Gap States of ZnO Thin Films by New Methods:Optical Spectroscopy,Optical Conductivity and Optical Dispersion Energy

The optical reflectance and transmittance spectra in the wavelength range of 300-2500 nm are used to compute the absorption coefficient of zinc oxide films annealed at different post-annealing temperatures 400, 500 and 600°C.The values of the cross point between the curves of the real and imaginary parts of the optical conductivity ɑ_1 and ɑ_1 with energy axis of films exhibit values that correspond to optical gaps and are about 3.25-3.3 eV. The maxima of peaks in plots dR/dλ and dT/dλ versus wavelength of films exhibit optical gaps at about 3.12-3.25 eV.The values of the fundamental indirect band gap obtained from the Tauc model are at about 3.14-3.2 eV. It can be seen that films annealed at 600°C have the minimum indirect optical band gap at about 3.15 eV. The films annealed at 600°C have Urbach＇s energy minimum of 1.38 eV and hence have minimum disorder. The dispersion energy d of films annealed at 500°C has the minimum value of 43 eV.

Ab initio Calculation of Intermolecular Dispersion Energy and Induction Energy of Nitramide Dimer

The dispersion energies, induction energies and their exchange counterparts (exchange-dispersion and ex-change-induction energies) between two interacting nitramide molecules at several separations are derived based upon symmetry-adapted perturbation theory (SAPT). The results show that (1) the effect of intramonomer electron correlation on dispersion energies and induction energies for nitramide dimer system is remarkable especially in the region near the van der Waals minimum distance (0.42 nm). (2) At smaller separations the dispersion energies and the induction energies are largely quenched by their exchange counterparts, and this case in induction interaction is much more remarkable than in dispersion interaction. (3) Since at shorter distances there exists the strong short-range interaction due to electron transfer which quickly decays and even disappears at larger separations, the two different R-dependency formulae of induction energies were found: one is ca. R-12.7 at short distances, and the other ca. R-7.0 at large separations. The latter R-dependency is similar to that (ca. R-7.2) of dispersion. (4) In the case of strong polar interaction existing in nitramide dimer, the true induction correlation terms of higher order than t(22)indE may be important.

Variations in Wave Energy and Amplitudes along the Energy Dispersion Paths of Nonstationary Barotropic Rossby Waves

The variations in the wave energy and the amplitude along the energy dispersion paths of the barotropic Rossby waves in zonally symmetric basic flow are studied by solving the wave energy equation,which expresses that the wave energy variability is determined by the divergence of the group velocity and the energy budget from the basic flow.The results suggest that both the wave energy and the amplitude of a leading wave increase significantly in the propagating region that is located south of the jet axis and enclosed by a southern critical line and a northern turning latitude.The leading wave gains the barotropic energy from the basic flow by eddy activities.The amplitude continuously climbs up a peak at the turning latitude due to increasing wave energy and enlarging horizontal scale(shrinking total wavenumber).Both the wave energy and the amplitude eventually decrease when the trailing wave continuously approaches southward to the critical line.The trailing wave decays and its energy is continuously absorbed by the basic flow.Furthermore,both the wave energy and the amplitude oscillate with a limited range in the propagating region that is located near the jet axis and enclosed by two turning latitudes.Both the leading and trailing waves neither develop nor decay significantly.The jet works as a waveguide to allow the waves to propagate a long distance.

