The increasing anthropogenic CO2 emission and global warming has challenged the China and other countries to seek new and better ways to meet the world’s increasing need for energy while reducing greenhouse gas emiss...The increasing anthropogenic CO2 emission and global warming has challenged the China and other countries to seek new and better ways to meet the world’s increasing need for energy while reducing greenhouse gas emissions.The overall proposition of this research is to develop a brand-new CO2 physical and chemical sequestration method by using solid waste of coal mining and cementitious material which are widely used for goaf backfilling in coal mining.This research developed a new testing system(constant temperature pressurized reaction chamber(CTPRC))to study the effects of different initial parameters on mineral carbonation such as different initial water-binder ratio,initial sample porosity and initial carbon dioxide pressure.The experimental results show that the CO2 consumption ratio is 15%,10%and 7%higher with relatively high initial water-binder ratio,initial sample porosity and initial CO2 pressure within 48 h.In addition,some physical and chemical evidence was found through the electron microscope scanning and XRD test to further explain the above test results.This proposed research will provide critical parameters for optimizing CO2 sequestration capacity in this cementitious backfilling material with forming agent.展开更多
The use of sequestered carbon dioxide(CO) as the heat exchange fluid in enhanced geothermal system(EGS) has significant potential to increase their productivity, contribute further to reducing carbon emissions and inc...The use of sequestered carbon dioxide(CO) as the heat exchange fluid in enhanced geothermal system(EGS) has significant potential to increase their productivity, contribute further to reducing carbon emissions and increase the economic viability of geothermal power generation. Coupled COsequestration and geothermal energy production from hot dry rock(HDR) EGS were first proposed 15 years ago but have yet to be practically implemented. This paper reviews some of the issues in assessing these systems with particular focus on the power generation and COsequestration capacity. The Habanero geothermal field in the Cooper Basin of South Australia is assessed for its potential COstorage capacity if supercritical COis used as the working fluid for heat extraction. The analysis suggests that the major COsequestration mechanisms are the storage in the fracture-stimulation damaged zone followed by diffusion into the pores within the rock matrix. The assessment indicates that 5% of working fluid loss commonly suggested as the storage capacity might be an over-estimate of the long-term COsequestration capacity of EGS in which supercritical COis used as the circulation fluid.展开更多
Sequestration of CO2 in deep and unmineable coal seams is one of the attractive alternatives to reduce its atmospheric concentration. Injection of CO2 in coal seams may help in enhancing the recovery of coalbed methan...Sequestration of CO2 in deep and unmineable coal seams is one of the attractive alternatives to reduce its atmospheric concentration. Injection of CO2 in coal seams may help in enhancing the recovery of coalbed methane. An experimental study has been carried out using coal samples from three different coal seams, to evaluate the enhanced gas recovery and sequestration potential of these coals. The coals were first saturated with methane and then by depressurization some of the adsorbed methane was desorbed. After partial desorption, CO2 was injected into the coals and subsequently they were depressurized again. Desorption of methane after the injections was studied, to investigate the ability of CO2 to displace and enhance the recovery of methane from the coals. The coals exhibited varying behavior of adsorption of CO2 and release of methane. For one coal, the release of methane was enhanced by injection of CO2, suggesting preferential adsorption of CO2 and desorption of methane. For the other two coals, CO2 injection did not produce incremental methane initially, as there was initial resistance to methane release. However with continued CO2 injection, most of the remaining methane was produced. The study suggested that preferential sorption behavior of coal and enhanced gas recovery pattern could not be generalized for all coals.展开更多
Less than 10% of oil is usually recovered from liquid-rich shales and this leaves much room for improvement, while water injection into shale formation is virtually impossible because of the extremely low permeability...Less than 10% of oil is usually recovered from liquid-rich shales and this leaves much room for improvement, while water injection into shale formation is virtually impossible because of the extremely low permeability of the formation matrix. Injecting carbon dioxide(CO2) into oil shale formations can potentially improve oil recovery. Furthermore, the large surface area in organicrich shale could permanently store CO2 without jeopardizing the formation integrity. This work is a mechanism study of evaluating the effectiveness of CO2-enhanced oil shale recovery and shale formation CO2 sequestration capacity using numerical simulation. Petrophysical and fluid properties similar to the Bakken Formation are used to set up the base model for simulation. Result shows that the CO_2 injection could increase the oil recovery factor from7.4% to 53%. In addition, petrophysical characteristics such as in situ stress changes and presence of a natural fracture network in the shale formation are proven to have impacts on subsurface CO2 flow. A response surface modeling approach was applied to investigate the interaction between parameters and generate a proxy model for optimizing oil recovery and CO2 injectivity.展开更多
Carbon Dioxide (CO2) storage and sequestration in unconventional shale resources has been attracting interest since last couple of years due to the very unique characteristics of such formations have made them a feasi...Carbon Dioxide (CO2) storage and sequestration in unconventional shale resources has been attracting interest since last couple of years due to the very unique characteristics of such formations have made them a feasible option for this object. Shale formations are found all around the world and the conventional assets are easily accessible, and also the huge move of operators toward developing unconventional reservoirs during past years leaves many of such formations ready for sequestering CO2. Today, the use of long horizontal wells that are drilled on a pad has the lowest amount of environmental footprint in which for storage and sequestration purpose also provides much more underground pore spaces available for CO2. In this paper we study the state of the art of the technology of CO2 storage and sequestration and provide different and fresh look for its complex phenomena from a mathematical modeling point of view. Moreover, we hope this study provides valuable insights into the use of depleted shale gas reservoirs for carbon sequestration, which as a result, a cleaner atmosphere will be achieved for the life of our next generations. Also, we present that the depleted shale gas reservoirs are very adequate for this purpose as they already have much of the infrastructure required to perform CO2 injection available in sites.展开更多
To reduce the emissions of carbon dioxide(CO) into the atmosphere, it is proposed to inject anthropogenic COinto deep geological formations. Deep un-mineable coalbeds are considered to be possible COrepositories becau...To reduce the emissions of carbon dioxide(CO) into the atmosphere, it is proposed to inject anthropogenic COinto deep geological formations. Deep un-mineable coalbeds are considered to be possible COrepositories because coal is able to adsorb a large amount of COinside its microporous structure.However, the response of coalbeds is complex because of coupled flow and mechanical processes. Injection of COcauses coal to swell, which leads to reductions in permeability and hence makes injection more difficult, and at the same time leads to changes in the mechanical properties which can affect the stress state in the coal and overlying strata. The mechanical properties of coal under storage conditions are of importance when assessing the integrity and safety of the storage scheme. On the other hand, the geomechanical response of coalbed will also influence the reservoir performance of coalbed. This paper provides an overview of processes associated with coalbed geosequestration of COwhile the importance of geomechanical characteristics of coalbeds is highlighted. The most recent findings about the interactions between gas transport and geomechanical characteristics of coal will be discussed and the essence will be delivered. The author suggests areas for future research efforts to further improve the understanding of enhanced coalbed methane(ECBM) and coalbed geosequestration of CO.展开更多
