Labyrinth seal can cause steam-exciting, the structural and operating parameters of labyrinth seal have effect on stability of rotor-system. For investigating the coupling influences of the structure and operating par...Labyrinth seal can cause steam-exciting, the structural and operating parameters of labyrinth seal have effect on stability of rotor-system. For investigating the coupling influences of the structure and operating parameters of labyrinth seals on dynamic coefficients, a model of calculating dynamic coefficients of labyrinth seals is presented using a two control volume model. The coupling influences of parameters on cross-coupled stiffness and direct damping of labyrinth seal are discussed. In the conclusion, a reference of preventing steam-exciting vibration and optimum determination of design parameters of labyrinth seals are provided.展开更多
Secondary structures of RNAs are the basis of understanding their tertiary structures and functions and so their predictions are widely needed due to increasing discovery of noncoding RNAs.In the last decades,a lot of...Secondary structures of RNAs are the basis of understanding their tertiary structures and functions and so their predictions are widely needed due to increasing discovery of noncoding RNAs.In the last decades,a lot of methods have been proposed to predict RNA secondary structures but their accuracies encountered bottleneck.Here we present a method for RNA secondary structure prediction using direct coupling analysis and a remove-and-expand algorithm that shows better performance than four existing popular multiple-sequence methods.We further show that the results can also be used to improve the prediction accuracy of the single-sequence methods.展开更多
The equivalent refractive index(ERI) method is employed to analyze the function of the strip waveguide directional coupling modulator(SWM). Through deducing the diagnostic equation of the Exmn mode of the four-lay...The equivalent refractive index(ERI) method is employed to analyze the function of the strip waveguide directional coupling modulator(SWM). Through deducing the diagnostic equation of the Exmn mode of the four-layer media film waveguide equivalent to the SWM,the transmission constant of the symmetrical mode of the positive phase and negative one and the coupling length of powerful transference are obtained. The veracity of ERI is validated with the example of Ex11 basal mode under conditions of comparing the three results of ERI,EIM and Marcatili.展开更多
The relativistic neutrino emissivity of the nucleonic direct URCA processes in neutron star matter is investigated within the relativistic Hartree-Fock approximation. We particularly study the influences of the tensor...The relativistic neutrino emissivity of the nucleonic direct URCA processes in neutron star matter is investigated within the relativistic Hartree-Fock approximation. We particularly study the influences of the tensor couplings of vector mesons ω and ρ on the nucleonic direct URCA processes. It is found that the inclusion of the tensor couplings of vector mesons w and p can slightly increase the maximum mass of neutron stars. In addition, the results indicate that the tensor couplings of vector mesons ω and ρ lead to obvious enhancement of the total neutrino emissivity for the nucleonic direct URCA processes, which must accelerate the cooling rate of the non- superfluid neutron star matter. However, when considering only the tensor coupling of vector meson ρ, the neutrino emissivity for the nucleonic direct URCA processes slightly declines at low densities and significantly increases at high densities. That is, the tensor coupling of vector meson ρ leads to the slow cooling rate of a low-mass neutron star and rapid cooling rate of a massive neutron star.展开更多
The RNA tertiary structure is essential to understanding the function and biological processes. Unfortunately, it is still challenging to determine the large RNA structure from direct experimentation or computational ...The RNA tertiary structure is essential to understanding the function and biological processes. Unfortunately, it is still challenging to determine the large RNA structure from direct experimentation or computational modeling. One promising approach is first to predict the tertiary contacts and then use the contacts as constraints to model the structure. The RNA structure modeling depends on the contact prediction accuracy. Although many contact prediction methods have been developed in the protein field, there are only several contact prediction methods in the RNA field at present. Here, we first review the theoretical basis and test the performances of recent RNA contact prediction methods for tertiary structure and complex modeling problems. Then, we summarize the advantages and limitations of these RNA contact prediction methods. We suggest some future directions for this rapidly expanding field in the last.展开更多
