Evaluation of the Oxidation Reactivity and Behavior of Exhaust Soot Particles from Diesel Engines with Different Emission Levels

The aim of this study was to investigate the oxidation reactivity and behavior of exhaust particulate matter(PM)from diesel engines.PM samples from two diesel engines(1K,CY4102)with different emission levels were collected by a thermophoretic system and a quartz filter.The oxidation reactivity,oxidation behaviors,and physicochemical properties of the PM samples were analyzed using thermogravimetric analysis(TGA),high-resolution transmission electron microscopy(HRTEM),Fourier-transform infrared spectrometry(FTIR),and Raman spectroscopy.The results showed that there was a great difference in the oxidation reactivity of soot particles emitted by the two different diesel engines.A qualitative analysis of the factors influencing oxidation reactivity showed that the nanostructure,degree of graphitization,and relative concentration of aliphatic C—H functional groups were the most important factors,whereas no significant correlation was found between the primary particle size and activation energy of the diesel soot.Based on the oxidation behavior analysis,the diesel soot particles exhibited both internal and surface oxidation modes during the oxidation process.Surface oxidation was dominant during the initial stage,and as oxidation progressed,the mode gradually changed to internal oxidation.Internal oxidation mode of soot particles from the 1K engine was significantly higher than that of CY4102.

Performance, Combustion and Emission Characteristics of Oxygenated Diesel in DI Engines: A Critical Review

The transition from non-renewable to renewable energy sources is a significant challenge of our time. In the fuel industry, oxygenated additives such as butanol are transforming conventional fuels into renewable biofuels. This technology has been utilized in reciprocating engines for decades. This paper reviews the viability of using an n-butanol blend as a short-term replacement for diesel by analyzing its physical and chemical properties, combustion, performance, and emission characteristics in compression ignition (CI) engines under various conditions, including variable load, speed, acceleration, and both stationary and transient cycles. N-Butanol exhibits higher viscosity, better lubricity, higher heating value, improved blend stability, enhanced cold-flow properties, and higher density. These factors influence spray formation, injection timing, atomization, and combustion characteristics. Its higher oxygen content improves the diffusion combustion stage and efficiency. Adding 5% and 10% n-butanol to diesel increases pressure and apparent heat release rate, slightly reduces temperature, and improves thermal efficiency, with mixed effects on CO and THC emissions and a notable decrease in particulate matter emissions. Fuel consumption increases, while the impact on NOx emissions varies. A 10% butanol blend is considered optimal for enhancing performance and reducing particulate emissions without significantly affecting NOx emissions. Blending up to 40% butanol with diesel does not require engine modifications or ECU recalibrations in engines calibrated for pure diesel. Due to its advantageous properties and performance, n-butanol is recommended as a superior alcohol-diesel blend than ethanol for short-term diesel replacement.

Investigating the Effects of Eichhornia Crassipes Biodiesel and Liquefied Petroleum Gas on the Performance and Emissions of a Dual-Fuel Engine

This study considers the effect of Eichhornia Crassipes Biodiesel(ECB)blends on the performances,combustion,and emission characteristics of a direct injection compression ignition engine operated in a dual-fuel mode(DFM)and equipped with an Exhaust gas recirculation technique(EGR).In particular,a single-cylinder,four-stroke,water-cooled diesel engine was utilized and four modes of fuel operation were considered:mode I,the engine operated with an ordinary diesel fuel;mode II,the engine operated with the addition of 2.4 L/min of lique-fied petroleum gas(LPG)and 20%EGR;mode III,20%ECB with 2.4 L/min LPG and 20%EGR;mode IV,40%ECB with 2.4 L/min LPG and 20%EGR.The operation conditions were constant engine speed(1500 rpm),var-iation of load(25%,50%,75%,and 100%),full load,with a compression ratio of 18,and a time injection of 23°BTDC(Before top died center).With regard to engine emissions,carbon dioxide(CO_(2)),carbon monoxide(CO),hydrocarbons(UHC),and nitrogen oxide(NOX)were measured using a gas analyzer.The smoke opacity was measured using an OPABOX smoke meter.By comparing the results related to the different modes with mode I at full load,the BTE(Brake thermal efficiency)increased by 20.17%,11.45%,and 12.66%with modes II,III,and IV,respectively.In comparison to the results for mode II,the BTE decreased due to the combustion of ECB blends by 7.26%and 6.24%for mode III and mode IV,respectively,at full load.In comparison to mode II,the Brake specific energy consumption(BSEC)increased with the ECB substitution.With ECB blends,there is a noticeable decrease in the CO,CO_(2),and UHC emissions at a partial load.Furthermore,the 20%ECB has no effect on CO emissions at full load.For modes II and IV,the CO_(2)increased by 33.33%and 19%,respectively,while the UHC emissions were reduced by 14.49%for mode III and 26.08%for mode IV.The smoke of mode III was lower by 7.21%,but for mode IV,it was higher by 12.37%.In addition,with mode III and mode IV,the NOx emissions increased by 30.50%and 18.80%,respectively.

