Two-dimensional metal–organic-framework(2D MOF)nanosheets with a modular nature and tunable structures exhibit a bright future for sensors,separation,and catalysis.Developing ultrathin 2D MOF nanosheets with unique p...Two-dimensional metal–organic-framework(2D MOF)nanosheets with a modular nature and tunable structures exhibit a bright future for sensors,separation,and catalysis.Developing ultrathin 2D MOF nanosheets with unique physical and chemical properties is urgently required but very challenging.Although the chemical exfoliation strategy has been regarded as a promising way to exfoliate large amounts of three-dimensional(3D)pillar-layered MOFs,this method still faces many problems and remains insufficient.In this study,a novel chemical exfoliation method is developed for the target preparation of 2D MOF monolayers from the 3D pillar-layered MOFs.The Co/Zn/Cu-MOFs with a pillar ligand of trans-1,2-bis(4-pyridyl)ethylene(bipyen)are subjected to be broken by the cleavage of CC bonds in the bipyen ligands via an ozone oxidation reaction.As chemical exfoliation is processed via the oxidation of the pillar ligand by ozone,the thickness of the 2D MOFs can be tuned by the control of oxidation time and the obtained 2D Co/Zn/Cu-MOF monolayers are functionalized with a–COOH group.This study provides an effective and general chemical exfoliation method to prepare monolayer MOFs from the 3D pillar-layered MOFs with bipyen as the pillar ligand.展开更多
Laser-induced breakdown spectroscopy was employed to determine the inorganic elements in coal. To improve the measurement's accuracy and precision, a new internal standardization scheme, which we named changed intern...Laser-induced breakdown spectroscopy was employed to determine the inorganic elements in coal. To improve the measurement's accuracy and precision, a new internal standardization scheme, which we named changed internal standardization, was compared with the traditional internal standardization and no internal standardization for the analysis of inorganic elements. The new internal standardization scheme used the atomic line of carbon at 247.86 nm and the molecular band of CN at 388.34 nm and C2 at 516.32 nm to normalize the lines of inorganic elements that were distributed in the same spectral channel. The performance of the utilization of the new internal standardization scheme was evaluated using a set of coal samples, including twenty calibration samples and five validation samples. The results show that the coefficients of determination R2 and the slope of calibration models coupled with changed internal standard- ization are better than that of the calibration models coupled with fixed internal standardization and no internal standardization. Moreover, the measurement accuracy and reproducibility of changed internal standardization for the analysis of five validation samples also yielded further improvement. The results that we obtained suggest that changed internal standardization could compensate for the matrix effects, as well as the influence of the difference in the spectral response of the light collection system.展开更多
Reliability of braking systems is a key requirement to ensure the safety of in using downward belt conveyor brakes. By analyzing and comparing three commonly used braking velocity curves, we conclude that the Harrison...Reliability of braking systems is a key requirement to ensure the safety of in using downward belt conveyor brakes. By analyzing and comparing three commonly used braking velocity curves, we conclude that the Harrison curve is the best. Given the characteristics of a downward belt conveyor, we studied the control in a closed-loop velocity, a conventional PID method and an optimal PID control method. We used MATLAB/Simulink to simulate the three control methods. Our simulation results show that opti- mal PID control is especially suitable for disc braking systems. To verif!/the results from theoretical anal- ysis and simulation, a multifunctional test-bed was developed to simulate the braking process of a disc brake system. Our experimental results demonstrate that the optimal PID control can make the output velocity to follow a preset velocity correctly with only small fluctuations, meeting the requirements of a flexible brake for a belt conveyor.展开更多
