This paper presents the results of a series of studies on the influence of curing conditions on the strength development of high strength concrete. The 1-, 3-, 7-, 14- and 28-day strengths of four different mixes of G...This paper presents the results of a series of studies on the influence of curing conditions on the strength development of high strength concrete. The 1-, 3-, 7-, 14- and 28-day strengths of four different mixes of Grade 75 similar to 80 concrete, with or without pulverized fuel ash and/or condensed silica fume, under five different curing regimes were investigated. It is revealed that the curing conditions have significant influence on both the short term and long term strength development of the concrete and that concrete mixes of the same grade but containing different mineral admixtures show distinct favour for a curing regime. These results will be helpful for evaluating suitable curing methods for high strength concrete with different mix proportions.展开更多
In this experimental work, three groups of cement-slag mortars namely OPC, OPC-slag, and slag mortars were made. All were cured in both water and air under room temperature. Strength development was studied up to 90 d...In this experimental work, three groups of cement-slag mortars namely OPC, OPC-slag, and slag mortars were made. All were cured in both water and air under room temperature. Strength development was studied up to 90 days. The mortars were prepared using 0%, 50%, and 100% replacement with slag. The sensitivity for all groups was obtained against the curing regime with the highest being attributed to the slag mortars. The highest and lowest strengths at early ages were attributed to OPC and slag mortars when both were cured in water. The highest and lowest strengths were attributed to OPC-slag and slag mortars at later ages, respectively. The highest strengths for OPC-slag, OPC, and slag mortars were as 72.0, 64.0, and 21.5 MPa at 90 days when the specimens cured in water, respectively. Strength loss was observed for all groups at later ages when cured in air under room temperature. The maximum and minimum, of about 8.0% and 1.3%, occurred at 56 and 90 days for slag and OPC-slag mortars, respectively.展开更多
The influence of curing temperature on the strength development of cement-stabilized mud has been well documented in terms of strength-increase rate and ultimate strength.However,the strength development model is not ...The influence of curing temperature on the strength development of cement-stabilized mud has been well documented in terms of strength-increase rate and ultimate strength.However,the strength development model is not mature for the extremely early stages.In addition,there is a lack of studies on quality control methods based on early-stage strength development.This paper presents a strength model for cement-stabilized mud to address these gaps,considering various curing temperatures and early-stage behaviors.In this study,a series of laboratory experiments was conducted on two types of muds treated with Portland blast furnace cement and ordinary Portland cement under four different temperatures.The results indicate that elevated temperatures expedite strength development and lead to higher long-term strength.The proposed model,which combines a three-step conversion process and a hyperbolic model at the reference temperature,enables accurate estimate of the strength development for cement-treated mud with any proportions cured under various temperatures.With this model,a practical early quality control method is introduced for applying cement-stabilized mud in field projects.The back-analysis parameters obtained from a 36-h investigation at temperature of 60C demonstrated a sufficient accuracy in predicting strength levels in practical applications.展开更多
This paper investigates the effectiveness of nano-modification on the strength enhancement of cementstabilized dredged sludge(CDS).Three types of nanoparticles including nano-SiO2(NS),nano-Al2O3(NA)and nano-MgO(NM)wer...This paper investigates the effectiveness of nano-modification on the strength enhancement of cementstabilized dredged sludge(CDS).Three types of nanoparticles including nano-SiO2(NS),nano-Al2O3(NA)and nano-MgO(NM)were used as cement admixtures for dredged sludge stabilization.Effects of single nanoparticle content,mass ratio of composite nanoparticles and curing time on the strength development of CDS were evaluated via a series of unconfined compressive strength(UCS)tests.The pH evolutions of CDS caused by nanoparticles were also examined by a range of pH tests.Furthermore,micromechanisms reflecting the strength evolutions were analyzed by performing scanning electron microscopy(SEM)and X-ray diffraction(XRD)tests.The results indicated that adding nanoparticles can significantly improve the UCS of CDS.For single nano-modification,the optimum contents of NS,NA and NM were 4%e6%,6%and 8%,which can increase the 7-and 28-d UCSs of CDS by 38%and 50%,17%and 