In this article,the experimental and finite element analysis is utilized to investigate the quasi-static compression features of sandwich constructions built with tapered tubes.3D printing technology was utilized to c...In this article,the experimental and finite element analysis is utilized to investigate the quasi-static compression features of sandwich constructions built with tapered tubes.3D printing technology was utilized to create the hollow centers of the tapering tubes,with and without corrugations.The results demonstrate that the energy absorption(EA)and specific energy absorption(SEA)of the single corrugated tapered tube sandwich are 51.6% and 19.8% higher,respectively,than those of the conical tube sandwich.Furthermore,the results demonstrate that energy absorbers can benefit from corrugation in order to increase their efficiency.Additionally,the tapered corrugated tubes'resistance to oblique impacts was studied.Compared to a straight tube,the tapered tube is more resistant to oblique loads and has a lower initial peak crushing force(PCF),according to numerical simulations.After conducting a parametric study,it was discovered that the energy absorption performance of the sandwich construction is significantly affected by the amplitude,number of corrugations,and wall thickness.EA and SEA of DTS with corrugation number of 8 increased by 17.4%and 29.6%,respectively,while PCF decreased by 9.2% compared to DTS with corrugation number of 10.展开更多
In this paper,the numerical simulation method is used to study the ballistic performances of hourglass lattice sandwich structures with the same mass under the vertical incidence of fragments.Attention is paid to eluc...In this paper,the numerical simulation method is used to study the ballistic performances of hourglass lattice sandwich structures with the same mass under the vertical incidence of fragments.Attention is paid to elucidating the influences of rod cross-section dimensions,structure height,structure layer,and rod inclination angle on the deformation mode,ballistic performances,and ability to change the ballistic direction of fragments.The results show that the ballistic performances of hourglass lattice sandwich structures are mainly affected by their structural parameters.In this respect,structural parameters optimization of the hourglass lattice sandwich structures enable one to effectively improve their ballistic limit velocity and,consequently,ballistic performances.展开更多
Biomass‐derived carbon is a promising electrode material in energy storage devices.However,how to improve its low capacity and stability,and slow diffusion kinetics during lithium storage remains a challenge.In this ...Biomass‐derived carbon is a promising electrode material in energy storage devices.However,how to improve its low capacity and stability,and slow diffusion kinetics during lithium storage remains a challenge.In this research,we propose a“self‐assembly‐template”method to prepare B,N codoped porous carbon(BN‐C)with a nanosandwich structure and abundant pyridinic N‐B species.The nanosandwich structure can increase powder density and cycle stability by constructing a stable solid electrolyte interphase film,shortening the Li^(+)diffusion pathway,and accommodating volume expansion during repeated charging/discharging.The abundant pyridinic N‐B species can simultaneously promote the adsorption/desorption of Li^(+)/PF_(6)^(−)and reduce the diffusion barrier.The BN‐C electrode showed a high lithium‐ion storage capacity of above 1140 mAh g^(−1)at 0.05 A g^(−1)and superior stability(96.5%retained after 2000 cycles).Moreover,owing to the synergistic effect of the nanosandwich structure and pyridinic N‐B species,the assembled symmetrical BN‐C//BN‐C full cell shows a high energy density of 234.7Wh kg^(−1),high power density of 39.38 kW kg−1,and excellent cycling stability,superior to most of the other cells reported in the literature.As the density functional theory simulation demonstrated,pyridinic N‐B shows enhanced adsorption activity for Li^(+)and PF_(6)^(−),which promotes an increase in the capacity of the anode and cathode,respectively.Meanwhile,the relatively lower diffusion barrier of pyridinic N‐B promotes Li^(+)migration,resulting in good rate performance.Therefore,this study provides a new approach for the synergistic modulation of a nanostructure and an active site simultaneously to fabricate the carbon electrode material in energy storage devices.展开更多
Double-layered microcapsule corrosion inhibitors were developed by sodium monofluorophosphate as the core material,polymethyl methacrylate as the inner wall material,and polyvinyl alcohol as the outer wall material co...Double-layered microcapsule corrosion inhibitors were developed by sodium monofluorophosphate as the core material,polymethyl methacrylate as the inner wall material,and polyvinyl alcohol as the outer wall material combining the solvent evaporation method and spray drying method.The protection by the outer capsule wall was used to prolong the service life of the corrosion inhibitor.The dispersion,encapsulation,thermal stability of microcapsules,and the degradation rate of capsule wall in concrete pore solution were analyzed by ultra-deep field microscopy,scanning electron microscopy,thermal analyzer,and sodium ion release rate analysis.The microcapsules were incorporated into mortar samples containing steel reinforcement,and the effects of double-layered microcapsule corrosion inhibitors on the performance of the cement matrix and the actual corrosion-inhibiting effect were analyzed.The experimental results show that the double-layered microcapsules have a moderate particle size and uniform distribution,and the capsules were completely wrapped.The microcapsules as a whole have good thermal stability below 230 ℃.The monolayer membrane structure microcapsules completely broke within 1 day in the simulated concrete pore solution,and the double-layer membrane structure prolonged the service life of the microcapsules to 80 days in the simulated concrete pore solution before the core material was completely released.The mortar samples containing steel reinforcement incorporated with the double-layered microcapsule corrosion inhibitors still maintained a higher corrosion potential than the monolayer microcapsule corrosion inhibitors control group at 60 days.The incorporation of double-layered microcapsules into the cement matrix has no significant adverse effect on the setting time and early strength.展开更多
The sandwich structure of cushioning packaging has an important influence on the cushioning performance.Mathematical fractal theory is an important graphic expression.Based on Hilbert fractal theory,a new sandwich str...The sandwich structure of cushioning packaging has an important influence on the cushioning performance.Mathematical fractal theory is an important graphic expression.Based on Hilbert fractal theory,a new sandwich structure was designed.The generation mechanism and recurrence formula of theHilbert fractal were expressed by Lin’s language,and the second-orderHilbert sandwich structure was constructed fromthermoplastic polyurethane.The constitutive model of the hyperelastic body was established by using the finite element method.With the unit mass energy absorption as the optimization goal,the fractal sandwich structure was optimized,and the best result was obtained when the order was 2.5 and the unit layer thickness was 0.75 mm.TheHilbert sandwich structure was compared with the rice-shaped sandwich structure commonly used in industry,and the Hilbert fractal structure had better energy absorption.This has practical significance for the development and application of newcushioning packaging structures.展开更多
