The dispersion of particles in turbulent semi-circular duct flows

The flow field in a semi-circular duct is simulated by Large Eddy Simulation(LES)and its particle field is simulated by Lagrange particle tracking method.Reynolds number Reb(based on bulk velocity and hydraulic diameter)is 80,000 and Ret(based on friction velocity and hydraulic diameter)is 3528.Particle diameter dpis chosen as 10,50,100,500 mm corresponding to St as 0.10,2.43,9.72,243.05.The results show that the intensity of the secondary flow near the ceiling is less than that near the floor because the ceiling is curved and able to inhibit the secondary flow.It is found that the difference between the semicircular duct and the square duct is that the secondary flow in a corner of the semi-circular duct is not symmetrical along the diagonal although they have the same generation mechanism.Regarding the particles,small particles(dp≤10 mm)are found to uniformly distribute in the duct,while large particles(dp≥50 mm)preferentially distribute in the corner and floor center.The maximum particles(dp=500mm)fall on the floor quickly and their dispersion mainly depends on the secondary flow near the floor.Particle deposition in the corner depends on particle size due to the effect of secondary flow and gravity.The effect of lift force on particles becomes more significant for 50 and 100 mm particles in comparison with other smaller particles.In the end,the effect of secondary flow is found to be more significant to dominate particle behavior than that of flow fluctuation.

RESEARCH ON THE PARTICLE DISPERSION IN THE PARTICULATE TWO-PHASE ROUND JET

In this paper, the three_dimensional vo rtex filament method was used to simulate the evolution of vortex structures in the axisymmetric round jet. The results agree well with the ones given by Chung and Troutt. Then one_coupling model was employed to calculate the particle motio n based on the computed flows. The results show that the particle motion is affe cted by flows obviously at the case of particle number St1 and negligibly at St1 ,particles distribute around the vortex structures uniformly at St ～1 . When perturbations with wavenumber 5 are introduced to vortex rings, part icles disperse wider along radial direction, which conforms to the experimental results. The degree of particle dispersion is in the direct ratio to the amplitu de of perturbation. The conclusions given in the paper are useful to the practic e usage.

Development of re-crosslinkable dispersed particle gels for conformance improvement in extremely high-temperature reservoirs

Micro-scale and nano-scale dispersed gel particles(DPG)are capable of deep migration in oil reservoirs due to their deformability,viscoelasticity,and suitable particle size.Therefore,it has been widely studied and applied in reservoir conformance control in recent years.However,for highly permeable channels,their plugging performance is still limited.In addition,conventional in situ cross-linked polymer gels(ISCPGs)have fast gelation time under extremely high-temperature conditions,which often causes problems such as difficulty in pumping.Therefore,a re-cross linkable dispersed particle gel(RDPG)system applied for conformance control in highly permeable channels of extremely high-temperature petroleum reservoirs was investigated.The particle size distribution,gelation time,gel strength,injection performance,and perfo rmance strength in po rous media were investigated using a laser particle size meter,the Sydansk bottle test method,rheometer,and core displacement experiments,respectively.Results show that the RDPG suspension can be stable for more than 6 months at room temperature with storage modulus G’much lower than 10 Pa.It can pass through the pore throat by elastic deformation effect and does not cause strong blockage.Moreover,it can undergo re-crosslinking reaction at 150℃to form a strong bulk gel.The gel strength G’of re-crosslinked RDPG can be as high as 69.3 Pa,which meets the strength requirement of conformance control.The RDPG suspension has the properties of easy injection,and it also has strong plugging,and high-temperature resistance after re-crosslinked in the core,which can be a very promising material for conformance improvement in extremely high-temperature reservoirs.

Probing the effect of Young's modulus on the plugging performance of micro-nano-scale dispersed particle gels

The effect of mechanical strength of the dispersed particle gel(DPG)on its macro plugging performance is significant,however,little study has been reported.In this paper,DPG particles with different mechanical strengths were obtained by mechanical shearing of bulk gels prepared with different formula.Young’s moduli of DPG particles on the micro and nano scales were measured by atomic force microscope for the first time.The mapping relationship among the formula of bulk gel,the Young’s moduli of the DPG particles and the final plugging performance were established.The results showed that when the Young’s moduli of the DPG particles increased from 82 to 328 Pa,the plugging rate increased significantly from 91.46%to 97.10%due to the distinctly enhanced stacking density and strength at this range.While when the Young’s moduli of the DPG particles surpassed 328 Pa,the further increase of plugging rate with the Young’s moduli of the DPG particles became insignificant.These results indicated that the improvement of plugging rate was more efficient by adjusting the Young’s moduli of the DPG particles within certain ranges,providing guidance for improving the macroscopic application properties of DPG systems in reservoir heterogeneity regulation.