35%,65%and 67%,respectively.Compared with single nano-modification,composite nano-modifications were more effective in improving the strength gain of CDS.The optimum mass ratios of composite nanoparticles,namely NS/NA,NS/NM and NA/NM,were 9/1,3/7 and 3/7,respectively.Based on the strength growth rate,the composite nanoparticles with NS/NM of 3/7 were highly recommended.The addition of nanoparticles obviously affected the pH evolution of CDS,which was mainly determined by the difference of OHproduction and consumption inside nano-modified CDS.The microstructural analysis revealed that C-S-H and C-A-H gels are the main cementitious products,and the addition of nanoparticles can obviously contribute to a denser and more homogenous microstructure of CDS.展开更多
HVFA (high-volume fly ash) concrete could be a sustainable way for by-product utilization to conserve natural resources and protect environment. HVFA concrete can play the role of a high-performance material that ma...HVFA (high-volume fly ash) concrete could be a sustainable way for by-product utilization to conserve natural resources and protect environment. HVFA concrete can play the role of a high-performance material that may be comparable to the conventional Portland cement concrete. The results of the research programme concerning the relationships between the composition of concrete (w/b ratio, fly ash content and type of cement) and their physical and mechanical properties are presented and discussed in the paper. It is found that the introduction of high-volume fly ash into concrete has caused a decrease in compressive strength at the early age of storage. The significant increase in strength was observed between 28 days and 90 days of curing. The high-volume fly ash concretes were characterized with lower water absorbability and sorptivity than control concrete.展开更多
Low-grade fly ash (rejected fly ash,rFA),a significant portion of the pulverized fuel ash (PFA) produced from coal-fired power plants and rejected from the ash classifying process,remains unused due to its high carbon...Low-grade fly ash (rejected fly ash,rFA),a significant portion of the pulverized fuel ash (PFA) produced from coal-fired power plants and rejected from the ash classifying process,remains unused due to its high carbon content and large particle size (>45μm).But it is thought that the rejected ash may have potential uses in chemical stabilization/solidification (S/S) processes which need relatively lower strengths and a lower chemical reactivity.Flue Gas Desulphurisation (FGD) sludge is a by-product of air pollution control equipment in coal fired power plants whose chemical composition is mainly gypsum.As there is no effective usage of both of these two materials,it is of interest to research on the possible activation of rFA using FGD.This paper presents experimental results of a study on the properties of rFA activated by the FGD in rFA-cement pastes.Different percentages of FGD were added into the mix to study the effects of the FGD on the reaction of the rFA blended cement pastes.The results show that FGD takes effect as an activator only at late curing ages.Adding Ca(OH) 2 enhances the effect of FGD on activating the hydration of rFA.Also,10% FGD by weight of rFA is the optimal addition in the rFA-cement pastes.The results of the compressive strength measurements correlate well with the porosity results.展开更多
A caisson breakwater is built on soft foundations after replacing the upper soft layer with sand. This paper presents a dynamic finite element method to investigate the strength degradation and associated pore pressur...A caisson breakwater is built on soft foundations after replacing the upper soft layer with sand. This paper presents a dynamic finite element method to investigate the strength degradation and associated pore pressure development of the intercalated soft layer under wave cyclic loading. By combining the undrained shear strength with the empirical formula of overconsolidation clay produced by unloading and the development model of pore pressure, the dynamic degradation law that describes the undrained shear strength as a function of cycle number and stress level is derived. Based on the proposed dynamic degradation law and M-C yield criterion, a dynamic finite element method is numerically implemented to predict changes in undrained shear strength of the intercalated soft layer by using the general-purpose FEM software ABAQUS, and the accuracy of the method is verified. The effects of cycle number and amplitude of the wave force on the degradation of the undrained shear strength of the intercalated soft layer and the associated excess pore pressure response are investigated by analyzing an overall distribution and three typical sections underneath the breakwater. By comparing the undrained shear strength distributions obtained by the static method and the quasi-static method with the undrained shear strength distributions obtained by the dynamic finite element method in the three typical sections, the superiority of the dynamic finite element method in predicting changes in undrained shear strength is demonstrated.展开更多