Variations in Amplitudes and Wave Energy along the Energy Dispersion Paths for Rossby Waves in the Quasigeostrophic Barotropic Model

Variations in wave energy and amplitude for Rossby waves are investigated by solving the wave energy equation for the quasigeostrophic barotropic potential vorticity model.The results suggest that compared with rays in the nondivergent barotropic model,rays in the divergent model can have enhanced meridional and zonal propagation,accompanied by a more dramatic variability in both wave energy and amplitude,which is caused by introducing the divergence effect of the free surface in the quasigeostrophic model.For rays propagating in a region enclosed by a turning latitude and a critical latitude,the wave energy approaches the maximum value inside the region,while the amplitude approaches the maximum at the turning latitude.Waves can develop when both the wave energy and amplitude increase.For rays propagating in a region enclosed by two turning latitudes,the wave energy approaches the minimum value at one turning latitude and the maximum value at the other latitude,while the total wavenumber approaches the maximum value inside the region.The resulting amplitude increases if the total wavenumber decreases or the wave energy increases more significantly and decreases if the total wavenumber increases or the wave energy decreases more significantly.The matched roles of the energy from the basic flow and the divergence of the group velocity contribute to the slightly oscillating wave energy,which causes a slightly oscillating amplitude as well as the slightly oscillating total wavenumber.

Three－dimensional Global Scale Permanent－wave Solutions of the Nonlinear Quasigeostrophic Potential Vorticity Equation and Energy Dispersion

The three-dimensional nonlinear quasi-geostrophic potential vorticity equation is reduced to a linear form in the stream function in spherical coordinates for the permanent wave solutions consisting of zonal wavenumbers from 0 to n and rn vertical components with a given degree n.This equation is solved by treating the coefficient of the Coriolis parameter square in the equation as the eigenvalue both for sinusoidal and hyperbolic variations in vertical direction. It is found that these solutions can represent the observed long term flow patterns at the surface and aloft over the globe closely. In addition, the sinusoidal vertical solutions with large eigenvalue G are trapped in low latitude,and the scales of these trapped modes are longer than 10 deg. lat. even for the top layer of the ocean and hence they are much larger than that given by the equatorial β-plane solutions.Therefore such baroclinic disturbances in the ocean can easily interact with those in the atmosphere.Solutions of the shallow water potential vorticity equation are treated in a similar manner but with the effective depth H=RT/g taken as limited within a small range for the atmosphere.The propagation of the flow energy of the wave packet consisting of more than one degree is found to be along the great circle around the globe both for barotropic and for baroclinic flows in the atmosphere.

Tropical Cyclone Energy Dispersion and Possible Self- Maintenance Mechanism of the Synoptic- Scale Wave Trains

The interaction between tropical cyclone(TC)and the large-scale mean flows such as the inter-tropical convergence zone(ITCZ)is investigated using a three-dimensional primitive equation model.Once a TC develops in the vicinity of the ITCZ region where satisfies both barotropic and baroclinic instabilities,the southeastward energy dispersion from the TC may disturb the ITCZ and thus help its breakdown.Cumulus convection can be organized in the region of cyclonic circulation,and the interaction between convective heating and the perturbation circulation may enhance the development of the waves,leading to the generation of a new tropical cyclone to the east.While the TC moves to the high latitude,the ITCZ will reform.Though repeating of this process,a synoptic-scale wave train oriented in the northwest-southeast direction can be generated and self-maintained.The results suggest that the mutual interaction among the low-frequency background flow,wave train pattern and TCs provides a possible mechanism for the origin of the summer synoptic scale wave train pattern over the western North Pacific.

Energy-dispersive X-ray Spectroscopy for the Quantitative Analysis of Pyrite Thin Specimens

To explore ways to improve the accuracy of quantitative analysis of samples in the micrometer to nanometer range of magnitudes,we adopted analytical transmission electron microscopy(AEM/EDS)for qualitative and quantitative analysis of pyrite materials.Additionally,the k factor of pyrite is calculated experimentally.To develop an appropriate non-standard quantitative analysis model for pyrite materials,the experimentally calculated k factor is compared with that estimated from the non-standard quantitative analytical model of the instrument software.The experimental findings demonstrate that the EDS attached to a TEM can be employed for precise quantitative analysis of micro-and nanoscale regions of pyrite materials.Furthermore,it serves as a reference for improving the results of the EDS quantitative analysis of other sulfides.

