In this article, a detection method for organic explosives by capillary electrophoresis (CE) is developed based on previous detection techniques. Firstly, a buffer solution consisting of 50 mmol·L-1 sodium dodecy...In this article, a detection method for organic explosives by capillary electrophoresis (CE) is developed based on previous detection techniques. Firstly, a buffer solution consisting of 50 mmol·L-1 sodium dodecyl sulfate (SDS), 20 mmol·L-1 sodium tetraborate and 5% methanol was prepared and the UV detection in this buffer solution was conducted for three common organic explosives, including TNT, DNT and PETN. Then, the capillary UV detection method was investigated in terms of the transition time repeatability, the linear relationship between mass concentration and peak area and the limit of detection. The results revealed good reliability and stability of this method. In addition, these samples were characterized by photodiode array detector (PDA) to verify the qualitative results of UV detection.展开更多
To objectively obtain the three-dimensional coordinates of the projectile fuze proximity explosion when projectile intersects the head of missile target, we propose a dynamic seven photoelectric detection screen test ...To objectively obtain the three-dimensional coordinates of the projectile fuze proximity explosion when projectile intersects the head of missile target, we propose a dynamic seven photoelectric detection screen test method, which is made up of six plane detection screens and a flash photoelectric dynamic detection screen. The three-dimensional coordinates calculation model of the projectile proximity explosion position based on seven plane detection screens with dynamic characteristics is established.According to the relation of the dynamic seven photoelectric detection screen planes and the time values,the analytical function of the projectile proximity explosion position parameters under non-linear motion is derived. The projectile signal filtering method based on discrete wavelet transform is explored in this work. Additionally, the projectile signal recognition algorithm using an improved particle swarm is proposed. Based on the characteristics of the time duration and the signal peak error for the projectile passing through the detection screen, the signals attribution of the same projectile passing through six detection screens are analyzed for obtaining precise time values of the same projectile passing through the detection screens. On the basis of the projectile fuze proximity explosion test, the linear motion model and the proposed non-linear motion model are used to calculate and compare the same group of projectiles proximity explosion position parameters. The comparison of test results verifies that the proposed test method and calculation model in this work accurately obtain the actual projectile proximity explosion position parameters.展开更多
Usefulness of sensor network applications in human life is increasing day by day and the concept of wireless connection promises new application areas. Sensor network can be very beneficial in saving human life from t...Usefulness of sensor network applications in human life is increasing day by day and the concept of wireless connection promises new application areas. Sensor network can be very beneficial in saving human life from terrorist attacks causing explosion in certain areas leading to casualties. But realization of the sensor network application in explosive detection requires high scalability of the sensor network and fast transmission of the information through real time monitoring and control. In this paper a novel mechanism for explosive trace detection in any populated area by the use of mobile telephony has been described. The aim is to create a system that will assure common men, local population and above all the nation a secured environment, without disturbing their freedom of movement. It would further help the police in detection of explosives more quickly, isolation of suicide bombers, remediation of explosives manufacturing sites, and forensic and criminal investigation. To achieve this, the paper has projected an idea that can combine the strength of the mobile phones, the polymer sensor and existing cellular network. The idea is to design and embed a tiny cog-nitive radio sensor node into the mobile phone that adapts to the changing environment by analyzing the RF surroundings and adjusting the spectrum use appropriately. The system would be capable of detecting explo-sives within a defined territory. It would communicate the location of the detected explosives to the respec-tive service provider, which in turn would inform the law and enforcement agency or Police.展开更多
The magnetic improvised explosive devices （IEDs）, also commonly known as a type of a sticky bomb, is simply constructed devices yet very lethal. This paper puts forward the idea of an electronic compass that is capa...The magnetic improvised explosive devices （IEDs）, also commonly known as a type of a sticky bomb, is simply constructed devices yet very lethal. This paper puts forward the idea of an electronic compass that is capable of sensing the change of a magnetic field generated by a magnet and translating it into interpretable data, which could act as the base for the further studies and assist in developing a greener automated system for detecting this device. The electronic compass is specifically chosen for reducing power consumption of systems in addition to the fact that it is available at a low cost.展开更多