NUMERICAL STUDY OF PARTICLE DISTRIBUTION IN WAKE OF LIQUID-PARTICLE FLOWS PAST A CIRCULAR CYLINDER USING DISCRETE VORTEX METHOD

Particle-laden water flows past a circular cylinder were numerically investigated. The discrete vortex method （DVM） was employed to evaluate the unsteady water flow fields and a Lagrangian approach was applied for tracking individual solid particles. A dispersion function was defined to represent the dispersion scale of the particle. The wake vortex patterns, the distributions and the time series of dispersion functions of particles with different Stokes numbers were obtained. Numerical results show that the particle distribution in the wake of the circular cylinder is closely related to the particle＇s Stokes number and the structure of wake vortices： （1） the intermediate sized particles with Stokes numbers, St, of 0.25, 1.0 and 4.0 can not enter the vortex cores and concen- trate near the peripheries of the vortex structures, （2） in the circular cylinder wake, the dispersion intensity of particles decreases as St is increased from 0.25 to 4.0.

Analysis of Equivalent Oxygen DifFusivity of Particle Dispersed Composites

This paper presents a new method to determine the equivalent oxygen diffusivities of particle dispersed composites. This method can be used to design FGM thermal barrier systems with the function of oxygen barrier. A qualitative explanation of the oxidation of nickel with the increment of zirconia contents in the composite samples can be accepted by this method. The values of equivalent oxygen diffusivities obtained with this method are in excellent agreement with those from the EMT method for the composites with ZrO2 particle dispersed phase when the volume fractions of dispersed phase are lower than 25%.

EFFECT OF DISPERSED PHASE PARTICLES ON ELECTRICAL CONDUCTION OF PEO-NaSCN

Fast ionic conductors are one kind of solid state material with ionic conductivity as high as that of melten salts or liquid electrolytes.Ionic conductivity is one of the important parameters for characterizing a fast ionic conductor.For a long time materialists and chemists have made great efforts in search of new fast ionic conductors with high ionic conductivity.In view of structure,they have synthesised silver and copper fast ionic conductors with so called open structures.But it is not so successful for searching more applicable alkaline fast ionic conductors.Since polymer has flexibility for making thin film,it concentrates attention on the polymer-alkaline salt complex.Fenton et al.have first reported poly(ethylene oxide) (PEO)-alkaline salt complex.Later on Armard et al.have investigated the electrical property of PEO-NaSCN.

Preparation of Fe_3O_4/PS Magnetic Particles by Dispersion Polymerization

Fe_3O_4/PS magnetic particles with core/shell structure has been prepared in the presence of Fe3O4 magnetic fluid in ethanol/water mixture.Magnetic particles with diameter size range from 5. 54 t0 187. 32 μm were obtained by different reaction conditions.Some parameters such as ethanol, PEG and monomer which affect particle size diameter and size distribution are discussed briefly in this paper.

THE SIZE EFFECT ON THE DISPERSION OF A PARTICLE IN A HOMOGENEOUS ISOTROPIC TURBULENCE

The mechanism of the response motion of a suspended particle to turbulent motion of its surrounding fluid is different according to si:e of turbulent eddies. The particle is dragged by the viscous force of large eddies, and meanwhile driven randomly by small eddies. Based on this understanding, the dispersion of a particle with finite size in a homogeneous isotropic turbulence is calculated in this study. Results show that there are two competing effects: when enhanced by the inertia of a particle, the long-term particle diffusivity is reduced by the finite size of the particle.

Effect of Particle Number Density on Wave Dispersion in a Two-Dimensional Yukawa System

Effect of the particle number density on the dispersion properties of longitudinal and transverse lattice waves in a two-dimensional Yukawa charged-dust system is investigated using molecular dynamics simulation. The dispersion relations for the waves are obtained. It is found that the frequencies of both the longitudinal and transverse dust waves increase with the density and when the density is sufficiently high a cutoff region appears at the short wavelength. With the increase of the particle number density, the common frequency tends to increase, and the sound speed of the longitudinal wave also increases, but that of the transverse wave remains low.

Evaluation of transmission risk of respiratory particles under different ventilation strategies in an elevator

People in elevators are at risk of respiratory infection because the elevator cabin is crowded and has poor ventilation.The exhaled particles may be inhaled by the susceptible person,deposited on the surface and suspended in the elevator,which can result in direct and indirect transmission.However,whether the air vent designs adopted in the elevator can effectively reduce the transmission risk of respiratory particles remains unknown.In this study,the dispersion of particles under four common ventilation strategies used in the commercial elevator was investigated by proven computational fluid dynamics(CFD)simulations.The flow field was simulated with the RNG κ-ξ turbulence model and the Lagrangian method was adopted to track particle trajectories.The effects of air vent layout and airflow rate on particle transmission were analyzed.We found that more than 50% of exhaled particles(average value)were suspended in the cabin and difficult to discharge under the investigated ventilation strategies.The deposited fraction of particles on the susceptible person reached up to 39.14% for infiltration ventilation,which led to a high risk of contact infection.Increasing the ventilation rate could not significantly reduce the inhalation proportion of particles due to the poor airflow distribution inside the elevator.A more proper ventilation strategy should be explored for the elevator to control transmission risk.

