Thermal runaway evolution of a 280 Ah lithium-ion battery with LiFePO_(4) as the cathode for different heat transfer modes constructed by mechanical abuse

Lithium iron phosphate batteries have been increasingly utilized in recent years because their higher safety performance can improve the increasing trend of recurring thermal runaway accidents.However,the safety performance and mechanism of high-capacity lithium iron phosphate batteries under internal short-circuit challenges remain to be explored.This work analyzes the thermal runaway evolution of high-capacity LiFePO_(4) batteries under different internal heat transfer modes,which are controlled by different penetration modes.Two penetration cases involving complete penetration and incomplete penetration were detected during the test,and two modes were performed incorporating nails that either remained or were removed after penetration to comprehensively reveal the thermal runaway mechanism.A theoretical model of microcircuits and internal heat conduction is also established.The results indicated three thermal runaway evolution processes for high-capacity batteries,which corresponded to the experimental results of thermal equilibrium,single thermal runaway,and two thermal runaway events.The difference in heat distribution in the three phenomena is determined based on the microstructure and material structure near the pinhole.By controlling the heat dissipation conditions,the time interval between two thermal runaway events can be delayed from 558 to 1417 s,accompanied by a decrease in the concentration of in-situ gas production during the second thermal runaway event.

Research on droplet transfer in oscillating arc narrow gap GMA welding

In this paper, the droplet transfer in oscillating arc narrow gap gas metal arc （ GMA ） welding was studied. According to the experimental results, the oscillating arc has effect on the droplet transfer mode. The droplet transfer frequency in narrow gap groove is higher than that in bead-on-plate welding. Because of the change of arc location in narrow gap groove, the droplet transfer in oscillating arc narrow gap changes regularly. The droplet transfer frequency near groove sidewall is higher than that at the middle of narrow gap groove.

CHARACTERISTICS OF DROPLET TRANSFER IN CO_2 LASER-MIG HYBRID WELDING WITH SHORTCIRCUITING MODE

LF6 aluminum alloy plates with 4.5 mm thickness are welded in this experiment. Welding is carried out by using the CO2 laser-MIG paraxial hybrid welding in fiat position. The experimental results indicate that the inherent droplet transfer cycle time of conventional MIG arc is changed due to the interaction between CO2 laser beam and MIG arc in the short-circuiting mode of laser-MIG hybrid welding. Because of the preheating action of CO2 laser to electrode and base material, the droplet transfer frequency of MIG arc is increased in the hybrid welding process. When laser power is increased to a certain degree, the droplet transfer frequency is decreased due to the effect of laser-induced keyhole. Furthermore, through analyzing the MIG welding current and arc voltage waveforms and the characteristics of droplet transfer in the hybrid welding process, the effect of laser energy and the action point between laser beam and arc on the frequency of droplet transfer and weld appearance is investigated in details.

Numerical analysis of typical droplets transfer mode in wire and arc additive manufacture process

A two-dimensional model was established for the first time by coupling moving wire and arc in CMT-WAAM and GMAWWAAM process,revealing the temperature,potential and droplet transition behavior of droplet metal.The droplet transition and the change of droplet transfer mode under different wire feeding speed were analyzed.The experiments and numerical simulation research found that droplet transition mode is projected transfer in GMAW-WAAM process under 150 A current,with a complete transition period is 14 ms.The droplet transition shows a short-circuit transition mode in CMT-WAAM process,with wire feeding speed of 5.5 m/min and a complete transition period is 20 ms.The droplet transition shows a mixture of droplet transfer and short-circuit transition mode in CMT-WAAM process,with wire feeding speed of 5.5 m/min and a complete transition period is 23 ms.Based on the theoretical research and experimental studies,the mechanism of droplet transfer mode in WAAM was studied,which can provide reference for optimizing parameters.