In order to understand the strength developing law of the epoxy asphalt mixture,a curing reaction model of the epoxy asphalt binder was proposed based upon the thermokinetic analysis.Given some assumptions,the model w...In order to understand the strength developing law of the epoxy asphalt mixture,a curing reaction model of the epoxy asphalt binder was proposed based upon the thermokinetic analysis.Given some assumptions,the model was developed by applying the Kissinger law as well as Arrhenius equation,and the differential scanning calorimetry was performed for estimating the model parameters.To monitor the strength development of the epoxy asphalt mixture,a strength test program was employed and then results were compared to those produced from the proposed model.The comparative evaluation shows that a good consistency exists between the outputs from test program and the proposed model,indicating that the proposed model can be used effectively for simulating the curing reaction process for the epoxy asphalt binder and predicting the strength development for the epoxy asphalt mixture.展开更多
A new calcium aluminate cement CA-670 was studied in the system of tabular alumina, white fused alumina (WFA), and bauxite based low cement castables. The flow ability, strength development, and hot strength ( HMOR...A new calcium aluminate cement CA-670 was studied in the system of tabular alumina, white fused alumina (WFA), and bauxite based low cement castables. The flow ability, strength development, and hot strength ( HMOR ) were investigated. Different types of additives were used for the CA-670 bonded castables. The results show CA-670 provides a good workability for each type of" castables. CA-670 displays a good compatibility with different types of additives. Testing on different batches of CA-670 shows good reproducible properties in each castable, which manifests good consistency and reliability of CA-670.展开更多
目的评价内侧突出技术对成人发育性髋关节发育不良(developmental dysplasia of the hip,DDH)患者THA术后外展肌力恢复的影响。方法回顾性分析2012年1月至2021年12月于武汉大学人民医院因DDH、股骨颈骨折、股骨头坏死及髋关节骨性关节...目的评价内侧突出技术对成人发育性髋关节发育不良(developmental dysplasia of the hip,DDH)患者THA术后外展肌力恢复的影响。方法回顾性分析2012年1月至2021年12月于武汉大学人民医院因DDH、股骨颈骨折、股骨头坏死及髋关节骨性关节炎行单侧髋关节置换116例患者,将患者分为DDH组(52例)及非DDH组(64例)。在术前,术后1、4、24及48周进行临床数据采集,具体包括Harris评分、VAS疼痛评分、双侧髋关节外展肌肌力矩比(HAMMR)。通过骨盆正位平片测量髋关节旋转中心内移距离,比较两组间外展肌力矩差异。结果患者随访时间12~18个月,平均随访时间14.3个月,其中DDH组52例患者髋关节Harris评分从术前(39.6±7.9)分改善至术后12个月(85.1±6.2)分,差异具有统计学意义(P<0.05)。DDH组52例患者髋关节旋转中心内移距离平均(15.5±6.0)mm,最小内移距离8 mm,最大内移距离24.4 mm,其中CroweⅠ型24例,CroweⅡ型19例,CroweⅢ型9例,DDH组患者术后6个月及12个月HAMMR分别为(85.3±7.4)%及(93.9±3.6)%,较术前显著改善(P<0.05),提示患侧外展肌力恢复接近对侧水平(100%)。通过皮尔逊相关性分析,旋转中心内移距离与HAMMR无明显相关性(r=-0.061,P=0.665>0.05)。对DDH组与非DDH组间HAMMR进行独立样本t检验发现,在术后1、5、12个月HAMMR比较,差异均无统计学意义(P>0.05)。结论DDH患者行THA术应用内侧突出技术,在有限范围内移旋转中心(内移距离不超过24.4 mm),对术后6个月后髋关节外展肌力的恢复无明显影响,术后髋关节功能及外展肌力得到明显改善。展开更多
文摘This paper presents the results of a series of studies on the influence of curing conditions on the strength development of high strength concrete. The 1-, 3-, 7-, 14- and 28-day strengths of four different mixes of Grade 75 similar to 80 concrete, with or without pulverized fuel ash and/or condensed silica fume, under five different curing regimes were investigated. It is revealed that the curing conditions have significant influence on both the short term and long term strength development of the concrete and that concrete mixes of the same grade but containing different mineral admixtures show distinct favour for a curing regime. These results will be helpful for evaluating suitable curing methods for high strength concrete with different mix proportions.
文摘In this experimental work, three groups of cement-slag mortars namely OPC, OPC-slag, and slag mortars were made. All were cured in both water and air under room temperature. Strength development was studied up to 90 days. The mortars were prepared using 0%, 50%, and 100% replacement with slag. The sensitivity for all groups was obtained against the curing regime with the highest being attributed to the slag mortars. The highest and lowest strengths at early ages were attributed to OPC and slag mortars when both were cured in water. The highest and lowest strengths were attributed to OPC-slag and slag mortars at later ages, respectively. The highest strengths for OPC-slag, OPC, and slag mortars were as 72.0, 64.0, and 21.5 MPa at 90 days when the specimens cured in water, respectively. Strength loss was observed for all groups at later ages when cured in air under room temperature. The maximum and minimum, of about 8.0% and 1.3%, occurred at 56 and 90 days for slag and OPC-slag mortars, respectively.
基金supported by funding from the National Natural Science Foundation of China (Grant Nos.51978303 and 52208367)the Fundamental Research Funds for the Central Universities (Grant No.2042023kfyq03).
