Comparison of two different methods for determining flow direction in catchment hydrological modeling

Digital elevation models （DEMs） are widely used to define the flow direction in distributed hydrological models for simulation of streamflow. In recent decades, numerous methods for flow direction determination have been applied successfully to mountainous regions. Nevertheless, some problems still exist when those methods are used for flat or gently sloped areas The present study reviews the conventional methods of determining flow direction for such landscapes and analyzes the problems of these methods. Two different methods of determining flow direction are discussed and were applied to the Xitiaoxi Catchment, located in the Taihu Basin in southern China, which has both mountainous and flat terrain. Both the agree method and the shortest path method use drainage networks derived from a remote sensing image to determine the correct location of the stream. The results indicate that the agree method provides a better fit with the DEM for the hilly region than the shortest path method. For the flat region where the flow has been diverted and rerouted by land managers, both methods require observation of the drainage network to determine the flow direction. In order to clarify the applicability of the two methods, both are employed in catchment hydrological models conceptually based on the Xinanjiang model and implemented with PCRaster. The simulation results show that both methods can be successfully applied in hydrological modeling. There are no evident differences in the modeled discharge when using the two methods at different spatial scales.

A Fast and Accurate LEO Satellite-Based Direct Position Determination Assisted by TDOA Measurements

This paper focuses on the trusted vessel position acquisition using passive localization based on the booming low-earth-orbit(LEO) satellites. As the high signal-to-noise ratio(SNR) reception cannot always be guaranteed at LEO satellites, the recently developed direct position determination(DPD)is adopted. For LEO satellite-based passive localization systems, an efficient DPD is challenging due to the excessive exhaustive search range leading from broad satellite coverage. In order to reduce the computational complexity, we propose a time difference of arrival-assisted DPD(TA-DPD) which minimizes the searching area by the time difference of arrival measurements and their variances. In this way, the size of the searching area is determined by both geometrical constraints and qualities of received signals, and signals with higher SNRs can be positioned more efficiently as their searching areas are generally smaller.Both two-dimensional and three-dimensional passive localization simulations using the proposed TA-DPD are provided to demonstrate its efficiency and validity. The superior accuracy performance of the proposed method, especially at low SNRs conditions, is also verified through the comparison to conventional two-step methods. Providing a larger margin in link budget for satellite-based vessel location acquisition,the TA-DPD can be a competitive candidate for trusted marine location service.

Evolution and application of in-seam drilling for gas drainage

The presence of seam gas in the form of methane or carbon dioxide presents a hazard to underground coal mining operations.In-seam drilling has been undertaken for the past three decades for gas drainage to reduce the risk of gas outburst and lower the concentrations of seam gas in the underground ventilation.The drilling practices have reflected the standards of the times and have evolved with the development of technology and equipment and the needs to provide a safe mining environment underground.Early practice was to adapt equipment from other felds,with rotary drilling being the only form of drilling available.This form of drainage allowed various levels of gas drainage coverage but with changing emphasis,research and development within the coal industry has created specifc equipment,technology and practices to accurately place in-seam boreholes to provide effcient and effective gas drainage.Research into gas content determination established a standard for the process and safe levels for mining operations to continue.Surveying technology improved from the wire-line,single-shot Eastman survey instruments which was time-dependent on borehole depth to electronic instruments located in the drill string which transmitted accurate survey data to the drilling crew without time delays.This allowed improved directional control and increased drilling rates.Directional drilling technology has now been established as the industry standard to provide effective gas drainage drilling.Exploration was identifed as an additional beneft with directional drilling as it has the ability to provide exploration data from long boreholes.The ability of the technology to provide safe and reliable means to investigate the need for inrush protection and water drainage ahead of mining has been established.Directional drilling technology has now been introduced to the Chinese coal industry for gas drainage through a practice of auditing,design,supply,training and ongoing support.Experienced drilling crews can offer site specifc gas drainage drilling services utilising the latest equipment and technology.