This paper adopts counterexample guided abstraction refinement scheme to alleviate the state explosion problem of deadlock detection. We extend the classical labeled transition system models by qualifying transitions ...This paper adopts counterexample guided abstraction refinement scheme to alleviate the state explosion problem of deadlock detection. We extend the classical labeled transition system models by qualifying transitions as certain and uncertain to make deadlock-freedom conservative, i.e. if the abstraction of a system is deadlock-free, then the system is deadlock-free. An abstraction refinement approach to deadlock detection is proposed, and the correctness of the approach is proved.展开更多
Fast neutron activation of nitrogen and oxygen contained in the explosives used for simulated mine samples has been preliminarily carried out in our laboratory. By spectroscopic analysis of characteristic γ-rays emit...Fast neutron activation of nitrogen and oxygen contained in the explosives used for simulated mine samples has been preliminarily carried out in our laboratory. By spectroscopic analysis of characteristic γ-rays emitted from activated nitrogen and oxygen, mine can be identified almost instantly. This technique integrated with robottes would be a method for mine scavenging.展开更多
The sensitive and on-site detection of inorganic explosives has raised serious concerns regarding public safety. However, high stability and non-volatility features currently limit their rapid on-site detection. Surfa...The sensitive and on-site detection of inorganic explosives has raised serious concerns regarding public safety. However, high stability and non-volatility features currently limit their rapid on-site detection. Surface-enhanced Raman spectroscopy （SERS） is emerging as a powerful technique for the trace-level detection of different molecules. Plasmonic Ag nanowires were produced by a hydrothermal synthesis method using polyvinylpyrrolidone （PVP） as a negatively charged stabilizer. Here, we report a rapid detection method for inorganic explosives based on a simple surface swab with a positively charged diethyldithiocarbamate-modified Ag nanowire membrane coupled with SERS. This membrane, serving as an excellent SERS substrate with high uniformity, stability, and reusability, can capture both typical oxidizers in inorganic explosives and organic nitro-explosives, via electrostatic interaction. The detection level of perchlorates （ClO4-）, chlorates （ClO3-）, nitrates （NO3）-, picric acid, and 2,4- dinitrophenol is as high as 2.0, 1.7, 0.1, 45.8, and 36.6 ng, respectively. In addition, simulated typical inorganic explosives such as black powders, firecrackers, and match heads could also be detected. We believe that this membrane represents an attractive alternative for rapid on-site detection of inorganic explosives with high efficiency.展开更多
In this work, a new porous Zrobased metal-organic framework （MOF） with a large Brunner-Emmet-Teller （BET） surface area was prepared by the solvothermal method using 4,4＇-（naphthalene-1,4-diyl）dibenzoic acid （N...In this work, a new porous Zrobased metal-organic framework （MOF） with a large Brunner-Emmet-Teller （BET） surface area was prepared by the solvothermal method using 4,4＇-（naphthalene-1,4-diyl）dibenzoic acid （NDDA） as the organic ligand, and the luminescent detection performance was studied systematically. The experiments comb- ing with computations indicate that the as-synthesized material can sensitively and selectively detect nitro explo- sives and metal ions, especially for 2,4,6-trinitrophenol （TNP） and Fe3＋, due to the possible electron transfer from inorganic moieties to organic moieties with naphthalene part. Interestingly, owing to its high porosity and large sur- face area, this Zr-MOF showed quick luminescent response time （in 1 min） for TNP and Fe3＋. The results obtained may provide useful information for the design of MOFs with the large permanent porosity in sensing applications for large molecules in the future.展开更多
Based on the features and requirements of gas drainage system, an optimized explosion resistance technology is done after a comprehensive analysis and research about the triple IR （Infrared Ray） flame detection tech...Based on the features and requirements of gas drainage system, an optimized explosion resistance technology is done after a comprehensive analysis and research about the triple IR （Infrared Ray） flame detection technology, explosion resistance valve technology and explosion resistance control technology. An intelligent PLC （Programmable Logic Controller） resistance control system is designed which can cut offthe gas branch quickly and accurately, and the controller have automatic pressure maintaining function, valve rotation limit function, remote and local control interlock function. The reliability and rationality of explosion resistance technology is verified by gas pipeline explosion propagation and resistance simulation test. Overall response time of explosion resistance system is less than 100ms, and the spread of fire in gas pipeline can be prevented effectively.展开更多