This work proposes a new simulation algorithm to improve message handling in discrete event formalism. We present an approach to minimize simulation execution time. To do this, we propose to reduce the number of excha...This work proposes a new simulation algorithm to improve message handling in discrete event formalism. We present an approach to minimize simulation execution time. To do this, we propose to reduce the number of exchanged messages between Parallel DEVS (PDEVS) components (simulators and coordinators). We propose three changes from PDEVS: direct coupling, flat structure and local schedule. The goal is the decentralisation of a number of tasks to make the simulators more autonomous and simplify the coordinators to achieve a greater speedup. We propose to compare the simulation results of several models to demonstrate the benefits of our approach.展开更多
As the high calibre candidate of lightweight and flexible solar cells,polymer solar cells(PSCs)have made tremendous progress in recent years.However,the active photovoltaic materials in PSCs are mainly synthesized by ...As the high calibre candidate of lightweight and flexible solar cells,polymer solar cells(PSCs)have made tremendous progress in recent years.However,the active photovoltaic materials in PSCs are mainly synthesized by metal-mediated coupling reaction requiring harsh reaction conditions,multiple-step synthesis,and cumbersome purification,which is not cost-efficient and may bring toxicity concerns.It is not favorable to the production of photovoltaic polymers and PSC devices on a large scale,and therefore unsuitable for the PSCs industrialization.Direct arylation coupling reaction via aromatic C―H bonds activation enables the synthesis of conjugated polymers under mild conditions and simultaneously reduces synthetic steps,difficulty,and toxic reaction byproducts.This review provides an overview of the history of preparing representative photovoltaic polymers utilized in PSCs through direct arylation reactions and discusses the activity and selectivity of C―H bonds in typical building blocks under different reaction conditions.Especially,the impact of direct arylation condition on defect formation and photovoltaic performance of the photovoltaic polymers is addressed and compared with conventional Stille coupling methods.展开更多
Design of a very large floating structure(VLFS)deployed near islands and reefs,different from those in the open sea,inevitably faces new technical challenges including numerical analysis methods.In this paper,a direct...Design of a very large floating structure(VLFS)deployed near islands and reefs,different from those in the open sea,inevitably faces new technical challenges including numerical analysis methods.In this paper,a direct coupling analysis method(DCAM)has been established based on the Boussinesq equations and the three-dimensional hydroelasisity theory with Rankine source method to analyze the responses of a VLFS in shallow sea with complicated geographical environment.Model tests have been carried out to validate the DCAM.To further verify the numerical methods and investigate the performance of such a VLFS,a“Scientific Research and Demonstration Platform(SRDP)”was built and deployed in 2019 at the site about 1000 m off an island with water depth around 40m in South China Sea.It is a simplified small model of a two-module semi-submersible-type VLFS.The numerical simulation of its responses on severe waves with focus on motions and connector forces is conduct by DCAM,and compared with the on-site measurements.Good agreement has been achieved.This approves the DCAM as a feasible tool for design and safety assessment of a VLFS deployed near islands and reefs.展开更多
In this paper, a novel algorithm is presented for direction of arrival(DOA) estimation and array self-calibration in the presence of unknown mutual coupling. In order to highlight the relationship between the array ...In this paper, a novel algorithm is presented for direction of arrival(DOA) estimation and array self-calibration in the presence of unknown mutual coupling. In order to highlight the relationship between the array output and mutual coupling coefficients, we present a novel model of the array output with the unknown mutual coupling coefficients. Based on this model, we use the space alternating generalized expectation-maximization(SAGE) algorithm to jointly estimate the DOA parameters and the mutual coupling coefficients. Unlike many existing counterparts, our method requires neither calibration sources nor initial calibration information. At the same time,our proposed method inherits the characteristics of good convergence and high estimation precision of the SAGE algorithm. By numerical experiments we demonstrate that our proposed method outperforms the existing method for DOA estimation and mutual coupling calibration.展开更多
