Determination of Equilibrium Distribution Coefficients of Impurities in Phosphorus by Vertical Zone-melting Technique

The equilibrium distribution coefficients of 12 impurities （As,Fe,Ca,Co,Al,Cr,Cu,Mg,Mn,Ni,Pb,Zn） in phosphorus were obtained by measuring their effective distribution coefficients at zone travel rate of 3,5,10,15,and 20 mm·h-1 in the purification process with vertical zone-melting technique.The results indicate that the method is reliable.The equilibrium distribution coefficients are below 0.3 except arsenic.

Theoretical calculation and experimental study on the load distribution coefficient (LDC) of three-ring gear reducer

In this paper, primary manufacturing and assembling errors of three-ring gear reducer （TRGR） are analyzed. TRGR is a new transmission type whose eccentric phase difference between middle ring plate and side ring plates is 120°, Its mass of middle ring plate is equal to that of side ring plate or 180°, and its inass of middle ring plate is twice of that of side ring plate, which affects load distribution between ring plates. The primary manufacturing and assembling errors include eccentric error of eccentric sheath E111, internal gear plate E1 and output external gear E11. A new theoretical method is presented in this paper, which converts load on ring plates into the dedendum bending stress of ring plate to calculate load distribution coefficient （ LDC ）, by means of gap element method （GEM）, one of finite element method （FEM）. The theoretical calculation and experimental study, which measures ring plate dedendum bending stress by means of sticking strain gauges on the dedendum of middle ring plate internal gear and side ring plate internal gears, are presented. The theoretical calculation and comparison with experiment result of LDC are implemented an two kinds of three-ring gear reducers whose eccentric phase difference between eccentric sheaths is 120° and 180°respectively. The research indicates that the result of theoretical calculation is consistent with that of experimental study. That is to say, the theoretical calculation method is feasible.

Study on Pressure Coefficient Distribution of the Airship Zhiyuan-1

A wind tunnel tests with different configurations,pitch and yaw angles were performed to study the wind load characteristics of the rigid model of the airship Zhiyuan-1. The rigid model was aimed to simulate a technical demonstrating stratospheric airship named Zhiyuan-1 according to the similarity principle of geometric and Reynolds number. Based on the results of wind tunnel test,the features of pressure coefficient distributions on the surface of the airship were described. It was indicated that the fins and the gondola of airship hardly have the effect on the pressure distribution on the surface of airship,but have obviously effect on the local areas near the fins and the gondola.

CLASSICAL LIMITS FOR THE COEFFICIENT OF VARIATION FOR THE NORMAL DISTRIBUTION

The exact classical limits for the coefficient of variation c for the normal distribution are derived. The hand-calculating approximated classical limits for c having high accuracy are given to meet practical engineering needs. Using Odeh and Owen's computational method and Brent's algorithm, the tables for the r-upper exact classical limits of coefficient of variation for normal distribution are calculated for the different confidence coefficient y, the sample size n=1(1)30,40,60,120, the sample coefficient of variation c=0.01(0.01)0.20. It is shown that if n<8,c<0.20, then the V -upper exact classical limits cu for c are slightly higher than the exact fiducial limits cu,F for c if. n>8, c<0.02,then cu-cu,f<5x10-6

Temperature field model in surface grinding: a comparative assessment

Grinding is a crucial process in machining workpieces because it plays a vital role in achieving the desired precision and surface quality.However,a significant technical challenge in grinding is the potential increase in temperature due to high specific energy,which can lead to surface thermal damage.Therefore,ensuring control over the surface integrity of workpieces during grinding becomes a critical concern.This necessitates the development of temperature field models that consider various parameters,such as workpiece materials,grinding wheels,grinding parameters,cooling methods,and media,to guide industrial production.This study thoroughly analyzes and summarizes grinding temperature field models.First,the theory of the grinding temperature field is investigated,classifying it into traditional models based on a continuous belt heat source and those based on a discrete heat source,depending on whether the heat source is uniform and continuous.Through this examination,a more accurate grinding temperature model that closely aligns with practical grinding conditions is derived.Subsequently,various grinding thermal models are summarized,including models for the heat source distribution,energy distribution proportional coefficient,and convective heat transfer coefficient.Through comprehensive research,the most widely recognized,utilized,and accurate model for each category is identified.The application of these grinding thermal models is reviewed,shedding light on the governing laws that dictate the influence of the heat source distribution,heat distribution,and convective heat transfer in the grinding arc zone on the grinding temperature field.Finally,considering the current issues in the field of grinding temperature,potential future research directions are proposed.The aim of this study is to provide theoretical guidance and technical support for predicting workpiece temperature and improving surface integrity.

