The humidity effect, namely the markedly positive correlation between the stable isotopic ratio in precipitation and the dew-point deficit ATd in the atmosphere, is put forward firstly and the relationships between t...The humidity effect, namely the markedly positive correlation between the stable isotopic ratio in precipitation and the dew-point deficit ATd in the atmosphere, is put forward firstly and the relationships between the δ18O in precipitation and ATd are analyzed for the Urumqi and Kunming stations, which have completely different climatic characteristics. Although the seasonal variations in δ18O and △Td exhibit differences between the two stations, their humidity effect is notable. The correlation coefficient and its confidence level of the humidity effect are higher than those of the amount effect at Kunming, showing the marked influence of the humidity conditions in the atmosphere on stable isotopes in precipitation. Using a kinetic model for stable isotopic fractionation, and according to the seasonal distribution of mean monthly temperature at 500 hPa at Kunming, the variations of the δ18O in condensate in cloud are simulated. A very good agreement between the seasonal variations of the simulated mean δ18O and the mean monthly temperature at 500 hPa is obtained, showing that the oxygen stable isotope in condensate of cloud experiences a temperature effect. Such a result is markedly different from the amount effect at the ground. Based on the simulations of seasonal variations of δ18O in falling raindrops, it can be found that, in the dry season from November to April, the increasing trend with falling distance of δ18O in falling raindrops corresponds remarkably to the great △Td, showing a strong evaporation enrichment function in falling raindrops; however, in the wet season from May to October, the δ18O in falling raindrops displays an unapparent increase corresponding to the small △Td, except in May. By comparing the simulated mean δ18O at the ground with the actual monthly δ18O in precipitation, we see distinctly that the two monthly δ18O variations agree very well. On average, the δ18O values are relatively lower because of the highly moist air, heavy rainfall, small ATd and weak evaporation enrichment function of stable isotopes in the falling raindrops, under the influence of vapor from the oceans; but they are relatively higher because of the dry air, light rainfall, great △Td and strong evaporation enrichment function in falling raindrops, under the control of the continental air mass. Therefore, the δ18O in precipitation at Kunming can be used to indicate the humidity situation in the atmosphere to a certain degree, and thus indicate the intensity of the precipitation and the strength of the monsoon indirectly. The humidity effect changes not only the magnitude of the stable isotopic ratio in precipitation but also its seasonal distribution due to its influence on the strength of the evaporation enrichment of stable isotopes in falling raindrops and the direction of the net mass transfer of stable isotopes between the atmosphere and the raindrops. Consequently, it is inferred that the humidity effect is probably one of the foremost causes generating the amount effect.展开更多
MODIS atmospheric profile products(MOD07_L2 and MYD07_L2)have been widely used for near-surface dew point temperature(T_(d))estimation.However,their accuracy over large scale has seldom been evaluated.In this study,we...MODIS atmospheric profile products(MOD07_L2 and MYD07_L2)have been widely used for near-surface dew point temperature(T_(d))estimation.However,their accuracy over large scale has seldom been evaluated.In this study,we validated these two products comprehensively against 2153 stations over China's Mainland.MOD07_L2 was suggested by our study because it achieved higher accuracy in either of two frequently-used methods.To be specific,the root-meansquare error(RMSE)achieved by MOD07_L2 and MYD07_L2 was 5.82 and 7.42℃,respectively.On this basis,a recent ground-based correction method was modified to further improve their accuracy.Our focus is to investigate whether this ground-based approach is applicable to large-scale remote sensing applications.The results show that this new method showed great potential for T_(d) estimation independently from ground observations.Through the introduction of MODIS land surface products,the RMSE it achieved for MOD07_L2 and MYD07_L2 was 5.23 and 5.59℃,respectively.Further analysis shows that it was particularly useful in capturing the annual average T_(d) patterns.The R2,RMSE,and bias of annual average daily mean T_(d) estimates were 0.95,1.84℃,and 0.53℃,and those achieved for annual average instantaneous T_(d) estimates were 0.94,2.09℃,and 0.75℃,respectively.展开更多
This paper describes construction and characterization of a dew/frost -point generator developed at national institute for standards. It is intended to operate in the range from -50 ℃to 0 ℃. The air flows through a ...This paper describes construction and characterization of a dew/frost -point generator developed at national institute for standards. It is intended to operate in the range from -50 ℃to 0 ℃. The air flows through a saturator controlled by a regulated flow meter. The reference dew/frost -point temperature was measured by standard platinum resistance thermometer (SPRT) connected to a resistance bridge. A comparative study between the saturator temperature of the new generator measured by SPRT and the dew/frost-point temperature of a calibrated chilled-mirror hygrometer was conducted. It helped to determine the uncertainty of saturator; this uncertainty was found to be between ±0.06℃ to -4- 0.15℃ at confidence limit of 95%.Several experiments were carried out in the mentioned range. Obtained results gave the confidence that NIS generator could be used as a primary humid air generator.展开更多
基金This work was supported by the National Natural Science Foundation of China(Grant Nos.90302006 and 40271025)the National High Technology Research and Development Program of China(863 Program,Grant No.2002AA 135360)the Program of the Education Department of Hunan Province(Grant No.03C210).