MORPHOLOGY EVOLUTION IN PTFE AS A FUNCTION OF MELT TIME AND TEMPERATURE——Ⅰ.HIGH MOLECULAR WEIGHT SINGLE-AND MULTI-MOLECULE FOLDED CHAIN SINGLE CRYSTALS AND BAND STRUCTURES

The effect of sintering dispersed dispersion and nano-emulsion particles of high molecular weightpolytetrafluoroethylene(PTFE)on a substrate as a function of“melt”time and temperature is described.Folded chain singlecrystals parallel to the substrate and as ribbons on-edge(with double striations),as well as bands,are produced for longersintering times;particle merger and diffusion of individual molecules,crystallizing as folded chain,single(or few)molecule,single crystals when“trapped”on the substrate by cooling occur for shorter sintering times.It is suggested the observedstructures develop with sintering time,in a mesomorphic melt.The structure of the nascent particles is also discussed.

Space–time correlations in turbulent flow: A review

This paper reviews some of the principal uses, over almost seven decades, of correlations, in both Eulerian and Lagrangian frames of reference, of properties of turbulent flows at variable spatial locations and variable time in- stants. Commonly called space-time correlations, they have been fundamental to theories and models of turbulence as well as for the analyses of experimental and direct numerical simulation turbulence data.

Effect of source location on particle dispersion in displacement ventilation rooms

A proposed computer model for predicting aerosol particle dispersion in indoor spaces was validated with experimental data found in the literature, and is then used to study the effect of the area and point source locations on particle dispersion in displacement ventilation （DV） rooms. The results show that aerosol source location has a strong impact on the spatial distribution and removal rate of indoor particles. Particle removal performance depends strongly on ventilation efficiency and particle deposition rate on indoor surfaces. Important consideration for both relative ventilation efficiency and deposition rate consists of the position of the aerosol source relative to the main airflow pattern and the occupied zone.

Reconstruction of Core-Shell Dispersed Particles in Impact Polypropylene Copolymer during Extrusion

We reported an approach to reconstruct the complex phase morphology of impact polypropylene copolymer （IPC） with core-shell dispersed particles and to optimize its toughness in approximate shear condition. The molten-state annealing results indicate that the phase structure with core-shell dispersed particles is unstable and could be completely destroyed by static annealing, resulting in the degradation of impact strength. By using a co-rotating twin screw extruder, we found that the dispersed particle with core-shell structure could be rebuilt in appropriate condition with the recovery of excellent impact strength due to both the huge interfacial tension during solidification and the great difference in viscosity of components. Results reveal that almost all the extruded IPCs show the impact strength 60%-90% higher than that of annealed IPCs at room temperature. And the twice-extruded IPC shows the highest impact strength, 446% higher than that of IPC annealed for 30 min. As for low temperature tests, the impact strength of extruded IPCs also increases by 33%-58%. According to adjusting the processing conditions including extrusion speed, extrusion frequency and temperature, an optimization of toughness was well established.

PDA MEASUREMENTS OF TWO-PHASE FLOW STRUCTURE AND PARTICLE DISPERSION FOR A PARTICLE-LADEN JET IN CROSSFLOW

The two-phase flow structure and particle dispersion for a dilute particle-laden jet in crossflow （JICF） were experimentally investigated by means of Phase Doppler Anemometry （PDA） measurement. The two-phase flow experiments were conducted for different flow conditions and solid particle parameters, including the ratio of the jet velocity to crossflow velocity, the particle size and mass loading. The experimental results indicate that the fine particles with the size of 70 micron and the mass loading of 0.05% have a minor influence on the mean and fluctuation velocity fields of the two-phase JICF. However, the fine particle transport by the two-phase JICF is dominantly and preferentially affected by the shear layer vortices and exhibits a somewhat enhanced dispersion as compared to the fluid. For the coarse particles with the particle size ranging from 300 micron to 700 micron and the mass loading less than 0.16%, the effect of the particle parameters on the fluid phase is associated with both the anisotropic properties of the flow field and the trajectory deviation of the settling particles from the fluid. Compared to the single-phase JICF, the two-phase JICF laden with the coarse particles is recognized to possess more pronounced mean velocity alteration and turbulence modulation of the fluid phase in the presence of the particles with the larger particle size and higher mass loading.