Analysis of the Emissions and Performance of a Diesel Engine Using Pumpkin Seed Oil Methyl Ester with Different Injection Pressures

Biodiesel fuel is a potential alternative energy source for diesel engines due to its physiochemical characteristics relatively similar to those of traditional diesel fuel.In this study,the performance,emission,and combustion features of a mono cylinder DI diesel engine are assessed using 20%Pumpkin seed methyl ester(PSOME20)and considering varying injection pressures(200,220,240,and 260 bar).The considered Pumpkin seed oil is converted into pumpkin biodiesel by transesterification and then used as fuel.The findings demonstrate that the Brake Thermal Efficiency(BTE)of PSOME20 can be raised by 1.68%,and the carbon monoxide(CO),hydrocarbon(HC),and smoke emanations can be lowered,while oxides of nitrogen(NOx)emissions are increased at an injection pressure(IP)of 240 bar compared to the standard IP of 200 bar.The cylinder pressure and the Heat Release Rate(HRR)become higher at 240 bar,whereas the ignition delay is shortened with respect to PSOME20 at a normal IP of 200 bar.

Experiment Study on the Exhaust-Gas Heat Exchanger for Small and Medium-Sized Marine Diesel Engine

This paper aims to design a special exchanger to recover the exhaust gas heat of marine diesel engines used in small and medium-sized fishing vessels,which can then be used to heat water up to 55°C–85°C for membrane desalination devices to produce fresh water.A new exhaust-gas heat exchanger of fins and tube,with a reinforced heat transfer tube section,unequal spacing fins,a mixing zone between the fin groups and four routes tube bundle,was designed.Numerical simulations were also used to provide reference information for structural design.Experiments were carried out for exhaust gas waste heat recovery from a marine diesel engine in an engine test bench utilizing the heat exchanger.The experimental results show that the difference between heat absorption by water and heat reduction of exhaust gas is less than 6.5%.After the water flow rate was adjusted,the exhaust gas waste heat recovery efficiency was higher than 70%,and the exhaust-gas heat exchanger’s outlet water temperature was 55°C–85°C at different engine loads.This means that the heat recovery from the exhaust gas of a marine diesel engine meets the requirement to drive a membrane desalination device to produce fresh water for fishers working in small and medium-sized fishing vessels.

Optimizing the Exhaust System of Marine Diesel Engines to Improve Low-speed Performances and Cylinder Working Conditions

Proper design of exhaust systems in marine high-power turbocharged diesel engines can contribute to improve the low-speed performance of these engines and make the working conditions of the cylinders more uniform.Here a high-power marine 16-cylinder V-type turbocharged diesel engine is simulated using the GT-Power software.The results reveal the differences induced by different exhaust system structures,such as an 8-cylinder-inpipe exhaust system with single/double superchargers and a 4-cylinder-in-pipe exhaust system with a single supercharger.After a comparative analysis,the 8-cylinder type with double superchargers is determined to be the optimal solution,and the structure of the exhaust system is further optimized.The simulations show that the optimized maximum exhaust temperature difference among cylinders is reduced by 66%.Finally,the simulation results and the optimized performance of the designed exhaust system are verified through experiments.

Effect of Palm Oil Biodiesel Blends on Engine Emission and Performance Characteristics in an Internal Combustion Engine

