To prevent and mitigate environmental degradation,high-performance and cost-effective electrochemical flexible energy storage systems need to be urgently developed.This demand has led to an increase in research on ele...To prevent and mitigate environmental degradation,high-performance and cost-effective electrochemical flexible energy storage systems need to be urgently developed.This demand has led to an increase in research on electrode materials for high-capacity flexible supercapacitors and secondary batteries,which have greatly aided the development of contemporary digital communications and electric vehicles.The use of layered double hydroxides(LDHs)as electrode materials has shown productive results over the last decade,owing to their easy production,versatile composition,low cost,and excellent physicochemical features.This review highlights the distinctive 2D sheet-like structures and electrochemical characteristics of LDH materials,as well as current developments in their fabrication strategies for expanding the application scope of LDHs as electrode materials for flexible supercapacitors and alkali metal(Li,Na,K)ion batteries.展开更多
In this paper, an extended analysis of the performance of different hybrid Rechargeable Energy Storage Systems (RESS) for use in Plug-in Hybrid Electric Vehicle (PHEV) with a series drivetrain topology is analyzed, ba...In this paper, an extended analysis of the performance of different hybrid Rechargeable Energy Storage Systems (RESS) for use in Plug-in Hybrid Electric Vehicle (PHEV) with a series drivetrain topology is analyzed, based on simulations with three different driving cycles. The investigated hybrid energy storage topologies are an energy optimized lithium-ion battery (HE) in combination with an Electrical Double-Layer Capacitor (EDLC) system, in combination with a power optimized lithium-ion battery (HP) system or in combination with a Lithium-ion Capacitor (LiCap) system, that act as a Peak Power System. From the simulation results it was observed that hybridization of the HE lithium-ion based energy storage system resulted from the three topologies in an increased overall energy efficiency of the RESS, in an extended all electric range of the PHEV and in a reduced average current through the HE battery. The lowest consumption during the three driving cycles was obtained for the HE-LiCap topology, where fuel savings of respectively 6.0%, 10.3% and 6.8% compared with the battery stand-alone system were achieved. The largest extension of the range was achieved for the HE-HP configuration (17% based on FTP-75 driving cycle). HP batteries however have a large internal resistance in comparison to EDLC and LiCap systems, which resulted in a reduced overall energy efficiency of the hybrid RESS. Additionally, it was observed that the HP and LiCap systems both offer significant benefits for the integration of a peak power system in the drivetrain of a Plug-in Hybrid Electric Vehicle due to their low volume and weight in comparison to that of the EDLC system.展开更多
We report a wire-shaped three-dimensional(3D)-hybrid supercapacitor with high volumetric capacitance and high energy density due to an interconnected 3D-configuration of the electrode allowing for large number of elec...We report a wire-shaped three-dimensional(3D)-hybrid supercapacitor with high volumetric capacitance and high energy density due to an interconnected 3D-configuration of the electrode allowing for large number of electrochemical active sites,easy access of electrolyte ions,and facile charge transport for flexible wearable applications.The interconnected and compact electrode delivers a high volumetric capacitance(gravimetric capacitance)of 73 F cm−3(2446 F g−1),excellent rate capability,and cycle stability.The 3D-nickel cobalt-layered double hydroxide onto 3D-nickel wire(NiCo LDH/3D-Ni)//the 3D-manganese oxide onto 3D-nickel wire(Mn3O4/3D-Ni)hybrid supercapacitor exhibits energy density of 153.3 Wh kg−1 and power density of 8810 W kg−1.The red lightemitting diode powered by the as-prepared hybrid supercapacitor can operate for 80 min after being charged for tens of seconds and exhibit excellent electrochemical stability under various deformation conditions.The results verify that such wire-shaped 3D-hybrid supercapacitors are promising alternatives for batteries with long charge–discharge times,for smart wearable and implantable devices.展开更多
A hybrid electrochemical energy storage device was fabricated in aqueous NaOH with the 2,2,6,6-tetramethyl-1-piperidinyloxy (TEMPO) nitroxide radical as the active material, hydroquinone as the counter electrode activ...A hybrid electrochemical energy storage device was fabricated in aqueous NaOH with the 2,2,6,6-tetramethyl-1-piperidinyloxy (TEMPO) nitroxide radical as the active material, hydroquinone as the counter electrode active material, and an OH -selective separating membrane. The working principle of this device was investigated and it can be considered as a supercapacitor-battery hybrid energy storage system. Device performance was characterized by cyclic voltammetry and galvanostatic charge-discharge testing. When using multi-walled carbon nanotubes (MWCNTs) as electrode support materials, a high pseudo-capacitance of 1280 F g -1 was obtained with the TEMPO nitroxide radical as the active material at a 1 mV s -1 scan rate. This was ~33 times larger than the inherent double layer capacitance of MWCNTs. The electrode material and active material dissolved in solution could potentially be substituted with similar materials. This simple design provides a new approach for fabricating high performance supercapacitor-battery hybrid energy storage devices.展开更多
1 Results Electrochemical energy storage devices such as lithium-ion batteries[1-2] and double-layer capacitors[3-4] have attracted a great deal of attention because of their potential application to electric hybrid v...1 Results Electrochemical energy storage devices such as lithium-ion batteries[1-2] and double-layer capacitors[3-4] have attracted a great deal of attention because of their potential application to electric hybrid vehicles. They utilize nonaqueous electrolyte solutions comprising from organic solvents and lithium or quaternary ammonium salts with fluorine-containing anions. This is because the relatively large anions with electron-withdrawing atoms enable ionic dissociation in dipolar aprotic solvents...展开更多
基金the National Natural Science Foundation of China(NSFC Grant No.62174152).
