Dialkyl-substituted terminal olefins were synthesized from the coupling reaction of a-olefins which were catalyzed by zirconocene dichloride/methylalumoxane （MAO） catalyst system under mild condition. High yield was...Dialkyl-substituted terminal olefins were synthesized from the coupling reaction of a-olefins which were catalyzed by zirconocene dichloride/methylalumoxane （MAO） catalyst system under mild condition. High yield was gained and no other oligmer was detected. It was found that the ratio of AI/Zr is responsible for the selectivity of product.展开更多
文摘Dialkyl-substituted terminal olefins were synthesized from the coupling reaction of a-olefins which were catalyzed by zirconocene dichloride/methylalumoxane （MAO） catalyst system under mild condition. High yield was gained and no other oligmer was detected. It was found that the ratio of AI/Zr is responsible for the selectivity of product.