Boron removal in purifying metallurgical grade silicon by CaO-SiO_2 slag refining

Boron removal from metallurgical grade silicon （MG-Si） using a calcium silicate slag was studied. The results show that it is impossible basically to remove boron using a pure SiO2 refining. The oxidizing ability of CaO-SiO2 slag for boron removal was characterized by establishing the thermodynamic relationship between the distribution coefficient of boron （LB） and the activities of SiO2 and CaO. The experimental results show that the distribution coefficient and the removal efficiency of boron are greatly improved with the increase of CaO proportion in the slag. The maximal value of LB reaches 1.57 with a slag composition of 60%CaO-40%SiO2 （mass fraction）. The boron content in the refined silicon is reduced from 18×10^-6 to 1.8×10^-6 using slag refining at 1600 ℃ for 3 h with a CaO-SiO2/MG-Si ratio of 2.5, and the removal efficiency of boron reaches 90%.

Phosphate removal from wastewater by model-La(Ⅲ)zeolite adsorbents

Phosphorus is one of the primary nutrients which leads to eutrophication and accelerates aging process in enclosed water bodies. Because of the poor phosphorus selectivity of other adsorbents, the novel La（Ⅲ）-modified zeolite adsorbent （LZA） was prepared by modifying 90 nm zeolite with lanthanide to selectively remove phosphate in the presence of various omnipresent anions, such as sulfates, bicarbonates, and chlorides. Through batch and fixed bed operation, the following optimum conditions were obtained： concentration of lanthanum chloride solution 0.05 mol/L; solid/liquor ratio 1/25; pH 10; calcination temperature 550℃; time 1 h. The value of the Freundlich model constants Kf and 1/n were found to be 16.76 mg/L and 0.2209, respectively. In addition, when calculated at pH 6.0, distribution coefficient KD could be as high as 36.6. Furthermore, in the alkaline pH range, solution of 0.8 mol/L NaCl was used to regenerate the saturated LZA, which could reach the high regeneration efficiency as high as 100%. Because of the good selectivity and regenerability of LZA, it might serve as a potential way for advanced phosphate removal from the sewage containing other anions.

Distribution and deposition of polycyclic aromatic hydrocarbons in precipitation in Guangzhou, South China

Polycyclic aromatic hydrocarbons （PAHs） were measured in precipitation from March to August 2005 in Guangzhou, South China. Fourteen PAHs were studied, and their total concentrations varied from 616.6 to 3486.7 ng/L in dissolved phase and from 403.8 to 3125.5 ng/L in particulate phase. The estimated deposition loading of PAHs was 3568 ug/m^2 during the monitoring period. The deposition of PAHs was a potential source for Pearl River comparing with the contents of surface water. In addition, the high concentration in precipitation here implied that PAHs pollution was a potential environmental problem in Guangzhou. Most precipitation concentrations of PAHs in March （the last month in winter in Guangzhou） were higher than in the other months （in rainy season）. PAHs inclined to be adsorbed to particulate phase with the increase of molecular weight in rainwater. Combustion of fossil fuel and biomass might be the major source of PAHs, while the direct leakage or volatilization from petroleum products might be insignificant.