Potential damage in composite structures caused by hail ice impact is an essential safety threat to the aircraft in flight.In this study,a nonlinear finite element(FE)model is developed to investigate the dynamic resp...Potential damage in composite structures caused by hail ice impact is an essential safety threat to the aircraft in flight.In this study,a nonlinear finite element(FE)model is developed to investigate the dynamic response and damage behavior of hybrid corrugated sandwich structures subjected to high velocity hail ice impact.The impact and breaking behavior of hail are described using the FE-smoothed particle hydrodynamics(FE-SPH)method.A rate-dependent progressive damage model is employed to capture the intra-laminar damage response;cohesive element and surface-based cohesive contact are implemented to predict the inter-laminar delamination and sheet/core debonding phenomena respectively.The transient processes of sandwich structure under different hail ice impact conditions are analyzed.Comparative analysis is conducted to address the influences of core shape and impact position on the impact performance of sandwich structures and the corresponding energy absorption characteristics are also revealed.展开更多
In the present study,experimental and numerical investigations were carried out to examine the behavior of sandwich panels with honeycomb cores.The high velocity impact tests were carried out using a compressed air gu...In the present study,experimental and numerical investigations were carried out to examine the behavior of sandwich panels with honeycomb cores.The high velocity impact tests were carried out using a compressed air gun.A sharp conical nosed projectile was impacted normally and with some offset distance(20 mm and 40 mm).The deformation,failure mode and energy dissipation characteristics were obtained for both kinds of loading.Moreover,the explicit solver was run in Abaqus to create the finite element model.The numerically obtained test results were compared with the experimental to check the accuracy of the modelling.The numerical result was further employed to obtain strain energy dissipation in each element by externally running user-defined code in Abaqus.Furthermore,the influence of inscribe circle diameter and cell wall and face sheet thickness on the energy dissipation,deformation and failure mode was examined.The result found that ballistic resistance and deformation were higher against offset impact compared to the normal impact loading.Sandwich panel impacted at 40 mm offset distance required 3 m/s and 1.9 m/s more velocity than 0 and 20 mm offset distance.Also,increasing the face sheet and wall thickness had a positive impact on the ballistic resistance in terms of a higher ballistic limit and energy absorption.However,inscribe circle diameter had a negative influence on the ballistic resistance.Also,the geometrical parameters of the sandwich structure had a significant influence on the energy dissipation in the different deformation directions.The energy dissipation in plastic work was highest for circumferential direction,regardless of impact condition followed by tangential,radial and axial directions.展开更多
Focused exploration of earth-abundant and cost-efficient non-noble metal electrocatalysts with superior hydrogen evolution reaction(HER)performance is very important for large-scale and efficient electrolysis of water...Focused exploration of earth-abundant and cost-efficient non-noble metal electrocatalysts with superior hydrogen evolution reaction(HER)performance is very important for large-scale and efficient electrolysis of water.Herein,a sandwich composite structure(designed as MS-Mo2C@NCNS)ofβ-Mo2C hollow nanotubes(HNT)and N-doped carbon nanosheets(NCNS)is designed and prepared using a binary NaCl–KCl molten salt(MS)strategy for HER.The temperature-dominant Kirkendall formation mechanism is tentatively proposed for such a three-dimensional hierarchical framework.Due to its attractive structure and componential synergism,MS-Mo2C@NCNS exposes more effective active sites,confers robust structural stability,and shows significant electrocatalytic activity/stability in HER,with a current density of 10 mA cm-2 and an overpotential of only 98 mV in 1 M KOH.Density functional theory calculations point to the synergistic effect of Mo2C HNT and NCNS,leading to enhanced electronic transport and suitable adsorption free energies of H*(ΔGH*)on the surface of electroactive Mo2C.More significantly,the MS-assisted synthetic methodology here provides an enormous perspective for the commercial development of highly active non-noble metal electrocatalysts toward efficient hydrogen evolution.展开更多
Based on the three-pattern decomposition of global atmospheric circulation(TPDGAC), this study investigates the double-layer structure of the Hadley circulation(HC) and its interdecadal evolution characteristics by us...Based on the three-pattern decomposition of global atmospheric circulation(TPDGAC), this study investigates the double-layer structure of the Hadley circulation(HC) and its interdecadal evolution characteristics by using monthly horizontal wind field from NCEP/NCAR reanalysis data from 1948—2011. The following major conclusions are drawn: First, the double-layer structure of the HC is an objective fact, and it constantly exists in April,May, June, October and November in the Southern Hemisphere. Second, the double-layer structure is more obvious in the Southern than in the Northern Hemisphere. Since the double-layer structure is sloped in the vertical direction, it should be taken into consideration when analyzing the variations of the strength and location of the center of the HC.Third, the strength of the double-layer structure of the HC in the Southern Hemisphere consistently exhibits decadal variations with a strong, weak and strong pattern in all five months(April, May, June, October, and November), with cycles of 20-30 a and 40-60 a. Fourth, the center of the HC(mean position of the double-layer structure) in the Southern Hemisphere consistently and remarkably shifts southward in all the five months. The net poleward shifts over the 64 years are 5.18°, 2.11°, 2.50°, 1.79° and 5.76° for the five respective months, with a mean shift of 3.47°.展开更多
When anti-ship missiles penetrate into the ship armor, fragments and shock waves caused by explosion will severely destroy the personnel and equipment on the ships. In this study, three double-layer bulkheads with dif...When anti-ship missiles penetrate into the ship armor, fragments and shock waves caused by explosion will severely destroy the personnel and equipment on the ships. In this study, three double-layer bulkheads with different interior sandwich structures were investigated, including X and hexagonal combined sandwich structure, cross-type honeycomb sandwich struc-ture and cell growth type honeycomb sandwich structure. The penetration processes of three different bulkhead structures were simulated by software ANSYS/LS-DYNA. The simulation shows that the double-layer bulkhead with cross-type honeycomb sandwich structure is the most suitable. Finally, the dynamic response characteristics of the cross-type sandwich bulkhead structure are analyzed.展开更多