A multilayer study of pCO2 for the Yellow and South China Seas in the surface waters was conducted based on data from four cruises sponsored by the China SOLAS Project in 2005 and 2006,including data for the surface m...A multilayer study of pCO2 for the Yellow and South China Seas in the surface waters was conducted based on data from four cruises sponsored by the China SOLAS Project in 2005 and 2006,including data for the surface microlayer(SML) ,subsurface layer(SSL) and surface layer(SL) . The carbon fluxes across the air-sea interface were calculated. The results showed that the pCO2 values in the surface waters of the study area decreased in the following order:pCO2 SML> pCO2 SSL> pCO2 SL. The highest values were found in March for all SML,SSL and SL,followed by those in April,and the lowest were in May. The pCO2 values had a significant positive correlation with temperature or salinity. While there was no relationship between pCO2 and longitude,there was a significant negative correlation between it and latitude,i.e.,'high latitude low pCO2'. By using four calculation models,the carbon dioxide fluxes(FC O2) in spring in the Yellow and South China Seas,which were found to act as a 'sink' of atmospheric CO2,were preliminarily estimated on the basis of the pCO2 data in the SML to be -7.00×106 t C and -22.35×106 t C,respectively. It is suggested that the FC O2calculated on the basis of pCO2 data in the SML is more reliable than that calculated on the basis of those in the SL.展开更多
The latest advancement of CO2 flooding and sequestration theory and technology in China is systematically described, and the future development direction is put forward. Based on the geological characteristics of cont...The latest advancement of CO2 flooding and sequestration theory and technology in China is systematically described, and the future development direction is put forward. Based on the geological characteristics of continental reservoirs, five theories and key technologies have been developed:(1) Enriched the understandings about the mass transfer characteristics of components between CO2 and crude oil in continental reservoirs, micro-flooding mechanism and sequestration mechanism of different geological bodies.(2) Established the design method of reservoir engineering parameters, injection-production control technology and development effect evaluation technology of CO2 flooding, etc.(3) Developed a series of production engineering technologies such as separated layer CO2 injection technology, high efficiency lifting technology, on-line wellbore corrosion monitoring and protection technology.(4) Innovated a series of surface engineering technology including CO2 capture technology, pipeline CO2 transportation, CO2 surface injection, and production gas circulation injection, etc.(5) Formed a series of supporting technologies including monitoring, and safety and environmental protection evaluation of CO2 flooding reservoir. On this basis, the technological development directions in the future have been put forward:(1) Breakthrough in low-cost CO2 capture technology to provide cheap CO2 gas source;(2) Improve the miscibility technology between CO2 and crude oil to enhance oil displacement efficiency;(3) Improve CO2 sweeping volume;(4) Develop more effective lifting tools and technologies;(5) Strengthen the research of basic theory and key technology of CO2 storage monitoring. CO2 flooding and sequestration in the Jilin Oilfield shows that this technology has broad application prospects in China.展开更多
The leakage of stored and transported CO2 is a risk for geological sequestration technology. One of the most challenging problems is to recognize and determine CO2 leakage signal in the complex atmosphere background. ...The leakage of stored and transported CO2 is a risk for geological sequestration technology. One of the most challenging problems is to recognize and determine CO2 leakage signal in the complex atmosphere background. In this work, a time series model was proposed to forecast the atmospheric CO2 variation and the approximation error of the model was utilized to recognize the leakage. First, the fitting neural network trained with recently past CO2 data was applied to predict the daily atmospheric CO2. Further, the recurrent nonlinear autoregressive with exogenous input(NARX) model was adopted to get more accurate prediction. Compared with fitting neural network, the approximation errors of NARX have a clearer baseline, and the abnormal leakage signal can be seized more easily even in small release cases. Hence, the fitting approximation of time series prediction model is a potential excellent method to capture atmospheric abnormal signal for CO2 storage and transportation technologies.展开更多
Based on practices of CO_(2) flooding tests in China and abroad,the recovery factor of carbon dioxide capture,utilization in displacing oil and storage(CCUS-EOR)in permanent sequestration scenario has been investigate...Based on practices of CO_(2) flooding tests in China and abroad,the recovery factor of carbon dioxide capture,utilization in displacing oil and storage(CCUS-EOR)in permanent sequestration scenario has been investigated in this work.Under the background of carbon neutrality,carbon dioxide injection into geological bodies should pursue the goal of permanent sequestration for effective carbon emission reduction.Hence,CCUS-EOR is an ultimate development method for oil reservoirs to maximize oil recovery.The limit recovery factor of CCUS-EOR development mode is put forward,the connotation differences between it and ultimate recovery factor and economically reasonable recovery factor are clarified.It is concluded that limit recovery factor is achievable with mature supporting technical base for the whole process of CCUS-EOR.Based on statistics of practical data of CO_(2) flooding projects in China and abroad such as North H79 block CO_(2) flooding pilot test at small well spacing in Jilin Oilfield etc.,the empirical relationship between the oil recovery factor of miscible CO_(2) flooding and cumulative CO_(2) volume injected is obtained by regression.Combined with the concept of oil production rate multiplier of gas flooding,a reservoir engineering method calculating CO_(2) flooding recovery factor under any miscible degree is established by derivation.It is found that when the cumulative CO_(2) volume injected is 1.5 times the hydrocarbon pore volume(HCPV),the relative deviation and the absolute difference between the recovery percentage and the limit recovery factor are less than 5%and less than 2.0 percentage points respectively.The limit recovery factor of CCUS-EOR can only be approached by large pore volume(PV)injection based on the technology of expanding swept volume.It needs to be realized from three aspects:large PV injection scheme design,enhancing miscibility degree and continuously expanding swept volume of injected CO_(2).展开更多
Urban areas are a major source of anthropogenic carbon dioxide (CO<sub><span style="font-family:Verdana;">2</span></sub><span style="font-family:Verdana;">) emissions ...Urban areas are a major source of anthropogenic carbon dioxide (CO<sub><span style="font-family:Verdana;">2</span></sub><span style="font-family:Verdana;">) emissions because of road traffic and local heating with natural gas, oil or coal. Rome is among the largest European cities (129,000 ha) with a large volume of green areas (69.6% of the total Municipality area). The CO</span><sub><span style="font-family:Verdana;">2</span></sub><span style="font-family:Verdana;"> sequestration (CS) capability for the greenery extending for about 300 km</span><sup><span style="font-family:Verdana;">2</span></sup><span style="font-family:Verdana;"> inside the area delimited by the Great Ring Road (GRA) in Rome was calculated combining satellite data with CS data measured in the field. Data from Sentinel-2 were collected and the Normalized Difference Vegetation Index (NDVI) was computed on a pixel-base. Three plant classes homogeneous in terms of annual NDVI profile were identified: deciduous trees (DT), evergreen trees (ET) and meadows (M) covering an area of 14,142.027 ha within the GRA, of which M had the highest percentage (48%), followed by DT (27%) and ET (25%). CS ranged from 428,241</span><span style="font-family:Verdana;">,</span><span style="font-family:Verdana;">492.9 </span><span style="font-family:Verdana;">T</span><span style="font-family:;" "=""><span style="font-family:Verdana;">ons CO</span><sub><span style="font-family:Verdana;">2</span></sub><span style="font-family:Verdana;"> year</span><sup><span style="font-family:Verdana;">-1</span></sup><span style="font-family:Verdana;"> (ET) to 263,072</span></span><span style="font-family:Verdana;">,</span><span style="font-family:;" "=""><span style="font-family:Verdana;">460.6 Tons CO</span><sub><span style="font-family:Verdana;">2</span></sub><span style="font-family:Verdana;"> year</span><sup><span style="font-family:Verdana;">-1</span></sup><span style="font-family:Verdana;"> (M). The total CS of the greenery inside the GRA was 1049,490,355.4 Tons CO</span><sub><span style="font-family:Verdana;">2</span></sub><span style="font-family:Verdana;"> year</span><sup><span style="font-family:Verdana;">-1</span></sup><span style="font-family:Verdana;"> resulting in an annual economic value of $772,424,901.6/ha. The CO</span><sub><span style="font-family:Verdana;">2</span></sub><span style="font-family:Verdana;"> sequestration capability of the considered plant classes could be incorporated into the national greenhouse gas emission budget to calculate the contribution of CO</span><sub><span style="font-family:Verdana;">2</span></sub><span style="font-family:Verdana;"> sequestration to the economy of Rome.</span></span>展开更多