Cotton bollworm(Helicoverpa armigera) is an important agricultural pest that causes severe yield loss to crops,particularly to cotton.Transgenic Bt crops have been successful in
Recent advances in stem cell technologies have opened new avenues for the treatment of a number of diseases still lacking effective therapeutic options.Cell transplantation has emerged as among the most promising clin...Recent advances in stem cell technologies have opened new avenues for the treatment of a number of diseases still lacking effective therapeutic options.Cell transplantation has emerged as among the most promising clinical intervention for disorders such as injuries,diabetes,liver diseases, neurodegeneration and heart failure (Lee et al., 2013; Forbes and Rosenthal, 2014; Tabar and Studer, 2014).展开更多
In 2016,CNPC managed to achieve a profit even despite the fact that the international oil price was lingering at a decade low.This was the third year in a row for the group to gain profit.Moreover,2016 was a year that...In 2016,CNPC managed to achieve a profit even despite the fact that the international oil price was lingering at a decade low.This was the third year in a row for the group to gain profit.Moreover,2016 was a year that marked significant gains for both CNPC’s operational and non-operational business,and the company also did excellent work in terms of international trading。展开更多
There are multiple operating modes in the real industrial process, and the collected data follow the complex multimodal distribution, so most traditional process monitoring methods are no longer applicable because the...There are multiple operating modes in the real industrial process, and the collected data follow the complex multimodal distribution, so most traditional process monitoring methods are no longer applicable because their presumptions are that sampled-data should obey the single Gaussian distribution or non-Gaussian distribution. In order to solve these problems, a novel weighted local standardization(WLS) strategy is proposed to standardize the multimodal data, which can eliminate the multi-mode characteristics of the collected data, and normalize them into unimodal data distribution. After detailed analysis of the raised data preprocessing strategy, a new algorithm using WLS strategy with support vector data description(SVDD) is put forward to apply for multi-mode monitoring process. Unlike the strategy of building multiple local models, the developed method only contains a model without the prior knowledge of multi-mode process. To demonstrate the proposed method's validity, it is applied to a numerical example and a Tennessee Eastman(TE) process. Finally, the simulation results show that the WLS strategy is very effective to standardize multimodal data, and the WLS-SVDD monitoring method has great advantages over the traditional SVDD and PCA combined with a local standardization strategy(LNS-PCA) in multi-mode process monitoring.展开更多
Complex industrial process often contains multiple operating modes, and the challenge of multimode process monitoring has recently gained much attention. However, most multivariate statistical process monitoring (MSPM...Complex industrial process often contains multiple operating modes, and the challenge of multimode process monitoring has recently gained much attention. However, most multivariate statistical process monitoring (MSPM) methods are based on the assumption that the process has only one nominal mode. When the process data contain different distributions, they may not function as well as in single mode processes. To address this issue, an improved partial least squares (IPLS) method was proposed for multimode process monitoring. By utilizing a novel local standardization strategy, the normal data in multiple modes could be centralized after being standardized and the fundamental assumption of partial least squares (PLS) could be valid again in multimode process. In this way, PLS method was extended to be suitable for not only single mode processes but also multimode processes. The efficiency of the proposed method was illustrated by comparing the monitoring results of PLS and IPLS in Tennessee Eastman(TE) process.展开更多
In 2019,the newly emerged SARS-CoV-2 virus caused pneumonia-like illness.The disease rapidly spread globally,leading to a worldwide outbreak referred to as the COVID-19 pandemic.