The development of conjugated nanomaterials with high sensitivity and super-amplified quenching effect for the detection of nitrophenol explosives is still a great challenge. Herein, we developed conjugated hollow nan...The development of conjugated nanomaterials with high sensitivity and super-amplified quenching effect for the detection of nitrophenol explosives is still a great challenge. Herein, we developed conjugated hollow nanospheres constructed by using aggregation-induced emission(AIE) active 1,3,5-tris(4-formyl-phenyl)benzene(TFPB). The high emission hollow nanospheres with uniform size and admirable dispersiveness exhibited obvious fluorescence quenching response with the addition of nitrophenol explosives owing to the photoinduced electron transfer(PET) from the hollow nanospheres to nitrophenol explosives. The Stern-Volmer constants of hollow spheres for 2,4,6-trinitrophenol(TNP), 4-nitrophenol(NP) and 2,4-dinitrophenol(DNP) can reach 9.67×10^5, 3.14×10^5 and 4.8×10^4 M-1, respectively. Furthermore, the handy test paper coated with hollow nanospheres was prepared and showed a good response toward TNP solutions and vapor. The study provides a novel strategy to construct AIE-active conjugated hollow nanospheres for efficient nitrophenol explosives sensing.展开更多
Anovel metal-organic framework{[In_(3)(TATAT)_(2)]·3CH_(3)NH_(3)·7NMF·8H_(2)O}[JLU-MOF101,H_(6)TATAT=5,5′,5″-(1,3,5-triazine-2,4,6-triyl)tris-(azanediyl)triisophthalate,NMF=N-methyl-formamide]with cor...Anovel metal-organic framework{[In_(3)(TATAT)_(2)]·3CH_(3)NH_(3)·7NMF·8H_(2)O}[JLU-MOF101,H_(6)TATAT=5,5′,5″-(1,3,5-triazine-2,4,6-triyl)tris-(azanediyl)triisophthalate,NMF=N-methyl-formamide]with cor topology has been synthesized under solvothermal conditions.The framework of JLU-MOF101 is constructed by{In(COO)_(4)}-nodes and a hexacarboxylic organic ligand.JLU-MOF101 exhibits excellent fluorescence properties in N,N-dimethylformamide(DMF)solution,and its emission spectrum can be greatly overlapped with the ultraviolet absorption spectra of trinitrophenol(TNP)and 2,4-dinitrophenol(2,4-DNP).As a result,JLU-MOF101 exhibits excellent performance of fluorescence quenching for TNP and 2,4-DNP.In addition,we demonstrate the selective detection capability of JLU-MOF101 through a large number of anti-interference tests.展开更多
文摘In this article, a detection method for organic explosives by capillary electrophoresis (CE) is developed based on previous detection techniques. Firstly, a buffer solution consisting of 50 mmol·L-1 sodium dodecyl sulfate (SDS), 20 mmol·L-1 sodium tetraborate and 5% methanol was prepared and the UV detection in this buffer solution was conducted for three common organic explosives, including TNT, DNT and PETN. Then, the capillary UV detection method was investigated in terms of the transition time repeatability, the linear relationship between mass concentration and peak area and the limit of detection. The results revealed good reliability and stability of this method. In addition, these samples were characterized by photodiode array detector (PDA) to verify the qualitative results of UV detection.
基金supported by Project of the National Natural Science Foundation of China (No.62073256, 61773305)the Key Science and Technology Program of Shaanxi Province (No.2020GY-125)Xi’an Science and Technology Innovation talent service enterprise project (No.2020KJRC0041)。
文摘To objectively obtain the three-dimensional coordinates of the projectile fuze proximity explosion when projectile intersects the head of missile target, we propose a dynamic seven photoelectric detection screen test method, which is made up of six plane detection screens and a flash photoelectric dynamic detection screen. The three-dimensional coordinates calculation model of the projectile proximity explosion position based on seven plane detection screens with dynamic characteristics is established.According to the relation of the dynamic seven photoelectric detection screen planes and the time values,the analytical function of the projectile proximity explosion position parameters under non-linear motion is derived. The projectile signal filtering method based on discrete wavelet transform is explored in this work. Additionally, the projectile signal recognition algorithm using an improved particle swarm is proposed. Based on the characteristics of the time duration and the signal peak error for the projectile passing through the detection screen, the signals attribution of the same projectile passing through six detection screens are analyzed for obtaining precise time values of the same projectile passing through the detection screens. On the basis of the projectile fuze proximity explosion test, the linear motion model and the proposed non-linear motion model are used to calculate and compare the same group of projectiles proximity explosion position parameters. The comparison of test results verifies that the proposed test method and calculation model in this work accurately obtain the actual projectile proximity explosion position parameters.
