The utilization of coal derived pyrite by electrolysis was studied. It is obvious that the sulfur and Fe in pyrite can be electrolyzed into Fe 3+ and SO 2- 4, and the no pollutant is drained off. In this paper, the in...The utilization of coal derived pyrite by electrolysis was studied. It is obvious that the sulfur and Fe in pyrite can be electrolyzed into Fe 3+ and SO 2- 4, and the no pollutant is drained off. In this paper, the influence of conditions, including electrolysis potential, time, temperature, the acidity of electrolysis solutions, the concentration of adding agent, the concentration of pyrite, and the rate of conversion of pyrite (Cr) was investigated. Cr increases with the rise of potential, time, temperature, acidity and the concentration of additive agent, but decreases with the rise of concentration of pyrite. At the certain conditions (at the potential of 3 0 V, temperature of 298 K, time of 12 h, the concentration of MnSO 4 of 6%, concentration of pyrite of 4%, and concentration of acid of 10%), Cr is high to 93%. In the same time, the mechanism of electrolysis of pyrite was provided. The electrolysis of pyrite is actually the recycle of Mn ion between anodic surface and pyrite. At last, the production of FeSO 4·7H 2O through electrolysis of pyrite was introduced.展开更多
Characteristic spectra in the 0.5-2.5 terahertz (THz) range of three commercial derv fuel oils have been obtained using THz time-domain spectroscopy and calculated using density functional theory.The simulated results...Characteristic spectra in the 0.5-2.5 terahertz (THz) range of three commercial derv fuel oils have been obtained using THz time-domain spectroscopy and calculated using density functional theory.The simulated results and experimental absorption curves suggest that the skeleton vibration is predominant in the THz region,and the absorption bumps of diesels are a superposition of various components.The investigation demonstrates that different diesels can be distinguished using THz time-domain spectroscopy and THz technology is a promising method to detect the composition and properties of diesels via chemical analysis.展开更多
文摘The utilization of coal derived pyrite by electrolysis was studied. It is obvious that the sulfur and Fe in pyrite can be electrolyzed into Fe 3+ and SO 2- 4, and the no pollutant is drained off. In this paper, the influence of conditions, including electrolysis potential, time, temperature, the acidity of electrolysis solutions, the concentration of adding agent, the concentration of pyrite, and the rate of conversion of pyrite (Cr) was investigated. Cr increases with the rise of potential, time, temperature, acidity and the concentration of additive agent, but decreases with the rise of concentration of pyrite. At the certain conditions (at the potential of 3 0 V, temperature of 298 K, time of 12 h, the concentration of MnSO 4 of 6%, concentration of pyrite of 4%, and concentration of acid of 10%), Cr is high to 93%. In the same time, the mechanism of electrolysis of pyrite was provided. The electrolysis of pyrite is actually the recycle of Mn ion between anodic surface and pyrite. At last, the production of FeSO 4·7H 2O through electrolysis of pyrite was introduced.
基金supported by the Program for New Century Excellent Talents in Universitythe National Natural Science Foundation of China+2 种基金the Research Fund for the Doctoral Program of Higher Educationthe State Key Laboratory of Heavy Oil Processing,China University of PetroleumForesight Fund Program from China University of Petroleum (Beijing)
文摘Characteristic spectra in the 0.5-2.5 terahertz (THz) range of three commercial derv fuel oils have been obtained using THz time-domain spectroscopy and calculated using density functional theory.The simulated results and experimental absorption curves suggest that the skeleton vibration is predominant in the THz region,and the absorption bumps of diesels are a superposition of various components.The investigation demonstrates that different diesels can be distinguished using THz time-domain spectroscopy and THz technology is a promising method to detect the composition and properties of diesels via chemical analysis.
