Sodium carbonate and carboxymethyl cellulose powders are compressed into two-component tablets with three mass ratios,97%:3%,95%:5% and 93%:7%.The dissolution tests for two-component tablets and reference pure sodium ...Sodium carbonate and carboxymethyl cellulose powders are compressed into two-component tablets with three mass ratios,97%:3%,95%:5% and 93%:7%.The dissolution tests for two-component tablets and reference pure sodium carbonate tablets are carried out at various temperatures.The dissolution process of each tablet is measured by electrical conductivity tracking method and the concentration of dissolved sodium carbonate is quanti fied with calibrated conductivity-concentration converting equation of sodium carbonate.The quanti fied dissolution data is fitted with both surface reaction model and diffusion layer model and the results clearly show that surface reaction model is suggested as the appropriate dissolution model for all measured tablets.Therefore,it is determined that carboxymethyl cellulose is a stable element to remain the dissolution mechanism of tablet unchanged.The dissolution rate constant quanti fied with surface reaction model presents that carboxymethyl cellulose-sodium carbonate two-component tablets obtain signi ficant higher dissolution rate constant than pure sodium carbonate tablet and higher proportion of carboxymethyl cellulose leads to apparent higher dissolution rate constant.The results prove for the usage of carboxymethyl cellulose in most practical applications at a relative low-level,the effect of carboxymethyl cellulose is effective and positive for two-component tablet to enhance the dissolution process and improve dissolution rate constant and this effect is speculated coming from its dynamic physical transforming process in water including dilation and conglutination.展开更多
To obtain satisfactory joining between titanium alloys end stainless steel, it is of great significance to study the process of Ti-Fe eutectic reaction. The preliminary studies about the liquid forming, spreading end ...To obtain satisfactory joining between titanium alloys end stainless steel, it is of great significance to study the process of Ti-Fe eutectic reaction. The preliminary studies about the liquid forming, spreading end the structure of the contact reaction between pure Ti and pure Fe are carried out at 1 120℃ for different holding times in high-frequency induction heated vacuum furnace. The results show that for Fe（particle-like）/Ti（plate-like） contact reaction couples, owing to Fe＇s higher density then titanium＇s, the Fe/Ti eutectic reaction develops in the thickness direction of plate-like Ti, named ＂deposition effect＂. Then the eutectic reaction can be realized without the inter-diffusion between Ti end Fe atoms, so the formation rate of the liquid phase is very quick. For Ti （particle-like）/ Fe （plate-like） contact reaction couples, the eutectic reaction has a strong direction, i.e. the eutectic liquid is formed mostly at the Ti side, which leads to much dissolution of Ti particle end very little dissolution of the Fe base metal. It can be seen that the diffusion rate of Fe in Ti determines the whole process of the eutectic reaction, behaved as that the dissolution rate of Ti （particle-like）/ Fe （plate-like） is much lower then that of Fe（particle-like）/Ti（plate-like）, end the dissolution rate of Ti obeys the square root law. Whatever means the Ti, Fe are assembled by, only dissolution process can be founded, the spread phenomena is unobvious, which is concerned with the formation of the inter- metallic compounds end the ＂deposition effect＂ of Fe.展开更多
Hydrothermal ore zoning is a transport-reaction problem in which infiltration is the principal Prcness of transport and dissolution/Precipitation is the Principal process of chemical reactions.Neglecting diffusion an...Hydrothermal ore zoning is a transport-reaction problem in which infiltration is the principal Prcness of transport and dissolution/Precipitation is the Principal process of chemical reactions.Neglecting diffusion and ion exchange/adsorption would not affect the basic attributes of hydrothermal ore zoning. Hydrothermal ore zoning belongs essentially to infiltration metasomatic zoning, it results from the formation and propagation of dissolution/precipitation waves through Permeable media. The authors apply the theory of coupled infiltration and dissolution/precipitation reactions in Physicochemical hydrodynamics to studying the structural characteristics of dissolution/precipitation waves, and apply furthermore the coherence principle in dynamic theory of multicomponent coupled systems to revealing the dynamic mechanisms of their formation. The results of investigation verify and develop . C. 's theory of infiltration metasomatic zoning,on the one hand, raising it from the qualitative, equilibrium thermodynamic basis to the quantitative dynamic level;on the other hand, and more importantly, applying theories of Physicochemical hydrodynamics and dynamics of multicomponent coupled systems to bringing to light the dynamic mechanisms of formation of the structure of hydrothermal ore zoning, and advancing a theory of hydrothermal ore zoning, putting forward new ideas on the nature of the problem of hydrothermal ore zoning, the essence of hydrothermal ore zoning and the structural characteristics and mechanisms of formation of hydrothermal ore zoning.展开更多
