Designing ultrastable P2/O3-type layered oxides for sodium ion batteries by regulating Na distribution and oxygen redox chemistry

P2/O3-type Ni/Mn-based layered oxides are promising cathode materials for sodium-ion batteries(SIBs)owing to their high energy density.However,exploring effective ways to enhance the synergy between the P2 and 03 phases remains a necessity.Herein,we design a P2/O3-type Na_(0.76)Ni_(0.31)Zn_(0.07)Mn_(0.50)Ti_(0.12)0_(2)(NNZMT)with high chemical/electrochemical stability by enhancing the coupling between the two phases.For the first time,a unique Na*extraction is observed from a Na-rich O3 phase by a Na-poor P2 phase and systematically investigated.This process is facilitated by Zn^(2+)/Ti^(4+)dual doping and calcination condition regulation,allowing a higher Na*content in the P2 phase with larger Na^(+)transport channels and enhancing Na transport kinetics.Because of reduced Na^(+)in the O3 phase,which increases the difficulty of H^(+)/Na^(+) exchange,the hydrostability of the O3 phase in NNZMT is considerably improved.Furthermore,Zn^(2+)/Ti^(4+)presence in NNZMT synergistically regulates oxygen redox chemistry,which effectively suppresses O_(2)/CO_(2) gas release and electrolyte decomposition,and completely inhibits phase transitions above 4.0 V.As a result,NNZMT achieves a high discharge capacity of 144.8 mA h g^(-1) with a median voltage of 3.42 V at 20 mA g^(-1) and exhibits excellent cycling performance with a capacity retention of 77.3% for 1000 cycles at 2000 mA g^(-1).This study provides an effective strategy and new insights into the design of high-performance layered-oxide cathode materials with enhanced structure/interface stability forSIBs.

Effect of stimulated Brillouin scattering on the gain saturation of distributed fiber Raman amplifier and its suppression by phase modulation

For distributed fiber Raman amplifiers（DFRAs）, stimulated Brillouin scattering（SBS） can deplete the pump once occurring and consequently generate gain saturation. On the basis of such a theory, theoretical gain saturation powers in DFRAs with various pump schemes are obtained by calculating SBS thresholds in them, and the experimental results show that they are in excellent agreement with the calculation results. The saturation power of the DFRA with a 300 m W forward pump is as low as 0 d Bm, which needs to be enhanced by phase modulation, and the effect is quantitatively studied. A simple model taking both modulation frequency and index into consideration is presented by introducing a correction factor to evaluate the effect of phase modulation on the enhancement of saturation power. Experimentally, it is shown that such a correction factor decreases as the modulation frequency increases and approaches zero when the modulation frequency becomes high enough. In particular, a phase modulation with a modulation frequency of 100 MHz and a modulation index of 1.380 can enhance the saturation power by 4.44 d B, and the correction factor is 0.25 d B, in which the modulation frequency is high enough. Additionally, the factor is 1.767 d B for the modulation frequency of 25 MHz. On this basis,phase modulations with various indexes and a fixed frequency of 25 MHz are adopted to verify the modified model, and the results are positive. To obtain the highest gain saturation power, the model is referable. The research results provide a guide for the design of practical DFRAs.

Fabrication of 32 Gb/s Electroabsorption Modulated Distributed Feedback Lasers by Selective Area Growth Technology

A 32 Gb/s monolithically integrated electroabsorption modulated laser is fabricated by selective area growth technology. The threshold current of the device is below 13mA. The output power exceeds 10mW at 0V bias when the injection current of the distributed feedback laser is 100mA at 25℃. The side mode suppression ratio is over 50 dB. A 32Gb/s eye diagram is measured with a 3.SVpp nonreturn-to-zero pseudorandom modulation signal at -2.3 V bias. A clearly opening eyediagram with a dynamic extinction ratio of 8.01 dB is obtained.

