The physical properties of the rock units associated with the Rio Bonito Formation are presented in this study with the focus on modelling reservoir quality based on petrophysics-derived parameters to evaluate CO_(2)s...The physical properties of the rock units associated with the Rio Bonito Formation are presented in this study with the focus on modelling reservoir quality based on petrophysics-derived parameters to evaluate CO_(2)storage potentials.It involves the modelling of the reservoir depths,thicknesses,flow zone indicators(FZI),and effective permeability(Keff)and presenting the CO_(2)storage efficiency factors peculiar to the rock units of the study location.Research results presented by this study for the stated objectives are not quite common in the region.Keff values range from 200 mD to higher than 2000 mD,and FZI values are generally above 1.0 mm and up to 13.0 mm within the portions covered by the drilled wells.The sandstone units recorded are up to 20 m thick in some cases.The Keff and FZI models indicate the sandstone reservoirs as permeable units to support the injection and circulation of CO_(2)within the potential reservoir units of the Rio Bonio Formation across São Paulo State.Apart from some points in the southeastern part of the study location,where the Rio Bonito are delineated at depths less than 800 m(minimum CO_(2)storage depth based on best practices),other portions are deeper,ranging from 950 m to 3500 m.Thin-bedded layers will affect the integrity of the rocks as CO_(2)storage tanks or reservoir seals/traps/overburden within the region.Sandstone bed thicknesses are up to 20 m in some cases.However,hybrid CO_(2)reservoir units are feasible,especially in portions where thin siltstone layers are sandwiched between sandstone units to provide considerable thicknesses based on CO_(2)storage standards.The current study shows that useable areas considering reservoir thickness,depth,and other physical qualities will significantly control the CO_(2)storage efficiency of the study location.Further studies featuring a detailed geophysical exploration of the site to confirm the availability and saturations of preexisting fluid(hydrocarbon and water)are encouraged to boost CO_(2)storage in the region.The related research-based results,as mentioned above,may be combined with the results of this research to determine the area's potentials for CO_(2)storage or hydrocarbon production with CO_(2)storage options.展开更多
针对火星独特的CO_(2)稀薄气体环境以及探测器高超声速进入火星过程中的高温真实气体效应,研究了CO_(2)多振动模式的激发特性。采用非结构网格和直接模拟蒙特卡洛法(Direct Simulation Monte Carlo method, DSMC),基于非谐振子振动激发...针对火星独特的CO_(2)稀薄气体环境以及探测器高超声速进入火星过程中的高温真实气体效应,研究了CO_(2)多振动模式的激发特性。采用非结构网格和直接模拟蒙特卡洛法(Direct Simulation Monte Carlo method, DSMC),基于非谐振子振动激发模型,通过将CO_(2)离解能均分到4种振动模态,进而限制各模态最高振动能级,模拟了含CO_(2)的5组分17反应的高温稀薄真实气体化学反应模型。计算了“火星探路者”在火星大气环境65 km高度、进入速度为7 453 m/s、攻角为0°下的高温化学非平衡效应流场。结果表明:CO_(2)在激波后大量分解并消耗大量能量;迎风面激波中各组分占比与探测器物面特性等均与文献结果相符,证明了本文对于CO_(2)振动激发处理方法的可行性。在此基础上加入N_2组分,模拟火星大气8组分44基元化学反应流场,通过改变来流密度与马赫数分析了流场特性的变化。结果表明:随着来流密度减小,流场温度呈现先增加后减小的趋势,物面热流密度增大;来流马赫数增加使得流场温度和压力上升,物面热流密度提高但是热流密度系数变化幅度很小。展开更多
At present,metal ions from spent lithium-ion batteries are mostly recovered by the acid leaching procedure,which unavoidably introduces potential pollutants to the environment.Therefore,it is necessary to develop more...At present,metal ions from spent lithium-ion batteries are mostly recovered by the acid leaching procedure,which unavoidably introduces potential pollutants to the environment.Therefore,it is necessary to develop more direct and effective green recycling methods.In this research,a method for the direct regeneration of anode materials is reported,which includes the particles size reduction of recovered raw materials by jet milling and ball milling,followed by calcination at high temperature after lithium supplementation.The regenerated LiNi_(0.5)Co_(0.2)Mn_(0.3)O_(2) single-crystal cathode material possessed a relatively ideal layered structure and a complete surface morphology when the lithium content was n(Ni+Co+Mn):n(Li)=1:1.10 at a sintering temperature of 920 0 C,and a sintering time of 12 h.The first discharge specific capacity was 154.87 mA·h·g^(-1) between 2.75 V and 4.2 V,with a capacity retention rate of 90% after 100 cycles.展开更多
基金sponsored by Fundação de AmparoàPesquisa do Estado de São Paulo(FAPESP)(2014/50279-4,2020/15230-5,2021/06158-1)Shell Brasil.