Developing a general and mild approach to upgrade alcohols into high value products is a hot topic in synthetic chemistry because alcohol is one of the most abundant raw chemicals.Specifically,direct coupling and deox...Developing a general and mild approach to upgrade alcohols into high value products is a hot topic in synthetic chemistry because alcohol is one of the most abundant raw chemicals.Specifically,direct coupling and deoxygenative coupling of alcohols are the two main approaches for the functionalization of alcohols to afford structurally diverse products,and it receives considerable attention.Despite significant advances in the field,there still remains a great challenge to develop a general approach accommodating both coupling reactions,as they commonly involve distinct pathways.Herein,we report an electrochemical approach for the direct coupling and deoxygenative coupling of alcohols with fluorenones.Under paired electrolysis,this catalyst-dependent protocol gives divergent access to diols and tertiary alcohols.Moreover,the synthetic utility of 9H-fluoren-9-ol products has been demonstrated in the synthesis of organic luminophores,phenanthrol,phenanthridine,and amino alcohol.The present approach exhibits some impressive features:(a)catalystdependent selectivity;(b)excellentfunctional-group tolerance(156 examples);(c)mild conditions;and(d)good scalability(∼20 gram scale).展开更多
A highly sensitive and temperature-compensated methane sensor based on a liquid-infiltrated photonic crystal fiber (PCF) is proposed. Two bigger holes near the core area are coated with a methane-sensitive compound fi...A highly sensitive and temperature-compensated methane sensor based on a liquid-infiltrated photonic crystal fiber (PCF) is proposed. Two bigger holes near the core area are coated with a methane-sensitive compound film, and specific cladding air holes are infiltrated into the liquid material to form new defective channels. The proposed sensor can achieve accurate measurement of methane concentration through temperature compensation. The sensitivity can reach to 20.07nm/% with a high linearity as the methane concentration is within the range of 0%-3.5% by volume. The proposed methane sensor can not only improve the measurement accuracy, but also reduce the metrical difficulty and simplify the process.展开更多
基金This project is supported by National Natural Science Foundation of China(59990472). Manuscript received on November 30, 1999 r
文摘Labyrinth seal can cause steam-exciting, the structural and operating parameters of labyrinth seal have effect on stability of rotor-system. For investigating the coupling influences of the structure and operating parameters of labyrinth seals on dynamic coefficients, a model of calculating dynamic coefficients of labyrinth seals is presented using a two control volume model. The coupling influences of parameters on cross-coupled stiffness and direct damping of labyrinth seal are discussed. In the conclusion, a reference of preventing steam-exciting vibration and optimum determination of design parameters of labyrinth seals are provided.
基金Project supported by the National Natural Science Foundation of China(Grant No.31570722).
文摘Secondary structures of RNAs are the basis of understanding their tertiary structures and functions and so their predictions are widely needed due to increasing discovery of noncoding RNAs.In the last decades,a lot of methods have been proposed to predict RNA secondary structures but their accuracies encountered bottleneck.Here we present a method for RNA secondary structure prediction using direct coupling analysis and a remove-and-expand algorithm that shows better performance than four existing popular multiple-sequence methods.We further show that the results can also be used to improve the prediction accuracy of the single-sequence methods.
文摘The equivalent refractive index(ERI) method is employed to analyze the function of the strip waveguide directional coupling modulator(SWM). Through deducing the diagnostic equation of the Exmn mode of the four-layer media film waveguide equivalent to the SWM,the transmission constant of the symmetrical mode of the positive phase and negative one and the coupling length of powerful transference are obtained. The veracity of ERI is validated with the example of Ex11 basal mode under conditions of comparing the three results of ERI,EIM and Marcatili.