Inclusion of intellectual property in standards brings importantchanges to the global competition model.Based on the furious international circumstances,Outline of the National Intellectual Property Strategy was publi...Inclusion of intellectual property in standards brings importantchanges to the global competition model.Based on the furious international circumstances,Outline of the National Intellectual Property Strategy was published in2008,indicating the strategic direction of intellectual property involved in standards.This article analyzes relative items from innovation and standard strategy implemen-tation aspects,and makes some suggestions.展开更多
The Outline of National Intellectual Property Strategy has brought opportunitiesand challenges for standardization in China.On the basis of analysis on international trends regardinginclusion of intellectual property ...The Outline of National Intellectual Property Strategy has brought opportunitiesand challenges for standardization in China.On the basis of analysis on international trends regardinginclusion of intellectual property rights in standards,this paper reviews achievements incombination of standardization and intellectual property in Jiangsu over recent years,andmakes some suggestions for future work.展开更多
The pursuit-evasion game models the strategic interaction among players, attracting attention in many realistic scenarios, such as missile guidance, unmanned aerial vehicles, and target defense. Existing studies mainl...The pursuit-evasion game models the strategic interaction among players, attracting attention in many realistic scenarios, such as missile guidance, unmanned aerial vehicles, and target defense. Existing studies mainly concentrate on the cooperative pursuit of multiple players in two-dimensional pursuit-evasion games. However, these approaches can hardly be applied to practical situations where players usually move in three-dimensional space with a three-degree-of-freedom control. In this paper,we make the first attempt to investigate the equilibrium strategy of the realistic pursuit-evasion game, in which the pursuer follows a three-degree-of-freedom control, and the evader moves freely. First, we describe the pursuer's three-degree-of-freedom control and the evader's relative coordinate. We then rigorously derive the equilibrium strategy by solving the retrogressive path equation according to the Hamilton-Jacobi-Bellman-Isaacs(HJBI) method, which divides the pursuit-evasion process into the navigation and acceleration phases. Besides, we analyze the maximum allowable speed for the pursuer to capture the evader successfully and provide the strategy with which the evader can escape when the pursuer's speed exceeds the threshold. We further conduct comparison tests with various unilateral deviations to verify that the proposed strategy forms a Nash equilibrium.展开更多
This study proposes a batch rapid quantitative analysis method for multiple elements by combining the advantages of standard curve(SC)and calibration-free laser-induced breakdown spectroscopy(CF-LIBS)technology to ach...This study proposes a batch rapid quantitative analysis method for multiple elements by combining the advantages of standard curve(SC)and calibration-free laser-induced breakdown spectroscopy(CF-LIBS)technology to achieve synchronous,rapid,and accurate measurement of elements in a large number of samples,namely,SC-assisted CF-LIBS.Al alloy standard samples,divided into calibration and test samples,were applied to validate the proposed method.SC was built based on the characteristic line of Pb and Cr in the calibration sample,and the contents of Pb and Cr in the test sample were calculated with relative errors of 6%and 4%,respectively.SC built using Cr with multiple characteristic lines yielded better calculation results.The relative contents of ten elements in the test sample were calculated using CF-LIBS.Subsequently,the SC-assisted CF-LIBS was executed,with the majority of the calculation relative errors falling within the range of 2%-5%.Finally,the Al and Na contents of the Al alloy were predicted.The results demonstrate that it effectively enables the rapid and accurate quantitative analysis of multiple elements after a single-element SC analysis of the tested samples.Furthermore,this quantitative analysis method was successfully applied to soil and Astragalus samples,realizing an accurate calculation of the contents of multiple elements.Thus,it is important to advance the LIBS quantitative analysis and its related applications.展开更多