Determination of Element Levels of Lagoon from Townships near Cocody City Abidjan Côte D’Ivoire Using Energy Dispersive X-Ray Fluorescence

Eight water bottles from Ebrie lagoon with pollution potency were studied using nuclear chemistry technique and Energy dispersive X-ray fluorescence. This pollution is characterized by pH and conductivity parameters, concentrations average in mg/L of metals such Fe (0.731), Mn (0.345), Cr (0.070), Cu (0.014) and concentrations of nutrients known to be pollutants and toxic for living or-ganisms. These heavy metals are dangerous to the lives, the local inhabitants and also a threat to aquatic life since this water is essential for the economical town, Abidjan. According to the Manganese concentration average (0.345 mg) values that higher than WHO (0.05 mg) value, the main likely source of pollu-tants is anthropogenic, industrial and agricultural. This study also shows the use of materials and lubricants near the lagoon that pollute this water.

Alpha-actinin expression at different differentiating time points from temporal lobe cerebral cortex neural stem cells to neuron-like cells using energy dispersive X-ray analysis

BACKGROUND： Alpha-actinin （ a -actinin） plays a key role in neuronal growth cone migration during directional differentiation from neural stem cells （NSCs） to neurons. OBJECTIVE： To detect in situ microdistribution and quantitative expression of a -actinin during directional differentiation of NSCs to neurons in the temporal lobe cerebral cortex of neonatal rats. DESIGN, TIME AND SETTING： Between January 2006 and December 2008, culture and directional differentiation of NSCs were performed at Department of Histology and Embryology, Preclinical Medical College, China Medical University. Immune electron microscopy was performed at Department of Histology and Embryology and Department of Electron Micrology, Preclinical Medical College, China Medical University. Spectrum analysis was performed at Laboratory of Electron Microscopy, Mental Research Institute, Chinese Academy of Sciences. MATERIALS： Basic fibroblast growth factor, epidermal growth factor, brain-derived nerve growth factor, type-1 insulin like growth factor, and a -actinin antibody were provided by Gibco BRL, USA; rabbit-anti-rat nestin monoclonal antibody, rabbit-anti-rat neuron specific enolase polyclonal antibody, and EDAX-9100 energy dispersive X-ray analysis were provided by PHILIPS Company, Netherlands. METHODS： NSCs, following primary and passage culture, were differentiated with serum culture medium （DMEM/F12 ＋ 10% fetal bovine serum ＋ 2 ng/mL brain-derived nerve growth factor ＋ 2 ng/mL type-1 insulin like growth factor）. MAIN OUTCOME MEASURES： Expression of a -actinin in neuron-like cells was quantitatively and qualitatively detected with immunocytochemistry using energy dispersive X-ray analysis. RESULTS： Immunocytochemistry, combined with electron microscopy, indicated that positive α -actinin expression was like a spheroid particle with high electron density. In addition, the expression was gradually concentrated from the nuclear edge to the cytoplasm and expanded into developing neurites, during differentiation of neural stem cells to neurons. Conversely, energy dispersive X-ray analysis indicated that the more mature the neural differentiation was, and the greater the expression of α -actinin. CONCLUSION： The gradual increase of α -actinin expression is related to growth, development, and maturity of differentiated neuron-like cells, in neonatal rat frontal lobe cortex, at different differentiating time points of NSCs to neurons.

Energy Dispersive X-Ray Spectroscopy of the Sohnari Member of Laki Formation from Southern Indus Basin of Pakistan

This study determines the geochemical and depositional environment analysis of the sediments of the Sohnari Member of the Laki Formation, Northern Kirthar Fold Belt of Pakistan. The Energy-Dispersive-X-Ray Spectroscopy (EDS) technique is used for the detection of major elements and the effects of shifting depositional climatic conditions of six representative samples which were acquired from the Sohnari Member of the Laki Formation at Lakhra area, Sindh, Pakistan. The sedimentological studies clarify that the sediments the Sonahri Member are relatively immature and most migrated in clastic mode. The availability of Silica shows that the Member was formed due to biochemical precipitation and detrital mode and was deposited at a fast rate of sediment deposition under the fluvio-deltaic depositional system. This is also deduced that the rapid rate of sediment deposition might be created a reducing atmosphere and allowing for the mineralization of sulphur.

