Enabling low-cost decentralized power reserves adopting carbon dioxide for green methane exchange in stabilized clathrate adsorbent

1.Challenges circular methane energy systems In recent decades,methane-based energy systems have rapidly gained traction across the globe because of the increasing availability of low-cost methane production capacity.However,fossil methane production and combustion lead to large greenhouse gas emissions,contributing to climate change[1].

Methane dehydroaromatization over Mo-modified H-MFI for gas to liquid catalysts

For direct gas to liquid（GTL）,a novel process producing energy sources for methane dehydroaromatization is needed.Supporting MoO3 on H-MFI zeolite shows the high catalytic capacity and a selective activity for dehydroaromatization of methane to benzene at 973 K in a fixed bed reactor.On the other hand,deactivation by coke on the active sites in all the catalysts is formed during the reaction.H2 co-feed suppressed the deactivation,which is probably due to the decrease in coking amount.Mo K-edge X-ray absorption fine structure（XAFS） results showed the formation of dispersed Mo2C species with low crystallinity after dehydroaromatization.Mo LIII-edge XANES（X-ray absorption near-edge structure） indicated the formation of active Mo species including Mo2C and Mo-oxycarbide（MoOxCy）,where the redox state should be independent in the absence/presence of H2.It is concluded that Mo-oxycarbide species act as highly active species,and their stability affected the durable activity in the presence of H2.

Evolution and application of in-seam drilling for gas drainage

The presence of seam gas in the form of methane or carbon dioxide presents a hazard to underground coal mining operations.In-seam drilling has been undertaken for the past three decades for gas drainage to reduce the risk of gas outburst and lower the concentrations of seam gas in the underground ventilation.The drilling practices have reflected the standards of the times and have evolved with the development of technology and equipment and the needs to provide a safe mining environment underground.Early practice was to adapt equipment from other felds,with rotary drilling being the only form of drilling available.This form of drainage allowed various levels of gas drainage coverage but with changing emphasis,research and development within the coal industry has created specifc equipment,technology and practices to accurately place in-seam boreholes to provide effcient and effective gas drainage.Research into gas content determination established a standard for the process and safe levels for mining operations to continue.Surveying technology improved from the wire-line,single-shot Eastman survey instruments which was time-dependent on borehole depth to electronic instruments located in the drill string which transmitted accurate survey data to the drilling crew without time delays.This allowed improved directional control and increased drilling rates.Directional drilling technology has now been established as the industry standard to provide effective gas drainage drilling.Exploration was identifed as an additional beneft with directional drilling as it has the ability to provide exploration data from long boreholes.The ability of the technology to provide safe and reliable means to investigate the need for inrush protection and water drainage ahead of mining has been established.Directional drilling technology has now been introduced to the Chinese coal industry for gas drainage through a practice of auditing,design,supply,training and ongoing support.Experienced drilling crews can offer site specifc gas drainage drilling services utilising the latest equipment and technology.

A new technology for coal and gas control based on the in situ stress distribution and the roadway layout

An auxiliary gas control technology is described that can reduce coal and gas outburst accidents when there is no existing protective coal seam and gas pre-draining is not effective.Numerical simulation methods were used to study the stress distribution ahead of the roadway face for different in situ stresses.The results from the simulation can then provide a new gas control technology.The results show that a high stress concentration,high stresses,and high displacement gradients appear ahead of the roadway face when the maximum in situ stress is aligned perpendicular to the roadway axis.The risk of gas outburst is higher when the stresses decrease rapidly over distance and when the release of more energy occurs immediately after driving the roadway.The gas outburst risk is much smaller when the in situ stress is aligned parallel to the roadway axis.During design of the coal mine most of the coal roadways should be arranged to parallel the maximum in situ stress.This will decrease the outburst risk in general and may be considered a new gas outburst prevention method.