文摘The influence of curing temperature on the strength development of cement-stabilized mud has been well documented in terms of strength-increase rate and ultimate strength.However,the strength development model is not mature for the extremely early stages.In addition,there is a lack of studies on quality control methods based on early-stage strength development.This paper presents a strength model for cement-stabilized mud to address these gaps,considering various curing temperatures and early-stage behaviors.In this study,a series of laboratory experiments was conducted on two types of muds treated with Portland blast furnace cement and ordinary Portland cement under four different temperatures.The results indicate that elevated temperatures expedite strength development and lead to higher long-term strength.The proposed model,which combines a three-step conversion process and a hyperbolic model at the reference temperature,enables accurate estimate of the strength development for cement-treated mud with any proportions cured under various temperatures.With this model,a practical early quality control method is introduced for applying cement-stabilized mud in field projects.The back-analysis parameters obtained from a 36-h investigation at temperature of 60C demonstrated a sufficient accuracy in predicting strength levels in practical applications.
基金This work was financially supported by the National Natural Science Foundation of China(Grant No.51972209).
文摘This paper investigates the effectiveness of nano-modification on the strength enhancement of cementstabilized dredged sludge(CDS).Three types of nanoparticles including nano-SiO2(NS),nano-Al2O3(NA)and nano-MgO(NM)were used as cement admixtures for dredged sludge stabilization.Effects of single nanoparticle content,mass ratio of composite nanoparticles and curing time on the strength development of CDS were evaluated via a series of unconfined compressive strength(UCS)tests.The pH evolutions of CDS caused by nanoparticles were also examined by a range of pH tests.Furthermore,micromechanisms reflecting the strength evolutions were analyzed by performing scanning electron microscopy(SEM)and X-ray diffraction(XRD)tests.The results indicated that adding nanoparticles can significantly improve the UCS of CDS.For single nano-modification,the optimum contents of NS,NA and NM were 4%e6%,6%and 8%,which can increase the 7-and 28-d UCSs of CDS by 38%and 50%,17%and 35%,65%and 67%,respectively.Compared with single nano-modification,composite nano-modifications were more effective in improving the strength gain of CDS.The optimum mass ratios of composite nanoparticles,namely NS/NA,NS/NM and NA/NM,were 9/1,3/7 and 3/7,respectively.Based on the strength growth rate,the composite nanoparticles with NS/NM of 3/7 were highly recommended.The addition of nanoparticles obviously affected the pH evolution of CDS,which was mainly determined by the difference of OHproduction and consumption inside nano-modified CDS.The microstructural analysis revealed that C-S-H and C-A-H gels are the main cementitious products,and the addition of nanoparticles can obviously contribute to a denser and more homogenous microstructure of CDS.
文摘HVFA (high-volume fly ash) concrete could be a sustainable way for by-product utilization to conserve natural resources and protect environment. HVFA concrete can play the role of a high-performance material that may be comparable to the conventional Portland cement concrete. The results of the research programme concerning the relationships between the composition of concrete (w/b ratio, fly ash content and type of cement) and their physical and mechanical properties are presented and discussed in the paper. It is found that the introduction of high-volume fly ash into concrete has caused a decrease in compressive strength at the early age of storage. The significant increase in strength was observed between 28 days and 90 days of curing. The high-volume fly ash concretes were characterized with lower water absorbability and sorptivity than control concrete.
文摘Low-grade fly ash (rejected fly ash,rFA),a significant portion of the pulverized fuel ash (PFA) produced from coal-fired power plants and rejected from the ash classifying process,remains unused due to its high carbon content and large particle size (>45μm).But it is thought that the rejected ash may have potential uses in chemical stabilization/solidification (S/S) processes which need relatively lower strengths and a lower chemical reactivity.Flue Gas Desulphurisation (FGD) sludge is a by-product of air pollution control equipment in coal fired power plants whose chemical composition is mainly gypsum.As there is no effective usage of both of these two materials,it is of interest to research on the possible activation of rFA using FGD.This paper presents experimental results of a study on the properties of rFA activated by the FGD in rFA-cement pastes.Different percentages of FGD were added into the mix to study the effects of the FGD on the reaction of the rFA blended cement pastes.The results show that FGD takes effect as an activator only at late curing ages.Adding Ca(OH) 2 enhances the effect of FGD on activating the hydration of rFA.Also,10% FGD by weight of rFA is the optimal addition in the rFA-cement pastes.The results of the compressive strength measurements correlate well with the porosity results.