文摘To prevent and mitigate environmental degradation,high-performance and cost-effective electrochemical flexible energy storage systems need to be urgently developed.This demand has led to an increase in research on electrode materials for high-capacity flexible supercapacitors and secondary batteries,which have greatly aided the development of contemporary digital communications and electric vehicles.The use of layered double hydroxides(LDHs)as electrode materials has shown productive results over the last decade,owing to their easy production,versatile composition,low cost,and excellent physicochemical features.This review highlights the distinctive 2D sheet-like structures and electrochemical characteristics of LDH materials,as well as current developments in their fabrication strategies for expanding the application scope of LDHs as electrode materials for flexible supercapacitors and alkali metal(Li,Na,K)ion batteries.
文摘In this paper, an extended analysis of the performance of different hybrid Rechargeable Energy Storage Systems (RESS) for use in Plug-in Hybrid Electric Vehicle (PHEV) with a series drivetrain topology is analyzed, based on simulations with three different driving cycles. The investigated hybrid energy storage topologies are an energy optimized lithium-ion battery (HE) in combination with an Electrical Double-Layer Capacitor (EDLC) system, in combination with a power optimized lithium-ion battery (HP) system or in combination with a Lithium-ion Capacitor (LiCap) system, that act as a Peak Power System. From the simulation results it was observed that hybridization of the HE lithium-ion based energy storage system resulted from the three topologies in an increased overall energy efficiency of the RESS, in an extended all electric range of the PHEV and in a reduced average current through the HE battery. The lowest consumption during the three driving cycles was obtained for the HE-LiCap topology, where fuel savings of respectively 6.0%, 10.3% and 6.8% compared with the battery stand-alone system were achieved. The largest extension of the range was achieved for the HE-HP configuration (17% based on FTP-75 driving cycle). HP batteries however have a large internal resistance in comparison to EDLC and LiCap systems, which resulted in a reduced overall energy efficiency of the hybrid RESS. Additionally, it was observed that the HP and LiCap systems both offer significant benefits for the integration of a peak power system in the drivetrain of a Plug-in Hybrid Electric Vehicle due to their low volume and weight in comparison to that of the EDLC system.
基金supported by national research foundation of Korea(NRF)(No.NRF-2019R1H1A2039743)S-Oil corporation,and “Human Resources Program in Energy Technology” of the Korea Institute of Energy Technology Evaluation and Planning(KETEP)granted financial resource from the Ministry of Trade,Industry and Energy,Republic of Korea(No.20194010201890)
文摘We report a wire-shaped three-dimensional(3D)-hybrid supercapacitor with high volumetric capacitance and high energy density due to an interconnected 3D-configuration of the electrode allowing for large number of electrochemical active sites,easy access of electrolyte ions,and facile charge transport for flexible wearable applications.The interconnected and compact electrode delivers a high volumetric capacitance(gravimetric capacitance)of 73 F cm−3(2446 F g−1),excellent rate capability,and cycle stability.The 3D-nickel cobalt-layered double hydroxide onto 3D-nickel wire(NiCo LDH/3D-Ni)//the 3D-manganese oxide onto 3D-nickel wire(Mn3O4/3D-Ni)hybrid supercapacitor exhibits energy density of 153.3 Wh kg−1 and power density of 8810 W kg−1.The red lightemitting diode powered by the as-prepared hybrid supercapacitor can operate for 80 min after being charged for tens of seconds and exhibit excellent electrochemical stability under various deformation conditions.The results verify that such wire-shaped 3D-hybrid supercapacitors are promising alternatives for batteries with long charge–discharge times,for smart wearable and implantable devices.
基金supported by the National Natural Science Foundation of China (50730005 and 20821003)the National Key Project on Basic Research (2011CB935700 and 2009CB930400)the Knowledge Innovation Program of the Chinese Academy of Sciences (KJCX2-YW-W26)
文摘A hybrid electrochemical energy storage device was fabricated in aqueous NaOH with the 2,2,6,6-tetramethyl-1-piperidinyloxy (TEMPO) nitroxide radical as the active material, hydroquinone as the counter electrode active material, and an OH -selective separating membrane. The working principle of this device was investigated and it can be considered as a supercapacitor-battery hybrid energy storage system. Device performance was characterized by cyclic voltammetry and galvanostatic charge-discharge testing. When using multi-walled carbon nanotubes (MWCNTs) as electrode support materials, a high pseudo-capacitance of 1280 F g -1 was obtained with the TEMPO nitroxide radical as the active material at a 1 mV s -1 scan rate. This was ~33 times larger than the inherent double layer capacitance of MWCNTs. The electrode material and active material dissolved in solution could potentially be substituted with similar materials. This simple design provides a new approach for fabricating high performance supercapacitor-battery hybrid energy storage devices.
文摘1 Results Electrochemical energy storage devices such as lithium-ion batteries[1-2] and double-layer capacitors[3-4] have attracted a great deal of attention because of their potential application to electric hybrid vehicles. They utilize nonaqueous electrolyte solutions comprising from organic solvents and lithium or quaternary ammonium salts with fluorine-containing anions. This is because the relatively large anions with electron-withdrawing atoms enable ionic dissociation in dipolar aprotic solvents...