文摘The physical properties of the rock units associated with the Rio Bonito Formation are presented in this study with the focus on modelling reservoir quality based on petrophysics-derived parameters to evaluate CO_(2)storage potentials.It involves the modelling of the reservoir depths,thicknesses,flow zone indicators(FZI),and effective permeability(Keff)and presenting the CO_(2)storage efficiency factors peculiar to the rock units of the study location.Research results presented by this study for the stated objectives are not quite common in the region.Keff values range from 200 mD to higher than 2000 mD,and FZI values are generally above 1.0 mm and up to 13.0 mm within the portions covered by the drilled wells.The sandstone units recorded are up to 20 m thick in some cases.The Keff and FZI models indicate the sandstone reservoirs as permeable units to support the injection and circulation of CO_(2)within the potential reservoir units of the Rio Bonio Formation across São Paulo State.Apart from some points in the southeastern part of the study location,where the Rio Bonito are delineated at depths less than 800 m(minimum CO_(2)storage depth based on best practices),other portions are deeper,ranging from 950 m to 3500 m.Thin-bedded layers will affect the integrity of the rocks as CO_(2)storage tanks or reservoir seals/traps/overburden within the region.Sandstone bed thicknesses are up to 20 m in some cases.However,hybrid CO_(2)reservoir units are feasible,especially in portions where thin siltstone layers are sandwiched between sandstone units to provide considerable thicknesses based on CO_(2)storage standards.The current study shows that useable areas considering reservoir thickness,depth,and other physical qualities will significantly control the CO_(2)storage efficiency of the study location.Further studies featuring a detailed geophysical exploration of the site to confirm the availability and saturations of preexisting fluid(hydrocarbon and water)are encouraged to boost CO_(2)storage in the region.The related research-based results,as mentioned above,may be combined with the results of this research to determine the area's potentials for CO_(2)storage or hydrocarbon production with CO_(2)storage options.
文摘针对火星独特的CO_(2)稀薄气体环境以及探测器高超声速进入火星过程中的高温真实气体效应,研究了CO_(2)多振动模式的激发特性。采用非结构网格和直接模拟蒙特卡洛法(Direct Simulation Monte Carlo method, DSMC),基于非谐振子振动激发模型,通过将CO_(2)离解能均分到4种振动模态,进而限制各模态最高振动能级,模拟了含CO_(2)的5组分17反应的高温稀薄真实气体化学反应模型。计算了“火星探路者”在火星大气环境65 km高度、进入速度为7 453 m/s、攻角为0°下的高温化学非平衡效应流场。结果表明:CO_(2)在激波后大量分解并消耗大量能量;迎风面激波中各组分占比与探测器物面特性等均与文献结果相符,证明了本文对于CO_(2)振动激发处理方法的可行性。在此基础上加入N_2组分,模拟火星大气8组分44基元化学反应流场,通过改变来流密度与马赫数分析了流场特性的变化。结果表明:随着来流密度减小,流场温度呈现先增加后减小的趋势,物面热流密度增大;来流马赫数增加使得流场温度和压力上升,物面热流密度提高但是热流密度系数变化幅度很小。
文摘At present,metal ions from spent lithium-ion batteries are mostly recovered by the acid leaching procedure,which unavoidably introduces potential pollutants to the environment.Therefore,it is necessary to develop more direct and effective green recycling methods.In this research,a method for the direct regeneration of anode materials is reported,which includes the particles size reduction of recovered raw materials by jet milling and ball milling,followed by calcination at high temperature after lithium supplementation.The regenerated LiNi_(0.5)Co_(0.2)Mn_(0.3)O_(2) single-crystal cathode material possessed a relatively ideal layered structure and a complete surface morphology when the lithium content was n(Ni+Co+Mn):n(Li)=1:1.10 at a sintering temperature of 920 0 C,and a sintering time of 12 h.The first discharge specific capacity was 154.87 mA·h·g^(-1) between 2.75 V and 4.2 V,with a capacity retention rate of 90% after 100 cycles.