Increasing global environmental issues and depleting fossil fuel reserves has necessitated the need for alternative and sustainable fuel. In this paper, the effects of biodiesel and its blend on engine emission and performance characteristics in an internal combustion engine were analyzed. Biodiesel derived from the transesterification of raw palm oil was blended with diesel fuel at different proportions designated as PO5 (5% Biodiesel and 95% Diesel), PO10 (10% Biodiesel and 90% Diesel), PO15 (15% Biodiesel and 85% Diesel), PO20 (20% Biodiesel and 80% Diesel), PO50 (50% Biodiesel and 50% Diesel), PO85 (85% Biodiesel and 15% Diesel), and PO100 (100% Biodiesel). A Lombardini 2-cylinder, four-stroke direct injection diesel engine with a compression ratio of 22.8 was developed using Ricardo Wave software in which diesel, palm oil biodiesel blends and pure biodiesel are used in the model, and the obtained results were analysed and presented. The simulation was done under varying engine speeds of 1200 rpm to 3200 rpm at full load condition. Biodiesel and its blends are more environment-friendly and non-toxic when compared to diesel fuel;it also improves the mechanical efficiency of the engines, and above all can also lead to a reduction in poverty among rural dwellers. The obtained results showed that brake specific fuel consumption and brake thermal efficiency increased with palm oil biodiesel blends as compared to diesel fuel which might be a result of biodiesel’s lower heating value, and the increase in thermal energy may be a result of the oxygenation of the biodiesel blend as compared to pure diesel. In terms of brake torque, palm oil biodiesel blends were lesser than diesel fuel. The CO, HC, and NOx emissions of palm oil biodiesel blends decreased significantly compared to that of pure diesel. From this study, palm oil biodiesel emits lesser emissions than diesel fuel and its performance characteristics are similar to diesel fuel. Therefore, palm oil biodiesel can be used without any modifications directly in a diesel engine. In addition, it can also be used as blends as an alternative and sustainable fuel, decreasing air pollution, and increasing environmental sustainability.

A Review and Comparison on Recent Optimization Methodologies for Diesel Engines and Diesel Power Generators

The electrical instability that frequently distinguishes the isolated networks and depends on diesel generators to supply their energy requirements leads to an operation of the diesel generator in a transient dynamic condition and/or at low loads. In addition, extended operation of the diesel generator at partial load develops the condensation of combustion residues on the engine cylinder walls, which, after a certain time, increases friction, reduces the efficiency of the equipment and increases its fuel consumption. On the other hand, recent regulatory changes have led to ever more stringent and evolving emission standards. Among these, the International Maritime Organization (IMO) and the Environmental Protection Agency (EPA) have implemented emission standards in order to reduce exhaust gas emitted by marine diesel engines. To phase lower emission engines as soon as possible, a Tier system was adopted. This paper presents a literature review of existing technologies available to optimize the energy performance of diesel engines and diesel generators in order to reduce the cost of electricity, to increase the diesel engine efficiency and to decrease their fuel consumption and greenhouse gases (GHG) emissions. The proposed optimization methodologies are based on the application of Pre-treatment, Internal treatment and Post-treatment technologies for diesel engines and on the application of mechanical and electrical technologies for diesel power generators (DPGs). The list of references given at the end of the paper should offer aids for students and researchers working in this field.

Effects of Hydrogen Addition on Power and Emissions Outputs from Diesel Engines

Energy efficiency and environmental impact have become dominant topics in internal combustion engines development. Among many strategies to improve power and emissions outputs from diesel engines is the partial mix of hydrogen and air as fresh charge components to form extremely lean and homogenous mixture, which resist the spontaneous combustion, while diesel fuel is injected directly inside combustion chamber using the conventional fuel injection systems. This contribution presents an analytical and experimental investigation for the effects of adding hydrogen on diesel engines power output and the reduction of emissions. Parametric analysis is used based on lamped parameters modeling of intake manifold to estimate in cylinder trapped charge. The fuel energy flow to engine cylinders is compared for a range of loads and concentrations to simulate relevant case studies. Diesel fuel reduction for significant range of part-load operation can be achieved by introducing hydrogen, along with power improvement emission reductions are affected positively as well. This is achievable without compromising the engine maximum efficiency, given that most engines are operated at small and part-load during normal driving conditions, which allow for introducing more hydrogen instead of large quantities of excess air during such operation conditions that also can be further improved by charge boosting.

Detection of cylinder pressure in diesel engines using cylinder head vibration and time series methods

This paper investigates the vibration characteristics of diesel engine cylinder heads by means of the time series method. With the concept of "Assumed System",the vibration transfer function of real cylinder head structures is established using the autoregressive-moving average models(ARMA models) of cylinder head surface vibration signals. Then this transfer function is successfully used to reconstruct the gas pressure trace inside the cylinder from measured cylinder head vibration signals. This offers an effective means for diesel engine cylinder pressure detection and condition monitoring.

Compacted graphite iron-A material solution for modern diesel engine cylinder blocks and heads

The demands for improved fuel economy,performance and emissions continue to pose challenges for engine designers and the materials they choose. This is particularly true for modern diesel engines,where the primary path to achieving improved engine performance and emissions is to increase the Peak Firing Pressure in the combustion chamber. The resulting increase in thermal and mechanical loading has required a change from conventional grey cast iron to Compacted Graphite Iron (CGI) in order to satisfy durability requirements without increasing the size or the weight of the engines. With at least 75% higher tensile strength,45% higher stiffness and approximately double the fatigue strength of conventional grey cast iron,CGI satisfies durability requirements and also provides the dimensional stability required to meet emissions legislation throughout the life of the engine. Currently,there are no CGI diesel engines running on the roads in North America. This is set to change considerably as new commercial vehicle and pick-up SUV diesel engines are launched with CGI cylinder blocks in 2008 and 2009. These initial programs will provide over 2 million CGI diesel engines when ramped to mature volume,potentially accounting for 10%-15% of the North American passenger vehicle fleet within the next four years.