Analysis of droplet transfer of pulsed MIG welding based on electrical signal and high-speed photography

In order to study how welding parameters affect welding quality and droplet transfer, a synchronous acquisition and analysis system is established to acquire and analyze electrical signal and instantaneous images of droplet transfer simultaneously, which is based on a self-developed soft-switching inverter. On the one hand, welding current and voltage signals are acquired and analyzed by a self-developed dynamic wavelet analyzer. On the other hand, images are filtered and optimized after they are captured by high-speed camera. The results show that instantaneous waveforms and statistical data of electrical signal contribute to make an overall assessment of welding quality, and that optimized high-speed images allow a visual and clear observation of droplet transfer process. The analysis of both waveforms and images leads to a further research on droplet transfer mechanism and provides a basis for precise control of droplet transfer.

Heat transfer analysis of atomized droplets during high velocity arc spraying

The heat transfer problem of the atomized droplets during high velocity arc spraying (HVAS) was modeled and solved by a numerical method using a Fe-Al alloy, and the influences of several important process parameters on the heat transfer behaviors of the atomized droplets were analyzed. The results show that the initial cooling rates of different size droplets range from 105 to 107 K/s, thus producing the coating microstructure with the features of rapid solidification. The droplet size, atomization gas pressure and droplet superheat have great influences on the heat transfer behavior of the droplet. The droplet temperature and cooling rate are much sensitive to the droplet sizes, but insensitive to the atomization gas pressure and droplet superheat. It can be predicted that the properties of HVAS coatings will be improved by decreasing droplet size as well as increasing atomization gas pressure and droplet superheat in certain extents.

Numerical analysis of arc-droplet behavior in thin wire high current MAG welding with magnetic control

High efficiency welding has always been one of the hot research subjects at home and overseas. Aiming at the problem of unstable droplet rotating spray transfer process in 450 A thin wire metal active gas arc(MAG) welding, a three-dimensional arc-droplet coupled model is established in this paper on the base of fluid dynamics to conduct numerical analysis for droplet transfer behavior with external magnetic controlled MAG welding, and used high-speed camera system to verify the simulation results. The results indicate that without external magnetic field, the droplet is transferred by the way of rotating spray, the arc is changeable and the spatter is serious. The electromagnetic force accelerates the radial liquid beam rotation under direct current(DC) magnetic field, and increases the angle between liquid beam and welding wire axis. Meanwhile, the rotation frequency of the liquid beam reaches 400 Hz, the area of arc column and heat loss increase under DC magnetic field. Based on the alternating magnetic field, the arc is the “bell shaped”, the arc stiffness raises, its temperature achieves 26 000 K, and the maximum speed of the liquid stream beam can reach 500 m/s. And the droplet transfer is more stable, the spatter significantly reduces, and welding quality is effectively improved.

SENSORING DROPLET SPRAY TRANSFER IN MIG WELDING BASED ON ARC SPECTRUM SIGNAL

The method to detect droplet transfer by means of arc spectrum, while the experiment sets, testing principle and data processing procedure,are presented. The experiment and analysis results show that arc spectrum signal can be utilized to detect and measure the transfer procedure, the transfer modes and the transfer parameters. The arc spectrum signal enjoys excellent quality with high signal amplitude. Each transfer mode has its specific typical signal mode, and the pulse outline corresponds to an integrated transferring procedure of one droplet. All these features of arc spectrum signal can be easily applied hi the control of transfer procedure,the identification and stabilization of transfer mode and the measurement of transfer parameters.

Droplet Transfer Behavior of Flux Cored Wire TIG Welding

This paper puts forward a new method to achieve flux cored wire TIG welding and uses high-speed photography to analyze the droplet transfer behavior and forces acting on the droplet. The droplet transfer forms include bridging transfer, slag column guided transfer, and non-contact transfer; each of these forms may be observed as the melting position of the welding wire changes. The important role of surface tension in the process of droplet transfer is proposed using static force balance theory and pinch instability theory. The phenomenon of droplet backward swing during welding process could be attributed to the vapor recoil force produced by vapors from the droplet. The welding experiments show that the proposed welding process is stable and that the weld quality produced is good.

Simulation of droplet transfer process and current waveform control of CO_2 arc welding

A simulation system used in the arc welding short circuit transfer process and current waveform control process was developed in this paper. The simulation results are basically consistent with welding technical experiments. The simulation system can be used to simulate and test the current waveform control parameters with welding variables. By this simulation system, the influence regularities of the current waveform control parameters in the CO 2 arc welding droplet short circuit transfer process can be got. Moreover, the basic mode of real time current waveform control can be also established by the simulation testing.