基金Supported by the National Natural Science Foundation of China under Grant Nos 11447165,11373047 and 11265009the Youth Innovation Promotion Association of Chinese Academy of Sciences under Grant No 2016056
文摘The relativistic neutrino emissivity of the nucleonic direct URCA processes in neutron star matter is investigated within the relativistic Hartree-Fock approximation. We particularly study the influences of the tensor couplings of vector mesons ω and ρ on the nucleonic direct URCA processes. It is found that the inclusion of the tensor couplings of vector mesons w and p can slightly increase the maximum mass of neutron stars. In addition, the results indicate that the tensor couplings of vector mesons ω and ρ lead to obvious enhancement of the total neutrino emissivity for the nucleonic direct URCA processes, which must accelerate the cooling rate of the non- superfluid neutron star matter. However, when considering only the tensor coupling of vector meson ρ, the neutrino emissivity for the nucleonic direct URCA processes slightly declines at low densities and significantly increases at high densities. That is, the tensor coupling of vector meson ρ leads to the slow cooling rate of a low-mass neutron star and rapid cooling rate of a massive neutron star.
基金Project supported by the National Natural Science Foundation of China (Grant No. 11704140)Self-determined Research Funds of CCNU from the Colleges' Basic Research and Operation of MOE (Grant No. CCNU20TS004).
文摘The RNA tertiary structure is essential to understanding the function and biological processes. Unfortunately, it is still challenging to determine the large RNA structure from direct experimentation or computational modeling. One promising approach is first to predict the tertiary contacts and then use the contacts as constraints to model the structure. The RNA structure modeling depends on the contact prediction accuracy. Although many contact prediction methods have been developed in the protein field, there are only several contact prediction methods in the RNA field at present. Here, we first review the theoretical basis and test the performances of recent RNA contact prediction methods for tertiary structure and complex modeling problems. Then, we summarize the advantages and limitations of these RNA contact prediction methods. We suggest some future directions for this rapidly expanding field in the last.
文摘This work proposes a new simulation algorithm to improve message handling in discrete event formalism. We present an approach to minimize simulation execution time. To do this, we propose to reduce the number of exchanged messages between Parallel DEVS (PDEVS) components (simulators and coordinators). We propose three changes from PDEVS: direct coupling, flat structure and local schedule. The goal is the decentralisation of a number of tasks to make the simulators more autonomous and simplify the coordinators to achieve a greater speedup. We propose to compare the simulation results of several models to demonstrate the benefits of our approach.
基金the National Natural Science Foundation of China(No.51773046)the Fundamental Research Funds for the Central Universities,the School of Materials Science and Engineering,Shaanxi Normal Universitythe Project of Key Laboratory of Organic Synthesis of Jiangsu Province,College of Chemistry Chemical Engineering and Materials Science,Soochow University。
文摘As the high calibre candidate of lightweight and flexible solar cells,polymer solar cells(PSCs)have made tremendous progress in recent years.However,the active photovoltaic materials in PSCs are mainly synthesized by metal-mediated coupling reaction requiring harsh reaction conditions,multiple-step synthesis,and cumbersome purification,which is not cost-efficient and may bring toxicity concerns.It is not favorable to the production of photovoltaic polymers and PSC devices on a large scale,and therefore unsuitable for the PSCs industrialization.Direct arylation coupling reaction via aromatic C―H bonds activation enables the synthesis of conjugated polymers under mild conditions and simultaneously reduces synthetic steps,difficulty,and toxic reaction byproducts.This review provides an overview of the history of preparing representative photovoltaic polymers utilized in PSCs through direct arylation reactions and discusses the activity and selectivity of C―H bonds in typical building blocks under different reaction conditions.Especially,the impact of direct arylation condition on defect formation and photovoltaic performance of the photovoltaic polymers is addressed and compared with conventional Stille coupling methods.
基金supported by the Ministry of Industry and Information Technology(Grant Nos.[2016]22,[2019]357)the Ministry of Science and Technology(Grant No.2013CB36102)+1 种基金supported by the National KeyResearch and Development Program of China(Grant No.2017YFBO202701)the Jiangsu Province ScienceFoundation for Youths(BK20190151).
