased with applied power.A p-type hydrogenated microcrystalline silicon（μc-Si：H） film was prepared on glass substrate.After optimization of the processing parameters in flow ratio of SiH4：B2H6：H2,a high quality μc-Si：H film with deposition rate above 1.0 nm/s was achieved in this work.

Selective Area Growth and Characterization of GaN Nanorods Fabricated by Adjusting the Hydrogen Flow Rate and Growth Temperature with Metal Organic Chemical Vapor Deposition

CaN nanorods are successfully fabricated by adjusting the flow rate ratio of hydrogen （H2）/nitrogen （N2） and growth temperature of the selective area growth （SAG） method with metal organic chemical vapor deposition （MOCVD）. The SAG template is obtained by nanospherical-lens photolithography. It is found that increasing the flow rate of 1-12 will change the CaN crystal shape from pyramid to vertical rod, while increasing the growth temperature will reduce the diameters of GaN rods to nanometer scale. Finally the CaN nanorods with smooth lateral surface and relatively good quality are obtained under the condition that the H2：N2 ratio is 1：1 and the growth temperature is 1030℃. The good crystal quality and orientation of GaN nanorods are confirmed by high resolution transmission electron microscopy. The cathodoluminescence spectrum suggests that the crystal and optical quality is also improved with increasing the temperature.

Effects of Temperature on the Deposition Rate of Supersaturated Silicic Acid on Ca-type Bentonite Tsuyoshi Sasagawa, Taiji Chida and Yuichi Niibori

Na-type bentonite is commonly used as a tunnel backfilling material to prevent groundwater and radionuclide migration during the construction of a geological disposal system for high-level radioactive waste in Japan. However, host rock fractures with strong water flow can develop groundwater paths in the backfilling material. Especially, the alteration to Ca-type bentonite causes degradation of the barrier performance and accelerates the development of groundwater paths. Additionally, using cementitious materials gradually changes pH between 13 and 8. High alkaline groundwater results in high solubility of silicic acid; therefore, silicic acid is eluted from the host rock. Downstream, in the low alkaline area, the groundwater becomes supersaturated in silicic acid. This acid is deposited on Ca-type bentonite, thus leading to the clogging of the groundwater paths. In the present study, we investigate the silicic acid deposition rate on Ca-type bentonite under 288-323 K for depths greater or equal to 500 m. The results indicate that temperature does not affect the silicic acid deposition rate up to 323 K. However, in this temperature range, the deposition of silicic acid on Ca-type bentonite in backfilled tunnels results in clogging of the flow paths.

Fabrication of Hydrogenated Microcrystalline Silicon Thin Films at Low Temperature by VHF-PECVD

Using H 2 diluted silane,series of μc Si∶H films are fabricated at low temperature with VHF PECVD.The thickness measurements reveal that the deposition rates are obviously enhanced with higher plasma excitation frequency or working pressure,but increase firstly and then decrease with the increase of plasma power density.Raman spectra show that the crystallinity and the average grain sizes of the films strongly depend on the temperature of substrate and the concentration of silane.However,the plasma excitation frequency only has effect on the crystallinity,and a maximum occurs during the further increase of plasma excitation frequency.From XRD and TEM experiments,three preferential crystalline orientations (111),(220) and (311) are observed,and the average grain sizes are different for every crystalline orientation.

Effects of rare earth on microstructures and properties of Ni-W-P-CeO_2-SiO_2 nano-composite coatings

Ni-W-P-CeO2-SiO2 nano-composite coatings were prepared on common carbon steel surface by pulse electrodeposition of nickel, tungsten, phosphorus, rare earth （nano-CeO2） and silicon carbide （nano-SiO2） particles. The effects of nano-CeO2 concentrations in electrolyte on microstructures and properties of nano-composite coatings were studied. The samples were characterized with chemical compositions, elements distributions, microhardness and microstructures. The results indicated that when nano-CeO2 concentration was controlled at 10 g/L, the nano-composite coatings possessed higher microhardness and compact microstmctures with clear outline of spherical matrix metal crystallites, fine crystallite sizes and uniform distribution of elements W, P, Ce and Si within the Ni-W-P matrix metal. Increasing the nano-CeO2 particles concentrations from 4 to 10 g/L led to refinement in grain structure and improvement of microstructures, while when increased to 14 g/L, the crystallite sizes began to increase again and there were a lot of small boss with nodulation shape appearing on the nano-composite coatings surface.

Characteristic of laser-MIG hybrid welding with filling additional cold wire for aluminum alloy

The weld appearance, deposition rate, welding efficiency, stability of arc, laser keyhole characteristic, and weld property were studied by using a novel laser-MIG hybrid welding process with filling wire of aluminum alloy. The results were also compared with those by conventional laser-MIG hybrid welding process. It was found that with the suitable process parameters this novel welding process for aluminum alloy was stable and final weld bead had fine appearance. Compared to conventional laser-MIG hybrid welding process, during this novel welding process the stability of arc, the laser keyhole characteristic and the weld property were similar, while the keyhole cycle frequency and keyhole opening area had differences of 1.23% and 15.34%, respectively, and the welding efficiency increased by about 31% without increasing heat input.

Mathematical model and magnetic-control mechanism of the stability of rotating spray transfer

To realize stable rotating spray transfer in the region of high constant current is the key of realizing high deposition rate MAG welding process without helium in shielding gas and extending the welding current range of traditional MAG welding process. In this paper, the magnetic control mechanism of the rotating spray transfer is stated and mathematical model is given. Theoretic basis is established, which implements high deposition rate MAG welding process with magnetic control instead of helium in shielding gas.

Anthropogenic Effect on Deposition Dynamics of Lake Sediments Based on ^(137)Cs and ^(210)Pb_(ex) Techniques in Jiuzhaigou National Nature Reserve,China

Radionuclide dating techniques characterized by137Cs and210Pbex have recently been applied in the study of lake sediments around the world.In this study,a chronological series of sediment cores was established based on137Cs and210Pbex analyses along with the evaluation of sediment properties,such as particle size distribution,total organic carbon(TOC),carbonate content,and acid-insoluble residue,to study sediment accumulation rates,sediment sources,and responses to human activities in the Jiuzhaigou National Nature Reserve in southwestern China.In terms of the particle size distribution of sediments,silt content was the highest,and clay and sand contents were relatively low.The sediments displayed high TOC contents because of the significant amounts of vegetation grown in the lakes.The carbonate content was also high due to the overall geological background of carbonates in Jiuzhaigou.Carbonate content tended to decline from top to bottom in the sediment cores,whereas the acid-insoluble residue tended to increase.These results suggested that the depth variation of the environmental parameters of the sediments in two lakes in Jiuzhaigou would correspond to each other.The results indicated that the sediment rate of Jiuzhaigou was generally high with strong siltation,indicating that serious soil loss was induced by intensive human activities in the basin over the past decades.The increases in the mass accumulation rate,contents of acid-insoluble residue,and mean particle size during the periods of 1840–1900s,late 1930s–early 1950s,1966–1978,and2003–2006 revealed the occurrence of severe soil and water loss as a result of extensive agricultural expansion,large-scale deforestation,and road construction in Jiuzhaigou.The deposition rate and the properties of lacustrine sediments could reflect the significant impact of human activities on lake sedimentation during Jiuzhaigou′s history.