In order to enhance the p-type doping concentration in the LBSF, boron was added into the aluminum paste and boron doped local back surface field(B-LBSF) was successfully fabricated in this work. Through boron dopin...In order to enhance the p-type doping concentration in the LBSF, boron was added into the aluminum paste and boron doped local back surface field(B-LBSF) was successfully fabricated in this work. Through boron doping in the LBSF, much higher doping concentration was observed for the B-LBSF over the Al-LBSF. Higher doping concentration in the LBSF is expected to lead to better rear passivation and lower rear contact resistance. Based on one thousand pieces of solar cells for each type, it was found that the rear passivated crystalline silicon solar cells with B-LBSF showed statistical improvement in their photovoltaic properties over those with Al-LBSF.展开更多
Nanocrystals of CeO2 with different doping concentrations of Sm3+ were synthesized by a novel and cost- effective method. The crystal structure, morphology and particle size were systematically investigated by X-ray ...Nanocrystals of CeO2 with different doping concentrations of Sm3+ were synthesized by a novel and cost- effective method. The crystal structure, morphology and particle size were systematically investigated by X-ray diffraction, scanning electron microscopy and transmission electron microscopy. Effects of the annealing temperature and doping concentrations on the microstructural properties of the crystals were studied. X-ray diffraction analysis indicates that the cubic structure of the CeO2 is not affected by the doping of Sm3+ up to a doping concentration of 20%. Different structural parameters such as lattice constant, surface area, bulk density and porosity of the crystal were determined and discussed. Microscopic images of the CeO2:Sm3+ suggest that the thermal decomposition of oxalate precursor is a suitable synthesis pathway to produce uniform-sized microparticles and nanoparticles. The influences of annealing temPerature and doping concentration of Sm3+ on the optical properties of the nanocrystals were also discussed. The photoluminescence excitation spectra reveal that the charge transfer band is redshifted with increasing annealing temperatures. Emission attains its maximum intensity for Sm3+ concentration of 1%, and higher concentrations lead to emission quenching.展开更多
基金Funded by the National Natural Science Foundation of China(61366004)the Research Fund for the Doctoral Program of Higher Education(20123601110006)the Jiangxi Provincial Department of Education(KJLD13008)
文摘In order to enhance the p-type doping concentration in the LBSF, boron was added into the aluminum paste and boron doped local back surface field(B-LBSF) was successfully fabricated in this work. Through boron doping in the LBSF, much higher doping concentration was observed for the B-LBSF over the Al-LBSF. Higher doping concentration in the LBSF is expected to lead to better rear passivation and lower rear contact resistance. Based on one thousand pieces of solar cells for each type, it was found that the rear passivated crystalline silicon solar cells with B-LBSF showed statistical improvement in their photovoltaic properties over those with Al-LBSF.
基金UGC (Govt. of India) and DST (Govt. of India) for the the financial assistance through SAP-DRS (No. F.530/12/DRS/2009 (SAP-1)) and DST-PURSE (SR/ S9/Z-23/2010/22 (C,G)) programs
文摘Nanocrystals of CeO2 with different doping concentrations of Sm3+ were synthesized by a novel and cost- effective method. The crystal structure, morphology and particle size were systematically investigated by X-ray diffraction, scanning electron microscopy and transmission electron microscopy. Effects of the annealing temperature and doping concentrations on the microstructural properties of the crystals were studied. X-ray diffraction analysis indicates that the cubic structure of the CeO2 is not affected by the doping of Sm3+ up to a doping concentration of 20%. Different structural parameters such as lattice constant, surface area, bulk density and porosity of the crystal were determined and discussed. Microscopic images of the CeO2:Sm3+ suggest that the thermal decomposition of oxalate precursor is a suitable synthesis pathway to produce uniform-sized microparticles and nanoparticles. The influences of annealing temPerature and doping concentration of Sm3+ on the optical properties of the nanocrystals were also discussed. The photoluminescence excitation spectra reveal that the charge transfer band is redshifted with increasing annealing temperatures. Emission attains its maximum intensity for Sm3+ concentration of 1%, and higher concentrations lead to emission quenching.