In this study, the hydrolysis of the insecticide ethiprole in buffered solutions at pH 4.0, 7.0 and 9.0, respectively, and the degradation and adsorption-desorption behaviors of ethiprole in ifve agricultural soil sam...In this study, the hydrolysis of the insecticide ethiprole in buffered solutions at pH 4.0, 7.0 and 9.0, respectively, and the degradation and adsorption-desorption behaviors of ethiprole in ifve agricultural soil samples from China were investigated. The half-lives under anaerobic conditions were faster than that in the aerobic experiment. Ethiprole was relatively stable under both acidic and neutral conditions while it was readily hydrolyzed under alkaling condition. The sorption of ethiprole on ifve soils was well described by the linear and Freundlich equation and mainly governed by soil organic matter. The exothermic process of ethiprole adsorption can also be well explained by physical adsorption. A weak adsorption capacity was observed in all soils, which could readily lead to leaching problems.展开更多
In terms of viscoelasticity, the relevant theory of wave i n granular media is analyzed in this paper. Under the conditions of slight deforma tion of granules, wave equation, complex number expressions of propagation ...In terms of viscoelasticity, the relevant theory of wave i n granular media is analyzed in this paper. Under the conditions of slight deforma tion of granules, wave equation, complex number expressions of propagation vecto r and attenuation vector, attenuation coefficient expressions of longitudinal wa ve and transverse wave, etc, are analyzed and deduced. The expressions of attenu ation coefficients of viscoelastic longitudinal wave and transverse wave show th a t the attenuation of wave is related to frequency. The higher the frequency is, the more the attenuation is, which is tested by the laboratory experiment. In a ddi tion, the energy dissipation is related to the higher frequency wave that is abs orbed by granular media. The friction amongst granular media also increase the e nergy dissipation. During the flowing situation the expression of transmission f actor of energy shows that the granular density difference is the key factor whi ch leads to the attenuation of vibrating energy. This has been proved by the exp eriment results.展开更多
基金supported by the National Natural Science Foundation of China (31272070)
文摘In this study, the hydrolysis of the insecticide ethiprole in buffered solutions at pH 4.0, 7.0 and 9.0, respectively, and the degradation and adsorption-desorption behaviors of ethiprole in ifve agricultural soil samples from China were investigated. The half-lives under anaerobic conditions were faster than that in the aerobic experiment. Ethiprole was relatively stable under both acidic and neutral conditions while it was readily hydrolyzed under alkaling condition. The sorption of ethiprole on ifve soils was well described by the linear and Freundlich equation and mainly governed by soil organic matter. The exothermic process of ethiprole adsorption can also be well explained by physical adsorption. A weak adsorption capacity was observed in all soils, which could readily lead to leaching problems.
文摘In terms of viscoelasticity, the relevant theory of wave i n granular media is analyzed in this paper. Under the conditions of slight deforma tion of granules, wave equation, complex number expressions of propagation vecto r and attenuation vector, attenuation coefficient expressions of longitudinal wa ve and transverse wave, etc, are analyzed and deduced. The expressions of attenu ation coefficients of viscoelastic longitudinal wave and transverse wave show th a t the attenuation of wave is related to frequency. The higher the frequency is, the more the attenuation is, which is tested by the laboratory experiment. In a ddi tion, the energy dissipation is related to the higher frequency wave that is abs orbed by granular media. The friction amongst granular media also increase the e nergy dissipation. During the flowing situation the expression of transmission f actor of energy shows that the granular density difference is the key factor whi ch leads to the attenuation of vibrating energy. This has been proved by the exp eriment results.