Influence of Fly Ash and Sewage Sludge Application on Cadmium and Lead Sorption by an Acidic Alfisol

The safe recycling of fly ash (FA) and sewage sludge (SS) in the agricultural processes comprises an important environmental technology on waste management. Soils amended with FA and SS may change their ability to adsorb heavy metals due to either increase of soil pH or decomposition of sludge-borne organic matter. Thus, Cd and Pb sorption was investigated by 1-month incubation under soil moisture content at field capacity and room temperature with an acidic Typic Haploxeroalf from central Greece amended with varying amounts of FA and SS. Batch experiments were conducted by equilibrating the soil samples with CaCl2 solutions containing 0-400 mg Pb L-1 or 0-100 mg Cd L-1. The results showed that the Freundlich equation described well the Cd and Pb sorption. Distribution coefficient (Kd) values of Pb were higher than those of Cd in all the treatments of this study. Application of FA increased Kd values for Cd and Pb to 8.2 and 2.3 times more than the controls, respectively. Simultaneous applications of FA and SS caused a Kd increase of 3.8 and 2.1 times compared to the treatments that received only SS for Cd and Pb, respectively. Treatment of SS alone did not significantly change Cd and Pb sorption compared to the controls. The sorption reactions seemed to be mainly affected by soil pH, which was revealed by the significant correlations of Cd and Pb sorption with soil pH. These suggested that fly ash was very useful as a low-cost adsorbent for Cd and Pb and could be used as an ameliorant for biosolid-amended acidic soils.

Study on Adsorption of Rare Earth Elements by Kaolinite

For better understanding the adsorption of rare earth elements (REEs) by clay minerals and its controlling factors, the experiments on adsorption of REEs in solutions with 1 g·L-1 kaolinite were performed at different conditions. The results are as follows: the REEs reach equilibrium in the adsorption-desorption process for 24; Langmuir′s adsorption curve is used for modeling the adsorption of REEs by kaolinite; a general trend is that the higher the contents of REEs are, the less obvious the fractionation is. Furthermore, there is significant effect of pH on the adsorption and fractionation of REEs by kaolinite, and the REEs distribution coefficient increases with increasing pH. When pH is nearly neutral, as reaches 7, heavy REEs are more adsorbed than light REEs.

Thermodynamics Behavior of Titanium for BOF Smelting Bearing Steel

When titanium element appears in bearing steel, it is very easy to create titanium nitride inclusion, which reduces the fatigue life of bearing steel. Based on the production data of bearing steel produced by BOF, it is found that the titanium takes its source in bearing steel; the factors-affecting titanium content, and the thermodynamics behavior of titanium under smelting condition were studied. The results show that the prime reasons of titanium content increment are the soluble aluminum content and the titanium oxide of slag. The comparison between the experimental data and theoretical ones shows that there is a big declination when the soluble aluminum content of steel is higher, which is caused by the nonequilibrium reaction of slag and steel. The apparent equilibrium distribution coefficient of titanium between slag and steel is Obtained by use of experimental data.

Prediction of Phase Behavior for Styrene/CO2/Polystyrene Mixtures

A lattice fluid model, Sanchez-Lacombe equation, is used to predict the phase behavior for a styrene/CO2/polystyrene ternary sys-tem. The binary parameters involved in the equation were optimized using experimental data. Phase diagrams and the distribution coefficients of styrene between polymer phase and fluid phase are obtained over a wide range of pressure, temperature and composition. The analysis of ter-nary phase diagrams indicates that this system at relatively high pressure or low temperature may display two-phase equilibrium, and at low pressures or high temperatures three-phase equilibrium may appear. The distribution coefficients of styrene between the fluid phase and the polymer phase increase asymptotically to unity when the concentration of styrene increases. The results provide thermodynamic knowledge for further exploitation of supercritical carbon dioxide assisted devolatilization and impregnation.