Water-quenched copper-nickel metallurgical slag enriched with olivine minerals exhibits promising potential for the production of CO_(2)-mineralized cementitious materials.In this work,copper-nickel slag-based cementi...Water-quenched copper-nickel metallurgical slag enriched with olivine minerals exhibits promising potential for the production of CO_(2)-mineralized cementitious materials.In this work,copper-nickel slag-based cementitious material(CNCM)was synthesized by using different chemical activation methods to enhance its hydration reactivity and CO_(2) mineralization capacity.Different water curing ages and carbonation conditions were explored related to their carbonation and mechanical properties development.Meanwhile,thermogravimetry differential scanning calorimetry and X-ray diffraction methods were applied to evaluate the CO_(2) adsorption amount and carbonation products of CNCM.Microstructure development of carbonated CNCM blocks was examined by backscattered electron imaging(BSE)with energy-dispersive X-ray spectrometry.Results showed that among the studied samples,the CNCM sample that was subjected to water curing for 3 d exhibited the highest CO_(2) sequestration amount of 8.51wt%at 80℃and 72 h while presenting the compressive strength of 39.07 MPa.This result indicated that 1 t of this CNCM can sequester 85.1 kg of CO_(2) and exhibit high compressive strength.Although the addition of citric acid did not improve strength development,it was beneficial to increase the CO_(2) diffusion and adsorption amount under the same carbonation conditions from BSE results.This work provides guidance for synthesizing CO_(2)-mineralized cementitious materials using large amounts of metallurgical slags containing olivine minerals.展开更多
In this paper, a regionally disaggregated global energy system model with a detailed treatment of the whole chain of CO2 capture and storage (CCS) is used to derive the cost-optimal global pattern of CO2 sequestration...In this paper, a regionally disaggregated global energy system model with a detailed treatment of the whole chain of CO2 capture and storage (CCS) is used to derive the cost-optimal global pattern of CO2 sequestration in regional detail over the period 2010-2050 under the target of halving global energy-related CO2 emissions in 2050 compared to the 2005 level. The major conclusions are the following. First, enhanced coalbed methane recovery will become a key early opportunity for CO2 sequestration, so coalrich regions such as the US, China, and India will play a leading role in global CO2 sequestration. Enhanced oil recovery will also have a participation in global CO2 sequestration from the initial stage of CCS deployment, which may be applied mainly in China, southeastern Asia, and West Africa in 2030 and mainly in the Middle East in 2050. Second, CO2 sequestration will be carried out in an increasing number of world regions over time. In particular, CCS will be deployed extensively in today’s developing countries. Third, an increasing amount of the captured CO2 will be stored in aquifers in many parts of the world due to their abundant and widespread availability and their low cost. It is shown that the share of aquifers in global CO2 sequestration reaches 82.0% in 2050.展开更多
Marine carbon sequestration is an important component of carbon dioxide capture, utilization and storage(CCUS) technology. It is crucial for achieving carbon peaking and carbon neutralization in China. However, CO_(2)...Marine carbon sequestration is an important component of carbon dioxide capture, utilization and storage(CCUS) technology. It is crucial for achieving carbon peaking and carbon neutralization in China. However, CO_(2) leakage may lead to seabed geological disasters and threaten the safety of marine engineering. Therefore, it is of great significance to study the safety monitoring technology of marine carbon sequestration.Zhanjiang is industrially developed and rich in carbon sources. Owing to the good physical properties and reservoirs and trap characteristics,Zhanjiang has huge storage potential. This paper explores the disaster mechanism associated with CO_(2) leakage in marine carbon sequestration areas. Based on the analysis of the development of Zhanjiang industry and relevant domestic monitoring technologies, several suggestions for safety monitoring of marine carbon sequestration are proposed: application of offshore aquaculture platforms, expansion and application of ocean observation networks, carbon sequestration safety monitoring and sensing system. Intended to build a comprehensive and multi-level safety monitoring system for marine carbon sequestration, the outcome of this study provides assistance for the development of marine carbon sequestration in China's offshore areas.展开更多
The process of capturing and storing carbon dioxide (CCS) was previously considered a crucial and time-sensitive approach for diminishing CO<sub>2</sub> emissions originating from coal, oil, and gas sector...The process of capturing and storing carbon dioxide (CCS) was previously considered a crucial and time-sensitive approach for diminishing CO<sub>2</sub> emissions originating from coal, oil, and gas sectors. Its implementation was seen necessary to address the detrimental effects of CO<sub>2</sub> on the atmosphere and the ecosystem. This recognition was achieved by previous substantial study efforts. The carbon capture and storage (CCS) cycle concludes with the final stage of CO<sub>2</sub> storage. This stage involves primarily the adsorption of CO<sub>2</sub> in the ocean and the injection of CO<sub>2</sub> into subsurface reservoir formations. Additionally, the process of CO<sub>2</sub> reactivity with minerals in the reservoir formations leads to the formation of limestone through injectivities. Carbon capture and storage (CCS) is the final phase in the CCS cycle, mostly achieved by the use of marine and underground geological sequestration methods, along with mineral carbonation techniques. The introduction of supercritical CO<sub>2</sub> into geological formations has the potential to alter the prevailing physical and chemical characteristics of the subsurface environment. This process can lead to modifications in the pore fluid pressure, temperature conditions, chemical reactivity, and stress distribution within the reservoir rock. The objective of this study is to enhance our existing understanding of CO<sub>2</sub> injection and storage systems, with a specific focus on CO<sub>2</sub> storage techniques and the associated issues faced during their implementation. Additionally, this research examines strategies for mitigating important uncertainties in carbon capture and storage (CCS) practises. Carbon capture and storage (CCS) facilities can be considered as integrated systems. However, in scientific research, these storage systems are often divided based on the physical and spatial scales relevant to the investigations. Utilising the chosen system as a boundary condition is a highly effective method for segregating the physics in a diverse range of physical applications. Regrettably, the used separation technique fails to effectively depict the behaviour of the broader significant system in the context of water and gas movement within porous media. The limited efficacy of the technique in capturing the behaviour of the broader relevant system can be attributed to the intricate nature of geological subsurface systems. As a result, various carbon capture and storage (CCS) technologies have emerged, each with distinct applications, associated prices, and social and environmental implications. The results of this study have the potential to enhance comprehension regarding the selection of an appropriate carbon capture and storage (CCS) application method. Moreover, these findings can contribute to the optimisation of greenhouse gas emissions and their associated environmental consequences. By promoting process sustainability, this research can address critical challenges related to global climate change, which are currently of utmost importance to humanity. Despite the significant advancements in this technology over the past decade, various concerns and ambiguities have been highlighted. Considerable emphasis was placed on the fundamental discoveries made in practical programmes related to the storage of CO<sub>2</sub> thus far. The study has provided evidence that despite the extensive research and implementation of several CCS technologies thus far, the process of selecting an appropriate and widely accepted CCS technology remains challenging due to considerations related to its technological feasibility, economic viability, and societal and environmental acceptance.展开更多