Possible Relevance of the Allende Meteorite Conditions in Prebiotic Chemistry: An Insight into the Chondrules and Organic Compounds

The study of the mineral and organic content of the Allende meteorite is important for our understanding of the molecular evolution of the universe as well as the ancient Earth. Previous studies have characterized the magnetic minerals present in ordinary and carbonaceous chondrites, providing information on the evolution of magnetic fields. The interaction of organic compounds with magnetic minerals is a possible source of chemical diversity, which is crucial for molecular evolution. Carbon compounds in meteorites are of great scientific interest for a variety of reasons, such as their relevance to the origins of chirality in living organisms. This study presents the characterization of organic and mineral compounds in the Allende meteorite. The structural and physicochemical characterization of the Allende meteorite was accomplished through light microscopy, powder X-ray diffraction with complementary Rietveld refinement, Raman and infrared spectroscopy, mass spectrometry, scanning electron microscopy, and atomic force microscopy using magnetic signal methods to determine the complex structure and the interaction of organic compounds with magnetic Ni-Fe minerals. The presence of Liesegang-like patterns of chondrules in fragments of the Allende structure may also be relevant to understanding how the meteorite was formed. Other observations include the presence of magnetic materials and nanorod-like solids with relatively similar sizes as well as the heterogeneous distribution of carbon in chondrules. Signals observed in the Raman and infrared spectra resemble organic compounds such as carbon nanotubes and peptide-like molecules that have been previously reported in other meteorites, making the Mexican Allende meteorite a feasible sample for the study of the early Earth and exoplanetary bodies.

New approaches to characterizing urban air particles in central London

Atmospheric particles in central London during July 1996 have been apportioned to sources by two complimentary techniques: (1) morphological characteristics, determined using high power light microscopy; (2) chemical composition determined by energy dispersive spectroscopy. During the study period, the majority of particles were found to be either biological in origin, or from vehicle related combustion processes. Trends in the latter group of particles are explored further. Numbers of particles per cubic metre were determined at an hourly resolution over a period of six days, and were found to be significantly correlated with other traffic pollutants such as benzene and 1,3 butadiene, although there is no relationship with mass of PM10 as measured by a nearby UK Government monitoring station. We suggest in this paper that numbers of particles from car exhausts are more representative of traffic pollution than current estimates which use monitoring by mass.

Rapid Biosynthesis of Silver Nanoparticles Using Cymbopogan Citratus (Lemongrass) and its Antimicrobial Activity

The present study deals with the rapid green synthesis of silver nanoparticles using fresh leaves of Cymbopogan Citratus(Lemongrass). Silver nanoparticles were formed within 8～10 minutes by microwave irradiation using aqueous solution of Ag NO3(1 m M) with fresh leaves extract of Cymbopogan Citratus. The synthesized silver nanoparticles were characterized by using UV-visible spectrophotometer analysis, nanoparticle tracking analyzer, transmission electron microscope and energy dispersive X-ray spectra. The antibacterial activity of these nanoparticles was studied against multiple drug resistant hospital isolates of E.coli, S.aureus,P.mirabilis and hospital isolates of S. typhi, K.pnuemoniae. Also, the antifungal activity of these nanoparticles was studied against C.albicans(hospital isolate) and A.niger(NCIM 616). The synergistic effect of silver nanoparticles along with antibiotics was also studied against multiple drug resistant hospital isolates and found to be effective. The extracellular synthesis of Silver nanoparticles using leaves of Cymbopogan Citratus appears to be rapid and eco-friendly.

