Efficient Direct Decomposition of NO over La_(0.8)A_(0.2)NiO_(3)(A=K, Ba, Y) Catalysts under Microwave Irradiation

La_(0.8)A_(0.2)NiO_(3) (A=K,Ba,Y) catalysts supported on the microwave-absorbing ceramic heating carrier were prepared by the sol-gel method.The crystalline phase and the catalytic activity of the La_(0.8)A_(0.2)NiO_(3)catalysts were characterized by XRD and H_(2) temperature-programmed reduction (TPR).The effects of reaction temperature,oxygen concentration,and gas flow rate on the direct decomposition of nitric oxide over the synthesized catalysts were studied under microwave irradiation (2.45 GHz).The XRD results indicated that the La_(0.8)A_(0.2)NiO_(3) catalysts formed an ABO_(3) perovskite structure,and the H_(2)-TPR results revealed that the relative reducibility of the catalysts increased in the order of La_(0.8)K_(0.2)NiO_(3)>La_(0.8)Ba_(0.2)NiO_(3)>La_(0.8)Y_(0.2)Ni O_(3).Under microwave irradiation,the highest NO conversion amounted to 98.9%,which was obtained with the La_(0.8)K_(0.2)NiO_(3) catalyst at 400℃.The oxygen concentration did not inhibit the NO decomposition on the La_(0.8)A_(0.2)NiO_(3) catalysts,thus the N_(2) selectivity exceeded 99.8%under excess oxygen at 550℃.The NOconversion of the La_(0.8)A_(0.2)NiO_(3) catalysts decreased linearly with the increase in the gas flow rate.

Roles of Oxygen Vacancy and Lower Valence Metallic Ion in Direct Decomposition of NO over La_（2－x）（Sr，Th）_xCuO_（4±λ）

Two systems of La_(2-x)Sr_xCuO_(4±λ) and La_(2-x)Th_xCuO_(4±λ) mixed oxides with K_2NiF_4structure were synthesized.The compositions and structures of the catalysts were characterized by means of XRD,XPS,chemical analysis and so on.The catalytic behavior for the direct decomposition of NO has been investigated.The results show that the catalytic activity is closely related to the oxygen vacancy and lower valence metallic ion in the direct decomposition of NO.The presence of oxygen vacancy is necessary for mixed oxide to have steady activity in NO decomposition.

Direct decomposition of nitric oxide in low temperature over iron-based perovskite-type catalyst modified by Ru

Iron-based perovskite-type compounds modified by Ru were prepared through sol-gel process to study its catalytic activity of NOx direct decomposition at low temperature and evaluate the conversion of NO under the experimental conditions. The catalytic activity of La 0.9Ce 0.1Fe 0.8-nCo 0.2RunO3 （n=0.01,0.03,0.05,0.07,0.09）series for the NO, NO-CO two components, CO-HC-NO three components were also analyzed. The catalytic investigation evidenced that the presence of Ru is necessary for making highly activity in decomposition of nitric oxide even at low temperature（400 ℃）and La 0.9Ce 0.9Fe 0.75Co 0.2Ru 0.05O3 （n=0.05） has better activity in all the samples, the conversion of it is 58.5%. With the reducing gas（CO,C3H6）added into the gas, the catalyst displayed very high activity in decomposition of NO and the conversion of it is 80% and 92.5% separately.

A DECOMPOSITION DEPENDED ON DIRECTIONS FOR NONSINGULAR LINEAR TRANSFORMATION

In this paper. we give a decomposition depending on p(1≤p≤n-2) orthonormaldirections assigned for nonsingular linear transformation F on a n-dimension (n≥3)Euclidean space En, and then prove foal there exist q(q=n-p) quasi-Principaldirections.for F depending on the preceding p orthonormal directions. As applicance ofthe preceding result, we derive that there exist at least two orthonormal principaldirections of strain in arbitrary plane of body which is in homogeneous deformation,and strain energy density is.function of 5 real numbers under arbitrary quasi-principalbase.for the preceding nonsingular linear transformation.

RECURSIVE FORMULAS OF HYPEREDGE DECOMPOSITION SETS

The concepts of the undirected and directed decompositions are introduced for a hyperedge.Then, the recursive formulas of the underected decomposition set SD(m) and directed decomposition set SPD(m) are derived for an m-vertex hyperedge.Furthermore,the recursive formulas of their cardinalities|SD(m)|and |SPD(m)| are yielded.