文摘Design of a very large floating structure(VLFS)deployed near islands and reefs,different from those in the open sea,inevitably faces new technical challenges including numerical analysis methods.In this paper,a direct coupling analysis method(DCAM)has been established based on the Boussinesq equations and the three-dimensional hydroelasisity theory with Rankine source method to analyze the responses of a VLFS in shallow sea with complicated geographical environment.Model tests have been carried out to validate the DCAM.To further verify the numerical methods and investigate the performance of such a VLFS,a“Scientific Research and Demonstration Platform(SRDP)”was built and deployed in 2019 at the site about 1000 m off an island with water depth around 40m in South China Sea.It is a simplified small model of a two-module semi-submersible-type VLFS.The numerical simulation of its responses on severe waves with focus on motions and connector forces is conduct by DCAM,and compared with the on-site measurements.Good agreement has been achieved.This approves the DCAM as a feasible tool for design and safety assessment of a VLFS deployed near islands and reefs.
基金supported by the National Natural Science Foundation of China (No. 61302141)
文摘In this paper, a novel algorithm is presented for direction of arrival(DOA) estimation and array self-calibration in the presence of unknown mutual coupling. In order to highlight the relationship between the array output and mutual coupling coefficients, we present a novel model of the array output with the unknown mutual coupling coefficients. Based on this model, we use the space alternating generalized expectation-maximization(SAGE) algorithm to jointly estimate the DOA parameters and the mutual coupling coefficients. Unlike many existing counterparts, our method requires neither calibration sources nor initial calibration information. At the same time,our proposed method inherits the characteristics of good convergence and high estimation precision of the SAGE algorithm. By numerical experiments we demonstrate that our proposed method outperforms the existing method for DOA estimation and mutual coupling calibration.
基金the National Natural Science Foundation of China(grant nos.21702113,92061110,22071102,and 91956110)Anhui University(grant no.S020318006/069)the National Science Foundation(grant no.CHE-1554906)for their financial support.
文摘Developing a general and mild approach to upgrade alcohols into high value products is a hot topic in synthetic chemistry because alcohol is one of the most abundant raw chemicals.Specifically,direct coupling and deoxygenative coupling of alcohols are the two main approaches for the functionalization of alcohols to afford structurally diverse products,and it receives considerable attention.Despite significant advances in the field,there still remains a great challenge to develop a general approach accommodating both coupling reactions,as they commonly involve distinct pathways.Herein,we report an electrochemical approach for the direct coupling and deoxygenative coupling of alcohols with fluorenones.Under paired electrolysis,this catalyst-dependent protocol gives divergent access to diols and tertiary alcohols.Moreover,the synthetic utility of 9H-fluoren-9-ol products has been demonstrated in the synthesis of organic luminophores,phenanthrol,phenanthridine,and amino alcohol.The present approach exhibits some impressive features:(a)catalystdependent selectivity;(b)excellentfunctional-group tolerance(156 examples);(c)mild conditions;and(d)good scalability(∼20 gram scale).
基金the National Key R&D Program of China under Grant No.2016YFC0801800National Natural Science Foundation of China under Grant No.51874301+1 种基金Science and Technology Innovation Project of Xuzhou City under Grant No.KC16SG264the Special Foundation for Excellent Young Teachers and Principals Program of Jiangsu Province,China.
文摘A highly sensitive and temperature-compensated methane sensor based on a liquid-infiltrated photonic crystal fiber (PCF) is proposed. Two bigger holes near the core area are coated with a methane-sensitive compound film, and specific cladding air holes are infiltrated into the liquid material to form new defective channels. The proposed sensor can achieve accurate measurement of methane concentration through temperature compensation. The sensitivity can reach to 20.07nm/% with a high linearity as the methane concentration is within the range of 0%-3.5% by volume. The proposed methane sensor can not only improve the measurement accuracy, but also reduce the metrical difficulty and simplify the process.