Reaction between basaltic melt and orthopyroxene at 3.0–4.5 GPa:Implications for the evolution of ocean island basalts in the mantle

Interactions between basaltic melt and orthopyroxenite(Opx)were investigated to gain a better understanding of the consequences of the residence and transport of ocean island basalts(OIBs)within the mantle.The experiments were conducted using a DS-3600 six-anvil apparatus at 3.0–4.5 GPa and 1300–1450℃.The basaltic melt and Opx coexisted at local equilibrium at these pressures and temperatures;the initial melts dissolved Opx,which modified their chemical composition,and clinopyroxene(Cpx)precipitated with or without garnet(Grt).The trace-element contents of Grt,Cpx,and melt were measured and the mineral–melt distribution coefficients(D)of Cpx–melt and Grt–melt were calculated,which can be used to assess the distribution of trace elements between basalt and minerals in the mantle.Two types of reaction rim were found in the experimental products,Cpx,and Cpx+Grt;this result indicates that residual rocks within the mantle should be pyroxenite or garnet pyroxenite.Both rock types are found in mantle xenoliths from Hawaii,and the rare-earth-element(REE)pattern of Cpx in these mantle pyroxenites matches those of Cpx in the experimental reaction rims.Furthermore,residual melts in the experimental products plot in similar positions to Hawaiian high-SiO_(2)OIBs on major-element Harker diagrams,and their trace-element patterns show the signature of residual Grt,particularly in runs at1350℃ and 4.0–4.5 GPa.Trace-element concentrations of the experimental residual melts plot in similar positions to the Hawaiian OIBs on commonly used discrimination diagrams(Ti vs.Zr,Cr vs.Y,Cr vs.V,Zr/Y vs.Zr,and Ti/Y vs.Nb/Y).These results indicate that reaction between basaltic melt and pyroxenite might contribute to the generation of Hawaiian high-SiO2 OIBs and account for their chemical variability.

Salt Effect on the Liquid-Liquid Equilibrium of （Water ＋ Propionic Acid ＋ Cyclohexanol） System at T=（298.2,303.2,and 308.2） K

Effects of salt and temperature on the liquid phase equilibrium of the(water + propionic acid + cyclohexanol) system were investigated.The liquid-liquid equilibrium data in the presence of KCl for various salt ionic strength of 0.5,1.0,1.5,2.0,and 2.5 mol·dm3 and in absence of the salt at T=(298.2,303.2,and 308.2)K were determined.The experimental results were correlated based on the Othmer-Tobias equation and Pitzer ion-interaction model.Thermodynamic properties such as distribution coefficients and activity coefficients of propionic acid in water + cyclohexanol were determined.In addition,the separation factor,S,of the chosen solvent was obtained for the investigated system.

Process parameters influence on zone refining and thermodynamics analysis of 1,2-diphenylethane

Effective distribution coefficients of 9 impurities in 1,2-diphenylethane have been calculated by directional crystallization under different ambient frozen temperature.The effect of varied zone size,temperature difference between the melt and ambient frozen environment,number of zone on purity of 1,2-diphenylethane have been also investigated during the process of zone refining.The results indicate that the product purity in the intermediate purified region with varied zone size is higher 0.04%–0.2%than that with constant zone size.The product purity increases with temperature difference between the melt and ambient frozen environment.The appropriate temperature difference is adopted 50°C.The product purity in the intermediate region of sample bar with 2 molten zones is higher 0.05%–0.43%than that with 1 molten zone.In addition,the change of enthalpy and entropy between impurities and 1,2-diphenylethane have been determined.

Wellbore drift flow relation suitable for full flow pattern domain and full dip range

Aiming at the simulation of multi-phase flow in the wellbore during the processes of gas kick and well killing of complex-structure wells(e.g.,directional wells,extended reach wells,etc.),a database including 3561 groups of experimental data from 32 different data sources is established.Considering the effects of fluid viscosity,pipe size,interfacial tension,fluid density,pipe inclination and other factors on multi-phase flow parameters,a new gas-liquid two-phase drift flow relation suitable for the full flow pattern and full dip range is established.The distribution coefficient and gas drift velocity models with a pipe inclination range of-90°–90°are established by means of theoretical analysis and data-driven.Compared with three existing models,the proposed models have the highest prediction accuracy and most stable performance.Using a well killing case with the backpressure method in the field,the applicability of the proposed model under the flow conditions with a pipe inclination range of-90°–80°is verified.The errors of the calculated shut in casing pressure,initial back casing pressure and casing pressure when adjusting the displacement are 2.58%,3.43%,5.35%,respectively.The calculated results of the model are in good agreement with the field backpressure data.