Preparation and characterization of La_(1-x)Ce_xFe_(1-y-n)Co_yRu_nO_3 compounds

The mixed oxides La1 -xCexFe1-y-nCOyRunO3 were prepared by sol-gel method and used as catalysts for NO direct decomposition. The catalysts were characterized by DTA - TG, XRD, IR and BET. XRD analysis reveals that the samples are in a pure perovskite phase in 550 - 650 ℃, and catalyst structure keeps long else 20 decrease, and lattice parameters enhance when Ru is introduced. The characteristic peaks of samples are stronger during a temperature increase, and the particle size grows faster. IR analysis shows that the position and shape of adsorption peaks are almost the same among all samples, but with the Ru content increasing, 600 cm^-1 peak stretches to a high frequency and changes to disorder. The wave numbers move to low frequency when n = 0. 05, yet it doesn＇ t vary obviously when n 〉 0. 05. The BET surface area testifies that particle sizes of all catalysts increase with temperature increasing.

Effects of minerals in ferric bauxite on sodium carbonate decomposition and volatilization

Direct reduction is an emerging technology for ferric bauxite utilization. However, because of sodium volatilization, its sodium carbonate consumption is considerably higher than that in ordinary bauxite processing technology. TG-DSC and XRD were applied to detecting phase transformation and mass loss in direct reduction to reveal the mechanism on sodium volatilization. The results show that the most significant influence factor of ferric bauxite on sodium volatilization in direct reduction system is its iron content. Sodium volatilization is probably ascribed to the instability of amorphous substances structure. Amorphous substances are the intermediate-products of the reaction, and the volatilization rate of sodium increases with its generating rate. These amorphous substances are volatile, thus, more sodium is volatilized with its generation. A small amount of amorphous substances are generated in the reaction between Na2CO3 and Al2O3; thus, only 3.15% of sodium is volatilized. Similarly, the volatilization rate is 1.87% in the reaction between Na2CO3 and SiO2. However, the volatilization rate reaches 7.64% in the reaction between Na2CO3 and Fe2O3 because of the generation of a large amount of amorphous substances.

Energy-Efficient Transceiver Design for Multi-Pair Two-Way Relay Systems

In this paper, we focus on energy-efficient transceiver and relay beamforming design for multi-pair two-way relay system. The multi-antenna users and the multi-antenna relay are considered in this work. Different from the existing works, the proposed algorithm is energy-efficient which is more applicable to the future green network. It considers both the sum-MSE problem and the power consumption problem for the users under the relay power constraint. Based on the optimal condition decomposition(OCD) method, the energy-efficient precoders at the users can be designed separately with limited information exchanged. The proposed relay beamforming algorithm is based on the alternative direction method of multipliers(ADMM) which has simpler iterative solution and enjoys good convergence. Simulation results demonstrate the performance of the proposed algorithms in terms of power consumption and MSE performance.

Magnesia base catalyst flue gas denitrate performance study

To control contamination of flue gas emission NOx, the author mixcd method of preparing new magnesia base catalyst and researched on denitrificating fine gas by directness catalytic decomposition. Usually removal rate of NO is regarded on the main evaluation criteria. The author analyzed calcination temperature of catalyzer manufacturing process, the temperature of flue gas desorption tower, bed height and efficiency denitrification of NO concentration. And discussed the result of both denitrate lore-and-aft of FT-IR and XRD. The experiment indicates that magnesia base catalyst is available to directness catalytic decomposition denitrificate flue gas. Through denitrification rate is from 85% to 95%. The ingredient of magnesia base catalyst is made from magnesia, firming agent, addition agent. Height denitration bed was 4 cm- 5 cm, deuitration reaction temperature is 130℃-170℃, through the analyses above, presumed that magnesia base catalyst exist activating of vice, and analyzed this vice preliminarily.

1-GENERATOR QUASI-CYCLIC CODES

This paper discusses the enumeration of 1-generator quasi-cyclic codes and describes an algorithm which will obtain one, and only one, generator for each 1-generator quasi-cyclic code.

Fractional Fourier transform on R^(2)and an application

We focus on the L^(p)(R^(2))theory of the fractional Fourier transform(FRFT)for 1≤p≤2.In L^(1)(R^(2)),we mainly study the properties of the FRFT via introducing the two-parameter chirp operator.In order to get the pointwise convergence for the inverse FRFT,we introduce the fractional convolution and establish the corresponding approximate identities.Then the well-defined inverse FRFT is given via approximation by suitable means,such as fractional Gauss means and Able means.Furthermore,if the signal F_(α,β)f is received,we give the process of recovering the original signal f with MATLAB.In L^(2)(R^(2)),the general Plancherel theorem,direct sum decomposition,and the general Heisenberg inequality for the FRFT are obtained.