Mechanism of cement-stabilized soil polluted by magnesium sulfate

In order to simulate and study the mechanism of cement stabilized soils polluted by different contents of magnesium sulfate(MS), a series of tests were conducted on the cemented soil samples, including unconfined compression strength(UCS) tests of blocks, X-ray diffraction(XRD) phase analysis of powder samples, microstructure by scanning electronic microscopy(SEM),element composition by energy dispersive spectrometry(EDS), and pore distribution analysis by Image Processed Plus 6.0(IPP 6.0)software. The UCS test results show that UCS of cemented soils reaches the peak value when the MS content is 4.5 g/kg. While, the UCS for Sample MS4 having the MS content of 18.0 g/kg is the lowest among all tested samples. Based on the EDS analysis results,Sample MS4 has the greater contents for the three elements, oxygen(O), magnesium(Mg) and sulfur(S), than Sample MS1. From the XRD phase analysis, C-A-S-H(3Ca O·Al2O3·3Ca SO4·32H2O and 3Ca O·Al2O3·Ca SO4·18H2O), M-A-H(Mg O·Al2O3·H2O), M-S-H(Mg O·Si O2·H2O), Mg(OH)2 and Ca SO4 phase diffraction peaks are obviously intense due to the chemical action associated with the MS. The pore distribution analysis shows that the hydrated products change the distribution of cemented soil pores and the pores with average diameter(AD) of 2-50 μm play a key role in terms of the whole structure of cemented soil. The microscopic structure of the cemented soil with MS exhibits the intertwined and embedded characteristics between the cement and granular soils from the SEM images of cemented soils. The microstructure analysis shows that the magnesium sulfate acts as the additive, which is beneficial to the soil strength when the MS content is low(i.e., Sample MS2). However, higher MS amount involving a chemical action makes samples crystallize and expand, which is adverse to the UCS of cemented soils(i.e., Sample MS4).

Typical Circulation Patterns and Associated Mechanisms for Persistent Heavy Rainfall Events over Yangtze–Huaihe River Valley during 1981–2020

Persistent heavy rainfall events(PHREs)over the Yangtze–Huaihe River Valley(YHRV)during 1981–2020 are classified into three types(type-A,type-B and type-C)according to pattern correlation.The characteristics of the synoptic systems for the PHREs and their possible development mechanisms are investigated.The anomalous cyclonic disturbance over the southern part of the YHRV during type-A events is primarily maintained and intensified by the propagation of Rossby wave energy originating from the northeast Atlantic in the mid–upper troposphere and the northward propagation of Rossby wave packets from the western Pacific in the mid–lower troposphere.The zonal propagation of Rossby wave packets and the northward propagation of Rossby wave packets during type-B events are more coherent than those for type-A events,which induces eastward propagation of stronger anomaly centers of geopotential height from the northeast Atlantic Ocean to the YHRV and a meridional anomaly in geopotential height over the Asian continent.Type-C events have“two ridges and one trough”in the high latitudes of the Eurasian continent,but the anomalous intensity of the western Pacific subtropical high(WPSH)and the trough of the YHRV region are weaker than those for type-A and type-B events.The composite synoptic circulation of four PHREs in 2020 is basically consistent with that of the corresponding PHRE type.The location of the South Asian high(SAH)in three of the PHREs in 2020 moves eastward as in the composite of the three types,but the position of the WPSH of the four PHREs is clearly westward and northward.Two water vapor conveyor belts and two cold air conveyor belts are tracked during the four PHREs in 2020,but the water vapor path from the western Pacific is not seen,which may be caused by the westward extension of the WPSH.