The utilization of CO_(2)-Enhanced Coal Bed Methane(CO_(2)-ECBM)technology is pivotal in realizing the environmentally responsible and efficient exploitation of Coalbed Methane(CBM)energy resources.The optimization of...The utilization of CO_(2)-Enhanced Coal Bed Methane(CO_(2)-ECBM)technology is pivotal in realizing the environmentally responsible and efficient exploitation of Coalbed Methane(CBM)energy resources.The optimization of carbon capture,utilization,and storage(CCUS)for carbon reduction mandates a nuanced understanding of the diverse geological attributes present in CBM reserves globally.Traditional estimations of CO_(2)-ECBM's carbon sequestration potential have predominantly relied on rudimentary empirical models,notably those proposed by the United States Department of Energy(DOE),which overlook the intrinsic geological conditions and the physicochemical properties of subsurface fluids.Addressing these limitations,our study implements the advanced DR/Henry mixed adsorption model in tandem with the Peng-Robinson equation of state(PR-EOS).This approach meticulously identifies the critical parameters governing the mass exchange ratios between CO_(2)and CH_(4),pertinent to in-situ geological environments.Subsequently,we have formulated a comprehensive carbon sequestration potential assessment framework.This innovative model adheres to the mass conservation principles for individual CO_(2)and CH_(4)components,taking into account the specific surface and stratigraphic conditions prevalent.Employing this refined methodology,we evaluated the CO_(2)-ECBM carbon sequestration potential of the 40 evaluation units of extensional,compressive,and cratonic continental coal bearing basins in China's three major temperature-pressure systems across different depth domains and coal ranks within 2000 m.Our findings reveal that the theoretical carbon sequestration capacity of China's continental coal-bearing basins is approximately 59.893 billion tons.Concurrently,the potential ECBM output stands at an estimated 4.92 trillion cubic meters,underscoring the substantial environmental and energy benefits inherent in harnessing CO_(2)-ECBM technology effectively.The regional analysis revealed that North and Northwest China hold the highest sequestration and recovery potential,followed by the Northeast and Southern regions,respectively.Specific areas,including the eastern edge of the Ordos Basin and southern Junggar Basin,Qinshui,Huoxi,Xishan,and other areas in Shanxi,present promising future prospects for geological carbon storage in unrecoverable coal seams.展开更多
This paper systematically reviews the current applications of various spatial information technologies in CO_(2)sequestration monitoring,analyzes the challenges faced by spatial information technologies in CO_(2)seque...This paper systematically reviews the current applications of various spatial information technologies in CO_(2)sequestration monitoring,analyzes the challenges faced by spatial information technologies in CO_(2)sequestration monitoring,and prospects the development of spatial information technologies in CO_(2)sequestration monitoring.Currently,the spatial information technologies applied in CO_(2)sequestration monitoring mainly include five categories:eddy covariance method,remote sensing technology,geographic information system,Internet of Things technology,and global navigation satellite system.These technologies are involved in three aspects:monitoring data acquisition,positioning and data transmission,and data management and decision support.Challenges faced by the spatial information technologies in CO_(2)sequestration monitoring include:selecting spatial information technologies that match different monitoring purposes,different platforms,and different monitoring sites;establishing effective data storage and computing capabilities to cope with the broad sources and large volumes of monitoring data;and promoting collaborative operations by interacting and validating spatial information technologies with mature monitoring technologies.In the future,it is necessary to establish methods and standards for designing spatial information technology monitoring schemes,develop collaborative application methods for cross-scale monitoring technologies,integrate spatial information technologies with artificial intelligence and high-performance computing technologies,and accelerate the application of spatial information technologies in carbon sequestration projects in China.展开更多
This study characterized the AA-01 depleted hydrocarbon reservoir in the KOKA field, Niger Delta, using a multidimensional approach. This investigation involved data validation analysis, evaluation of site suitability...This study characterized the AA-01 depleted hydrocarbon reservoir in the KOKA field, Niger Delta, using a multidimensional approach. This investigation involved data validation analysis, evaluation of site suitability for CO_(2) storage, and compositional simulation of hydrocarbon components. The primary objective was to determine the initial components and behavior of the hydrocarbon system required to optimize the injection of CO_(2) and accompanying impurities, establishing a robust basis for subsequent sequestration efforts in the six wells in the depleted KOKA AA-01 reservoir. The process, simulated using industry software such as ECLIPSE, PVTi, SCAL, and Petrel, included a compositional fluid analysis to confirm the pressure volume temperature(PVT) hydrocarbon phases and components. This involved performing a material balance on the quality of the measured data and matching the initial reservoir pressure with the supplied data source. The compositional PVT analysis adopted the Peng–Robinson equation of state to model fluid flow in porous media and estimate the necessary number of phases and components to describe the system accurately. Results from this investigation indicate that the KOKA AA-01 reservoir is suitable for CO_(2)sequestration. This conclusion is based on the reservoir's good quality, evidenced by an average porosity of 0.21 and permeability of 1 111.0 mD, a measured lithological depth of 9 300 ft, and characteristic reservoir – seal properties correlated from well logs. The study confirmed that volumetric behavior predictions are directly linked to compositional behavior predictions, which are essential during reservoir initialization and data quality checks. Additionally, it highlighted that a safe design for CO_(2) storage relies on accurately representing multiphase behaviour across wide-ranging pressure–temperature–composition conditions.展开更多
The UN International Panel Environment Programme (“UNEP”), 2023 Emissions Gap Report urgently presses the global community to adopt a two-pronged approach to reduce atmospheric concentration of CO2—expedite efforts...The UN International Panel Environment Programme (“UNEP”), 2023 Emissions Gap Report urgently presses the global community to adopt a two-pronged approach to reduce atmospheric concentration of CO2—expedite efforts to reduce annual CO2 emissions;and increase investment in large-scale carbon dioxide removal (“CDR”) projects. The Gap Report sets a 2050 target of six-gigatons annual land-based CDR. Our proposed agroforestry project will convert thirty-five-million acres of rangeland in the American Great Plains to silvopasture, combining growing trees and raising livestock. Employing agroforestry interests 61% of Great Plaints farmers/ranchers recently surveyed. The Project plans to annually collect + six-gigatons CO2 equiv. of fallen leaves and store the stable carbon-rich biomass underground for centuries. The purpose of this paper is to describe the framework for formation of a global partnership at the local, regional, and international levels to coordinate public and private financing mechanisms, implement, and operate a large-scale CDR Project that will meaningfully impact the global effort to mitigate climate change.展开更多
基金the National Natural Science Foundation of China(No.51304207)the Fundamental Research Funds for the Key Laboratory of Coal-based CO2 capture and geological storage,China University of Mining and Technology(No.2016A03).