文摘Usefulness of sensor network applications in human life is increasing day by day and the concept of wireless connection promises new application areas. Sensor network can be very beneficial in saving human life from terrorist attacks causing explosion in certain areas leading to casualties. But realization of the sensor network application in explosive detection requires high scalability of the sensor network and fast transmission of the information through real time monitoring and control. In this paper a novel mechanism for explosive trace detection in any populated area by the use of mobile telephony has been described. The aim is to create a system that will assure common men, local population and above all the nation a secured environment, without disturbing their freedom of movement. It would further help the police in detection of explosives more quickly, isolation of suicide bombers, remediation of explosives manufacturing sites, and forensic and criminal investigation. To achieve this, the paper has projected an idea that can combine the strength of the mobile phones, the polymer sensor and existing cellular network. The idea is to design and embed a tiny cog-nitive radio sensor node into the mobile phone that adapts to the changing environment by analyzing the RF surroundings and adjusting the spectrum use appropriately. The system would be capable of detecting explo-sives within a defined territory. It would communicate the location of the detected explosives to the respec-tive service provider, which in turn would inform the law and enforcement agency or Police.
基金supported by the Malaysia Ministry of Higher Education under FRGS Grant No.6071306
文摘The magnetic improvised explosive devices （IEDs）, also commonly known as a type of a sticky bomb, is simply constructed devices yet very lethal. This paper puts forward the idea of an electronic compass that is capable of sensing the change of a magnetic field generated by a magnet and translating it into interpretable data, which could act as the base for the further studies and assist in developing a greener automated system for detecting this device. The electronic compass is specifically chosen for reducing power consumption of systems in addition to the fact that it is available at a low cost.
基金supported by the Natural Science Foundation of Shanghai (Grant No.09ZR1412100)the National Natural Science Foundation of China (Grant No.60673115)the Shanghai Leading Academic Discipline Project (Grant No.J50103)
文摘This paper adopts counterexample guided abstraction refinement scheme to alleviate the state explosion problem of deadlock detection. We extend the classical labeled transition system models by qualifying transitions as certain and uncertain to make deadlock-freedom conservative, i.e. if the abstraction of a system is deadlock-free, then the system is deadlock-free. An abstraction refinement approach to deadlock detection is proposed, and the correctness of the approach is proved.
文摘Fast neutron activation of nitrogen and oxygen contained in the explosives used for simulated mine samples has been preliminarily carried out in our laboratory. By spectroscopic analysis of characteristic γ-rays emitted from activated nitrogen and oxygen, mine can be identified almost instantly. This technique integrated with robottes would be a method for mine scavenging.
基金We thank the financial support from the National Basic Research Program of China （973 Program, No. 2013CB934301）, the National Natural Science Foundation of China （NSFC, Nos. 21377068 and 21575077）.
文摘The sensitive and on-site detection of inorganic explosives has raised serious concerns regarding public safety. However, high stability and non-volatility features currently limit their rapid on-site detection. Surface-enhanced Raman spectroscopy （SERS） is emerging as a powerful technique for the trace-level detection of different molecules. Plasmonic Ag nanowires were produced by a hydrothermal synthesis method using polyvinylpyrrolidone （PVP） as a negatively charged stabilizer. Here, we report a rapid detection method for inorganic explosives based on a simple surface swab with a positively charged diethyldithiocarbamate-modified Ag nanowire membrane coupled with SERS. This membrane, serving as an excellent SERS substrate with high uniformity, stability, and reusability, can capture both typical oxidizers in inorganic explosives and organic nitro-explosives, via electrostatic interaction. The detection level of perchlorates （ClO4-）, chlorates （ClO3-）, nitrates （NO3）-, picric acid, and 2,4- dinitrophenol is as high as 2.0, 1.7, 0.1, 45.8, and 36.6 ng, respectively. In addition, simulated typical inorganic explosives such as black powders, firecrackers, and match heads could also be detected. We believe that this membrane represents an attractive alternative for rapid on-site detection of inorganic explosives with high efficiency.