Determination of Water Diffusion Coefficients and Dynamics in Adhesive/Carbon Fiber Reinforced Epoxy Resin Composite Joints

To determinate the water diffusion coefficients and dynamics in adhesive/carben fiber reinforced epoxy resin composite joints, energy dispersive X-ray spectroscopy analysis（EDX） is used to establish the content change of oxy- gen in the adhesive in adhesive/carbon fther reinforced epoxy resin composite joints. As water is made up of oxygen and hydrogen, the water diffusion coefficients and dynamics in adhesive/carben fiber reinforced epoxy resin composite joints can be obtained from the change in the content of oxygen in the adhesive during humidity aging, via EDX analy-sis. The authors have calculated the water diffusion coefficients and dynamics in the adhesive/carbon fiber reinforced epoxy resin composite joints with the aid of beth energy dispersive X-ray spectroscopy and elemental analysis. The de- termined results with EDX analysis are almost the same as those determined with elemental analysis and the results al- so show that the durability of the adhesive/carbon fther reinforced epoxy resin composite joints subjected to silane cou- pling agent treatment is better than those subjected to sand paper burnishing treatment and chemical oxidation treat- ment.

Study of Effects of Beta Term and Nonlinear Advection on the Structure of Tropical Cyclones

The effects of the Beta term on the typhoon structure are examined within the linear framework in terms of an analytical method of 2-D Fourier representation and numerical experiments by a Beta-plane quasi-geostrophic barotropic model. Results show that the joint effects of the difference of Rossby phase velocities and the dispersion of typhoon energy keep the maximum wind velocity reasonably evolving rather than irrestrictively increasing. On the one hand, the nonlinear advection accelerates typhoon vortex damping, and on the other, the high pressure system formed downstream due to energy dispersion makes it easy to maintain.

Effect of Cu on Microstructures of Manganese Steel by EDXA and SEM

In order to investigate the distribution of Cu and Mg, and the effect of Cu on the microstructure of steels, manganese steels containing various Cu contents were annealed at 1260, 1100 and 1000℃, respectively, for I h and subsequently cooled to room temperature in the furnace to simulate the pre-rolling anneal. The results indicate that Cu is not microscopically segregated in the annealed steels. The scanning electron microscopy （SEM） observation shows that the main microstructure consist of ferrite and pearlite; the percentage of pearlite in the steels increases with increasing Cu content. The grain size reduces with the decrease of the annealing temperature. The results of energy dispersive X-ray analysis （EDXA） suggest that Cu content in pearlite is higher than that in ferrite, demonstrating that the microstructure-segregation of Cu occurred. However, the cast specimens show that Cu content in MnS and S-rich phases is high. In addition, Cu of 0.2%-0.4% could improve the distribution of MnS and S-rich inclusions. The optimal Cu content in steels and the optimal annealing temperature between 1100-1200℃ were determined.

PREPARATION AND SURFACE PROPERTIES OF ACRYLIC COPOLYMERS CONTAINING FLUORINATED MONOMERS

A series of copolymers comprising butylmethacrylate, styrene, butylacrylate, hydroxypropyl acrylate and perfluoroalkyl methacrylate were synthesized by the free radical polymerization using BPO as an initiator. The surface property of the copolymer films was subsequently characterized. The contact angle measurements and energy dispersive analysis of X-ray （EDAX） show that the length and content of perfluoroalkyl side chains in the copolymers are crucial for the preparation of the film with low surface energy. At a given content of fluorinated monomers in the copolymers, the longer the perfluoroalkyl side chain, the larger the water contact angle of the copolymer films will be. On the other hand, the higher the content of fluorinated monomers, the lower the surface energy is. The water contact angle increases with the increase of the fluorinated monomer content and reaches a plateau at 3 wt% of fluorinated monomer content.

EFFECT OF ENERGY DISPERSION ON THE STRUCTURE AND MOTION OF TROPICAL CYCLONE

The energy dispersion of a typhoon vortex and its effect on the typhoon motion are studied using an analytical method of double-Fourier expansion as well as a numerical model in a β-plane nondivergent barotropic framework. The analytic model and the linear version of the numerical model give essentially the same result:the energy dispersion from a tropical cyclone can creat an L-H-L wave train to the east of the tropical cyclone.Three numerical experiments, integrated for 7 model days by the nonlinear model,indicate that the closed high in the wave train produces obvious in- fluence on the structure and movement of the tropical cyclone.