文摘The increasing anthropogenic CO2 emission and global warming has challenged the China and other countries to seek new and better ways to meet the world’s increasing need for energy while reducing greenhouse gas emissions.The overall proposition of this research is to develop a brand-new CO2 physical and chemical sequestration method by using solid waste of coal mining and cementitious material which are widely used for goaf backfilling in coal mining.This research developed a new testing system(constant temperature pressurized reaction chamber(CTPRC))to study the effects of different initial parameters on mineral carbonation such as different initial water-binder ratio,initial sample porosity and initial carbon dioxide pressure.The experimental results show that the CO2 consumption ratio is 15%,10%and 7%higher with relatively high initial water-binder ratio,initial sample porosity and initial CO2 pressure within 48 h.In addition,some physical and chemical evidence was found through the electron microscope scanning and XRD test to further explain the above test results.This proposed research will provide critical parameters for optimizing CO2 sequestration capacity in this cementitious backfilling material with forming agent.
基金funded by Australian Research Council Discovery Project(Grant No.DP110104766)financial support from the China Australia Geological Storage of CO_2 Project(CAGS)Australia-China Young Researchers Exchange Program 2012
文摘The use of sequestered carbon dioxide(CO) as the heat exchange fluid in enhanced geothermal system(EGS) has significant potential to increase their productivity, contribute further to reducing carbon emissions and increase the economic viability of geothermal power generation. Coupled COsequestration and geothermal energy production from hot dry rock(HDR) EGS were first proposed 15 years ago but have yet to be practically implemented. This paper reviews some of the issues in assessing these systems with particular focus on the power generation and COsequestration capacity. The Habanero geothermal field in the Cooper Basin of South Australia is assessed for its potential COstorage capacity if supercritical COis used as the working fluid for heat extraction. The analysis suggests that the major COsequestration mechanisms are the storage in the fracture-stimulation damaged zone followed by diffusion into the pores within the rock matrix. The assessment indicates that 5% of working fluid loss commonly suggested as the storage capacity might be an over-estimate of the long-term COsequestration capacity of EGS in which supercritical COis used as the circulation fluid.
文摘Sequestration of CO2 in deep and unmineable coal seams is one of the attractive alternatives to reduce its atmospheric concentration. Injection of CO2 in coal seams may help in enhancing the recovery of coalbed methane. An experimental study has been carried out using coal samples from three different coal seams, to evaluate the enhanced gas recovery and sequestration potential of these coals. The coals were first saturated with methane and then by depressurization some of the adsorbed methane was desorbed. After partial desorption, CO2 was injected into the coals and subsequently they were depressurized again. Desorption of methane after the injections was studied, to investigate the ability of CO2 to displace and enhance the recovery of methane from the coals. The coals exhibited varying behavior of adsorption of CO2 and release of methane. For one coal, the release of methane was enhanced by injection of CO2, suggesting preferential adsorption of CO2 and desorption of methane. For the other two coals, CO2 injection did not produce incremental methane initially, as there was initial resistance to methane release. However with continued CO2 injection, most of the remaining methane was produced. The study suggested that preferential sorption behavior of coal and enhanced gas recovery pattern could not be generalized for all coals.
基金support from the Warwick Energy Group and University of Oklahoma to publish this work
文摘Less than 10% of oil is usually recovered from liquid-rich shales and this leaves much room for improvement, while water injection into shale formation is virtually impossible because of the extremely low permeability of the formation matrix. Injecting carbon dioxide(CO2) into oil shale formations can potentially improve oil recovery. Furthermore, the large surface area in organicrich shale could permanently store CO2 without jeopardizing the formation integrity. This work is a mechanism study of evaluating the effectiveness of CO2-enhanced oil shale recovery and shale formation CO2 sequestration capacity using numerical simulation. Petrophysical and fluid properties similar to the Bakken Formation are used to set up the base model for simulation. Result shows that the CO_2 injection could increase the oil recovery factor from7.4% to 53%. In addition, petrophysical characteristics such as in situ stress changes and presence of a natural fracture network in the shale formation are proven to have impacts on subsurface CO2 flow. A response surface modeling approach was applied to investigate the interaction between parameters and generate a proxy model for optimizing oil recovery and CO2 injectivity.
文摘Carbon Dioxide (CO2) storage and sequestration in unconventional shale resources has been attracting interest since last couple of years due to the very unique characteristics of such formations have made them a feasible option for this object. Shale formations are found all around the world and the conventional assets are easily accessible, and also the huge move of operators toward developing unconventional reservoirs during past years leaves many of such formations ready for sequestering CO2. Today, the use of long horizontal wells that are drilled on a pad has the lowest amount of environmental footprint in which for storage and sequestration purpose also provides much more underground pore spaces available for CO2. In this paper we study the state of the art of the technology of CO2 storage and sequestration and provide different and fresh look for its complex phenomena from a mathematical modeling point of view. Moreover, we hope this study provides valuable insights into the use of depleted shale gas reservoirs for carbon sequestration, which as a result, a cleaner atmosphere will be achieved for the life of our next generations. Also, we present that the depleted shale gas reservoirs are very adequate for this purpose as they already have much of the infrastructure required to perform CO2 injection available in sites.
文摘To reduce the emissions of carbon dioxide(CO) into the atmosphere, it is proposed to inject anthropogenic COinto deep geological formations. Deep un-mineable coalbeds are considered to be possible COrepositories because coal is able to adsorb a large amount of COinside its microporous structure.However, the response of coalbeds is complex because of coupled flow and mechanical processes. Injection of COcauses coal to swell, which leads to reductions in permeability and hence makes injection more difficult, and at the same time leads to changes in the mechanical properties which can affect the stress state in the coal and overlying strata. The mechanical properties of coal under storage conditions are of importance when assessing the integrity and safety of the storage scheme. On the other hand, the geomechanical response of coalbed will also influence the reservoir performance of coalbed. This paper provides an overview of processes associated with coalbed geosequestration of COwhile the importance of geomechanical characteristics of coalbeds is highlighted. The most recent findings about the interactions between gas transport and geomechanical characteristics of coal will be discussed and the essence will be delivered. The author suggests areas for future research efforts to further improve the understanding of enhanced coalbed methane(ECBM) and coalbed geosequestration of CO.
