Electroslag remelting(ESR) gives a combination of liquid metal refining and solidification structure control.One of the typical aspects of liquid metal refining during ESR for the advanced steel and alloy production i...Electroslag remelting(ESR) gives a combination of liquid metal refining and solidification structure control.One of the typical aspects of liquid metal refining during ESR for the advanced steel and alloy production is desulfurization.It involves two patterns, i.e., slag–metal reaction and gas–slag reaction(gasifying desulfurization).In this paper, the advances in desulfurization practices of ESR are reviewed.The effects of processing parameters, including the initial sulfur level of consumable electrode, remelting atmosphere, deoxidation schemes of ESR,slag composition, melting rate, and electrical parameters on the desulfurization in ESR are assessed.The interrelation between desulfurization and sulfide inclusion evolution during ESR is discussed, and advancements in the production of sulfur-bearing steel at a high-sulfur level during ESR are described.The remaining challenges for future work are also proposed.展开更多
The systematic research about the adsorption desulfurization and competitive behavior from 1-hexene over cesium-exchanged Y zeolites has been investigated. The structural properties of the adsorbents were characterize...The systematic research about the adsorption desulfurization and competitive behavior from 1-hexene over cesium-exchanged Y zeolites has been investigated. The structural properties of the adsorbents were characterized by X-ray diffraction（XRD）, N_2 sorption（BET） and thermal analysis（TGA）. The effects of calcination temperature, calcination atmosphere, and adsorption temperature were studied by the dynamic and static tests. The competitive adsorption mechanisms between thiophene and 1-hexene were studied by in-situ Fourier transform infrared spectroscopy（in-situ FTIR） and temperature-programmed desorption（TPD）. CsY adsorbents exhibited high selectivity for thiophene even when a large amount of olefins exist.In-situ FTIR spectra of thiophene and 1-hexene adsorption indicated that both thiophene and 1-hexene were mainly adsorbed on CsY via π-complexation. The higher desorption activated energy and higher adsorption heat of thiophene than 1-hexene obtained by thiophene-TPD and hexene-TPD has revealed that thiophene is adsorbed more strongly in CsY adsorbents than 1-hexene.展开更多
基金financially supported by the National Natural Science Foundation of China (Nos.51874026 and 52074027)the Fundamental Research Funds for the Central Universities (No.FRF-TP-18-004A3)the State Key Laboratory of Advanced Metallurgy of China (No.41619019)。
文摘Electroslag remelting(ESR) gives a combination of liquid metal refining and solidification structure control.One of the typical aspects of liquid metal refining during ESR for the advanced steel and alloy production is desulfurization.It involves two patterns, i.e., slag–metal reaction and gas–slag reaction(gasifying desulfurization).In this paper, the advances in desulfurization practices of ESR are reviewed.The effects of processing parameters, including the initial sulfur level of consumable electrode, remelting atmosphere, deoxidation schemes of ESR,slag composition, melting rate, and electrical parameters on the desulfurization in ESR are assessed.The interrelation between desulfurization and sulfide inclusion evolution during ESR is discussed, and advancements in the production of sulfur-bearing steel at a high-sulfur level during ESR are described.The remaining challenges for future work are also proposed.
基金financially supported by the National Natural Science Foundation of China(No.21276086)supported by the National Natural Science Foundation of China(No.21276086)
文摘The systematic research about the adsorption desulfurization and competitive behavior from 1-hexene over cesium-exchanged Y zeolites has been investigated. The structural properties of the adsorbents were characterized by X-ray diffraction（XRD）, N_2 sorption（BET） and thermal analysis（TGA）. The effects of calcination temperature, calcination atmosphere, and adsorption temperature were studied by the dynamic and static tests. The competitive adsorption mechanisms between thiophene and 1-hexene were studied by in-situ Fourier transform infrared spectroscopy（in-situ FTIR） and temperature-programmed desorption（TPD）. CsY adsorbents exhibited high selectivity for thiophene even when a large amount of olefins exist.In-situ FTIR spectra of thiophene and 1-hexene adsorption indicated that both thiophene and 1-hexene were mainly adsorbed on CsY via π-complexation. The higher desorption activated energy and higher adsorption heat of thiophene than 1-hexene obtained by thiophene-TPD and hexene-TPD has revealed that thiophene is adsorbed more strongly in CsY adsorbents than 1-hexene.