As users’access to the network has evolved into the acquisition of mass contents instead of IP addresses,the IP network architecture based on end-to-end communication cannot meet users’needs.Therefore,the Informatio...As users’access to the network has evolved into the acquisition of mass contents instead of IP addresses,the IP network architecture based on end-to-end communication cannot meet users’needs.Therefore,the Information-Centric Networking(ICN)came into being.From a technical point of view,ICN is a promising future network architecture.Researching and customizing a reasonable pricing mechanism plays a positive role in promoting the deployment of ICN.The current research on ICN pricing mechanism is focused on paid content.Therefore,we study an ICN pricing model for free content,which uses game theory based on Nash equilibrium to analysis.In this work,advertisers are considered,and an advertiser model is established to describe the economic interaction between advertisers and ICN entities.This solution can formulate the best pricing strategy for all ICN entities and maximize the benefits of each entity.Our extensive analysis and numerical results show that the proposed pricing framework is significantly better than existing solutions when it comes to free content.展开更多
基金The work described in this paper was jointly supported by the National Natural Science Foundation of China(No.U22A20417,21903026,21975081,21975079,22178126,22108085)China Postdoctoral Science Foundation(2022M711196)+1 种基金Science and Technology Program of Guangzhou(2023A04J1357)the SRP Program。
文摘Two-dimensional metal–organic-framework(2D MOF)nanosheets with a modular nature and tunable structures exhibit a bright future for sensors,separation,and catalysis.Developing ultrathin 2D MOF nanosheets with unique physical and chemical properties is urgently required but very challenging.Although the chemical exfoliation strategy has been regarded as a promising way to exfoliate large amounts of three-dimensional(3D)pillar-layered MOFs,this method still faces many problems and remains insufficient.In this study,a novel chemical exfoliation method is developed for the target preparation of 2D MOF monolayers from the 3D pillar-layered MOFs.The Co/Zn/Cu-MOFs with a pillar ligand of trans-1,2-bis(4-pyridyl)ethylene(bipyen)are subjected to be broken by the cleavage of CC bonds in the bipyen ligands via an ozone oxidation reaction.As chemical exfoliation is processed via the oxidation of the pillar ligand by ozone,the thickness of the 2D MOFs can be tuned by the control of oxidation time and the obtained 2D Co/Zn/Cu-MOF monolayers are functionalized with a–COOH group.This study provides an effective and general chemical exfoliation method to prepare monolayer MOFs from the 3D pillar-layered MOFs with bipyen as the pillar ligand.
基金supported by Open Research Fund of State Key Laboratory of Pulsed Power Laser Technology of China(No.SKL2013KF03)National Natural Science Foundation of China(Nos.51206055,51476061)+3 种基金the Fundamental Research Funds for the Central Universities of China(No.2014ZZ0014)the New Star of Pearl River on Science and Technology of Guangzhou,China(No.2014J2200054)the Key Laboratory of Efficient and Clean Energy Utilization of Guangdong Higher Education Institutes of China(No.KLB10004)Guangdong Province Key Laboratory of Efficient and Clean Energy Utilization,China(No.2013A061401005)
文摘Laser-induced breakdown spectroscopy was employed to determine the inorganic elements in coal. To improve the measurement's accuracy and precision, a new internal standardization scheme, which we named changed internal standardization, was compared with the traditional internal standardization and no internal standardization for the analysis of inorganic elements. The new internal standardization scheme used the atomic line of carbon at 247.86 nm and the molecular band of CN at 388.34 nm and C2 at 516.32 nm to normalize the lines of inorganic elements that were distributed in the same spectral channel. The performance of the utilization of the new internal standardization scheme was evaluated using a set of coal samples, including twenty calibration samples and five validation samples. The results show that the coefficients of determination R2 and the slope of calibration models coupled with changed internal standard- ization are better than that of the calibration models coupled with fixed internal standardization and no internal standardization. Moreover, the measurement accuracy and reproducibility of changed internal standardization for the analysis of five validation samples also yielded further improvement. The results that we obtained suggest that changed internal standardization could compensate for the matrix effects, as well as the influence of the difference in the spectral response of the light collection system.
文摘Reliability of braking systems is a key requirement to ensure the safety of in using downward belt conveyor brakes. By analyzing and comparing three commonly used braking velocity curves, we conclude that the Harrison curve is the best. Given the characteristics of a downward belt conveyor, we studied the control in a closed-loop velocity, a conventional PID method and an optimal PID control method. We used MATLAB/Simulink to simulate the three control methods. Our simulation results show that opti- mal PID control is especially suitable for disc braking systems. To verif!/the results from theoretical anal- ysis and simulation, a multifunctional test-bed was developed to simulate the braking process of a disc brake system. Our experimental results demonstrate that the optimal PID control can make the output velocity to follow a preset velocity correctly with only small fluctuations, meeting the requirements of a flexible brake for a belt conveyor.