基金This work was supported by the Key Project of the National Natural Science Foundation of China(No.40490263)the National Natural Science Foundation of China(Nos.40706040,40376022 and 40606023)+1 种基金the Doctoral Program for Higher Education(20030423007)Scientific Research Promotional fund for Middle-age and Young Scientist of Shandong Province(2007BS08015).
文摘A multilayer study of pCO2 for the Yellow and South China Seas in the surface waters was conducted based on data from four cruises sponsored by the China SOLAS Project in 2005 and 2006,including data for the surface microlayer(SML) ,subsurface layer(SSL) and surface layer(SL) . The carbon fluxes across the air-sea interface were calculated. The results showed that the pCO2 values in the surface waters of the study area decreased in the following order:pCO2 SML> pCO2 SSL> pCO2 SL. The highest values were found in March for all SML,SSL and SL,followed by those in April,and the lowest were in May. The pCO2 values had a significant positive correlation with temperature or salinity. While there was no relationship between pCO2 and longitude,there was a significant negative correlation between it and latitude,i.e.,'high latitude low pCO2'. By using four calculation models,the carbon dioxide fluxes(FC O2) in spring in the Yellow and South China Seas,which were found to act as a 'sink' of atmospheric CO2,were preliminarily estimated on the basis of the pCO2 data in the SML to be -7.00×106 t C and -22.35×106 t C,respectively. It is suggested that the FC O2calculated on the basis of pCO2 data in the SML is more reliable than that calculated on the basis of those in the SL.
基金Supported by the China National Science and Technology Major Project(2016ZX05016)
文摘The latest advancement of CO2 flooding and sequestration theory and technology in China is systematically described, and the future development direction is put forward. Based on the geological characteristics of continental reservoirs, five theories and key technologies have been developed:(1) Enriched the understandings about the mass transfer characteristics of components between CO2 and crude oil in continental reservoirs, micro-flooding mechanism and sequestration mechanism of different geological bodies.(2) Established the design method of reservoir engineering parameters, injection-production control technology and development effect evaluation technology of CO2 flooding, etc.(3) Developed a series of production engineering technologies such as separated layer CO2 injection technology, high efficiency lifting technology, on-line wellbore corrosion monitoring and protection technology.(4) Innovated a series of surface engineering technology including CO2 capture technology, pipeline CO2 transportation, CO2 surface injection, and production gas circulation injection, etc.(5) Formed a series of supporting technologies including monitoring, and safety and environmental protection evaluation of CO2 flooding reservoir. On this basis, the technological development directions in the future have been put forward:(1) Breakthrough in low-cost CO2 capture technology to provide cheap CO2 gas source;(2) Improve the miscibility technology between CO2 and crude oil to enhance oil displacement efficiency;(3) Improve CO2 sweeping volume;(4) Develop more effective lifting tools and technologies;(5) Strengthen the research of basic theory and key technology of CO2 storage monitoring. CO2 flooding and sequestration in the Jilin Oilfield shows that this technology has broad application prospects in China.
基金the National Natural Science Foundation of China(21808181)China Postdoctoral Science Foundation(2019M653651)+1 种基金Shaanxi Provincial Science and Technology Department(2017ZDXM-GY-115)Basic Research Project of Natural Science in Shaanxi Province(2020JM-021)。
文摘The leakage of stored and transported CO2 is a risk for geological sequestration technology. One of the most challenging problems is to recognize and determine CO2 leakage signal in the complex atmosphere background. In this work, a time series model was proposed to forecast the atmospheric CO2 variation and the approximation error of the model was utilized to recognize the leakage. First, the fitting neural network trained with recently past CO2 data was applied to predict the daily atmospheric CO2. Further, the recurrent nonlinear autoregressive with exogenous input(NARX) model was adopted to get more accurate prediction. Compared with fitting neural network, the approximation errors of NARX have a clearer baseline, and the abnormal leakage signal can be seized more easily even in small release cases. Hence, the fitting approximation of time series prediction model is a potential excellent method to capture atmospheric abnormal signal for CO2 storage and transportation technologies.
基金Supported by CNPC Science and Technology Project(kt2022-8-202021ZZ01).
文摘Based on practices of CO_(2) flooding tests in China and abroad,the recovery factor of carbon dioxide capture,utilization in displacing oil and storage(CCUS-EOR)in permanent sequestration scenario has been investigated in this work.Under the background of carbon neutrality,carbon dioxide injection into geological bodies should pursue the goal of permanent sequestration for effective carbon emission reduction.Hence,CCUS-EOR is an ultimate development method for oil reservoirs to maximize oil recovery.The limit recovery factor of CCUS-EOR development mode is put forward,the connotation differences between it and ultimate recovery factor and economically reasonable recovery factor are clarified.It is concluded that limit recovery factor is achievable with mature supporting technical base for the whole process of CCUS-EOR.Based on statistics of practical data of CO_(2) flooding projects in China and abroad such as North H79 block CO_(2) flooding pilot test at small well spacing in Jilin Oilfield etc.,the empirical relationship between the oil recovery factor of miscible CO_(2) flooding and cumulative CO_(2) volume injected is obtained by regression.Combined with the concept of oil production rate multiplier of gas flooding,a reservoir engineering method calculating CO_(2) flooding recovery factor under any miscible degree is established by derivation.It is found that when the cumulative CO_(2) volume injected is 1.5 times the hydrocarbon pore volume(HCPV),the relative deviation and the absolute difference between the recovery percentage and the limit recovery factor are less than 5%and less than 2.0 percentage points respectively.The limit recovery factor of CCUS-EOR can only be approached by large pore volume(PV)injection based on the technology of expanding swept volume.It needs to be realized from three aspects:large PV injection scheme design,enhancing miscibility degree and continuously expanding swept volume of injected CO_(2).