Measurement and Characterization of Microwave Interaction between Integrated Distributed Feedback Laser Diode and Electro-Absorption Modulator

Integrated electro-absorption-modulated distributed feedback laser diodes(EMLs)are attracting much interest in optical communications for the advantages of a compact structure,low power consumption,and high-speed modulation.In integrated EML,the microwave interaction between the distributed feedback laser diode(DFB-LD)and the electro-absorption modulator(EAM)has a nonnegligible influence on the modulation performance,especially at the high-frequency region.In this paper,integrated EML was investigated as a three-port network with two electrical inputs and a single optical output,where the scattering matrix of the integrated device was theoretically deduced and experimentally measured.Based on the theoretical model and the measured data,the microwave equivalent circuit model of the integrated device was established,from which the microwave interaction between DFB-LD and EAM was successfully extracted.The results reveal that the microwave interaction within integrated EML contains both the electrical isolation and optical coupling.The electrical isolation is bidirectional while the optical coupling is directional,which aggravates the microwave interaction in the direction from DFB-LD to EAM.

虚拟I/O模块在DCS以太网通信接口模块上的实现

为减少硬件模块的重复开发,在保留原DCS软硬件系统架构不变的基础上,在以太网通信接口模块硬件上虚拟不同的I/O模块。虚拟I/O模块与硬点I/O模块具有一致的输入、输出及参数属性,且组态方式和产物格式一致。同一以太网通信模块上可在不同的虚拟I/O槽位上配置不同的虚拟I/O模块,如Modbus TCP虚拟I/O模块和GOOSE虚拟I/O模块,进而在同一硬件实现不同的通信功能。虚拟I/O模块的使用一方面减少了DCS系统硬件模块的种类,简化备品备件,另一方面也提高了通信扩展的灵活性和便利性。

Sparse Rev-Shift Coded Modulation with Novel Overhead Bound

To provide reliability in distributed systems,combination property(CP)is desired,where k original packets are encoded into n≥k packets and arbitrary k are sufficient to reconstruct all the original packets.Shift-and-add(SA)encoding combined with zigzag decoding(ZD)obtains the CP-ZD,which is promising to reap low computational complexity in the encoding/decoding process of these systems.As densely coded modulation is difficult to achieve CP-ZD,research attentions are paid to sparse coded modulation.The drawback of existing sparse CP-ZD coded modulation lies in high overhead,especially in widely deployed setting m<k,where m≜n−k.For this scenario,namely,m<k,a sparse reverseorder shift(Rev-Shift)CP-ZD coded modulation is designed.The proof that Rev-Shift possesses CP-ZD is provided.A lower bound for the overhead,as far as we know is the first for sparse CP-ZD coded modulation,is derived.The bound is found tight in certain scenarios,which shows the code optimality.Extensive numerical studies show that compared to existing sparse CP-ZD coded modulation,the overhead of Rev-Shift reduces significantly,and the derived lower bound is tight when k or m approaches 0.

An autobias control system for the electro optic modulator used in a quantum key distribution system

In a quantum key distribution system, it is crucial to keep the extinction ratio of the coherent pulses stable. This means that the direct current bias point of the electro-optic modulator （EOM） used for generating coherent pulses must be locked. In this paper, an autobias control system based on a lock-in-amplifier for the EOM is introduced. Its drift information extracting theory and control method are analyzed comprehensively. The long term drift of the extinction ratio of the coherent pulses is measured by a single photon detector, which indicates that the autobias control system is effective for stabilizing the bias point of the EOM.

Modulation bandwidth enhancement in monolithic integrated two-section DFB lasers based on the detuned loading effect

Modulation bandwidth enhancement in a directly modulated two-section distributed feedback(TS-DFB)laser based on a detuned loading effect is investigated and experimentally demonstrated.The results show that the 3-dB bandwidth of the TS-DFB laser is increased to 17.6 GHz and that chirp parameter can be reduced to 2.24.Compared to the absence of a detuned loading effect,there is a 4.6 GHz increase and a 2.45 reduction,respectively.After transmitting a 10 Gb/s non-return-to-zero(NRZ)signal through a 5-km fiber,the modulation eye diagram still achieves a large opening.Eight-channel laser arrays with precise wavelength spacing are fabricated.Each TS-DFB laser in the array has side mode suppression ratios(SMSR)>49.093 dB and the maximum wavelength residual<0.316 nm.