文摘Cotton bollworm(Helicoverpa armigera) is an important agricultural pest that causes severe yield loss to crops,particularly to cotton.Transgenic Bt crops have been successful in
基金supported by Fondation pour la Recherche Médicale(Equipe FRM),SATT Sud Est-Accelerator of Technology Transfer,Association France Parkinson,Fondation de France(Committee Parkinson),COST Action CM1106
文摘Recent advances in stem cell technologies have opened new avenues for the treatment of a number of diseases still lacking effective therapeutic options.Cell transplantation has emerged as among the most promising clinical intervention for disorders such as injuries,diabetes,liver diseases, neurodegeneration and heart failure (Lee et al., 2013; Forbes and Rosenthal, 2014; Tabar and Studer, 2014).
文摘In 2016,CNPC managed to achieve a profit even despite the fact that the international oil price was lingering at a decade low.This was the third year in a row for the group to gain profit.Moreover,2016 was a year that marked significant gains for both CNPC’s operational and non-operational business,and the company also did excellent work in terms of international trading。
基金Project(61374140)supported by the National Natural Science Foundation of China
文摘There are multiple operating modes in the real industrial process, and the collected data follow the complex multimodal distribution, so most traditional process monitoring methods are no longer applicable because their presumptions are that sampled-data should obey the single Gaussian distribution or non-Gaussian distribution. In order to solve these problems, a novel weighted local standardization(WLS) strategy is proposed to standardize the multimodal data, which can eliminate the multi-mode characteristics of the collected data, and normalize them into unimodal data distribution. After detailed analysis of the raised data preprocessing strategy, a new algorithm using WLS strategy with support vector data description(SVDD) is put forward to apply for multi-mode monitoring process. Unlike the strategy of building multiple local models, the developed method only contains a model without the prior knowledge of multi-mode process. To demonstrate the proposed method's validity, it is applied to a numerical example and a Tennessee Eastman(TE) process. Finally, the simulation results show that the WLS strategy is very effective to standardize multimodal data, and the WLS-SVDD monitoring method has great advantages over the traditional SVDD and PCA combined with a local standardization strategy(LNS-PCA) in multi-mode process monitoring.
基金National Natural Science Foundation of China ( No. 61074079) Shanghai Leading Academic Discipline Project,China ( No.B504)
文摘Complex industrial process often contains multiple operating modes, and the challenge of multimode process monitoring has recently gained much attention. However, most multivariate statistical process monitoring (MSPM) methods are based on the assumption that the process has only one nominal mode. When the process data contain different distributions, they may not function as well as in single mode processes. To address this issue, an improved partial least squares (IPLS) method was proposed for multimode process monitoring. By utilizing a novel local standardization strategy, the normal data in multiple modes could be centralized after being standardized and the fundamental assumption of partial least squares (PLS) could be valid again in multimode process. In this way, PLS method was extended to be suitable for not only single mode processes but also multimode processes. The efficiency of the proposed method was illustrated by comparing the monitoring results of PLS and IPLS in Tennessee Eastman(TE) process.
基金the Primary and Secondary Healthcare Department,Punjab for the financial support to this project。
文摘In 2019,the newly emerged SARS-CoV-2 virus caused pneumonia-like illness.The disease rapidly spread globally,leading to a worldwide outbreak referred to as the COVID-19 pandemic.
基金Research on Common Technology in Standardization and Related Standards Development of the Specialized Project of Key Technical Standards Promotion during the"Eleventh Five-Year Plan (2006-2010)"
文摘Inclusion of intellectual property in standards brings importantchanges to the global competition model.Based on the furious international circumstances,Outline of the National Intellectual Property Strategy was published in2008,indicating the strategic direction of intellectual property involved in standards.This article analyzes relative items from innovation and standard strategy implemen-tation aspects,and makes some suggestions.
文摘The Outline of National Intellectual Property Strategy has brought opportunitiesand challenges for standardization in China.On the basis of analysis on international trends regardinginclusion of intellectual property rights in standards,this paper reviews achievements incombination of standardization and intellectual property in Jiangsu over recent years,andmakes some suggestions for future work.