Coating of finely dispersed particles by two-fluid nozzle

Particle coatings are used extensively to generate dispersed solids with well-defined properties, e.g., to protect active ingredients, with most coating processes using core particles of a diameter larger than 200 μm. This work contributes to the development of a coating process for fine dispersed particles （diam- eter less than 50 μm） by combining two particle-formulation processes, namely, coating and spray drying. The feasibility of the operation is based on and demonstrated by the innovative application of a two-fluid nozzle. Experiments were conducted by using glass particles as core particles and sodium benzoate as the coating agent. The coating of finely dispersed particles is achieved by the spraying of particles and coating solution as a homogeneous suspension. The aim is to create droplets with only one contained particle at the nozzle outlet. After evaporation of the water in the droplet, a thin solid film is built on the particle surface. The suspension viscosity was measured and compared with empirical equations from the literature. The liquid-film thickness on the particle surface was calculated to predict the building of a uniform coating layer or agglomerates. In this study, the feasibility of pneumatic transport through the nozzle and an investigation of the process were illustrated. The agglomeration fraction and degree of coating of the particle surface were analyzed optically by scanning electron microscopy. In this way, the influence of different processes and suspension parameters on the product quality were determined.

POWER LAW DISTRIBUTION AND SELF-ORGANIZED CRITICALITY OF DISPERSED PARTICLES

Research on particulate characteristics has been an important frontier in physics and chemistry during the past decades. It has however been mostly focused on granular materials with short-range interactions. In this work, it was found that the power law of particle size distribution applied to the long-range interacting system of floating dust in air, from which we deduced that self-organized criticality might hold for floating dust just as granular materials with short-range interactions. This feature may reveal underlying kinetic mechanisms, important in dispersed particle systems. In industry, power law of size distribution of dispersed particles can be used to investigate the change of dust size, and the power law parameter could be taken as an important index for dust separation.

Effects of supply air temperature and inlet location on particle dispersion in displacement ventilation rooms

The effects of supply temperature and vertical location of inlet air on particle dispersion in a displacement ventilated （DV） room were numerically modeled with validation by experimental data from the literature. The results indicate that the temperature and vertical location of inlet supply air did not greatly affect the air distribution in the upper parts of a DV room, but could significantly influence the airflow pattern in the lower parts of the room, thus affecting the indoor air quality with contaminant sources located at the lower level, such as particles from working activities in an office. The numerical results also show that the inlet location would slightly influence the relative ventilation efficiency for the same air supply volume, but particle concentration in the breathing zone would be slightly lower with a low horizontal wall slot than a rectangular diffuser. Comparison of the results for two different supply temperatures in a DV room shows that, although lower supply temperature means less incoming air volume, since the indoor flow is mainly driven by buoyancy, lower supply temperature air could more efficiently remove passive sources （such as particles released from work activities in an office）. However, in the breathing zone it gives higher concentration as compared to higher supply air temperature. To obtain good indoor air quality, low supply air temperature should be avoided because concentration in the breathing zone has a stronger and more direct impact on human health.

The highly dispersed Co-based nanoparticles encapsulated into porous N-doping carbon polyhedral with the low content of Ru modification as a promising cathode catalyst for long-life Li-O_(2)batteries

Lithium(Li)-O_(2)batteries have triggered worldwide interest due to their ultrahigh theoretical energy density.However,it is a long shot for the grand-scale applications of Li-O_(2)battery at current stage owing to its significant polarization,inferior cycling life,and irreversible decomposition of Li2O_(2).Herein,a facile way of preparing the highly dispersed Co-based nanoparticles encapsulated into porous N-doping carbon polyhedral with the low content of Ru modification(LRu@HDCo-NC)is explored through the pyrolysis of Co/Zn based zeolitic imidazole frameworks(ZIFs)containing Ru-based ligands.Even with the very small amount of Ru introduction(1.8%),LRu@HDCo-NC still exhibits the superior oxygen evolution reaction/oxygen reduction reaction(OER/ORR)performance and also inhibits side reactions in Li-O_(2)battery because of the abundant pores,plentiful surface N heteroatoms,and highly dispersed metal-based sites which are induced by the volatilization of Zn,and conductive/stable carbon skeleton derived from ZIFs.When applied in Li-O_(2)batteries,LRu@HDCo-NC cathode delivers a high discharge capacity of 15,973 mAh·g^(-1)at 200 mA·g^(-1),good capacity retention at higher rate(12,362 mAh·g^(-1)at 500 mA·g^(-1))and outstanding stability for>300 cycles with low voltage polarization of<2.3 V under a cut-off capacity of 1,000 mAh·g^(-1)at 500 mA·g^(-1).More critically,a series of ex situ and in situ characterization technologies disclose that the LRu@HDCo-NC cathodes can effectively promote the reversible reactions in Li-O_(2)batteries.