文摘Urban areas are a major source of anthropogenic carbon dioxide (CO<sub><span style="font-family:Verdana;">2</span></sub><span style="font-family:Verdana;">) emissions because of road traffic and local heating with natural gas, oil or coal. Rome is among the largest European cities (129,000 ha) with a large volume of green areas (69.6% of the total Municipality area). The CO</span><sub><span style="font-family:Verdana;">2</span></sub><span style="font-family:Verdana;"> sequestration (CS) capability for the greenery extending for about 300 km</span><sup><span style="font-family:Verdana;">2</span></sup><span style="font-family:Verdana;"> inside the area delimited by the Great Ring Road (GRA) in Rome was calculated combining satellite data with CS data measured in the field. Data from Sentinel-2 were collected and the Normalized Difference Vegetation Index (NDVI) was computed on a pixel-base. Three plant classes homogeneous in terms of annual NDVI profile were identified: deciduous trees (DT), evergreen trees (ET) and meadows (M) covering an area of 14,142.027 ha within the GRA, of which M had the highest percentage (48%), followed by DT (27%) and ET (25%). CS ranged from 428,241</span><span style="font-family:Verdana;">,</span><span style="font-family:Verdana;">492.9 </span><span style="font-family:Verdana;">T</span><span style="font-family:;" "=""><span style="font-family:Verdana;">ons CO</span><sub><span style="font-family:Verdana;">2</span></sub><span style="font-family:Verdana;"> year</span><sup><span style="font-family:Verdana;">-1</span></sup><span style="font-family:Verdana;"> (ET) to 263,072</span></span><span style="font-family:Verdana;">,</span><span style="font-family:;" "=""><span style="font-family:Verdana;">460.6 Tons CO</span><sub><span style="font-family:Verdana;">2</span></sub><span style="font-family:Verdana;"> year</span><sup><span style="font-family:Verdana;">-1</span></sup><span style="font-family:Verdana;"> (M). The total CS of the greenery inside the GRA was 1049,490,355.4 Tons CO</span><sub><span style="font-family:Verdana;">2</span></sub><span style="font-family:Verdana;"> year</span><sup><span style="font-family:Verdana;">-1</span></sup><span style="font-family:Verdana;"> resulting in an annual economic value of $772,424,901.6/ha. The CO</span><sub><span style="font-family:Verdana;">2</span></sub><span style="font-family:Verdana;"> sequestration capability of the considered plant classes could be incorporated into the national greenhouse gas emission budget to calculate the contribution of CO</span><sub><span style="font-family:Verdana;">2</span></sub><span style="font-family:Verdana;"> sequestration to the economy of Rome.</span></span>
基金supported by the Intergovernmental International Science and Technology Innovation Cooperation Key Project of the National Key Research and Development Program of China (No.2022YFE0135100)the National Natural Science Foundation of China (No.52072171)+1 种基金the Beijing Nova Program (No.20220484057)the Priority Academic Program Development of Jiangsu Higher Education Institutions (PAPD).
文摘Water-quenched copper-nickel metallurgical slag enriched with olivine minerals exhibits promising potential for the production of CO_(2)-mineralized cementitious materials.In this work,copper-nickel slag-based cementitious material(CNCM)was synthesized by using different chemical activation methods to enhance its hydration reactivity and CO_(2) mineralization capacity.Different water curing ages and carbonation conditions were explored related to their carbonation and mechanical properties development.Meanwhile,thermogravimetry differential scanning calorimetry and X-ray diffraction methods were applied to evaluate the CO_(2) adsorption amount and carbonation products of CNCM.Microstructure development of carbonated CNCM blocks was examined by backscattered electron imaging(BSE)with energy-dispersive X-ray spectrometry.Results showed that among the studied samples,the CNCM sample that was subjected to water curing for 3 d exhibited the highest CO_(2) sequestration amount of 8.51wt%at 80℃and 72 h while presenting the compressive strength of 39.07 MPa.This result indicated that 1 t of this CNCM can sequester 85.1 kg of CO_(2) and exhibit high compressive strength.Although the addition of citric acid did not improve strength development,it was beneficial to increase the CO_(2) diffusion and adsorption amount under the same carbonation conditions from BSE results.This work provides guidance for synthesizing CO_(2)-mineralized cementitious materials using large amounts of metallurgical slags containing olivine minerals.
文摘In this paper, a regionally disaggregated global energy system model with a detailed treatment of the whole chain of CO2 capture and storage (CCS) is used to derive the cost-optimal global pattern of CO2 sequestration in regional detail over the period 2010-2050 under the target of halving global energy-related CO2 emissions in 2050 compared to the 2005 level. The major conclusions are the following. First, enhanced coalbed methane recovery will become a key early opportunity for CO2 sequestration, so coalrich regions such as the US, China, and India will play a leading role in global CO2 sequestration. Enhanced oil recovery will also have a participation in global CO2 sequestration from the initial stage of CCS deployment, which may be applied mainly in China, southeastern Asia, and West Africa in 2030 and mainly in the Middle East in 2050. Second, CO2 sequestration will be carried out in an increasing number of world regions over time. In particular, CCS will be deployed extensively in today’s developing countries. Third, an increasing amount of the captured CO2 will be stored in aquifers in many parts of the world due to their abundant and widespread availability and their low cost. It is shown that the share of aquifers in global CO2 sequestration reaches 82.0% in 2050.
文摘Marine carbon sequestration is an important component of carbon dioxide capture, utilization and storage(CCUS) technology. It is crucial for achieving carbon peaking and carbon neutralization in China. However, CO_(2) leakage may lead to seabed geological disasters and threaten the safety of marine engineering. Therefore, it is of great significance to study the safety monitoring technology of marine carbon sequestration.Zhanjiang is industrially developed and rich in carbon sources. Owing to the good physical properties and reservoirs and trap characteristics,Zhanjiang has huge storage potential. This paper explores the disaster mechanism associated with CO_(2) leakage in marine carbon sequestration areas. Based on the analysis of the development of Zhanjiang industry and relevant domestic monitoring technologies, several suggestions for safety monitoring of marine carbon sequestration are proposed: application of offshore aquaculture platforms, expansion and application of ocean observation networks, carbon sequestration safety monitoring and sensing system. Intended to build a comprehensive and multi-level safety monitoring system for marine carbon sequestration, the outcome of this study provides assistance for the development of marine carbon sequestration in China's offshore areas.
文摘The process of capturing and storing carbon dioxide (CCS) was previously considered a crucial and time-sensitive approach for diminishing CO<sub>2</sub> emissions originating from coal, oil, and gas sectors. Its implementation was seen necessary to address the detrimental effects of CO<sub>2</sub> on the atmosphere and the ecosystem. This recognition was achieved by previous substantial study efforts. The carbon capture and storage (CCS) cycle concludes with the final stage of CO<sub>2</sub> storage. This stage involves primarily the adsorption of CO<sub>2</sub> in the ocean and the injection of CO<sub>2</sub> into subsurface reservoir formations. Additionally, the process of CO<sub>2</sub> reactivity with minerals in the reservoir formations leads to the formation of limestone through injectivities. Carbon capture and storage (CCS) is the final phase in the CCS cycle, mostly achieved by the use of marine and underground geological sequestration methods, along with mineral carbonation techniques. The introduction of supercritical CO<sub>2</sub> into geological formations has the potential to alter the prevailing physical and chemical characteristics of the subsurface environment. This process can lead to modifications in the pore fluid pressure, temperature conditions, chemical reactivity, and stress distribution within the reservoir rock. The objective of this study is to enhance our existing understanding of CO<sub>2</sub> injection and storage systems, with a specific focus on CO<sub>2</sub> storage techniques and the associated issues faced during their implementation. Additionally, this research examines strategies for mitigating important uncertainties in carbon capture and storage (CCS) practises. Carbon capture and storage (CCS) facilities can be considered as integrated systems. However, in scientific research, these storage systems are often divided based on the physical and spatial scales relevant to the investigations. Utilising the chosen system as a boundary condition is a highly effective method for segregating the physics in a diverse range of physical applications. Regrettably, the used separation technique fails to effectively depict the behaviour of the broader significant system in the context of water and gas movement within porous media. The limited efficacy of the technique in capturing the behaviour of the broader relevant system can be attributed to the intricate nature of geological subsurface systems. As a result, various carbon capture and storage (CCS) technologies have emerged, each with distinct applications, associated prices, and social and environmental implications. The results of this study have the potential to enhance comprehension regarding the selection of an appropriate carbon capture and storage (CCS) application method. Moreover, these findings can contribute to the optimisation of greenhouse gas emissions and their associated environmental consequences. By promoting process sustainability, this research can address critical challenges related to global climate change, which are currently of utmost importance to humanity. Despite the significant advancements in this technology over the past decade, various concerns and ambiguities have been highlighted. Considerable emphasis was placed on the fundamental discoveries made in practical programmes related to the storage of CO<sub>2</sub> thus far. The study has provided evidence that despite the extensive research and implementation of several CCS technologies thus far, the process of selecting an appropriate and widely accepted CCS technology remains challenging due to considerations related to its technological feasibility, economic viability, and societal and environmental acceptance.