The validating and identifying of the droplet transfer character signal from arc light in oscillating wire feed mode

The character of droplet transfer arc light sense signal is studied and validated in oscillating feed mode. And a novel mini photoelectric arc light sensor together with the controlling circuit used to automatically stabilize the signal range is developed. Further more the automatically identifying of the droplet transfer character signal from arc light is realized reliably.

Droplet transfer behavior of the stainless steel coated electrode with double-layer coating

In this paper, the droplet transfer behavior of the stainless steel coated electrode with double layer coating is researched by means of those experimental methods, such as high speed camera, collecting droplet in water, surfacing on the steel plate et al. The results show that the droplet transfer indexes of coated electrode are mainly controlled by the size of droplet, which affects the transfer behavior of droplet. The distribution characteristic of the droplet size of the electrode affects the numerical relationship among droplet transfer indexes. The metallurgical process of the coated electrode with double layer coating is carried out continuously in different zones. The main reason for the coated electrode with double layer coating gaining excellent usability quality is that the droplets realize the 'quasi flux wall guided transfer pattern'.

Continuous droplet rebound on heated surfaces and its effects on heat transfer property: A lattice Boltzmann study

A thermal multiphase lattice Boltzmann(LB) model is used to study the behavior of droplet impact on hot surface and the relevant heat transfer properties.After validating the correctness of the codes through the D^(2) law,the simulations of intrinsic contact angle and the temperature-dependent surface tension are performed.The LB model is then used to simulate the droplet impact on smooth and micro-hole heated surface.On the smooth surface,the impinging droplet is reluctant to rebound,unless the intrinsic wettability of the solid surface is fairly good.On the micro-hole surface,however,the micro-holes provide favorable sites for generating a high-pressure vapor cushion underneath the impinging droplet,which thereby facilitates the continuous droplet rebound.For the continuously rebounding droplet.The time evolution of volume and temperature display obvious oscillations.The achievable height of the rebounding droplet increases as the intrinsic wettability of the solid surface becomes better,and the maximum transient heat flux is found to be directly proportional to the droplet rebounding height.Within a certain time interval,the continuous rebounding behavior of the droplet is favorable for enhancing the total heat quantity/heat transfer efficiency,and the influence of intrinsic wettability on the total heat during droplet impingement is greater than that of the superheat.The LB simulations not only present different states of droplets on hot surfaces,but also guide the design of the micro-hole surface with desirable heat transfer properties.

Arc light sensing of droplet transfer in pulsed GMAW process and its mechanism

A new method and if.''principle .fi)r 's*ensin.q dry)Plet iran.5/dr in aide W ')/ steel and aluminum alloy have been researched in this paper. A practical arc light sensing and controlling system has been developed. The reliability of the arc light characteristic signal that indicates droplet detachment and the control accuracy of the system have been verified using high-speed photography Based on the mathematical model set up in the paper, the mechanism of the signal and relative phenomena were analyzed The parameters, which influence arc light radiation were given and the limitation of this sensing method was discussed.

Stability analysis of CO_(2)gas shielded welding short-circuit transition process based on GMAW dynamic model

Base on the arc phase and short-circuit phase and their relationship, the paper considers the changes of the extension of wire, the arc length, liquid bridge resistance and mass of liquid bridge, combines the improved “mass-spring” model with the loop model of welding power system, puts forward the critical judgment condition of droplet transition, and establishes a more accurate dynamic model for describing the short-circuit transition process. The dynamic changes of short-circuit transfer frequency, welding current and voltage, contact droplet and residual droplet equivalent radius and droplet equivalent radius at different wire feeding speeds were calculated and analyzed, and compared with the experimental results. It shows that the fluctuation of droplet displacement, velocity and wire extension length at the optimal arc starting point is the smallest. The smaller the initial liquid bridge curvature radius is, the better the stability of short-circuit transfer is.