Diesel Engine Valve Clearance Fault Diagnosis Based on Features Extraction Techniques and FastICA-SVM

Numerous vibration-based techniques are rarely used in diesel engines fault diagnosis in a direct way, due to the surface vibration signals of diesel engines with the complex non-stationary and nonlinear time-varying fea- tures. To investigate the fault diagnosis of diesel engines, fractal correlation dimension, wavelet energy and entropy as features reflecting the diesel engine fault fractal and energy characteristics are extracted from the decomposed signals through analyzing vibration acceleration signals derived from the cylinder head in seven different states of valve train. An intelligent fault detector FastICA-SVM is applied for diesel engine fault diagnosis and classification. The results demonstrate that FastlCA-SVM achieves higher classification accuracy and makes better general- ization performance in small samples recognition. Besides, the fractal correlation dimension and wavelet energy and entropy as the special features of diesel engine vibration signal are considered as input vectors of classifier FastlCA- SVM and could produce the excellent classification results. The proposed methodology improves the accuracy of fea- ture extraction and the fault diagnosis of diesel engines.

Combination of biodiesel-ethanol-diesel fuel blend and SCR catalyst assembly to reduce emissions from a heavy-duty diesel engine

In this study, the efforts to reduce NOx and particulate matter （PM） emissions from a diesel engine using both ethanol-selective catalytic reduction （SCR） of NOx over an Ag/Al2O3 catalyst and a biodiesel-ethanol-diesel fuel blend （BE-diesel） on an engine bench test are discussed. Compared with diesel fuel, use of BE-diesel increased PM emissions by 14% due to the increase in the soluble organic fraction （SOF） of PM, but it greatly reduced the Bosch smoke number by 60%-80% according to the results from 13-mode test of European Stationary Cycle （ESC） test. The SCR catalyst was effective in NOx reduction by ethanol, and the NOx conversion was approximately 73%. Total hydrocarbons （THC） and CO emissions increased significantly during the SCR of NOx process. Two diesel oxidation catalyst （DOC） assemblies were used after Ag/Al2O3 converter to remove CO and HC. Different oxidation catalyst showed opposite effect on PM emission. The PM composition analysis revealed that the net effect of oxidation catalyst on total PM was an integrative effect on SOF reduction and sulfate formation of PM. The engine bench test results indicated that the combination of BE-diesel and a SCR catalyst assembly could provide benefits for NOx and PM emissions control even without using diesel particle filters （DPFs）.

Influence of Diesel Engine Intake Throttle and Late Post Injection Process on the Rise of Temperature in the Diesel Oxidation Catalyst

In order to effectively implement DPF(Diesel Particulate Filters)regeneration control,thermal management of exhaust products before and inside Diesel Oxidation Catalyst(DOC)is necessary.In the present study,the Influence of the intake throttle valve and late post injection process on temperature rise inside DOC is analyzed through engine bench tests.The steady experiment results show that adjustment of the intake throttle valve can effectively increase exhaust temperature before DOC;in particular,with intake throttle valve opening at 20%,temperature before DOC can be increased by about 170℃ with respect to the full opening.An increase in the late post injection quantity can produce a significant rise of the temperature inside DOC,however its impact on the exhaust temperature before DOC is relatively limited.As the late post injection quantity increases,Hydrocarbon(HC)emissions also grow;in the present work it is shown that with a proper injection quantity,a considerable temperature increase inside the DOC can be obtained with relatively low HC emission.More specifically,with the intake throttle valve at 30%and DOC reaching ignition temperature as the late post injection quantity is increased,the exhaust temperature after DOC can be made larger than 550℃,adequate for DPF active regeneration.