Deterministic quantum key distribution based on Gaussian-modulated EPR correlations

This paper proposes a deterministic quantum key distribution scheme based on Gaussian-modulated continuous variable EPR correlations. This scheme can implement fast and efficient key distribution. The security is guaranteed by continuous variable EPR entanglement correlations produced by nondegenerate optical parametric amplifier. For general beam splitter eavesdropping strategy, the secret information rate ΔI = I（α, β）-I（α, ε） is calculated in view of Shannon information theory. Finally the security analysis is presented.

Locally Minimum Storage Regenerating Codes in Distributed Cloud Storage Systems

In distributed cloud storage systems, inevitably there exist multiple node failures at the same time. The existing methods of regenerating codes, including minimum storage regenerating(MSR) codes and minimum bandwidth regenerating(MBR) codes, are mainly to repair one single or several failed nodes, unable to meet the repair need of distributed cloud storage systems. In this paper, we present locally minimum storage regenerating(LMSR) codes to recover multiple failed nodes at the same time. Specifically, the nodes in distributed cloud storage systems are divided into multiple local groups, and in each local group(4, 2) or(5, 3) MSR codes are constructed. Moreover, the grouping method of storage nodes and the repairing process of failed nodes in local groups are studied. Theoretical analysis shows that LMSR codes can achieve the same storage overhead as MSR codes. Furthermore, we verify by means of simulation that, compared with MSR codes, LMSR codes can reduce the repair bandwidth and disk I/O overhead effectively.

An Improved Submodule Unified Pulse Modulation Scheme for a Hybrid Modular Multilevel Converter

This paper presents an improved submodule unified pulse width modulation(SUPWM)scheme for a hybrid modular multilevel converter(MMC)composed of half-bridge submodules(HBSMs)and full-bridge submodules(FBSMs).The proposed SUPWM scheme can achieve an output voltage of(2N+1)(where N is the number of submodules in each arm)levels,which is the same as that of the carrier-phase-shifted PWM(CPSPWM)scheme.Meanwhile,the proposed SUPWM scheme can alleviate the uneven loss distributions between the left leg and right leg in FBSMs of the hybrid MMC.Moreover,the capacitor voltages of the sub-modules can be well balanced without complicated closed-loop voltage balancing controllers.The validity of the proposed SUPWM scheme is verified by both the simulated and experimental results.

Thermo-hydraulic analysis for sub-module of Chinese HCSB TBM design

Thermo-hydraulic calculation and analysis for sub-module of Chinese HCSB TBM were carried out using FE code ANSYS. Results indicate that temperature distribution in materials used in sub-module is reasonable and acceptable.

面向边缘计算的TCA1C DDoS检测模型

边缘计算弥补了传统云计算数据传输开销大的不足,但边缘网络中存储和计算资源受限的特殊性限制了其部署复杂安全算法的能力,更易受到分布式拒绝服务(DDoS)攻击。针对目前边缘网络中DDoS攻击检测方法性能不高、未对卸载任务分类处理、对多属性的流量处理能力弱的问题,提出一种基于任务分类的Attention-1D-CNN DDoS检测模型TCA1C,对通信链路中的流量按不同的卸载任务进行分类,使单个任务受到攻击时不会影响整个链路中计算任务卸载的安全性,再对同一任务下的流量提取属性值并进行归一化处理。处理后的数据输入到Attention-1D-CNN,通道Attention和空间Attention学习数据特征对DDoS检测的贡献度,利用筛选函数剔除低于特征阈值的冗余信息,降低模型学习过程的复杂度,使模型快速收敛。仿真结果表明:TCA1C模型在缩短DDoS检测所用时间的情况下,检测准确率高达99.73%,检测性能优于DT、ELM、LSTM和CNN;当多个卸载任务在面临特定攻击概率时,卸载任务分类能有效降低不同任务的相互影响,使终端设备的计算任务在卸载过程中保持较高的安全性。

Passive decoy-state quantum key distribution using weak coherent pulses with modulator attenuation