Distributed adaptive direct position determination based on diffusion framework

The conventional direct position determination（DPD） algorithm processes all received signals on a single sensor.When sensors have limited computational capabilities or energy storage,it is desirable to distribute the computation among other sensors.A distributed adaptive DPD（DADPD）algorithm based on diffusion framework is proposed for emitter localization.Unlike the corresponding centralized adaptive DPD（CADPD） algorithm,all but one sensor in the proposed algorithm participate in processing the received signals and estimating the common emitter position,respectively.The computational load and energy consumption on a single sensor in the CADPD algorithm is distributed among other computing sensors in a balanced manner.Exactly the same iterative localization algorithm is carried out in each computing sensor,respectively,and the algorithm in each computing sensor exhibits quite similar convergence behavior.The difference of the localization and tracking performance between the proposed distributed algorithm and the corresponding CADPD algorithm is negligible through simulation evaluations.

High-Precision Direct Determination of the ^(87)Sr/^(86)Sr Isotope Ratio of Bottled Sr-Rich Natural Mineral Drinking Water Using MC-ICP-MS

Strontium has four naturally occurring stable isotopes,84Sr,86Sr,87Sr,and 88Sr,with abundances of 0.56,9.87,approximately 7.04,and 82.53 atomic %,respectively.The 87Sr/86Sr isotope ratio is variable due to the addition of radiogenic 87Sr produced by the beta decay of 87Rb with a half-life of 4.88 ± 0.05 Ga.Thus,

DIRECT DETERMINATION OF NEODYMIUM AND ERBIUM IN RARE EARTH MIXTURE BY DERIVATIVE SPECTROPHOTOMETRY

The absorption spectra of 4f electron transitions of the complexes of neodymium and erbium with 8-hydroxyquinoline-5-sulphonic acid in the presence of diethylamine and ethanol have been measured by normal and third-derivative spectrophotometry. Their molar absorptivities are 70.7 l.mol^(-1).cm^(-1) for Nd and 62.5 l.mol^(-1).cm^(-1) for Er. They are 7.6 times and 14.9 times greater than those of corresponding chlorides, respectively. Use of the third-derivative spectra both eliminates the interference of Ce(Ⅳ) and increases the sensitivity for Nd and Er. Beer,s Law was obeyed from 0-10 ug/ml of Nd and Er. The method has been applied to the determination of neodymium and erbium in rare earth mixtures.

Hapten design to prepare monoclonal antibodies and establishment of immunoassay for direct screening of oxamichydrazide in chicken,the metabolite of nifuraldezone

In this study,two novel haptens of oxamichydrazide(OXZ),the metabolite of nifuraldezone,were designed and synthesized by derivatization with ethyl-4-bromobutanoate and ethyl-2-bromoacetate for the first time.The rationality of the haptens was enlightened by conformational alignment and electronic evaluations based on computional chemistry.The synthesized haptens were efficient in generating antibody response to OXZ.A monoclonal antibody(mAb)named 2D9 with high affinity was obtained and used to establish an indirect competitive enzyme-linked immunosorbent assay(icELISA)for the direct determination of OXZ in chicken samples without the need for derivatization step.Under optimum conditions,the developed icELISA showed an IC50 value of 0.66 ng mL^(−1),and limit of detection of 0.11μg kg^(−1)in chicken.The average recoveries were found to be 80.4-91.3%with a coefficient of variation less than 9.0%.In conclusion,we have successfully desigened haptens,prepared mAbs and developed an immunoassay for the direct determination of OXZ in chicken samples without the need for a derivatization step for the first time.This provides a potentially rapid,accurate,and sensitive screening tool for nifuraldezone residue in animal-derived food.

