Colored layered double hydroxides (LDHs) can be synthesized by introducing colored cations such as Fe^3+ and Cr^3 +, which call be used as thermal stabilizers for polyvinyl chloride (PVC). The yellowish Mg/Fe an...Colored layered double hydroxides (LDHs) can be synthesized by introducing colored cations such as Fe^3+ and Cr^3 +, which call be used as thermal stabilizers for polyvinyl chloride (PVC). The yellowish Mg/Fe and bluish Mg/Cr LDHs are prepared by the co-precipitation method. The results show that the MgsCr_ CO3 and Mg3Fe_ CO3 colored layered double hydroxides can stabilize PVC for more than 30 min under the thermal aging temperature of 180 ℃. The preparation can use cheap Mg(OH) 2 instead of MgCl2, which produces a much smaller amount of the by-product NH4Cl. It is known that NH4Cl is a cheap fertilizer that is difficult to sell; therefore, the preparation is much greener and more economic than the one using magnesium salt.展开更多
Working principles of silicon double P-N junction color sensor are introduced and a color measurement system to distinguish tooth color difference is designed in this paper.This system consists of silicon double P-N j...Working principles of silicon double P-N junction color sensor are introduced and a color measurement system to distinguish tooth color difference is designed in this paper.This system consists of silicon double P-N junction,a small optical fiber probe,signal process circuit and an MSP430FG439 single-chip system.Small in size,this system can measure different parts of the tooth in a fast and convenient way with high-accuracy.Thus,this system will be very promising in building prosthodontics and tooth fabrication.展开更多
We fabricate white phosphorescent organic light-emitting diodes (PHOLEDs) with three dopants and double emissive layer (EML) to achieve color stability. The white PHOLEDs use FIrpic dopant for blue EML (B- EML),...We fabricate white phosphorescent organic light-emitting diodes (PHOLEDs) with three dopants and double emissive layer (EML) to achieve color stability. The white PHOLEDs use FIrpic dopant for blue EML (B- EML), and Ir(ppy)3:Ir(piq)3 dopants for green:red EML (GR-EML) with N,N'-dicarbazolyl-3, 5-benzene (mCP) as host material. Thicknesses of B-EML and GR-EML are adjusted to form a narrow recombination zone at two EML's interface and charge trapping happens in EML according to wide highest occupied molecular orbital and/or lowest unoccupied molecular orbital energy band gap of mCP and smaller energy band gap of dopants. The total thickness of both EMLs is fixed at 30 nm in the device structure of ITO (150 nm)/MoO3 (2 nm)/N,N'-diphenyl-N,N'-bis(1-naphthyl-phenyl)-(1,1″-biphenyl)-4, 4'-diamine (70 nm)/ meP:Firpic-8.0% (12 nm)/mCP:Ir(ppy)3-3.0%:Ir(piq)3-1.5% (18 nm)/2″,2',2"'-(1,3,5-benzinetriyl)-tris(1- phenyl-l-H-benzimidazole) (30 nm)/8-hydroxyquinolinolato-lithium (2 nm)/A1 (120 nm). White PHOLED shows 18.25 cd/A of luminous efficiency and white color coordinates of (0.358 and 0.378) at 5000 cd/m2 and color stability with slight CIExy change of (0.028 and 0.002) as increasing luminance from 1000 to 5000 cd/m^2.展开更多
基金The Fundamental Research Funds for the Central Universities,the Scientific Innovation Research of College Graduates in Jiangsu Province(No.CXLX12-0105)the Analysis and Test Fund of Southeast University(No.201226)
文摘Colored layered double hydroxides (LDHs) can be synthesized by introducing colored cations such as Fe^3+ and Cr^3 +, which call be used as thermal stabilizers for polyvinyl chloride (PVC). The yellowish Mg/Fe and bluish Mg/Cr LDHs are prepared by the co-precipitation method. The results show that the MgsCr_ CO3 and Mg3Fe_ CO3 colored layered double hydroxides can stabilize PVC for more than 30 min under the thermal aging temperature of 180 ℃. The preparation can use cheap Mg(OH) 2 instead of MgCl2, which produces a much smaller amount of the by-product NH4Cl. It is known that NH4Cl is a cheap fertilizer that is difficult to sell; therefore, the preparation is much greener and more economic than the one using magnesium salt.
基金supported by the Innovation Fund for Small Technology-based Firms of China (No.06C26222200838).
文摘Working principles of silicon double P-N junction color sensor are introduced and a color measurement system to distinguish tooth color difference is designed in this paper.This system consists of silicon double P-N junction,a small optical fiber probe,signal process circuit and an MSP430FG439 single-chip system.Small in size,this system can measure different parts of the tooth in a fast and convenient way with high-accuracy.Thus,this system will be very promising in building prosthodontics and tooth fabrication.
文摘We fabricate white phosphorescent organic light-emitting diodes (PHOLEDs) with three dopants and double emissive layer (EML) to achieve color stability. The white PHOLEDs use FIrpic dopant for blue EML (B- EML), and Ir(ppy)3:Ir(piq)3 dopants for green:red EML (GR-EML) with N,N'-dicarbazolyl-3, 5-benzene (mCP) as host material. Thicknesses of B-EML and GR-EML are adjusted to form a narrow recombination zone at two EML's interface and charge trapping happens in EML according to wide highest occupied molecular orbital and/or lowest unoccupied molecular orbital energy band gap of mCP and smaller energy band gap of dopants. The total thickness of both EMLs is fixed at 30 nm in the device structure of ITO (150 nm)/MoO3 (2 nm)/N,N'-diphenyl-N,N'-bis(1-naphthyl-phenyl)-(1,1″-biphenyl)-4, 4'-diamine (70 nm)/ meP:Firpic-8.0% (12 nm)/mCP:Ir(ppy)3-3.0%:Ir(piq)3-1.5% (18 nm)/2″,2',2"'-(1,3,5-benzinetriyl)-tris(1- phenyl-l-H-benzimidazole) (30 nm)/8-hydroxyquinolinolato-lithium (2 nm)/A1 (120 nm). White PHOLED shows 18.25 cd/A of luminous efficiency and white color coordinates of (0.358 and 0.378) at 5000 cd/m2 and color stability with slight CIExy change of (0.028 and 0.002) as increasing luminance from 1000 to 5000 cd/m^2.