Effects of Turbulent Dispersion of Atmospheric Balance Motions of Planetary Boundary Layer

New Reynolds' mean momentum equations including both turbulent viscosity and dispersion are used to analyze atmospheric balance motions of the planetary boundary layer. It is pointed out that turbulent dispersion with r 0 will increase depth of Ekman layer, reduce wind velocity in Ekman layer and produce a more satisfactory Ekman spiral lines fit the observed wind hodograph. The wind profile in the surface layer including tur-bulent dispersion is still logarithmic but the von Karman constant k is replaced by k1 = 1 -2/k, the wind increasesa little more rapidly with height.

PREPARATION, COMPLEX MECHANISM AND STRUCTURE MODEL OF METALLOPHTHALOCYANINE-Fe_3O_4 NANOPARTICLES COMPOSITE

MPc-Fe3O4-nanoparticles composite(M= Co, Cu , Ni, Mn ) have been prepared and the factors that influence their mean size have been studied. The mean size of the nanoparticles composite increase with the increase of complex temperature. The interaction of MPc with Fe3O4 nanoparticles has been studied. There are M-O covalent bonding and ionic bonding between MPc and Fe3Q4 nanoparticles. The intensities of M-O bonding and ionic bonding are in vestigated . The complex mechanism of MPc with Fe3O4 nanoparticles have been studied. First, there are complex between MPc and all Fe3O4 nanoparticles. Then, Fe3O4 nanoparticles accumulate together to form the accumulators, MPc have the function of cohering Fe3O4 nanoparticles. A considerable number of MPc combine with Fe3O4 nanoparticles on the surface of the accumu-lators to form MPc-Fe3O4 nanoparticles composite. All the above proesses take place spontaneously. The structuremodel of MPc-Fe3O4 nanoparticles composite has also been investigated. Inside the MPc-Fe3O4 nanoparticles composite, Fe3O4 nanoparticles accumulate together without order, on the surface of the composite, MPc form molecular dispersion layer. The threshold of molecular dispersion layer are also investigated.

Numerical study of the effects of Planetary Boundary Layer structure on the pollutant dispersion within built-up areas

The effects of different Planetary Boundary Layer（PBL） structures on pollutant dispersion processes within two idealized street canyon configurations and a realistic urban area were numerically examined by a Computational Fluid Dynamics（CFD） model. The boundary conditions of different PBL structures/conditions were provided by simulations of the Weather Researching and Forecasting model. The simulated results of the idealized 2D and 3D street canyon experiments showed that the increment of PBL instability favored the downward transport of momentum from the upper flow above the roof to the pedestrian level within the street canyon. As a result, the flow and turbulent fields within the street canyon under the more unstable PBL condition are stronger. Therefore, more pollutants within the street canyon would be removed by the stronger advection and turbulent diffusion processes under the unstable PBL condition. On the contrary, more pollutants would be concentrated in the street canyon under the stable PBL condition. In addition, the simulations of the realistic building cluster experiments showed that the density of buildings was a crucial factor determining the dynamic effects of the PBL structure on the flow patterns. The momentum field within a denser building configuration was mostly transported from the upper flow, and was more sensitive to the PBL structures than that of the sparser building configuration. Finally, it was recommended to use the Mellor-Yamada-Nakanishi-Niino（MYNN） PBL scheme, which can explicitly output the needed turbulent variables, to provide the boundary conditions to the CFD simulation.

A THREE-DIMENSIONAL RANDOM DISPERSION MODEL WITHIN SURFACE LAYER

Taking advantage of the relation of lateral Lagrangian time scale T_(LY) with the stability and height, we establish a three-dimensional random dispersion model and simulate the dispersing process of a ground source within the surface layer. The results calculated show that under the condition of stable stratifica- tion our model is obviously better improved than those obtained by assuming T_(LY) to be constant, while under unstable condition, not much improved.

Thermal Stability and Thermal Aging of Poly(vinyl chloride)/MgAl Layered Double Hydroxides Composites

MgAl-LDH（layered double hydroxides） were prepared with CO（NH2）2, NH4 Cl and NH3·H2O by the coprecipitation method, respectively. Corresponding composite membranes were prepared by the coating method. LDHs were characterized by WAXS, CO2-TPD and SEM. The morphology of the PVC/LDHs composite membranes were characterized by means of SEM. The thermal stability of the membranes was analyzed by air aging box and TGA-FTIR. The SEM results show that nano-particles can be compatible with poly（vinyl chloride）（PVC） matrix homogeneously by the stirring-ultrasound blend method with two steps. Furthermore, the air aging box results proved that MgAl-CO（NH2）2-LDH has the best effect on thermal stability of PVC. TGA-FTIR results show that MgAl-CO（NH2）2-LDH could adsorb more HCl that resulted from the degradation of PVC and improve the pyrolysis temperature of the first degradation stage by 15 K compared with PVC.