Effects of different combustion modes on the thermal efficiency and emissions of a diesel pilot-ignited natural gas engine under low-medium loads

Research on dual-fuel(DF)engines has become increasingly important as engine manufacturers seek to reduce carbon dioxide emissions.There are significant advantages of using diesel pilot-ignited natural gas engines as DF engines.However,different combustion modes exist due to variations in the formation of the mixture.This research used a simulation model and numerical simulations to explore the combustion characteristics of high-pressure direct injection(HPDI),partially premixed compression ignition(PPCI),and double pilot injection premixed compression ignition(DPPCI)combustion modes under a low-medium load.The results revealed that the DPPCI combustion mode provides higher gross indicated thermal efficiency and more acceptable total hydrocarbon(THC)emission levels than the other modes.Due to its relatively good performance,an experimental study was conducted on the DPPCI mode engine to evaluate the impact of the diesel dual-injection strategy on the combustion process.In the DPPCI mode,a delay in the second pilot ignition injection time increased THC emissions(a maximum value of 4.27g/(kW·h)),decreased the emission of nitrogen oxides(a maximum value of 7.64 g/(kW·h)),increased and then subsequently decreased the gross indicated thermal efficiency values,which reached 50.4%under low-medium loads.

Reliability of gas holdup measurements using the differential pressure method in a cyclone-static micro-bubble flotation column

Gas holdup is one of the key parameters in flotation process. Gas holdup as measured by a differential pressure method was investigated and the relative errors compared to the average gas holdup from the volume expansion method. The errors were used to establish optimum measurement positions. The results show that the measurement position should be in the middle of the column and in the region half way from the center to the wall (the half-radius). The gas holdup along the axial direction is lower at the bottom and higher at the top of the floatation column. The gas holdup along the radial direction is lower near the wall and higher near the center of the flotation column. The average gas holdup measure- ment can be replaced by regional gas holdup values.

Investigation on the application of reformed coke oven gas in direct reduction iron production with a mathematical model

To investigate the application of reformed coke oven gas （COG） in producing the direct reduction iron （DRI）, we simulated a countercurrent gas solid moving bed reactor in which the iron ore pellet was reduced by reformed COG. An ordinary differential equation （ODE） was set based on the unreacted shrinking core model considering both mass and energy balances of the reactor. The concentration and temperature profiles of all species within the reactor were obtained by solving the ODE sys tem. The solid conversion and gas utilization were studied by changing gas flow rate, solid flow rate, reactor length, and the ratio of O/CHa to guide the practical application of COG in DRI production. Model results showed that COG was suitable for the DRI production. In order to meet the requirement of the industrial production, the minimum gas flow rate was set as 130,000 Nm3/h, and the maximum production was 90 t/h. The reactor length and the mole ratio x（O）： x（CH4） were depended on the actual industrial situations.

Applying a new method for direct collection, volume quantification and determination of N_2 emission from water

The emission of N2 is important to remove excess N from lakes, ponds, and wetlands. To investigate the gas emission from water, Gao et al.（2013） developed a new method using a bubble trap device to collect gas samples from waters. However, the determination accuracy of sampling volume and gas component concentration was still debatable. In this study, the method was optimized for in situ sampling, accurate volume measurement and direct injection to a gas chromatograph for the analysis of N2 and other gases. By the optimized new method, the recovery rate for N2 was 100.28% on average; the mean coefficient of determination（R2） was 0.9997; the limit of detection was 0.02%. We further assessed the effects of the new method, bottle full of water, vs. vacuum bag and vacuum vial methods, on variations of N2 concentration as influenced by sample storage times of 1,2, 3, 5, and 7 days at constant temperature of 15°C, using indices of averaged relative peak area（%） in comparison with the averaged relative peak area of each method at 0 day.The indices of the bottle full of water method were the lowest（99.5%–108.5%） compared to the indices of vacuum bag and vacuum vial methods（119%–217%）. Meanwhile, the gas chromatograph determination of other gas components（O2, CH4, and N2O） was also accurate. The new method was an alternative way to investigate N2 released from various kinds of aquatic ecosystems.