Combustion kinetics of the hydrochar was investigated using a multi-Gaussian-distributed activation energy model(DAEM)to ex-pand the knowledge on the combustion mechanisms.The results demonstrated that the kinetic par...Combustion kinetics of the hydrochar was investigated using a multi-Gaussian-distributed activation energy model(DAEM)to ex-pand the knowledge on the combustion mechanisms.The results demonstrated that the kinetic parameters calculated by the multi-Gaussian-DAEM accurately represented the experimental conversion rate curves.Overall,the feedstock combustion could be divided into four stages:the decomposition of hemicellulose,cellulose,lignin,and char combustion.The hydrochar combustion could in turn be divided into three stages:the combustion of cellulose,lignin,and char.The mean activation energy ranges obtained for the cellulose,lignin,and char were 273.7-292.8,315.1-334.5,and 354.4-370 kJ/mol,respectively,with the standard deviations of 2.1-23.1,9.5-27.4,and 12.1-22.9 kJ/mol,re-spectively.The cellulose and lignin contents first increased and then decreased with increasing hydrothermal carbonization(HTC)temperature,while the mass fraction of char gradually increased.展开更多
通过热重红外联用研究煤与污泥不同掺混比例样品的燃烧特性以及气体排放特性,分别利用Coats-Redfern模型和分布式活化能模型(distributed activation energy model,DAEM)对污泥与煤的掺烧过程进行动力学分析,研究2种模型的适用性。结果...通过热重红外联用研究煤与污泥不同掺混比例样品的燃烧特性以及气体排放特性,分别利用Coats-Redfern模型和分布式活化能模型(distributed activation energy model,DAEM)对污泥与煤的掺烧过程进行动力学分析,研究2种模型的适用性。结果表明,与单一煤样相比,10%掺混比例样品的着火点降低了11℃,可燃性能改善,稳燃性能提高,综合燃烧特性指数提高。此外,10%掺混比例样品燃烧过程中NO和SO 2的吸收峰比单一煤样的吸收峰低,说明一定比例掺混煤和污泥可以降低污染物的排放浓度。另外DAEM的拟合相关性系数比Coats-Redfern模型更高,表明DAEM更加适用于污泥与煤混合燃烧过程动力学分析。展开更多
Carbon fiber is a kind of new polymer material with excellent mechanical properties and being applied widely.The process of carbon fiber prepared by bamboo tar,including extraction,condensation,spinning,oxidation and ...Carbon fiber is a kind of new polymer material with excellent mechanical properties and being applied widely.The process of carbon fiber prepared by bamboo tar,including extraction,condensation,spinning,oxidation and carbonation,is influenced by the pyrolysis kinetics significantly.In this paper,the thermogravimetric analysis(TGA)of bamboo tar produced in the process of pyrolysis and gasification of the bamboo which is known as Phylostachys sulphurea,was analyzed by the distributed activation energy model(DAEM)to understand the kinetic properties and parameters of bamboo tar.The thermogravimetric analysis of bamboo tar which is used as the raw material of carbon fiber was conducted under 5 different heating rates(i.e.5,10,15,30 and 50℃/min,etc.)in nitrogen atmosphere.The results show that the activation energy of bamboo tar and the exponential factor increased significantly with the increase of the heating rate,and the low heating rate is advantageous to the extraction of bamboo tar solvent and the thermal polycondensation,which can provide scientific reference for the optimization of carbon fiber technology.The thermal weight results show that the temperature range of bamboo tar being decomposed rapidly is 213℃-410℃.The ranges of the activation energy were calculated by DAEM,which have small difference in comparisons with five heating rates when the conversion rate is at 0.1-0.6 and the average value of the activation energy is 119 kJ/mol.The stability range of the activation energy is enlarged when the conversion rate is greater than 0.6 and heating rate increases.展开更多
基金the National Nat-ural Science Foundation of China(Nos.52074029,51804026)the USTB-NTUT Joint Research Program(No.06310063)Chuan Wang would like to acknowledge the funding support from Vinnova(dnr:2017-01327).
文摘Combustion kinetics of the hydrochar was investigated using a multi-Gaussian-distributed activation energy model(DAEM)to ex-pand the knowledge on the combustion mechanisms.The results demonstrated that the kinetic parameters calculated by the multi-Gaussian-DAEM accurately represented the experimental conversion rate curves.Overall,the feedstock combustion could be divided into four stages:the decomposition of hemicellulose,cellulose,lignin,and char combustion.The hydrochar combustion could in turn be divided into three stages:the combustion of cellulose,lignin,and char.The mean activation energy ranges obtained for the cellulose,lignin,and char were 273.7-292.8,315.1-334.5,and 354.4-370 kJ/mol,respectively,with the standard deviations of 2.1-23.1,9.5-27.4,and 12.1-22.9 kJ/mol,re-spectively.The cellulose and lignin contents first increased and then decreased with increasing hydrothermal carbonization(HTC)temperature,while the mass fraction of char gradually increased.
文摘通过热重红外联用研究煤与污泥不同掺混比例样品的燃烧特性以及气体排放特性,分别利用Coats-Redfern模型和分布式活化能模型(distributed activation energy model,DAEM)对污泥与煤的掺烧过程进行动力学分析,研究2种模型的适用性。结果表明,与单一煤样相比,10%掺混比例样品的着火点降低了11℃,可燃性能改善,稳燃性能提高,综合燃烧特性指数提高。此外,10%掺混比例样品燃烧过程中NO和SO 2的吸收峰比单一煤样的吸收峰低,说明一定比例掺混煤和污泥可以降低污染物的排放浓度。另外DAEM的拟合相关性系数比Coats-Redfern模型更高,表明DAEM更加适用于污泥与煤混合燃烧过程动力学分析。
基金This work was financially supported by the National Natural Science Foundation of China(551376056)“Study of regulation mechanisms and photo-thermal properties of photosynthetic hydrogen production under the condition of multiphase biomass flow”.
文摘Carbon fiber is a kind of new polymer material with excellent mechanical properties and being applied widely.The process of carbon fiber prepared by bamboo tar,including extraction,condensation,spinning,oxidation and carbonation,is influenced by the pyrolysis kinetics significantly.In this paper,the thermogravimetric analysis(TGA)of bamboo tar produced in the process of pyrolysis and gasification of the bamboo which is known as Phylostachys sulphurea,was analyzed by the distributed activation energy model(DAEM)to understand the kinetic properties and parameters of bamboo tar.The thermogravimetric analysis of bamboo tar which is used as the raw material of carbon fiber was conducted under 5 different heating rates(i.e.5,10,15,30 and 50℃/min,etc.)in nitrogen atmosphere.The results show that the activation energy of bamboo tar and the exponential factor increased significantly with the increase of the heating rate,and the low heating rate is advantageous to the extraction of bamboo tar solvent and the thermal polycondensation,which can provide scientific reference for the optimization of carbon fiber technology.The thermal weight results show that the temperature range of bamboo tar being decomposed rapidly is 213℃-410℃.The ranges of the activation energy were calculated by DAEM,which have small difference in comparisons with five heating rates when the conversion rate is at 0.1-0.6 and the average value of the activation energy is 119 kJ/mol.The stability range of the activation energy is enlarged when the conversion rate is greater than 0.6 and heating rate increases.