Computer simulation of short-circuiting transfer welding under waveform control on inverter power source

A simulation model is introduced about the non-linearity process of short-circuiting transfer in CO2 arc welding for displaying the interaction between the inverter power source and welding arc under waveform control. In the simulation model, the feedback signals of current and voltage are taken respectively at the different phase in a short circuit periodic time and applied to the PWM （pulse width modulation） module in a model of inverter power source to control the output of power source. The simulation operation about the dynamic process of CO2 short-circuiting transfer welding is implemented on the founded simulation model with a peak arc current of 400 A and a peak voltage of 35 V, producing the dynamic arc waveforms which can embody the effect of inverter harmonic wave. The simulating waveforms are close to that of welding experiments.

Experimental investigation of dynamic mass transfer during droplet formation using micro-LIF in a coaxial microchannel

The mass transfer of Rhodamine 6G from the droplet to the continuous phase in a coaxial micro-channel is studied using micro-LIF(Laser-Induced Fluorescence).The mass distribution inside droplet is measured and visualized.The experimental results affirm that there exists the internal circulation inside the droplet and it could enhance the convective mass transfer.The stagnant center of vortices is also observed.The extraction fraction could reach 40%80%.In order to establish the mass transfer model,different flow rates of the dispersed and continuous phase are adopted.The high continuous phase flow rate and low dispersed phase flow rate are both beneficial to enhance mass transfer by expediting the internal circulation.A modified mass transfer model is found to calculate the extraction fraction.A good agreement between the model and experiment in various conditions demonstrates that the mass transfer model in this work is reliable and feasible.

Influence of shielding gas on the transfer behavior of droplets

High-speed photography is utilized to capture an image of the arc area during the welding process.The variation in arc shape and droplet transfer behavior is compared when employing shielding gases of different components and proportions(e.g.,80%Ar+20%CO_(2),85%Ar+10%CO_(2)+5%O2,65%Ar+26.5%He+8%CO_(2)+0.5%O2)using a Ф1.2 mm welding wire under 360 A current.Furthermore,the effects of various shielding gas components on the stability of the welding process are discussed.It was determined that the addition of oxygen and helium changed the arc’s shape and the behavior of the droplet transfer,and the welding process stability increased.

The internal circulations on internal mass transfer rate of a single drop in nonlinear uniaxial extensional flow

The internal flow of a droplet in the nonlinear extensional flow field will exhibit more than two internal circulations with the variation of nonlinear intensity(E).In this paper,the effect of positions and sizes of internal circulations on internal mass transfer rate of a single spherical droplet in a nonlinear extensional flow field is studied and compared with that in a linear extensional flow field.The simulation results show that when E≥0,there are two symmetrical internal circulations in the droplet,which is the same with that in a linear extensional flow.The limit value of mass transfer rate Sh is 15,which is equal to that in a linear extensional flow,no matter how large E is.When E≤-3/7,the number of internal flow circulation of a droplet increase to four and the transfer rate Sh increases.When E=-1,the maximum internal transfer rate Sh equals 30 which is twice of that in a linear extensional flow.The generation of new flow circulations in droplets and the circulation positions will enhance mass transfer when E≤-3/7,which provides a new idea for enhancing the internal mass transfer rate of droplets.

On the Effect of Mist Flow on the Heat Transfer Performances of a Three-Copper- Sphere Configuration

The cooling of a(pebble bed)spent fuel in a high-temperature gas-cooled reactor(HTGR)is adversely affected by an increase in the temperature of the used gas(air).To investigate this problem,a configuration consisting of three copper spheres arranged in tandem subjected to a forced mistflow inside a cylindrical channel is considered.The heat transfer coefficients and related variations as a function of Reynolds number are investigated accord-ingly.The experimental results show that when compared to those with only airflow,the heat transfer coefficient of the spherical elements with mistflow(j=112 kg/m2 hr,Re=55000)increases by 180%,75%,and 20%,respec-tively for thefirst,second,and third spherical element(the corresponding heat transfer enhancement ratio being 2.3,1.4,and 1.1).Additional numerical simulations reveal that the presence of stagnant zones with intense vortex formation around each spherical element contributes significantly to determine the heat transfer behavior.