基金Financial support by the National Key Basic Re- search Programof China （＂973＂） （No. 2013CB733503）, the National Natural Science Foundation of China （Nos. 21606007, 21136001 and 21536001） and the Funda- mental Research Funds for the Central Universities （No. ZY1509） is greatly appreciated.
文摘In this work, a new porous Zrobased metal-organic framework （MOF） with a large Brunner-Emmet-Teller （BET） surface area was prepared by the solvothermal method using 4,4＇-（naphthalene-1,4-diyl）dibenzoic acid （NDDA） as the organic ligand, and the luminescent detection performance was studied systematically. The experiments comb- ing with computations indicate that the as-synthesized material can sensitively and selectively detect nitro explo- sives and metal ions, especially for 2,4,6-trinitrophenol （TNP） and Fe3＋, due to the possible electron transfer from inorganic moieties to organic moieties with naphthalene part. Interestingly, owing to its high porosity and large sur- face area, this Zr-MOF showed quick luminescent response time （in 1 min） for TNP and Fe3＋. The results obtained may provide useful information for the design of MOFs with the large permanent porosity in sensing applications for large molecules in the future.
文摘Based on the features and requirements of gas drainage system, an optimized explosion resistance technology is done after a comprehensive analysis and research about the triple IR （Infrared Ray） flame detection technology, explosion resistance valve technology and explosion resistance control technology. An intelligent PLC （Programmable Logic Controller） resistance control system is designed which can cut offthe gas branch quickly and accurately, and the controller have automatic pressure maintaining function, valve rotation limit function, remote and local control interlock function. The reliability and rationality of explosion resistance technology is verified by gas pipeline explosion propagation and resistance simulation test. Overall response time of explosion resistance system is less than 100ms, and the spread of fire in gas pipeline can be prevented effectively.
基金the National Natural Science Foundation of China(21835001,51773080,21674041,51573068,21221063)Program for Changbaishan Scholars of Jilin Province,Jilin Province Project(20160101305JC)the“Talents Cultivation Program”of Jilin University.
文摘The development of conjugated nanomaterials with high sensitivity and super-amplified quenching effect for the detection of nitrophenol explosives is still a great challenge. Herein, we developed conjugated hollow nanospheres constructed by using aggregation-induced emission(AIE) active 1,3,5-tris(4-formyl-phenyl)benzene(TFPB). The high emission hollow nanospheres with uniform size and admirable dispersiveness exhibited obvious fluorescence quenching response with the addition of nitrophenol explosives owing to the photoinduced electron transfer(PET) from the hollow nanospheres to nitrophenol explosives. The Stern-Volmer constants of hollow spheres for 2,4,6-trinitrophenol(TNP), 4-nitrophenol(NP) and 2,4-dinitrophenol(DNP) can reach 9.67×10^5, 3.14×10^5 and 4.8×10^4 M-1, respectively. Furthermore, the handy test paper coated with hollow nanospheres was prepared and showed a good response toward TNP solutions and vapor. The study provides a novel strategy to construct AIE-active conjugated hollow nanospheres for efficient nitrophenol explosives sensing.
基金supported by the National Natural Science Foundation of China(Nos.22171100,22288101)and the“111”Project of China(No.B17020).
文摘Anovel metal-organic framework{[In_(3)(TATAT)_(2)]·3CH_(3)NH_(3)·7NMF·8H_(2)O}[JLU-MOF101,H_(6)TATAT=5,5′,5″-(1,3,5-triazine-2,4,6-triyl)tris-(azanediyl)triisophthalate,NMF=N-methyl-formamide]with cor topology has been synthesized under solvothermal conditions.The framework of JLU-MOF101 is constructed by{In(COO)_(4)}-nodes and a hexacarboxylic organic ligand.JLU-MOF101 exhibits excellent fluorescence properties in N,N-dimethylformamide(DMF)solution,and its emission spectrum can be greatly overlapped with the ultraviolet absorption spectra of trinitrophenol(TNP)and 2,4-dinitrophenol(2,4-DNP).As a result,JLU-MOF101 exhibits excellent performance of fluorescence quenching for TNP and 2,4-DNP.In addition,we demonstrate the selective detection capability of JLU-MOF101 through a large number of anti-interference tests.
