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甲醇POSR制氢的反应网络热力学分析和有效因子的估算 被引量:5
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作者 蒋元力 黄强 +1 位作者 陈卫航 曹云丽 《燃料化学学报》 EI CAS CSCD 北大核心 2003年第4期349-354,共6页
在Cu/ZnO/Al2O3催化剂上对甲醇部分氧化蒸汽重整制备氢气反应的动力学过程进行了研究。在常压和473K~1073K温度范围内对该反应网络中的甲醇部分氧化、甲醇蒸汽重整、甲醇分解和水煤气反应的化学平衡进行了分析。在对这些反应的催化剂Cu... 在Cu/ZnO/Al2O3催化剂上对甲醇部分氧化蒸汽重整制备氢气反应的动力学过程进行了研究。在常压和473K~1073K温度范围内对该反应网络中的甲醇部分氧化、甲醇蒸汽重整、甲醇分解和水煤气反应的化学平衡进行了分析。在对这些反应的催化剂Cu/ZnO/Al2O3动力学研究的基础上,根据有效因子的基本概念,考虑催化剂颗粒内的扩散限制,对每个反应沿反应器床层的有效因子进行了估算。 展开更多
关键词 甲醇部分氧化蒸汽重整 化学平衡 扩散限制 有效因子
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Global Existence of the Equilibrium Diffusion Model in Radiative Hydrodynamics
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作者 Chunjin LIN Thierry GOUDON 《Chinese Annals of Mathematics,Series B》 SCIE CSCD 2011年第4期549-568,共20页
This paper is devoted to the analysis of the Cauchy problem for a system of PDEs arising in radiative hydrodynamics. This system, which comes from the so-called equilibrium diffusion regime, is a variant of the usual ... This paper is devoted to the analysis of the Cauchy problem for a system of PDEs arising in radiative hydrodynamics. This system, which comes from the so-called equilibrium diffusion regime, is a variant of the usual Euler equations, where the energy and pressure functionals are modified to take into account the effect of radiation and the energy balance containing a nonlinear diffusion term acting on the temperature. The problem is studied in the multi-dimensional framework. The authors identify the existence of a strictly convex entropy and a stability property of the system, and check that the Kawashima-Shizuta condition holds. Then, based on these structure properties, the wellposedness close to a constant state can be proved by using fine energy estimates. The asymptotic decay of the solutions are also investigated. 展开更多
关键词 Radiative hydrodynamics Initial value problem equilibrium diffusion regime Energy method
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Mn Diffusion at Early Stage of Intercritical Annealing of 5Mn Steel
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作者 Xi-nan LUO Xiao-yan ZHONG +3 位作者 Hai-wen LUO Hui-hua ZHOU Cun-yu WANG Jie SHI 《Journal of Iron and Steel Research International》 SCIE EI CAS CSCD 2015年第11期1015-1019,共5页
Mn distribution and austenite morphology at the early stage of intercritical annealing of 5Mn steel were investigated. It was experimentally demonstrated that a newly formed 20 nm-thick austenite was formed without th... Mn distribution and austenite morphology at the early stage of intercritical annealing of 5Mn steel were investigated. It was experimentally demonstrated that a newly formed 20 nm-thick austenite was formed without the partitioning of Mn. The elemental analysis confirmed that the growth of austenite should be controlled by the diffusion of C prior to the diffusion of Mn at a low heating rate. The austenite growth started under negligible-partitioning local equilibrium mode and then switched to partitioning local equilibrium mode. Mn segregation at the γ/α interface suggested that the collector plate mechanism was the essential way of Mn partitioning at the early stage of austenite growth. 展开更多
关键词 Mn diffusion austenite nucleation intercritical annealing negligible-partitioning local equilibrium diffusion mechanism
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