Synthesis and Adsorption Properties of Chelating Resins Containing Sulfoxide and Heterocyclic Functional Groups

Several of new chelating resins containing sulfoxide and heterocyclic functional groups （3-aminopyridine and 2-mercaptobenzothiazole） based on macroporous chloromethylated polystyrene were synthesized and characterized by elemental analysis and infrared spectra. Their adsorption capacities towards Zn^2＋, Cu^2＋, Pb^2＋, Hg^2＋ and Ag^＋ at pH 3.0 and 6.0 were investigated in detail. It was found that the adsorption capacities of the resins containing bis[（3-pyridylaminoethyl）sulfoxide or （2-benzothiazolylthioethyl）sulfoxide for the above ions were higher than that on ones containing single above-mentioned groups.

Distribution and release of 2,4,5-trichlorobiphenyl in ice

The distribution of persistent organic pollutants（POPs） in ice and the release of POPs from ice during ice melting have an important influence on the eco-environment and water quality of a river. Through laboratory simulation experiments, the distribution and release of 2,4,5-trichlorobiphenyl（PCB29） in ice and the partition coefficients of PCB29 in ice water at different temperatures, concentrations, and p H levels were studied. The results showed that, at different temperatures and concentrations, the concentration of PCB29 in ice increased progressively with depth. The modes of release of different concentrations of PCB29 from ice were obtained. A large amount of PCB29 was released rapidly in the first melting period, and then the remaining PCB29 was released uniformly. The p H value dominated both the distribution and late release of PCB29 in ice. In ice water, at different temperatures, concentrations, and p H levels, the majority of PCB29 entered the water, and a lesser amount remained in the ice. Finally, laboratory experiment results were verified with field investigations. A theoretical framework is provided by this research of the behavior of POPs in ice under different environmental conditions, but a more quantitative understanding of the behavior of POPs in ice will need to be developed through further laboratory studies combined with field investigations.

Oxidation of Solid Phase and Ionic Strength Effect to the Cesium Adsorption on Pumice Tuff

In-situ oxidation of solid phase was considered to investigate adsorption behavior under different geochemical parameters like pH, initial concentration and ionic strength. Pumice tuff, a potential host rock for low and intermediate radioactive wastes, has been affected by the redox zone. The characterization of the fresh and oxidized tuff was performed by X-ray diffractometer, scanning electron microscope and mercury intrusion porosimetry. In order to compare the difference of distribution coefficient (Kd) in fresh and oxidized pumice tuffs, a batch adsorption study was carried out at the range of pH (4 - 12), ionic strength (0.003, 0.1, 1.0 and 3.0 mol/dm3) and initial cesium concentration (10dž, 10LJ, 10Lj and 10lj mol/dm3). Based on experimental Kd values, ionic strength was found to be the most influential factor, whereas the effects of pH, initial Cs concentration and weathering condition of pumice tuff were negligible. The recalculated Kd values suggest that the existing surface complexation model is applicable to explain the sorption coefficients through the wide range of solution conditions.

Reduction of chromium oxides in stainless steel dust

The recovery of metal oxides from stainless steel dust using C（graphite）, SiFe, and Al as reductants was investigated under various conditions. The apparent distribution ratio of Cr（L Cr ′^m/s ） in the recovered metal and residual slag phases was defined as the major performance metric. The results show that the recovery ratio of metals increases as the ratio of CaO ：SiO2 by mass in the residual slag increases to 1.17. The residual content of metals in the slag decreases as the Al2O3 content of the slag is increased from approximately 8wt% to 10wt%. The recovery ratio of Cr increases with increasing L Cr ′^ m/s , and a linear relationship between L Cr ′^m/s and the activity coefficient ratio of CrO in the slag and the recovered metal phase is observed. The combination of C and SiFe or Al as the reducing agents reveals that Si is the more effective coreductant.