Diatomaceous earth (DE) is a natural inert dust used to control insect pests in stored grain as an alternative to synthetic residual insecticides. Various DE formulations are now registered as a grain protectant or ...Diatomaceous earth (DE) is a natural inert dust used to control insect pests in stored grain as an alternative to synthetic residual insecticides. Various DE formulations are now registered as a grain protectant or for structural treatment in many different countries throughout the world. The mode of action of DE is through the absorption of cuticular waxes in the insect cuticle, and insect death occurs from desiccation. The main advantages of using DE are its low mammalian toxicity and its stability. The main limitations to widespread commercial use of DE are reduction of the bulk density and flowability of grain, irritant hazards during application and reduction in efficacy at high moisture contents. This paper is an updated review of published results of researches related to the use of DEs and discusses their potential use in large-scale, commercial storage and in small scale applications.展开更多
Laboratory bioassays were conducted to determine the effect of food source on the survival of Tribolium castaneum Herbst, Oryzaephilus surinamensis L. and Rhyzopertha dominica F., after exposure to five diatomaceous e...Laboratory bioassays were conducted to determine the effect of food source on the survival of Tribolium castaneum Herbst, Oryzaephilus surinamensis L. and Rhyzopertha dominica F., after exposure to five diatomaceous earth (DE) formulations: Protect-It, Insecto, Perma-GuardTM, Dryacide and SilicoSec. Adults of these species were exposed to DEs at the rate of 0.5 mg/cm^2 for 1 day on filter paper inside plastic Petri dishes. After exposure, the initial mortality was counted and live individuals of the three species were held for a week in glass vials containing 50 mg wheat flour, rice and whole wheat, respectively. In the second experiment, after 1 day exposure to DEs, beetles were transferred to Petri dishes without food and held for a week to determine if the presence of food source would decrease the mortality of beetles. Experiments were carried out at 27℃ and 55% RH in the dark. The initial mortality in both of the experiments reached 100% for the three species exposed to Protect-It and in the case ofR. dominica and O. surinamensis exposed to Dryacide. In contrast, low level of mortality (〈 10%) was observed for T. castaneum exposed to Perma-GuardTM and Insecto. The mortality after the post-treatment period on food was decreased for the three species exposed to Perma-GuardTM and in the case of T. castaneum and R. dominica exposed to Insecto and SilicoSec. Adults of O. surinamensis were the most susceptible followed by R. dominica and 100% adult mortality was obtained, whereas T. castaneum were the least susceptible beetles to DEs. Protect-It and Dryacide were the most efficient DE formulations and can be used effectively in a stored grain integrated pest management program.展开更多
Adults ofRhyzopertha dominica (F.), the lesser grain borer, were exposed on four varieties of rough rice with Dobie indices of susceptibility of 1.1 to 1.1 (low), and four varieties with Dobie indices of susceptib...Adults ofRhyzopertha dominica (F.), the lesser grain borer, were exposed on four varieties of rough rice with Dobie indices of susceptibility of 1.1 to 1.1 (low), and four varieties with Dobie indices of susceptibility of 3.4 to 3.8 (high). The varieties with low and high Dobie indices were classified as resistant and susceptible, respectively, to R. dominica. The purpose of the study was to evaluate control of R. dominica through the use of diatomaceous earth (DE) in combination with rice varieties that were either susceptible or resistant to R. dominica. The rice was treated with varying rates of the commercial DE Insecto, up to a maximum of 1 000 mg DE/kg of rice. Adult mortality at each application rate of DE was generally greater on three of four resistant varieties compared to three of four susceptible varieties. Progeny production from the parental generation exposed on the rice was also greater in 3 of the 4 resistant varieties compared to 3 of the 4 susceptible varieties at DE rates of 500 mg/kg or more. Progeny production in rice treated with a maximum rate of 1 000 mg/kg DE ranged from 7-44 adults on the resistant varieties compared to 75-155 adults on the susceptible varieties. At DE rates of 500, 750, and 1 000 mg/kg, the percentage of insect-damaged kernels (IDK) was also greater in 3/4 resistant varieties than in the susceptible varieties. Results show combining the use of DE with varietal resistance of rough rice to R. dominica could be used to limit populations of this insect in stored rice and help prevent economic damage.展开更多
The widespread use of water-repellent superhydrophobic surfaces is limited by the inherent fragility of their micro-and nanoscale roughness, which is prone to damage and degradation. Here, we report a non-fluorinated ...The widespread use of water-repellent superhydrophobic surfaces is limited by the inherent fragility of their micro-and nanoscale roughness, which is prone to damage and degradation. Here, we report a non-fluorinated volumetric superhydrophobic nanocomposites that demonstrate mechanochemical robustness. The nanocomposites are produced through the addition of microscale diatomaceous earth and nanoscale fumed silica particles to high-temperature vulcanized silicone rubber. The water-repellency of the surface and bulk of nanocomposites having 120 phr of filler was determined based on the water contact angle and contact angle hysteresis. We compared the water-repellency of nanocomposites of differing diatomaceous earth to fumed silica mass ratios. Increasing the amount of diatomaceous earth enhanced the water-repellency of the nanocomposite surface, whereas an increased amount of fumed silica improved the water-repellency of the bulk material. Moreover, increasing the diatomaceous earth/fumed silica mass ratio improved the cross-linking density and hardness values of the nanocomposite.Despite being subjected to a range of mechanical durability tests, including sandpaper abrasion,knife scratching, tape peeling, water jet impact, and sandblasting, the nanocomposite maintained a water contact angle of 163. and contact angle hysteresis of 2°. When the water-repellency of the prepared nanocomposites eventually deteriorated, we restored their superhydrophobicity by removing the upper surface of the nanocomposite. This extraordinary robustness stems from the embedded low surface energy micro/nanostructures distributed throughout the nanocomposite. We also demonstrated the chemical stability, UV resistance, and self-cleaning abilities of the nanocomposite to illustrate the potential for real-life applications of this material.展开更多
文摘Diatomaceous earth (DE) is a natural inert dust used to control insect pests in stored grain as an alternative to synthetic residual insecticides. Various DE formulations are now registered as a grain protectant or for structural treatment in many different countries throughout the world. The mode of action of DE is through the absorption of cuticular waxes in the insect cuticle, and insect death occurs from desiccation. The main advantages of using DE are its low mammalian toxicity and its stability. The main limitations to widespread commercial use of DE are reduction of the bulk density and flowability of grain, irritant hazards during application and reduction in efficacy at high moisture contents. This paper is an updated review of published results of researches related to the use of DEs and discusses their potential use in large-scale, commercial storage and in small scale applications.
