Precise Molecular Weight Determination and Structure Characterization of End-functionalized Polymers:An NMR Approach via Combination of One-dimensional and Two-dimensional Techniques

We present here the application of one-dimensional and two-dimensional NMR techniques to characterize the structure of methoxyl end-functionalized polystyrenes （PS）. The peaks in 1H-NMR spectra corresponding to main-chain, side-chain and chain-end groups are assigned by 1H-1H gCOSY, 1H-13C gHSQC and gHMBC spectra. For the first time, the spin-lattice relaxation time （T1） of protons of the chain-ends is revealed to be affected more by polymer molecular weight （MW） than by the protons of the main-chains and the side-chains （almost independent from MW）. As a result, a much higher delay time （dl） for chain-ends （d1〉 20T1） is needed for quantitative NMR measurement when using end-group estimation method to obtain the MW of PS, which is in accordance with the value estimated by GPC. An improved method for the polymer MW determination is established, by combination of different NMR techniques to distinguish the peaks, and a large dl setting to achieve quantitative NMR analysis.

Value Assessment of Wetland Ecosystem Services in the Da Hinggan Mountains, China

This study examined regional differences in ecosystem services for the Da Hinggan Mountains(DHM),China.A correction index was constructed based on ten-year average net primary productivity(NPP)data.A new equivalent factor table that was suitable for the assessment of wetlands in the DHM was formed by using the expert weight determination method(EWDM).An evaluation model was established for evaluating the ecosystem service value(ESV)of wetlands in the DHM.The results show that in 2020,the total ESV of wetlands reached 93361×10^(6) USD,with the forest swamp and marsh ecosystems contributing the most.From the perspective of value composition,regulating services and supporting services are the main service functions of wetlands in the DHM.From 2010 to2020,ESV provided by wetlands increased by 4337×10^(6) USD/yr in the DHM.The value of forest swamp and peatland ecosystems increased by 18.6%and 12.7%,respectively,whereas the value of swamp,shrub swamp,and marsh decreased.The research results are of significance for contributing to local government performance evaluation and determining financial compensation for the provision of wetland ecosystem services.

SYNTHESIS AND NMR CHARACTERIZATION OF PRECURSORS OF EPOXY NETWORK AS POLYMER HOST FOR SOLID ELECTROLYTE

To raise the room temperature ionic conductivity and improve the mechanical strength of a PEO-based polymer electrolyte, a noncrystalline two-component epoxy electrolyte system has been prepared. The diglycidyl ether of polyethylene glycols as precursors of the system were synthesized by a two-step process. The presumed structure of the product was characterized, by ^(13)C, ~1H NMR and IR spectroscopy. It was found that a side-reaction occurred between the secondary hydroxyl group of PEG-chlorohydrin and epichlorohydrin in some degree, resulting in a by- product containing—CH_2Cl side group. By selecting a characteristic signal, which is undistorted by the increase in the length of CH_2 CH_2—O segment, a ~1H NMR approach of determining the equivalent epoxy weight (EEW) was proposed. The method is valid to specimens even though the EEW is as high as 2,000. The examination of the specimens by DSC showed that epoxidation greatly depressed the crystallinity of the PEG's, whereas the T_g was raised.

Orbit determination using incremental phase and TDOA of X-ray pulsar

X-ray pulsars offer stable, periodic X-ray pulse sequences that can be used in spacecraft positioning systems. A method using X-ray pulsars to determine the initial orbit of a satellite is presented in this paper. This method suggests only one detector to be equipped on the satellite and assumes that the detector observes three pulsars in turn. To improve the performance, the use of incremental phase in one observation duration is proposed, and the incremental phase is combined with the time difference of arrival(TDOA). Then, a weighted least squares(WLS) algorithm is formulated to calculate the initial orbit. Numerical simulations are performed to assess the proposed orbit determination method.