A series of doped barium hexaferrites BaFe12-2xMnxSnxO19 （x = 0.0-1.0） particles were prepared by the co-precipitation/molten salt method. The particle size and crystalline of the samples BaFe12-2xMnxSnxO19 decrease...A series of doped barium hexaferrites BaFe12-2xMnxSnxO19 （x = 0.0-1.0） particles were prepared by the co-precipitation/molten salt method. The particle size and crystalline of the samples BaFe12-2xMnxSnxO19 decrease with an increase in the doping amount x. When x is less than 0.8, the pure BaFe12-2xMnxSnxO19 particles with hexagonal plate morphology are obtained. The effects of substitution on magnetic properties were evaluated and compared to nomal BaFe12O19. The specific magnetizations （Ms） of doped materials have been significantly improved. Among all these compositions, the BaFe10.4Mn0.8Sn0.8O19 sample has the highest Ms value of 81.8 A？m2？kg-1 at room temperature and its intrinsic coercivity （Hc） is 44.5 kA？m-1. The as-prepared doped barium ferrites exhibit a low temperature coefficient of coercivity close to zero. The coercivity is independent of temperature when x is in the a range 0.5-0.7.展开更多
基金Funded by National Natural Science Foundation of China (Nos.20801016, 20701013, and 60971020)Postdoctoral Foundation of Heilongjiang Province(No. LRB07-231)Fundamental Research Funds for the Central Universities(No.HEUCF201210010)
文摘A series of doped barium hexaferrites BaFe12-2xMnxSnxO19 （x = 0.0-1.0） particles were prepared by the co-precipitation/molten salt method. The particle size and crystalline of the samples BaFe12-2xMnxSnxO19 decrease with an increase in the doping amount x. When x is less than 0.8, the pure BaFe12-2xMnxSnxO19 particles with hexagonal plate morphology are obtained. The effects of substitution on magnetic properties were evaluated and compared to nomal BaFe12O19. The specific magnetizations （Ms） of doped materials have been significantly improved. Among all these compositions, the BaFe10.4Mn0.8Sn0.8O19 sample has the highest Ms value of 81.8 A？m2？kg-1 at room temperature and its intrinsic coercivity （Hc） is 44.5 kA？m-1. The as-prepared doped barium ferrites exhibit a low temperature coefficient of coercivity close to zero. The coercivity is independent of temperature when x is in the a range 0.5-0.7.