文摘Laboratory bioassays were conducted to determine the effect of food source on the survival of Tribolium castaneum Herbst, Oryzaephilus surinamensis L. and Rhyzopertha dominica F., after exposure to five diatomaceous earth (DE) formulations: Protect-It, Insecto, Perma-GuardTM, Dryacide and SilicoSec. Adults of these species were exposed to DEs at the rate of 0.5 mg/cm^2 for 1 day on filter paper inside plastic Petri dishes. After exposure, the initial mortality was counted and live individuals of the three species were held for a week in glass vials containing 50 mg wheat flour, rice and whole wheat, respectively. In the second experiment, after 1 day exposure to DEs, beetles were transferred to Petri dishes without food and held for a week to determine if the presence of food source would decrease the mortality of beetles. Experiments were carried out at 27℃ and 55% RH in the dark. The initial mortality in both of the experiments reached 100% for the three species exposed to Protect-It and in the case ofR. dominica and O. surinamensis exposed to Dryacide. In contrast, low level of mortality (〈 10%) was observed for T. castaneum exposed to Perma-GuardTM and Insecto. The mortality after the post-treatment period on food was decreased for the three species exposed to Perma-GuardTM and in the case of T. castaneum and R. dominica exposed to Insecto and SilicoSec. Adults of O. surinamensis were the most susceptible followed by R. dominica and 100% adult mortality was obtained, whereas T. castaneum were the least susceptible beetles to DEs. Protect-It and Dryacide were the most efficient DE formulations and can be used effectively in a stored grain integrated pest management program.
文摘Adults ofRhyzopertha dominica (F.), the lesser grain borer, were exposed on four varieties of rough rice with Dobie indices of susceptibility of 1.1 to 1.1 (low), and four varieties with Dobie indices of susceptibility of 3.4 to 3.8 (high). The varieties with low and high Dobie indices were classified as resistant and susceptible, respectively, to R. dominica. The purpose of the study was to evaluate control of R. dominica through the use of diatomaceous earth (DE) in combination with rice varieties that were either susceptible or resistant to R. dominica. The rice was treated with varying rates of the commercial DE Insecto, up to a maximum of 1 000 mg DE/kg of rice. Adult mortality at each application rate of DE was generally greater on three of four resistant varieties compared to three of four susceptible varieties. Progeny production from the parental generation exposed on the rice was also greater in 3 of the 4 resistant varieties compared to 3 of the 4 susceptible varieties at DE rates of 500 mg/kg or more. Progeny production in rice treated with a maximum rate of 1 000 mg/kg DE ranged from 7-44 adults on the resistant varieties compared to 75-155 adults on the susceptible varieties. At DE rates of 500, 750, and 1 000 mg/kg, the percentage of insect-damaged kernels (IDK) was also greater in 3/4 resistant varieties than in the susceptible varieties. Results show combining the use of DE with varietal resistance of rough rice to R. dominica could be used to limit populations of this insect in stored rice and help prevent economic damage.
基金the Natural Sciences and Engineering Research Council of Canada (NSERC)K-Line Insulators Limited (Toronto, Canada) for financial support。
文摘The widespread use of water-repellent superhydrophobic surfaces is limited by the inherent fragility of their micro-and nanoscale roughness, which is prone to damage and degradation. Here, we report a non-fluorinated volumetric superhydrophobic nanocomposites that demonstrate mechanochemical robustness. The nanocomposites are produced through the addition of microscale diatomaceous earth and nanoscale fumed silica particles to high-temperature vulcanized silicone rubber. The water-repellency of the surface and bulk of nanocomposites having 120 phr of filler was determined based on the water contact angle and contact angle hysteresis. We compared the water-repellency of nanocomposites of differing diatomaceous earth to fumed silica mass ratios. Increasing the amount of diatomaceous earth enhanced the water-repellency of the nanocomposite surface, whereas an increased amount of fumed silica improved the water-repellency of the bulk material. Moreover, increasing the diatomaceous earth/fumed silica mass ratio improved the cross-linking density and hardness values of the nanocomposite.Despite being subjected to a range of mechanical durability tests, including sandpaper abrasion,knife scratching, tape peeling, water jet impact, and sandblasting, the nanocomposite maintained a water contact angle of 163. and contact angle hysteresis of 2°. When the water-repellency of the prepared nanocomposites eventually deteriorated, we restored their superhydrophobicity by removing the upper surface of the nanocomposite. This extraordinary robustness stems from the embedded low surface energy micro/nanostructures distributed throughout the nanocomposite. We also demonstrated the chemical stability, UV resistance, and self-cleaning abilities of the nanocomposite to illustrate the potential for real-life applications of this material.