文摘The humidity effect, namely the markedly positive correlation between the stable isotopic ratio in precipitation and the dew-point deficit ATd in the atmosphere, is put forward firstly and the relationships between the δ18O in precipitation and ATd are analyzed for the Urumqi and Kunming stations, which have completely different climatic characteristics. Although the seasonal variations in δ18O and △Td exhibit differences between the two stations, their humidity effect is notable. The correlation coefficient and its confidence level of the humidity effect are higher than those of the amount effect at Kunming, showing the marked influence of the humidity conditions in the atmosphere on stable isotopes in precipitation. Using a kinetic model for stable isotopic fractionation, and according to the seasonal distribution of mean monthly temperature at 500 hPa at Kunming, the variations of the δ18O in condensate in cloud are simulated. A very good agreement between the seasonal variations of the simulated mean δ18O and the mean monthly temperature at 500 hPa is obtained, showing that the oxygen stable isotope in condensate of cloud experiences a temperature effect. Such a result is markedly different from the amount effect at the ground. Based on the simulations of seasonal variations of δ18O in falling raindrops, it can be found that, in the dry season from November to April, the increasing trend with falling distance of δ18O in falling raindrops corresponds remarkably to the great △Td, showing a strong evaporation enrichment function in falling raindrops; however, in the wet season from May to October, the δ18O in falling raindrops displays an unapparent increase corresponding to the small △Td, except in May. By comparing the simulated mean δ18O at the ground with the actual monthly δ18O in precipitation, we see distinctly that the two monthly δ18O variations agree very well. On average, the δ18O values are relatively lower because of the highly moist air, heavy rainfall, small ATd and weak evaporation enrichment function of stable isotopes in the falling raindrops, under the influence of vapor from the oceans; but they are relatively higher because of the dry air, light rainfall, great △Td and strong evaporation enrichment function in falling raindrops, under the control of the continental air mass. Therefore, the δ18O in precipitation at Kunming can be used to indicate the humidity situation in the atmosphere to a certain degree, and thus indicate the intensity of the precipitation and the strength of the monsoon indirectly. The humidity effect changes not only the magnitude of the stable isotopic ratio in precipitation but also its seasonal distribution due to its influence on the strength of the evaporation enrichment of stable isotopes in falling raindrops and the direction of the net mass transfer of stable isotopes between the atmosphere and the raindrops. Consequently, it is inferred that the humidity effect is probably one of the foremost causes generating the amount effect.
基金supported by Ministry of Science and Technology of the People’s Republic of China[grant number:2021YFC3000201]National Natural Science Foundation of China[grant number:42071032]Youth Innovation Promotion Association of the Chinese Academy of Sciences[grant number:2020056].
文摘MODIS atmospheric profile products(MOD07_L2 and MYD07_L2)have been widely used for near-surface dew point temperature(T_(d))estimation.However,their accuracy over large scale has seldom been evaluated.In this study,we validated these two products comprehensively against 2153 stations over China's Mainland.MOD07_L2 was suggested by our study because it achieved higher accuracy in either of two frequently-used methods.To be specific,the root-meansquare error(RMSE)achieved by MOD07_L2 and MYD07_L2 was 5.82 and 7.42℃,respectively.On this basis,a recent ground-based correction method was modified to further improve their accuracy.Our focus is to investigate whether this ground-based approach is applicable to large-scale remote sensing applications.The results show that this new method showed great potential for T_(d) estimation independently from ground observations.Through the introduction of MODIS land surface products,the RMSE it achieved for MOD07_L2 and MYD07_L2 was 5.23 and 5.59℃,respectively.Further analysis shows that it was particularly useful in capturing the annual average T_(d) patterns.The R2,RMSE,and bias of annual average daily mean T_(d) estimates were 0.95,1.84℃,and 0.53℃,and those achieved for annual average instantaneous T_(d) estimates were 0.94,2.09℃,and 0.75℃,respectively.
文摘This paper describes construction and characterization of a dew/frost -point generator developed at national institute for standards. It is intended to operate in the range from -50 ℃to 0 ℃. The air flows through a saturator controlled by a regulated flow meter. The reference dew/frost -point temperature was measured by standard platinum resistance thermometer (SPRT) connected to a resistance bridge. A comparative study between the saturator temperature of the new generator measured by SPRT and the dew/frost-point temperature of a calibrated chilled-mirror hygrometer was conducted. It helped to determine the uncertainty of saturator; this uncertainty was found to be between ±0.06℃ to -4- 0.15℃ at confidence limit of 95%.Several experiments were carried out in the mentioned range. Obtained results gave the confidence that NIS generator could be used as a primary humid air generator.