Passive decoy-state quantum key distribution is more desirable than the active one in some scenarios. It is also affected by the imperfections of the devices. In this paper, the influence of modulator attenuation on the passive decoy-state method is considered. We introduce and analyze the unbalanced Mach-Zehnder interferometer, briefly, and combining with the virtual source and imaginary unitary transformation, we characterize the passive decoy-state method using a weak coherent photon source with modulator attenuation. According to the attenuation parameter 6, the pass efficiencies are given. Then, the key generation rate can be acquired. From numerical simulations, it can be seen that modulator attenuation has a non- negligible influence on the performance of passive-state QKD protocol. Based on the research, the analysis method of virtual source and imaginary unitary transformation are preferred in analyzing passive decoy state protocol, and the passive decoy-state method is better than the active one and is close to the active vacuum ＋ weak decoy state under the condition of having the same modulator attenuation.

Deterministic Quantum Key Distribution Using Gaussian-Modulated Squeezed States

A continuous variable ping-pong scheme,which is utilized to generate deterministic private key,is proposed. The proposed scheme is implemented physically by using Gaussian-modulated squeezed states.The deterministic characteristic, i.e.,no basis reconciliation between two parties,leads a nearly two-time efficiency comparing to the standard quantum key distribution schemes.Especially,the separate control mode does not need in the proposed scheme so that it is simpler and more available than previous ping-pong schemes.The attacker may be detected easily through the fidelity of the transmitted signal,and may not be successful in the beam splitter attack strategy.

Phase shift effects of radio-frequency bias on ion energy distribution in continuous wave and pulse modulated inductively coupled plasmas

A retarding field energy analyzer（RFEA） is used to measure the time-averaged ion energy distributions（IEDs） on the substrate in both continuous wave（CW） and synchronous pulse modulated radio-frequency（RF） inductively coupled Ar plasmas（ICPs）.The effects of the phase shift θ between the RF bias voltage and the RF source on the IED is investigated under various discharge conditions.It is found that as θ increases from 0 to π,the IED moves towards the low-energy side,and its energy width becomes narrower.In order to figure out the physical mechanism,the voltage waveforms on the substrate are also measured.The results show that as θ increases from 0 to π,the amplitude of the voltage waveform decreases and,meanwhile,the average sheath potential decreases as well.Specifically,the potential drop in the sheath on the substrate exhibits a maximum value at the same phase（i.e.,θ = 0） and a minimum value at the opposite phase（i.e.,θ = π）.Therefore,when ions traverse across the sheath region above the substrate,they obtain less energies at lower sheath potential drop,leading to lower ion energy.Besides,as θ increases from π to 2π,the IEDs and their energy widths change reversely.

MoS_(2)核壳球上氧掺杂的动力学调制及其电化学分解水效应

在氩气气氛中900℃煅烧前驱物MoS_(2)核壳超级球得到MoS_(2)核壳球。在升温速率为20、10、5、2℃·min^(-1)时,MoS_(2)核壳球上氧掺杂量分别从前驱物的23.1%降低到17.6%、10.8%、5.5%、6.2%。结果表明较低的升温速率可以导致更低的氧掺杂量。基于前驱物特殊的准分子超晶格结构,提出了原位阴离子交换反应机理,以深入理解MoS_(2)核壳球上氧掺杂的动力学调制机理。电化学性能研究表明通过调制氧掺杂量可以有效改善MoS_(2)核壳球电化学分解水的性能。

An Anti-Poisoning Attack Method for Distributed AI System

In distributed AI system, the models trained on data from potentially unreliable sources can be attacked by manipulating the training data distribution by inserting carefully crafted samples into the training set, which is known as Data Poisoning. Poisoning will to change the model behavior and reduce model performance. This paper proposes an algorithm that gives an improvement of both efficiency and security for data poisoning in a distributed AI system. The past methods of active defense often have a large number of invalid checks, which slows down the operation efficiency of the whole system. While passive defense also has problems of missing data and slow detection of error source. The proposed algorithm establishes the suspect hypothesis level to test and extend the verification of data packets and estimates the risk of terminal data. It can enhance the health degree of a distributed AI system by preventing the occurrence of poisoning attack and ensuring the efficiency and safety of the system operation.