In order to ensure the safety of coal mine shaft construction, a double-layer steel plate concrete composite shaft wall structure was proposed. However, fewer studies were conducted on this structure, which made engin...In order to ensure the safety of coal mine shaft construction, a double-layer steel plate concrete composite shaft wall structure was proposed. However, fewer studies were conducted on this structure, which made engineers too confused to fully recognize its feasibility of this structure. Hence, based on the previous experimental research on the Taohutu mine construction project in Ordos in Inner Mongolia, this research paper aims to provide a widely deep numerical analysis by the usage of the finite element software, in fact, to establish the corresponding numerical analysis model and make a comparison with the experimental data to get the rationality of the verified model. The influence of the composite characteristics of the steel plate and concrete on the ultimate bearing capacity and stress field of the shaft wall structure is studied here through the method of multi-factor analysis. Also, the optimal design scheme of the double-layer steel plate and concrete composite shaft wall structure is proposed in this research paper.展开更多
Novel sandwich structure-like nanofiber multilayered meshes were fabricated via electrospinning. The purpose of the present work was to control zoledronic acid release via the novel structure of sandwich structure-lik...Novel sandwich structure-like nanofiber multilayered meshes were fabricated via electrospinning. The purpose of the present work was to control zoledronic acid release via the novel structure of sandwich structure-like meshes. The in vitro release experiments reveal that the drug release speed and initial burst release were controllable by adjusting the thicknesses of electrospun barrier mesh and drug-loaded mesh. Compared with those of other drug delivery systems, the main advantages of the sandwich structure-like fiber meshes are facile preparation conditions and the generality for hydrophobic and hydrophilic pharmaceuticals.展开更多
To develop the microwave absorbing(MA)properties of cementitious material mixed with mine solid waste,the iron tailings cementitious microwave absorbing materials were prepared.The iron tailings was treated into diffe...To develop the microwave absorbing(MA)properties of cementitious material mixed with mine solid waste,the iron tailings cementitious microwave absorbing materials were prepared.The iron tailings was treated into different particle sizes by planetary ball mill,and the physicochemical properties of iron tailings were tested by laser particle size analyzer and scanning electron microscope(SEM).The electromagnetic parameters of iron tailings cementitious materials were characterized by a vector network analyzer and simulated MA properties,and the MA properties of iron tailings-cement composite system with steel fiber as absorber was studied.Based on the design of the single-layer structure,optimum mix ratio and thickness configuration method of double-layer structure were further studied,meanwhile,the mechanical properties and engineering application were analyzed and discussed.The results show that the particle size of iron tailings can afiect its electromagnetic behavior in cementitious materials,and the smaller particles lead the increase of demagnetisation efiect induced by domain wall motion and achieve better microwave absorbing properties in cementitious materials.When the thickness of matching layer and absorbing layer is 5 mm,the optimized microwave absorbing properties of C1/C3 double-layer cementitious material can obtain optimal RL value of-27.61 dB and efiective absorbing bandwidth of 0.97 GHz,which attributes to the synergistic efiect of impedance matching and attenuation characteristics.The double-layer microwave absorbing materials obtain excellent absorbing properties and show great design flexibility and diversity,which can be used as a suitable candidate for the preparation of favorable microwave absorbing cementitious materials.展开更多
Due to the incompatibility of the interlaminar deformations,the interface debonding or cracking usually happens in a layered magnetoelectric(ME)structure under an applied load.In this paper,the transient responses of ...Due to the incompatibility of the interlaminar deformations,the interface debonding or cracking usually happens in a layered magnetoelectric(ME)structure under an applied load.In this paper,the transient responses of the anti-plane interface cracks in piezoelectric(PE)-piezomagnetic(PM)sandwich structures are studied by the standard methods of the integral transform and singular integral equation.Discussion on the numerical examples indicates that the PE-PM-PE structure under electric impact is more likely to fracture than the PM-PE-PM structure under a magnetic impact.The dynamic stress intensity factors(DSIFs)are more sensitive to the variation of the active layer thickness.The effects of the material constants on the DSIFs are dependent on the roles played by PE and PM media during the deformation process.展开更多
Aircraft laminated composite components often suffer a variety of high velocity impacts with large quantity of energy,which usually affects aircraft behavior and would incur component damages,even disastrous consequen...Aircraft laminated composite components often suffer a variety of high velocity impacts with large quantity of energy,which usually affects aircraft behavior and would incur component damages,even disastrous consequences.Therefore,one investigates the impact resistance of a new type of composite material,Ti/CFRP/Ti sandwich structure,and launches impact tests by using an air gun test system.Then one acquires the critical breakthrough rate of the structure and analyzes the damages.The results show that the main failure mode of the front titanium sheet is shear plugging and brittle fracture of adhesive layer with fiber breakage,while the back titanium sheet is severely ripped.The rear damage is worse than the front one.Compared with traditional CFRP laminates,the critical breakthrough rate of Ti/CFRP/Ti sandwich structure is improved by 69.9% when suffered the impact of a bearing ball with 2mm radius.展开更多