基金the Institute of Particle and Science Engineering,University of Leeds and Procter & Gamble Newcastle Innovation Centre(UK) for partially funding the project
文摘Sodium carbonate and carboxymethyl cellulose powders are compressed into two-component tablets with three mass ratios,97%:3%,95%:5% and 93%:7%.The dissolution tests for two-component tablets and reference pure sodium carbonate tablets are carried out at various temperatures.The dissolution process of each tablet is measured by electrical conductivity tracking method and the concentration of dissolved sodium carbonate is quanti fied with calibrated conductivity-concentration converting equation of sodium carbonate.The quanti fied dissolution data is fitted with both surface reaction model and diffusion layer model and the results clearly show that surface reaction model is suggested as the appropriate dissolution model for all measured tablets.Therefore,it is determined that carboxymethyl cellulose is a stable element to remain the dissolution mechanism of tablet unchanged.The dissolution rate constant quanti fied with surface reaction model presents that carboxymethyl cellulose-sodium carbonate two-component tablets obtain signi ficant higher dissolution rate constant than pure sodium carbonate tablet and higher proportion of carboxymethyl cellulose leads to apparent higher dissolution rate constant.The results prove for the usage of carboxymethyl cellulose in most practical applications at a relative low-level,the effect of carboxymethyl cellulose is effective and positive for two-component tablet to enhance the dissolution process and improve dissolution rate constant and this effect is speculated coming from its dynamic physical transforming process in water including dilation and conglutination.
文摘To obtain satisfactory joining between titanium alloys end stainless steel, it is of great significance to study the process of Ti-Fe eutectic reaction. The preliminary studies about the liquid forming, spreading end the structure of the contact reaction between pure Ti and pure Fe are carried out at 1 120℃ for different holding times in high-frequency induction heated vacuum furnace. The results show that for Fe（particle-like）/Ti（plate-like） contact reaction couples, owing to Fe＇s higher density then titanium＇s, the Fe/Ti eutectic reaction develops in the thickness direction of plate-like Ti, named ＂deposition effect＂. Then the eutectic reaction can be realized without the inter-diffusion between Ti end Fe atoms, so the formation rate of the liquid phase is very quick. For Ti （particle-like）/ Fe （plate-like） contact reaction couples, the eutectic reaction has a strong direction, i.e. the eutectic liquid is formed mostly at the Ti side, which leads to much dissolution of Ti particle end very little dissolution of the Fe base metal. It can be seen that the diffusion rate of Fe in Ti determines the whole process of the eutectic reaction, behaved as that the dissolution rate of Ti （particle-like）/ Fe （plate-like） is much lower then that of Fe（particle-like）/Ti（plate-like）, end the dissolution rate of Ti obeys the square root law. Whatever means the Ti, Fe are assembled by, only dissolution process can be founded, the spread phenomena is unobvious, which is concerned with the formation of the inter- metallic compounds end the ＂deposition effect＂ of Fe.
文摘Hydrothermal ore zoning is a transport-reaction problem in which infiltration is the principal Prcness of transport and dissolution/Precipitation is the Principal process of chemical reactions.Neglecting diffusion and ion exchange/adsorption would not affect the basic attributes of hydrothermal ore zoning. Hydrothermal ore zoning belongs essentially to infiltration metasomatic zoning, it results from the formation and propagation of dissolution/precipitation waves through Permeable media. The authors apply the theory of coupled infiltration and dissolution/precipitation reactions in Physicochemical hydrodynamics to studying the structural characteristics of dissolution/precipitation waves, and apply furthermore the coherence principle in dynamic theory of multicomponent coupled systems to revealing the dynamic mechanisms of their formation. The results of investigation verify and develop . C. 's theory of infiltration metasomatic zoning,on the one hand, raising it from the qualitative, equilibrium thermodynamic basis to the quantitative dynamic level;on the other hand, and more importantly, applying theories of Physicochemical hydrodynamics and dynamics of multicomponent coupled systems to bringing to light the dynamic mechanisms of formation of the structure of hydrothermal ore zoning, and advancing a theory of hydrothermal ore zoning, putting forward new ideas on the nature of the problem of hydrothermal ore zoning, the essence of hydrothermal ore zoning and the structural characteristics and mechanisms of formation of hydrothermal ore zoning.