基金financially supported by the National Natural Science Foundation of China(Grant No.51279128)the National Natural Science Fund for Innovative Research Groups Science Foundation(Grant No.51321065)the Construction Science and Technology Project of Ministry of Transport of the People’s Republic of China(Grant No.2013328224070)
文摘A caisson breakwater is built on soft foundations after replacing the upper soft layer with sand. This paper presents a dynamic finite element method to investigate the strength degradation and associated pore pressure development of the intercalated soft layer under wave cyclic loading. By combining the undrained shear strength with the empirical formula of overconsolidation clay produced by unloading and the development model of pore pressure, the dynamic degradation law that describes the undrained shear strength as a function of cycle number and stress level is derived. Based on the proposed dynamic degradation law and M-C yield criterion, a dynamic finite element method is numerically implemented to predict changes in undrained shear strength of the intercalated soft layer by using the general-purpose FEM software ABAQUS, and the accuracy of the method is verified. The effects of cycle number and amplitude of the wave force on the degradation of the undrained shear strength of the intercalated soft layer and the associated excess pore pressure response are investigated by analyzing an overall distribution and three typical sections underneath the breakwater. By comparing the undrained shear strength distributions obtained by the static method and the quasi-static method with the undrained shear strength distributions obtained by the dynamic finite element method in the three typical sections, the superiority of the dynamic finite element method in predicting changes in undrained shear strength is demonstrated.
基金Funded by the Project of National Science and Technology Ministry of China(No.2009BAG15B03)
文摘In order to understand the strength developing law of the epoxy asphalt mixture,a curing reaction model of the epoxy asphalt binder was proposed based upon the thermokinetic analysis.Given some assumptions,the model was developed by applying the Kissinger law as well as Arrhenius equation,and the differential scanning calorimetry was performed for estimating the model parameters.To monitor the strength development of the epoxy asphalt mixture,a strength test program was employed and then results were compared to those produced from the proposed model.The comparative evaluation shows that a good consistency exists between the outputs from test program and the proposed model,indicating that the proposed model can be used effectively for simulating the curing reaction process for the epoxy asphalt binder and predicting the strength development for the epoxy asphalt mixture.
文摘A new calcium aluminate cement CA-670 was studied in the system of tabular alumina, white fused alumina (WFA), and bauxite based low cement castables. The flow ability, strength development, and hot strength ( HMOR ) were investigated. Different types of additives were used for the CA-670 bonded castables. The results show CA-670 provides a good workability for each type of" castables. CA-670 displays a good compatibility with different types of additives. Testing on different batches of CA-670 shows good reproducible properties in each castable, which manifests good consistency and reliability of CA-670.
文摘目的评价内侧突出技术对成人发育性髋关节发育不良(developmental dysplasia of the hip,DDH)患者THA术后外展肌力恢复的影响。方法回顾性分析2012年1月至2021年12月于武汉大学人民医院因DDH、股骨颈骨折、股骨头坏死及髋关节骨性关节炎行单侧髋关节置换116例患者,将患者分为DDH组(52例)及非DDH组(64例)。在术前,术后1、4、24及48周进行临床数据采集,具体包括Harris评分、VAS疼痛评分、双侧髋关节外展肌肌力矩比(HAMMR)。通过骨盆正位平片测量髋关节旋转中心内移距离,比较两组间外展肌力矩差异。结果患者随访时间12~18个月,平均随访时间14.3个月,其中DDH组52例患者髋关节Harris评分从术前(39.6±7.9)分改善至术后12个月(85.1±6.2)分,差异具有统计学意义(P<0.05)。DDH组52例患者髋关节旋转中心内移距离平均(15.5±6.0)mm,最小内移距离8 mm,最大内移距离24.4 mm,其中CroweⅠ型24例,CroweⅡ型19例,CroweⅢ型9例,DDH组患者术后6个月及12个月HAMMR分别为(85.3±7.4)%及(93.9±3.6)%,较术前显著改善(P<0.05),提示患侧外展肌力恢复接近对侧水平(100%)。通过皮尔逊相关性分析,旋转中心内移距离与HAMMR无明显相关性(r=-0.061,P=0.665>0.05)。对DDH组与非DDH组间HAMMR进行独立样本t检验发现,在术后1、5、12个月HAMMR比较,差异均无统计学意义(P>0.05)。结论DDH患者行THA术应用内侧突出技术,在有限范围内移旋转中心(内移距离不超过24.4 mm),对术后6个月后髋关节外展肌力的恢复无明显影响,术后髋关节功能及外展肌力得到明显改善。