基金supported in part by the Strategic Priority Research Program of Chinese Academy of Sciences(XDA27030100)National Natural Science Foundation of China(72293575, 11832001)。
文摘The pursuit-evasion game models the strategic interaction among players, attracting attention in many realistic scenarios, such as missile guidance, unmanned aerial vehicles, and target defense. Existing studies mainly concentrate on the cooperative pursuit of multiple players in two-dimensional pursuit-evasion games. However, these approaches can hardly be applied to practical situations where players usually move in three-dimensional space with a three-degree-of-freedom control. In this paper,we make the first attempt to investigate the equilibrium strategy of the realistic pursuit-evasion game, in which the pursuer follows a three-degree-of-freedom control, and the evader moves freely. First, we describe the pursuer's three-degree-of-freedom control and the evader's relative coordinate. We then rigorously derive the equilibrium strategy by solving the retrogressive path equation according to the Hamilton-Jacobi-Bellman-Isaacs(HJBI) method, which divides the pursuit-evasion process into the navigation and acceleration phases. Besides, we analyze the maximum allowable speed for the pursuer to capture the evader successfully and provide the strategy with which the evader can escape when the pursuer's speed exceeds the threshold. We further conduct comparison tests with various unilateral deviations to verify that the proposed strategy forms a Nash equilibrium.
基金supported by the Major Science and TechnologyTechnol-ogy Projects in Gansu Province(No.22ZD6FA021-5)Industrial Support Project of Gansu Province(Nos.2023CYZC-19 and 2021CYZC-22)+1 种基金Science and Technol-ogy Project of Gansu Province(Nos.23YFFA0074,22JR5RA137,and 22JR5RA151)Central Leading Local Science and Technology Development Fund Projects(No.23ZYQA293).
文摘This study proposes a batch rapid quantitative analysis method for multiple elements by combining the advantages of standard curve(SC)and calibration-free laser-induced breakdown spectroscopy(CF-LIBS)technology to achieve synchronous,rapid,and accurate measurement of elements in a large number of samples,namely,SC-assisted CF-LIBS.Al alloy standard samples,divided into calibration and test samples,were applied to validate the proposed method.SC was built based on the characteristic line of Pb and Cr in the calibration sample,and the contents of Pb and Cr in the test sample were calculated with relative errors of 6%and 4%,respectively.SC built using Cr with multiple characteristic lines yielded better calculation results.The relative contents of ten elements in the test sample were calculated using CF-LIBS.Subsequently,the SC-assisted CF-LIBS was executed,with the majority of the calculation relative errors falling within the range of 2%-5%.Finally,the Al and Na contents of the Al alloy were predicted.The results demonstrate that it effectively enables the rapid and accurate quantitative analysis of multiple elements after a single-element SC analysis of the tested samples.Furthermore,this quantitative analysis method was successfully applied to soil and Astragalus samples,realizing an accurate calculation of the contents of multiple elements.Thus,it is important to advance the LIBS quantitative analysis and its related applications.
基金supported by the Key R&D Program of Anhui Province in 2020 under Grant No.202004a05020078China Environment for Network Innovations(CENI)under Grant No.2016-000052-73-01-000515.
文摘As users’access to the network has evolved into the acquisition of mass contents instead of IP addresses,the IP network architecture based on end-to-end communication cannot meet users’needs.Therefore,the Information-Centric Networking(ICN)came into being.From a technical point of view,ICN is a promising future network architecture.Researching and customizing a reasonable pricing mechanism plays a positive role in promoting the deployment of ICN.The current research on ICN pricing mechanism is focused on paid content.Therefore,we study an ICN pricing model for free content,which uses game theory based on Nash equilibrium to analysis.In this work,advertisers are considered,and an advertiser model is established to describe the economic interaction between advertisers and ICN entities.This solution can formulate the best pricing strategy for all ICN entities and maximize the benefits of each entity.Our extensive analysis and numerical results show that the proposed pricing framework is significantly better than existing solutions when it comes to free content.