Electron paramagnetic resonance spectra, absorption spectra, cathodoluminescence spectra and infrared spectra of sphalerite from the Lechang remoulded sedimentary lead-zinc deposit have been studied so as to provide m...Electron paramagnetic resonance spectra, absorption spectra, cathodoluminescence spectra and infrared spectra of sphalerite from the Lechang remoulded sedimentary lead-zinc deposit have been studied so as to provide microscopic evidence for the formation conditions and mineralization stages of the deposit as well as the geochemical processes of mineralization. On the basis of thermodynamic calculations, the stable fields of sphalerite from different mineralization stages were determined and are shown in logfs_2-logfo_2 diagrams; furthermore. the physico-chemical conditions of mineralization and the properties of mineralization solutions are discussed so that reliability of the genetic information provided by the spectroscopy of sphalerite may also be verified. It is suggested that the temperature and pH value of the mineralization system decrease, and so do the fugacities of O_2, S_2, H_2. and H_2S and the activities of HS^- and SO_4^(2-) from the early to late stages of minerahzation.展开更多
1 Introduction The eastern Tianshan region covers around 60000 km2in area and is located in the eastern part of Xinjiang.The district contains various types mineral commodities including Cu,Ni,Au,Fe,Pb and Zn(Wang et ...1 Introduction The eastern Tianshan region covers around 60000 km2in area and is located in the eastern part of Xinjiang.The district contains various types mineral commodities including Cu,Ni,Au,Fe,Pb and Zn(Wang et al.,2006).The Dannanhu belt in eastern part of the area is interpreted as a volcanic arc and forms an important mineralized zone bordered by the Turpan-Hami Basin to the north and Kanggur back-arc basin to the south.展开更多
文摘Electron paramagnetic resonance spectra, absorption spectra, cathodoluminescence spectra and infrared spectra of sphalerite from the Lechang remoulded sedimentary lead-zinc deposit have been studied so as to provide microscopic evidence for the formation conditions and mineralization stages of the deposit as well as the geochemical processes of mineralization. On the basis of thermodynamic calculations, the stable fields of sphalerite from different mineralization stages were determined and are shown in logfs_2-logfo_2 diagrams; furthermore. the physico-chemical conditions of mineralization and the properties of mineralization solutions are discussed so that reliability of the genetic information provided by the spectroscopy of sphalerite may also be verified. It is suggested that the temperature and pH value of the mineralization system decrease, and so do the fugacities of O_2, S_2, H_2. and H_2S and the activities of HS^- and SO_4^(2-) from the early to late stages of minerahzation.
基金financially supported by Chinese National Basic Research 973 Program(2014CB440803)the National Natural Science Foundation of China(41572077)China Geological Survey Bureau(12120114065801,121201001000150010 and 121201004000150017-43)
文摘1 Introduction The eastern Tianshan region covers around 60000 km2in area and is located in the eastern part of Xinjiang.The district contains various types mineral commodities including Cu,Ni,Au,Fe,Pb and Zn(Wang et al.,2006).The Dannanhu belt in eastern part of the area is interpreted as a volcanic arc and forms an important mineralized zone bordered by the Turpan-Hami Basin to the north and Kanggur back-arc basin to the south.