Emission and performance study emulsi ed orange peel oil biodiesel in an aspirated research engine

This study paves the way on reducing smoke emission and NO_x emissions of research diesel engine by detailing the e ect of water addition in biodiesel. Fuel samples were prepared with di erent concentrations of water in orange peel oil biodiesel(94% waste orange peel oil biodiesel + 4% water + 2% Span 80(WOPOBDE1) and 90% waste orange peel oil biodiesel + 8% water + 2% Span 80(WOPOBDE2). Span 80 was employed as a nonionic surfactant, which emulsifies water in biodiesel. Experimental results revealed that the nitrogen oxides and smoke emission of orange peel oil biodiesel emulsion were reduced by 11%–19% and 3%–21%, respectively, compared to that of neat orange peel oil biodiesel(WOPOBD). In addition, the introduction of orange peel oil–water emulsions in the diesel engine considerably reduced the emissions of unburned hydrocarbons and carbon monoxide. The overall hydrocarbon emission of WOPOBDE2 was 12.2% lower than that of WOPOBD and 16.3% lower than that of diesel. The overall CO emission of WOPOBDE2 was 17% lower than that of base fuel(WOPOBD) and 21.8% lower than that of diesel. Experimental results revealed that modified fuel had higher brake thermal e ciency and lower brake specific fuel consumption than that of base fuel at all engine brake power levels.

HC-PM COUPLING MODEL FOR PARTICULATE MATTER EMISSION OF DIESEL ENGINES

A rapid, phenomenological model that predicts paniculate matter (PM) emissionof diesel engines is developed and formulated. The model is a chemical equilibrium compositionmodel, and is based on the formation mechanisms of PM and unburned hydrocarbon (HC) emissions ofdiesel engines. It can evaluate the emission concentration of PM via the emission concentration ofHC. To validate the model, experiments are carried out in two research diesel engines. Comparisonsof the model results with the experimental data show good agreement. The model can be used toevaluate the concentration of PM emission of diesel engines under lack of PM measuring instruments.In addition, the model is useful for computer simulations of diesel engines, as well as electroniccontrol unit (ECU) designs for electronically controlled diesel engines.

Design and Research of the EQ6105DTAA Diesel Engine

The EQ6105DTAA diesel engine which first pattern en gi ne is EQD6105T is developed through the original EQ6102 diesel engine and other advanced engine structures. This paper analyses performance parameters, general layout and parts design process of the diesel engine. The development cycle is s horten by CAD/CAE/CAM technology. Through experiment, the general performance of the engine is in keeping ahead in our country. With boosting mid-cooling technology and related designing correction in EQ6105 DTAA diesel engine, it had obtained better motivity and economy. The full load s teady smog emission and smog emission during simulated free accelerating are all meeting with GB14761.6-93, GB3847-1999 limit requirement. The prototype had p assed reliability test and has reliable parts. It performance indexes are in the leading position in same diesel engine in China. The 13 working conditions gas pollute and particle discharging in this pro totype can meet the limit requirement of GB17691-2001, phase I. The EQ6105DTAA diesel engine parts has good generality with existing types, which lower down th e production cost.

Research on Spray, Combustion and Emission Characteristics for DI Diesel Engine

To improve the combustion chamber shape that can decrease the directed injection （DI） diesel emission, the theories of DI diesel spray, combustion and pollutant formation model are analysed and implemented based on the CFD code FIRE. Results show that the chamber with contracting orifice can get stronger squish swirl intensity. The results of the verification studies show a good accordance with the measurements and reveal that the individual processes of spray, evolution, combustion and pollutant formation are well captured in FIRE. Finally, based on the analyzing and comparing of the calculation results of different chambers, a combustion chamber of contracting orifice geometry with lower emission is proposed.

Large eddy simulation of fuel injection and mixing process in a diesel engine

The large eddy simulation （LES） approach implemented in the KIVA-3V code and based on one-equation sub-grid turbulent kinetic energy model are employed for numerical computation of diesel sprays in a constant volume vessel and in a Caterpillar 3400 series diesel engine. Computational results are compared with those obtained by an RANS （RNG k-e） model as well as with experimental data. The sensitivity of the LES results to mesh resolution is also discussed. The results show that LES generally provides flow and spray characteristics in better agreement with experimental data than RANS; and that small-scale random vortical structures of the in-cylinder turbulent spray field can be captured by LES. Furthermore, the penetrations of fuel droplets and vapors calculated by LES are larger than the RANS result, and the sub-grid turbulent kinetic energy and sub-grid turbulent viscosity provided by the LES model are evidently less than those calculated by the RANS model. Finally, it is found that the initial swirl significantly affects the spray penetration and the distribution of fuel vapor within the combustion chamber.

Effect of Petroleum Products on Soil Catalase and Dehydrogenase Activities

The effect of refined petroleum products on the activities of selected enzymes (catalase and dehydrogenase) was studied. There was a significant decrease (p kerosene > diesel > engine oil. However, a significant increase (p diesel > petrol > engine oil. On the whole the results reveal that refined petroleum products alter soil biochemistry.