Ship collision accidents are catastrophic accidents, and as the main energy-absorbing structure, the anti-collision capacity of the side structure has an important influence on the crashworthiness of the ship. It is n...Ship collision accidents are catastrophic accidents, and as the main energy-absorbing structure, the anti-collision capacity of the side structure has an important influence on the crashworthiness of the ship. It is necessary to improve the crashworthiness of the ship by increasing energy absorption of the side structure, in such ways as adding a filling sandwich in a single hull. The aim of the present study is to discuss the crashworthiness of the side structure stressed under lateral dynamic loads through simulation with the finite element code MSC/Dytran. The collision force, the damage deformation, the critical collision speed as well as the energy absorption of a side structure improved with a filling sandwich are compared to the standard structure through numerical simulations. The results indicate that a sandwich panel structure is an advanced ship protection structure that can remarkably improve the ability of the side structure to withstand collisions; the effect of the tube-style sandwich panel structure has the best results. The outcome of this study provides a reference for the crashworthiness assessment of side structures and the crashworthiness optimization design of new side structures.展开更多
The so-called″X-cor sandwich structure″is a highly promising novel material as an alternative to honeycomb used in aircraft.Although much work has been conducted on the performance of the X-cor sandwich structure,th...The so-called″X-cor sandwich structure″is a highly promising novel material as an alternative to honeycomb used in aircraft.Although much work has been conducted on the performance of the X-cor sandwich structure,the gap is still hardly bridged between experimental results and theoretical analyses.Therefore,a method has been innovated to establish semi-empirical formula for the prediction of compressive and shear moduli of X-cor sandwich structure composites,by combining theoretical analyses and experimental data.In addition,aprediction software was first developed based on the proposed method,of which the accuracy was verified through confirmatory experiments.This software can offer a direct reference or guide for engineers in structural designing.展开更多
The propagation of acoustic waves in a homogeneous isotropic semiconducting layer sandwiched between two homogeneous transversely isotropic piezoelectric halfspaces has been investigated. The mathematical model of the...The propagation of acoustic waves in a homogeneous isotropic semiconducting layer sandwiched between two homogeneous transversely isotropic piezoelectric halfspaces has been investigated. The mathematical model of the problem is depicted by a set of partial differential equations of motion, Gauss equation in piezoelectric material and electron diffusion equation in semiconductor along with the boundary conditions to be satisfied at the piezoelectric-semiconductor interfaces. The secular equations describing the symmetric and asymmetric modes of wave propagation have been derived in compact form after obtaining the analytical expressions for various field quantities that govern the wave motion. The complex secular equation has been solved numerically using functional interaction method along with irreducible cardano method. The computer simulated results are obtained with the help of MATLAB software for 6 mm cadmium selenide (CdSe) piezoelectric material and n-type silicon (Si) semiconductor in respect of dispersion curve, attenuation and specific loss factor of energy dissipation for symmetric (sym) and asymmetric (asym) modes of wave propagation. The study may find applications in non-destructive testing, resonators, waveguides etc.展开更多
A wood-based X-type lattice sandwich structure was manufactured by insertion-glue method.The birch was used as core,and Oriented Strand Board was used as panel of the sandwich structure.The short beam shear properties...A wood-based X-type lattice sandwich structure was manufactured by insertion-glue method.The birch was used as core,and Oriented Strand Board was used as panel of the sandwich structure.The short beam shear properties and the failure modes of the wood-based X-type lattice sandwich structure with different core direction(vertical and parallel),unit specification(120 mm×60 mm and 60 mm×60 mm),core size(50 mm and 60 mm),and drilling depth(9 mm and 12 mm)were investigated by a short beam shear test and the establishment of a theoretical model to study the equivalent shear modulus and deflection response of the X-type lattice sandwich structure.Results from the short beam shear test and the theoretical model showed that the failure modes of the wood-based X-type lattice sandwich structure were mainly the wrinkling and crushing of the panels under three-point bending load.The experimental values of deflection response of various type specimens were higher than the theoretical values of them.For the core direction of parallel,the smaller the unit specification is,the shorter the core size is,and the deeper the drilling depth is,the greater the short beam shear properties of the wood-based X-type lattice sandwich structure is.展开更多
Ion transport of sandwich cementitious materials(SCM) exposed to chloride environment was investigated by accelerated diffusion method and natural diffusion method. Pore structure and micromorphology of SCM were inv...Ion transport of sandwich cementitious materials(SCM) exposed to chloride environment was investigated by accelerated diffusion method and natural diffusion method. Pore structure and micromorphology of SCM were investigated by MIP and SEM-EDS. In comparison with the monolayer structural high performance concrete(HPC), conductive charge for 6 hours, chloride diffusion coefficient, and apparent chloride diffusion coeffi cient of SCM were decreased by 30%-40%, two orders of magnitude and 40%-50%, respectively. Pore structure of ultra low ion permeability cementitious materials(ULIPCM) prepared for the facesheet is superior to that of HPC prepared for the core. As for porosity, the most probable pore radius, the content of pores with radius 50 nm and the surface area of pores, the order is ULIPCM展开更多
基金the grants from the National Natural Science Foundation of China(Nos.52078152 and 12002095)Guangzhou Government-University Union Fund(No.202201020532)。
文摘In this article,the experimental and finite element analysis is utilized to investigate the quasi-static compression features of sandwich constructions built with tapered tubes.3D printing technology was utilized to create the hollow centers of the tapering tubes,with and without corrugations.The results demonstrate that the energy absorption(EA)and specific energy absorption(SEA)of the single corrugated tapered tube sandwich are 51.6% and 19.8% higher,respectively,than those of the conical tube sandwich.Furthermore,the results demonstrate that energy absorbers can benefit from corrugation in order to increase their efficiency.Additionally,the tapered corrugated tubes'resistance to oblique impacts was studied.Compared to a straight tube,the tapered tube is more resistant to oblique loads and has a lower initial peak crushing force(PCF),according to numerical simulations.After conducting a parametric study,it was discovered that the energy absorption performance of the sandwich construction is significantly affected by the amplitude,number of corrugations,and wall thickness.EA and SEA of DTS with corrugation number of 8 increased by 17.4%and 29.6%,respectively,while PCF decreased by 9.2% compared to DTS with corrugation number of 10.