A direct position determination method with combined TDOA and FDOA based on particle filter

The localization of a stationary transmitter using moving receivers is considered. The original Direct Position Determination （DPD） methods, with combined Time Difference of Arrival （TDOA） and Frequency Difference of Arrival （FDOA）, do not perform well under low Signal-to-Noise Ratio （SNR）, and worse still, the computation cost is difficult to accept when the computational capabilities are limited. To get better positioning performance, we present a new DPD algorithm that proves to be more computationally efficient and more precise for weak signals than the conventional approach. The algorithm partitions the signal received with the same receiver into multiple non-overlapping short-time signal segments, and then uses the TDOA, the FDOA and the coherency among the short-time signals to locate the target. The fast maximum likelihood estimation, one iterative method based on particle filter, is designed to solve the problem of high computation load. A secondary but important result is a derivation of closed-form expressions of the Cramer-Rao Lower Bound （CRLB）. The simulation results show that the algorithm proposed in this paper outperforms the traditional DPD algorithms with more accurate results and higher computational efficiency, and especially at low SNR, it is more close to the CRLB.

Preparation of Nanosized CoHCF Modified Electrode and Its Application to Electroanalysis of Hemoglobin

A cobalt hexacyanoferrate （CoHCF） nanoparticle （size ca. 60 nm） chemically modified electrode （CME） was fabricated and the electrochemical behavior of hemoglobin （Hb） at this nanosized CoHCF CME was studied. In comparison with a bare glassy carbon electrode （GCE） and a general CoHCF CME electrodeposited in a traditional manner, the present nanosized CoHCF CME performed efficiently electrocatalytic reduction for Hb with relatively high sensitivity, stability, and longlife, Combined with liquid chromatography （LC）, the nanosized CoHCF CME was used as the electrochemical detector of Hb in the established flow injection analysis-electrochemical determination （FIA-ECD） system. The peak current was a linear function of concentrations in the range from 2.5×10^-8 to 5.0×10^-6mol/L for Hb, with detection limit of 1.4×10^-8 mol/L. The FIA-ECD system has been successfully applied to assess the Hb content of clinic blood samples with advantages of sensitiveness, speediness, easy control and small sample-consumption.

Comparison of direct and indirect determinations of dynamic ventilation rate in a modern dairy free stall barn

Reliable estimation of the ventilation rate(VR)in intensive livestock buildings is necessary for studying building environmental control strategies and predicting indoor air quality and air emissions.As direct air exchange measurements are time-consuming and expensive,it is environmentally inefficient to measure livestock building VR continuously in practice.Hence,indirect VR estimation methods have been widely used in modelling environmental control and air emissions,and also to measure airflow in the field.The accuracy of indirect measurement methods needs to be evaluated by comparing with direct measurements.In this study,the direct and indirect methods of determining hourly and daily mean VRs were applied to a mechanically-ventilated dairy free stall barn monitored by the 24-month National Air Emissions Monitoring Study.The direct method was used to continuously monitor fan rotational speeds,and differential static pressures,coupled with periodic in-situ fan performance assessments,to calculate the VR.The indirect method consisted of estimating the VR using CO2 concentration measurements and the CO2 mass balance method.The average daily and hourly means(mean±SD)of directly measured barn ventilation rates for two years were(246±73)m3/s and(245±77)m3/s,respectively.The average daily and hourly means(mean±SD)of barn ventilation rates estimated by the CO2 mass balance method were(287±93.4)m3/s and(287±118)m3/s,respectively.Correlation analyses showed a strong correlation between the indirect CO2 mass balance method and direct measurement methods(r=0.93 for daily means and r=0.85 for hourly means).

DIRECT PROOF OF THE DETERMINANT EXPRESSION FOR FLAGGED SKEW TABLEAUX

Flagged skew tableaux are generalizationa of Young tableaux in which each row (column)has an upper and lower bound on the entries. It has been shown that they are enumerated byflagged skew Schur functions. By introducing the dominance technique, we preeent an alternateproof for this conclusion directly.