基金funded by the National Natural Science Foundation of China under Grant Numbers 42202179 and U2244207supported by the National Key Laboratory of Petroleum Resources and Engineering at the China University of Petroleum,under Project Number PRP/open-2217+1 种基金Further support came from the State Key Laboratory of Shale Oil and Gas Enrichment Mechanisms and Effective Developmenta part of the'National Coal Seam(Series)Gas Geological Survey and Evaluation,a project number DD20240051 under the China Geological Survey。
文摘The utilization of CO_(2)-Enhanced Coal Bed Methane(CO_(2)-ECBM)technology is pivotal in realizing the environmentally responsible and efficient exploitation of Coalbed Methane(CBM)energy resources.The optimization of carbon capture,utilization,and storage(CCUS)for carbon reduction mandates a nuanced understanding of the diverse geological attributes present in CBM reserves globally.Traditional estimations of CO_(2)-ECBM's carbon sequestration potential have predominantly relied on rudimentary empirical models,notably those proposed by the United States Department of Energy(DOE),which overlook the intrinsic geological conditions and the physicochemical properties of subsurface fluids.Addressing these limitations,our study implements the advanced DR/Henry mixed adsorption model in tandem with the Peng-Robinson equation of state(PR-EOS).This approach meticulously identifies the critical parameters governing the mass exchange ratios between CO_(2)and CH_(4),pertinent to in-situ geological environments.Subsequently,we have formulated a comprehensive carbon sequestration potential assessment framework.This innovative model adheres to the mass conservation principles for individual CO_(2)and CH_(4)components,taking into account the specific surface and stratigraphic conditions prevalent.Employing this refined methodology,we evaluated the CO_(2)-ECBM carbon sequestration potential of the 40 evaluation units of extensional,compressive,and cratonic continental coal bearing basins in China's three major temperature-pressure systems across different depth domains and coal ranks within 2000 m.Our findings reveal that the theoretical carbon sequestration capacity of China's continental coal-bearing basins is approximately 59.893 billion tons.Concurrently,the potential ECBM output stands at an estimated 4.92 trillion cubic meters,underscoring the substantial environmental and energy benefits inherent in harnessing CO_(2)-ECBM technology effectively.The regional analysis revealed that North and Northwest China hold the highest sequestration and recovery potential,followed by the Northeast and Southern regions,respectively.Specific areas,including the eastern edge of the Ordos Basin and southern Junggar Basin,Qinshui,Huoxi,Xishan,and other areas in Shanxi,present promising future prospects for geological carbon storage in unrecoverable coal seams.
基金Supported by the CNPC Science and Technology Major Project(2021ZZ01-05).
文摘This paper systematically reviews the current applications of various spatial information technologies in CO_(2)sequestration monitoring,analyzes the challenges faced by spatial information technologies in CO_(2)sequestration monitoring,and prospects the development of spatial information technologies in CO_(2)sequestration monitoring.Currently,the spatial information technologies applied in CO_(2)sequestration monitoring mainly include five categories:eddy covariance method,remote sensing technology,geographic information system,Internet of Things technology,and global navigation satellite system.These technologies are involved in three aspects:monitoring data acquisition,positioning and data transmission,and data management and decision support.Challenges faced by the spatial information technologies in CO_(2)sequestration monitoring include:selecting spatial information technologies that match different monitoring purposes,different platforms,and different monitoring sites;establishing effective data storage and computing capabilities to cope with the broad sources and large volumes of monitoring data;and promoting collaborative operations by interacting and validating spatial information technologies with mature monitoring technologies.In the future,it is necessary to establish methods and standards for designing spatial information technology monitoring schemes,develop collaborative application methods for cross-scale monitoring technologies,integrate spatial information technologies with artificial intelligence and high-performance computing technologies,and accelerate the application of spatial information technologies in carbon sequestration projects in China.
文摘This study characterized the AA-01 depleted hydrocarbon reservoir in the KOKA field, Niger Delta, using a multidimensional approach. This investigation involved data validation analysis, evaluation of site suitability for CO_(2) storage, and compositional simulation of hydrocarbon components. The primary objective was to determine the initial components and behavior of the hydrocarbon system required to optimize the injection of CO_(2) and accompanying impurities, establishing a robust basis for subsequent sequestration efforts in the six wells in the depleted KOKA AA-01 reservoir. The process, simulated using industry software such as ECLIPSE, PVTi, SCAL, and Petrel, included a compositional fluid analysis to confirm the pressure volume temperature(PVT) hydrocarbon phases and components. This involved performing a material balance on the quality of the measured data and matching the initial reservoir pressure with the supplied data source. The compositional PVT analysis adopted the Peng–Robinson equation of state to model fluid flow in porous media and estimate the necessary number of phases and components to describe the system accurately. Results from this investigation indicate that the KOKA AA-01 reservoir is suitable for CO_(2)sequestration. This conclusion is based on the reservoir's good quality, evidenced by an average porosity of 0.21 and permeability of 1 111.0 mD, a measured lithological depth of 9 300 ft, and characteristic reservoir – seal properties correlated from well logs. The study confirmed that volumetric behavior predictions are directly linked to compositional behavior predictions, which are essential during reservoir initialization and data quality checks. Additionally, it highlighted that a safe design for CO_(2) storage relies on accurately representing multiphase behaviour across wide-ranging pressure–temperature–composition conditions.
文摘The UN International Panel Environment Programme (“UNEP”), 2023 Emissions Gap Report urgently presses the global community to adopt a two-pronged approach to reduce atmospheric concentration of CO2—expedite efforts to reduce annual CO2 emissions;and increase investment in large-scale carbon dioxide removal (“CDR”) projects. The Gap Report sets a 2050 target of six-gigatons annual land-based CDR. Our proposed agroforestry project will convert thirty-five-million acres of rangeland in the American Great Plains to silvopasture, combining growing trees and raising livestock. Employing agroforestry interests 61% of Great Plaints farmers/ranchers recently surveyed. The Project plans to annually collect + six-gigatons CO2 equiv. of fallen leaves and store the stable carbon-rich biomass underground for centuries. The purpose of this paper is to describe the framework for formation of a global partnership at the local, regional, and international levels to coordinate public and private financing mechanisms, implement, and operate a large-scale CDR Project that will meaningfully impact the global effort to mitigate climate change.