基金supported by the Defense Industrial Technology Development Program(Grant No.JCKY2018604B004)the National Natural Science Foundation of China(Grant No.11972007)。
文摘In this paper,the numerical simulation method is used to study the ballistic performances of hourglass lattice sandwich structures with the same mass under the vertical incidence of fragments.Attention is paid to elucidating the influences of rod cross-section dimensions,structure height,structure layer,and rod inclination angle on the deformation mode,ballistic performances,and ability to change the ballistic direction of fragments.The results show that the ballistic performances of hourglass lattice sandwich structures are mainly affected by their structural parameters.In this respect,structural parameters optimization of the hourglass lattice sandwich structures enable one to effectively improve their ballistic limit velocity and,consequently,ballistic performances.
基金Jiangsu Key Lab of Biomass Energy and Material,Grant/Award Number:JSBEMS‐202101National Natural Science Foundation of China,Grant/Award Numbers:51902162,51902162+4 种基金National Key R&D Program of China,Grant/Award Number:2022YFB4201904Foundation of Jiangsu Key Lab of Biomass Energy and Material,Grant/Award Number:JSBEM‐S‐202101National Key R&D Program,Grant/Award Number:2022YFB4201904Jiangsu Co‐Innovation Center of Efficient Processing and Utilization of Forest Resources,the International Innovation Center for Forest Chemicals and Materialsanjing Forestry University。
文摘Biomass‐derived carbon is a promising electrode material in energy storage devices.However,how to improve its low capacity and stability,and slow diffusion kinetics during lithium storage remains a challenge.In this research,we propose a“self‐assembly‐template”method to prepare B,N codoped porous carbon(BN‐C)with a nanosandwich structure and abundant pyridinic N‐B species.The nanosandwich structure can increase powder density and cycle stability by constructing a stable solid electrolyte interphase film,shortening the Li^(+)diffusion pathway,and accommodating volume expansion during repeated charging/discharging.The abundant pyridinic N‐B species can simultaneously promote the adsorption/desorption of Li^(+)/PF_(6)^(−)and reduce the diffusion barrier.The BN‐C electrode showed a high lithium‐ion storage capacity of above 1140 mAh g^(−1)at 0.05 A g^(−1)and superior stability(96.5%retained after 2000 cycles).Moreover,owing to the synergistic effect of the nanosandwich structure and pyridinic N‐B species,the assembled symmetrical BN‐C//BN‐C full cell shows a high energy density of 234.7Wh kg^(−1),high power density of 39.38 kW kg−1,and excellent cycling stability,superior to most of the other cells reported in the literature.As the density functional theory simulation demonstrated,pyridinic N‐B shows enhanced adsorption activity for Li^(+)and PF_(6)^(−),which promotes an increase in the capacity of the anode and cathode,respectively.Meanwhile,the relatively lower diffusion barrier of pyridinic N‐B promotes Li^(+)migration,resulting in good rate performance.Therefore,this study provides a new approach for the synergistic modulation of a nanostructure and an active site simultaneously to fabricate the carbon electrode material in energy storage devices.
基金Fund by the National Key Technology Research and Development Program of the Ministry of Science and Technology of China (No.2018YFD1101002-03)。
文摘Double-layered microcapsule corrosion inhibitors were developed by sodium monofluorophosphate as the core material,polymethyl methacrylate as the inner wall material,and polyvinyl alcohol as the outer wall material combining the solvent evaporation method and spray drying method.The protection by the outer capsule wall was used to prolong the service life of the corrosion inhibitor.The dispersion,encapsulation,thermal stability of microcapsules,and the degradation rate of capsule wall in concrete pore solution were analyzed by ultra-deep field microscopy,scanning electron microscopy,thermal analyzer,and sodium ion release rate analysis.The microcapsules were incorporated into mortar samples containing steel reinforcement,and the effects of double-layered microcapsule corrosion inhibitors on the performance of the cement matrix and the actual corrosion-inhibiting effect were analyzed.The experimental results show that the double-layered microcapsules have a moderate particle size and uniform distribution,and the capsules were completely wrapped.The microcapsules as a whole have good thermal stability below 230 ℃.The monolayer membrane structure microcapsules completely broke within 1 day in the simulated concrete pore solution,and the double-layer membrane structure prolonged the service life of the microcapsules to 80 days in the simulated concrete pore solution before the core material was completely released.The mortar samples containing steel reinforcement incorporated with the double-layered microcapsule corrosion inhibitors still maintained a higher corrosion potential than the monolayer microcapsule corrosion inhibitors control group at 60 days.The incorporation of double-layered microcapsules into the cement matrix has no significant adverse effect on the setting time and early strength.
基金supported by the Natural Science Foundation of Tianjin Munici-pality[21YDTPJC00480]the Science and Technology Project of Tianjin[20YDTPJC00830].
文摘The sandwich structure of cushioning packaging has an important influence on the cushioning performance.Mathematical fractal theory is an important graphic expression.Based on Hilbert fractal theory,a new sandwich structure was designed.The generation mechanism and recurrence formula of theHilbert fractal were expressed by Lin’s language,and the second-orderHilbert sandwich structure was constructed fromthermoplastic polyurethane.The constitutive model of the hyperelastic body was established by using the finite element method.With the unit mass energy absorption as the optimization goal,the fractal sandwich structure was optimized,and the best result was obtained when the order was 2.5 and the unit layer thickness was 0.75 mm.TheHilbert sandwich structure was compared with the rice-shaped sandwich structure commonly used in industry,and the Hilbert fractal structure had better energy absorption.This has practical significance for the development and application of newcushioning packaging structures.
基金supported by the Natural Science Foundation of Jiangsu Province(Grant No.BK20180855)Research Fund of State Key Laboratory of Mechanics and Control of Mechanical Structures(Grant No.MCMS-E-0219Y01)Research and Practice Innovation Program of postgraduates in Jiangsu Province(Grant No.KYCX20-3076)。
文摘Potential damage in composite structures caused by hail ice impact is an essential safety threat to the aircraft in flight.In this study,a nonlinear finite element(FE)model is developed to investigate the dynamic response and damage behavior of hybrid corrugated sandwich structures subjected to high velocity hail ice impact.The impact and breaking behavior of hail are described using the FE-smoothed particle hydrodynamics(FE-SPH)method.A rate-dependent progressive damage model is employed to capture the intra-laminar damage response;cohesive element and surface-based cohesive contact are implemented to predict the inter-laminar delamination and sheet/core debonding phenomena respectively.The transient processes of sandwich structure under different hail ice impact conditions are analyzed.Comparative analysis is conducted to address the influences of core shape and impact position on the impact performance of sandwich structures and the corresponding energy absorption characteristics are also revealed.
文摘In the present study,experimental and numerical investigations were carried out to examine the behavior of sandwich panels with honeycomb cores.The high velocity impact tests were carried out using a compressed air gun.A sharp conical nosed projectile was impacted normally and with some offset distance(20 mm and 40 mm).The deformation,failure mode and energy dissipation characteristics were obtained for both kinds of loading.Moreover,the explicit solver was run in Abaqus to create the finite element model.The numerically obtained test results were compared with the experimental to check the accuracy of the modelling.The numerical result was further employed to obtain strain energy dissipation in each element by externally running user-defined code in Abaqus.Furthermore,the influence of inscribe circle diameter and cell wall and face sheet thickness on the energy dissipation,deformation and failure mode was examined.The result found that ballistic resistance and deformation were higher against offset impact compared to the normal impact loading.Sandwich panel impacted at 40 mm offset distance required 3 m/s and 1.9 m/s more velocity than 0 and 20 mm offset distance.Also,increasing the face sheet and wall thickness had a positive impact on the ballistic resistance in terms of a higher ballistic limit and energy absorption.However,inscribe circle diameter had a negative influence on the ballistic resistance.Also,the geometrical parameters of the sandwich structure had a significant influence on the energy dissipation in the different deformation directions.The energy dissipation in plastic work was highest for circumferential direction,regardless of impact condition followed by tangential,radial and axial directions.
基金the National Natural Science Foundation of China(Nos.52072151,52171211,52102253,52271218,U22A20145)the Jinan Independent Innovative Team(2020GXRC015)+1 种基金the Major Program of Shandong Province Natural Science Foundation(ZR2021ZD05)the Science and Technology Program of University of Jinan(XKY2119).
文摘Focused exploration of earth-abundant and cost-efficient non-noble metal electrocatalysts with superior hydrogen evolution reaction(HER)performance is very important for large-scale and efficient electrolysis of water.Herein,a sandwich composite structure(designed as MS-Mo2C@NCNS)ofβ-Mo2C hollow nanotubes(HNT)and N-doped carbon nanosheets(NCNS)is designed and prepared using a binary NaCl–KCl molten salt(MS)strategy for HER.The temperature-dominant Kirkendall formation mechanism is tentatively proposed for such a three-dimensional hierarchical framework.Due to its attractive structure and componential synergism,MS-Mo2C@NCNS exposes more effective active sites,confers robust structural stability,and shows significant electrocatalytic activity/stability in HER,with a current density of 10 mA cm-2 and an overpotential of only 98 mV in 1 M KOH.Density functional theory calculations point to the synergistic effect of Mo2C HNT and NCNS,leading to enhanced electronic transport and suitable adsorption free energies of H*(ΔGH*)on the surface of electroactive Mo2C.More significantly,the MS-assisted synthetic methodology here provides an enormous perspective for the commercial development of highly active non-noble metal electrocatalysts toward efficient hydrogen evolution.
基金National Natural Science Foundation of China(41475068,40805034)Special Scientific Research Project for Public Interest(GYHY201206009)Fundamental Research Funds for the Central Universities of China(lzujbky-2014-203)
文摘Based on the three-pattern decomposition of global atmospheric circulation(TPDGAC), this study investigates the double-layer structure of the Hadley circulation(HC) and its interdecadal evolution characteristics by using monthly horizontal wind field from NCEP/NCAR reanalysis data from 1948—2011. The following major conclusions are drawn: First, the double-layer structure of the HC is an objective fact, and it constantly exists in April,May, June, October and November in the Southern Hemisphere. Second, the double-layer structure is more obvious in the Southern than in the Northern Hemisphere. Since the double-layer structure is sloped in the vertical direction, it should be taken into consideration when analyzing the variations of the strength and location of the center of the HC.Third, the strength of the double-layer structure of the HC in the Southern Hemisphere consistently exhibits decadal variations with a strong, weak and strong pattern in all five months(April, May, June, October, and November), with cycles of 20-30 a and 40-60 a. Fourth, the center of the HC(mean position of the double-layer structure) in the Southern Hemisphere consistently and remarkably shifts southward in all the five months. The net poleward shifts over the 64 years are 5.18°, 2.11°, 2.50°, 1.79° and 5.76° for the five respective months, with a mean shift of 3.47°.
文摘When anti-ship missiles penetrate into the ship armor, fragments and shock waves caused by explosion will severely destroy the personnel and equipment on the ships. In this study, three double-layer bulkheads with different interior sandwich structures were investigated, including X and hexagonal combined sandwich structure, cross-type honeycomb sandwich struc-ture and cell growth type honeycomb sandwich structure. The penetration processes of three different bulkhead structures were simulated by software ANSYS/LS-DYNA. The simulation shows that the double-layer bulkhead with cross-type honeycomb sandwich structure is the most suitable. Finally, the dynamic response characteristics of the cross-type sandwich bulkhead structure are analyzed.
文摘In order to ensure the safety of coal mine shaft construction, a double-layer steel plate concrete composite shaft wall structure was proposed. However, fewer studies were conducted on this structure, which made engineers too confused to fully recognize its feasibility of this structure. Hence, based on the previous experimental research on the Taohutu mine construction project in Ordos in Inner Mongolia, this research paper aims to provide a widely deep numerical analysis by the usage of the finite element software, in fact, to establish the corresponding numerical analysis model and make a comparison with the experimental data to get the rationality of the verified model. The influence of the composite characteristics of the steel plate and concrete on the ultimate bearing capacity and stress field of the shaft wall structure is studied here through the method of multi-factor analysis. Also, the optimal design scheme of the double-layer steel plate and concrete composite shaft wall structure is proposed in this research paper.
文摘Novel sandwich structure-like nanofiber multilayered meshes were fabricated via electrospinning. The purpose of the present work was to control zoledronic acid release via the novel structure of sandwich structure-like meshes. The in vitro release experiments reveal that the drug release speed and initial burst release were controllable by adjusting the thicknesses of electrospun barrier mesh and drug-loaded mesh. Compared with those of other drug delivery systems, the main advantages of the sandwich structure-like fiber meshes are facile preparation conditions and the generality for hydrophobic and hydrophilic pharmaceuticals.
基金Funded by the Natural Science Foundation of Nanping of China(No.N2021J002)Guangdong Basic and Applied Basic Research Foundation(No.2020A1515110304)+3 种基金Guangzhou Science and Technology Plan(No.202102020224)Natural Science Foundation of Fujian Province(No.2020Y0092)Natural Science Foundation of Fujian Province(No.2023J011044)Resource Chemical Industry and Technology Foundation of Nanping(No.N2020Z003)。
文摘To develop the microwave absorbing(MA)properties of cementitious material mixed with mine solid waste,the iron tailings cementitious microwave absorbing materials were prepared.The iron tailings was treated into different particle sizes by planetary ball mill,and the physicochemical properties of iron tailings were tested by laser particle size analyzer and scanning electron microscope(SEM).The electromagnetic parameters of iron tailings cementitious materials were characterized by a vector network analyzer and simulated MA properties,and the MA properties of iron tailings-cement composite system with steel fiber as absorber was studied.Based on the design of the single-layer structure,optimum mix ratio and thickness configuration method of double-layer structure were further studied,meanwhile,the mechanical properties and engineering application were analyzed and discussed.The results show that the particle size of iron tailings can afiect its electromagnetic behavior in cementitious materials,and the smaller particles lead the increase of demagnetisation efiect induced by domain wall motion and achieve better microwave absorbing properties in cementitious materials.When the thickness of matching layer and absorbing layer is 5 mm,the optimized microwave absorbing properties of C1/C3 double-layer cementitious material can obtain optimal RL value of-27.61 dB and efiective absorbing bandwidth of 0.97 GHz,which attributes to the synergistic efiect of impedance matching and attenuation characteristics.The double-layer microwave absorbing materials obtain excellent absorbing properties and show great design flexibility and diversity,which can be used as a suitable candidate for the preparation of favorable microwave absorbing cementitious materials.
基金Project supported by the National Natural Science Foundation of China(Nos.11272222,11502108,and 11611530686)the Natural Science Foundation for Distinguished Young Scholars of Jiangsu Province of China(No.BK20140037)
文摘Due to the incompatibility of the interlaminar deformations,the interface debonding or cracking usually happens in a layered magnetoelectric(ME)structure under an applied load.In this paper,the transient responses of the anti-plane interface cracks in piezoelectric(PE)-piezomagnetic(PM)sandwich structures are studied by the standard methods of the integral transform and singular integral equation.Discussion on the numerical examples indicates that the PE-PM-PE structure under electric impact is more likely to fracture than the PM-PE-PM structure under a magnetic impact.The dynamic stress intensity factors(DSIFs)are more sensitive to the variation of the active layer thickness.The effects of the material constants on the DSIFs are dependent on the roles played by PE and PM media during the deformation process.
基金funded by the Priority Academic Program Development of Jiangsu Higher Education Institutions
文摘Aircraft laminated composite components often suffer a variety of high velocity impacts with large quantity of energy,which usually affects aircraft behavior and would incur component damages,even disastrous consequences.Therefore,one investigates the impact resistance of a new type of composite material,Ti/CFRP/Ti sandwich structure,and launches impact tests by using an air gun test system.Then one acquires the critical breakthrough rate of the structure and analyzes the damages.The results show that the main failure mode of the front titanium sheet is shear plugging and brittle fracture of adhesive layer with fiber breakage,while the back titanium sheet is severely ripped.The rear damage is worse than the front one.Compared with traditional CFRP laminates,the critical breakthrough rate of Ti/CFRP/Ti sandwich structure is improved by 69.9% when suffered the impact of a bearing ball with 2mm radius.
基金Sponsored by the National Natural Science Foundation of China(Grant No.51579202)
文摘Ship collision accidents are catastrophic accidents, and as the main energy-absorbing structure, the anti-collision capacity of the side structure has an important influence on the crashworthiness of the ship. It is necessary to improve the crashworthiness of the ship by increasing energy absorption of the side structure, in such ways as adding a filling sandwich in a single hull. The aim of the present study is to discuss the crashworthiness of the side structure stressed under lateral dynamic loads through simulation with the finite element code MSC/Dytran. The collision force, the damage deformation, the critical collision speed as well as the energy absorption of a side structure improved with a filling sandwich are compared to the standard structure through numerical simulations. The results indicate that a sandwich panel structure is an advanced ship protection structure that can remarkably improve the ability of the side structure to withstand collisions; the effect of the tube-style sandwich panel structure has the best results. The outcome of this study provides a reference for the crashworthiness assessment of side structures and the crashworthiness optimization design of new side structures.
基金supported by the Aviation Science Fund of China(Nos.2015ZE52049,2015ZE521049)
文摘The so-called″X-cor sandwich structure″is a highly promising novel material as an alternative to honeycomb used in aircraft.Although much work has been conducted on the performance of the X-cor sandwich structure,the gap is still hardly bridged between experimental results and theoretical analyses.Therefore,a method has been innovated to establish semi-empirical formula for the prediction of compressive and shear moduli of X-cor sandwich structure composites,by combining theoretical analyses and experimental data.In addition,aprediction software was first developed based on the proposed method,of which the accuracy was verified through confirmatory experiments.This software can offer a direct reference or guide for engineers in structural designing.
文摘The propagation of acoustic waves in a homogeneous isotropic semiconducting layer sandwiched between two homogeneous transversely isotropic piezoelectric halfspaces has been investigated. The mathematical model of the problem is depicted by a set of partial differential equations of motion, Gauss equation in piezoelectric material and electron diffusion equation in semiconductor along with the boundary conditions to be satisfied at the piezoelectric-semiconductor interfaces. The secular equations describing the symmetric and asymmetric modes of wave propagation have been derived in compact form after obtaining the analytical expressions for various field quantities that govern the wave motion. The complex secular equation has been solved numerically using functional interaction method along with irreducible cardano method. The computer simulated results are obtained with the help of MATLAB software for 6 mm cadmium selenide (CdSe) piezoelectric material and n-type silicon (Si) semiconductor in respect of dispersion curve, attenuation and specific loss factor of energy dissipation for symmetric (sym) and asymmetric (asym) modes of wave propagation. The study may find applications in non-destructive testing, resonators, waveguides etc.
基金supported by National Natural Science Foundation of China(31470581)Fundamental Research Funds for the Central Universities(2572016EBJ1).
文摘A wood-based X-type lattice sandwich structure was manufactured by insertion-glue method.The birch was used as core,and Oriented Strand Board was used as panel of the sandwich structure.The short beam shear properties and the failure modes of the wood-based X-type lattice sandwich structure with different core direction(vertical and parallel),unit specification(120 mm×60 mm and 60 mm×60 mm),core size(50 mm and 60 mm),and drilling depth(9 mm and 12 mm)were investigated by a short beam shear test and the establishment of a theoretical model to study the equivalent shear modulus and deflection response of the X-type lattice sandwich structure.Results from the short beam shear test and the theoretical model showed that the failure modes of the wood-based X-type lattice sandwich structure were mainly the wrinkling and crushing of the panels under three-point bending load.The experimental values of deflection response of various type specimens were higher than the theoretical values of them.For the core direction of parallel,the smaller the unit specification is,the shorter the core size is,and the deeper the drilling depth is,the greater the short beam shear properties of the wood-based X-type lattice sandwich structure is.
基金Funded by the National Natural Science Foundation of China(Nos.51002072 and 51562024)the Jiangxi Science and Technology Support Project(Nos.20133BBE50027 and 20143BBM26055)
文摘Ion transport of sandwich cementitious materials(SCM) exposed to chloride environment was investigated by accelerated diffusion method and natural diffusion method. Pore structure and micromorphology of SCM were investigated by MIP and SEM-EDS. In comparison with the monolayer structural high performance concrete(HPC), conductive charge for 6 hours, chloride diffusion coefficient, and apparent chloride diffusion coeffi cient of SCM were decreased by 30%-40%, two orders of magnitude and 40%-50%, respectively. Pore structure of ultra low ion permeability cementitious materials(ULIPCM) prepared for the facesheet is superior to that of HPC prepared for the core. As for porosity, the most probable pore radius, the content of pores with radius 50 nm and the surface area of pores, the order is ULIPCM